共查询到20条相似文献,搜索用时 587 毫秒
1.
The standard thermodynamic properties at 25°C, 1 bar (ΔG
fo, ΔH
fo, S
o, C
Po, V
o, ω) and the coefficients of the revised Helgeson–Kirkham–Flowers equations of state were evaluated for several aqueous complexes
formed by dissolved metals and either arsenate or arsenite ions. The guidelines of Shock and Helgeson (Geochim Cosmochim Acta
52:2009–2036, 1988) and Sverjensky et al. (Geochim Cosmochim Acta 61:1359–1412, 1997) were followed and corroborated with alternative approaches, whenever possible. The SUPCRT92 computer code was used to generate
the log K of the destruction reactions of these metal–arsenate and metal–arsenite aqueous complexes at pressures and temperatures required
by the EQ3/6 software package, version 7.2b. Apart from the AlAsO4o and FeAsO4o complexes, our log K at 25°C, 1 bar are in fair agreement with those of Whiting (MS Thesis, Colorado School of Mines, Golden, CO, 1992). Moreover, the equilibrium constants evaluated in this study are in good to fair agreement with those determined experimentally
for the Ca–dihydroarsenate and Ca–hydroarsenate complexes at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) and for Fe(III)–hydroarsenate complex at 25°C (Raposo et al., J Sol Chem 35:79–94, 2006), whereas the disagreement with the log K measured for the Ca–arsenate complex at 40°C (Mironov et al., Russ J Inorg Chem 40:1690, 1995) might be due to uncertainties in this measured value. The implications of aqueous complexing between dissolved metals and
arsenate/arsenite ions were investigated for seawater, high-temperature geothermal liquids and acid mine drainage and aqueous
solutions deriving from mixing of acid mine waters and surface waters.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献
2.
The low-temperature heat capacity (C
P) of stishovite (SiO2) synthesized with a multi-anvil device was measured over the range of 5–303 K using the heat capacity option of a physical
properties measurement system (PPMS) and around ambient temperature using a differential scanning calorimeter (DSC). The entropy
of stishovite at standard temperature and pressure calculated from DSC-corrected PPMS data is 24.94 J mol−1 K−1, which is considerably smaller (by 2.86 J mol−1 K−1) than that determined from adiabatic calorimetry (Holm et al. in Geochimica et Cosmochimica Acta 31:2289–2307, 1967) and about 4% larger than the recently reported value (Akaogi et al. in Am Mineral 96:1325–1330, 2011). The coesite–stishovite phase transition boundary calculated using the newly determined entropy value of stishovite agrees
reasonably well with the previous experimental results by Zhang et al. (Phys Chem Miner 23:1–10, 1996). The calculated phase boundary of kyanite decomposition reaction is most comparable with the experimental study by Irifune
et al. (Earth Planet Sci Lett 77:245–256, 1995) at low temperatures around 1,400 K, and the calculated slope in this temperature range is mostly consistent with that determined
by in situ X-ray diffraction experiments (Ono et al. in Am Mineral 92:1624–1629, 2007). 相似文献
3.
In this paper, we analyze the impact of physical and chemical heterogeneity on solute travel time to a pumping well. We consider
a solute undergoing reversible linear instantaneous equilibrium sorption. Both the distribution coefficient, K
d
, and the transmissivity field, T, are considered spatially variable, and are modeled as partially correlated spatial random functions. Groundwater flow and
solute transport are then solved within the context of a numerical Monte Carlo framework. The results are analyzed on the
basis of dimensional analysis techniques. Simple and compact expressions characterizing the dependence of the target travel
time moments on relevant dimensionless groups are proposed. The functional form of these expressions is inspired by, and is
consistent with, the previous works of Sanchez-Vila and Rubin (Water Resour. Res. 39(4):1086, 2003) and Riva et al. (J. Contam. Hydrol. 82:23–43, 2006) A key result is that the effects of the chemical and physical heterogeneities on the mean travel time can be decoupled consistently
with existing analytical results. The relative role of physical and geochemical heterogeneities in travel time variance is
more complex, and such a decoupling is not observed. Potential uses of this work include the assessment of aquifer reclamation
time by means of a single pumping well. 相似文献
4.
Elastic wave velocities for dense (99.8% of theoretical density) isotropic polycrystalline specimens of synthetic pyrope (Mg3Al2Si3O12) were measured to 1,000 K at 300 MPa by the phase comparison method of ultrasonic interferometry in an internally heated
gas-medium apparatus. The temperature derivatives of the elastic moduli [(∂Ks/∂T)
P
= −19.3(4); (∂G/∂T)
P
= −10.4(2) MPa K−1] measured in this study are consistent with previous acoustic measurements on both synthetic polycrystalline pyrope in a
DIA-type cubic anvil apparatus (Gwanmesia et al. in Phys Earth Planet Inter 155:179–190, 2006) and on a natural single crystal by the rectangular parallelepiped resonance (RPR; Suzuki and Anderson in J Phys Earth 31:125–138,
1983) method but |(∂Ks/∂T)
P
| is significantly larger than from a Brillouin spectroscopy study of single-crystal pyrope (Sinogeikin and Bass in Phys Earth
Planet Inter 203:549–555, 2002). Alternative approaches to the retrieval of mixed derivatives of the elastic moduli from joint analysis of data from this
study and from the solid-medium data of Gwanmesia et al. in Phys Earth Planet Inter 155:179–190 (2006) yield ∂2
G/∂P∂T = [0.07(12), 0.20(14)] × 10−3 K−1 and ∂2
K
S
/∂P∂T = [−0.20(24), 0.22(26)] × 10−3 K−1, both of order 10−4 K−1 and not significantly different from zero. More robust inference of the mixed derivatives will require solid-medium acoustic
measurements of precision significantly better than 1%. 相似文献
5.
Pradip Roul Alexander Schinner Klaus Kassner 《Geotechnical and Geological Engineering》2011,29(4):597-610
This work is a contribution to the understanding of the mechanical properties of non-cohesive granular materials in the presence
of friction and a continuation of our previous work (Roul et al. 2010) on numerical investigation of the macroscopic mechanical properties of sand piles. Besides previous numerical results obtained
for sand piles that were poured from a localized source (“point source”), we here consider sand piles that were built by adopting
a “line source” or “raining procedure”. Simulations were carried out in two-dimensional systems with soft convex polygonal
particles, using the discrete element method (DEM). First, we focus on computing the macroscopic continuum quantities of the
resulting symmetric sand piles. We then show how the construction history of the sand piles affects their mechanical properties
including strain, fabric, volume fraction, and stress distributions; we also show how the latter are affected by the shape
of the particles. Finally, stress tensors are studied for asymmetric sand piles, where the particles are dropped from either
a point source or a line source. We find that the behaviour of stress distribution at the bottom of an asymmetric sand pile
is qualitatively the same as that obtained from an analytical solution by Didwania and co-workers (Proc R Soc Lond A 456:2569–2588,
2000). 相似文献
6.
James M. D. Day Colin G. Macpherson David Lowry D. Graham Pearson 《Contributions to Mineralogy and Petrology》2012,164(1):177-183
Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) report laser-assisted fluorination (LF) and secondary ionization mass spectrometry (SIMS) 18O/16O datasets for olivine grains from the Canary Islands of Gran Canaria, Tenerife, La Gomera, La Palma and El Hierro. As with prior studies of oxygen isotopes in Canary Island lavas (e.g. Thirlwall et al. Chem Geol 135:233–262, 1997; Day et al. Geology 37:555–558, 2009, Geochim Cosmochim Acta 74:6565–6589, 2010), these authors find variations in δ18Ool (~4.6–6.0 ‰) beyond that measured for mantle peridotite olivine (Mattey et al. Earth Planet Sci Lett 128:231–241, 1994) and interpret this variation to reflect contributions from pyroxenite-peridotite mantle sources. Furthermore, Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) speculate that δ18Ool values for La Palma olivine grains measured by LF (Day et al. Geology 37:555–558, 2009, Geochim Cosmochim Acta 74:6565–6589, 2010) may be biased to low values due to the presence of altered silicate, possibly serpentine. The range in δ18Ool values for Canary Island lavas are of importance for constraining their origin. Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) took a subset (39 SIMS analyses from 13 grains from a single El Hierro lava; EH4) of a more extensive dataset (321 SIMS analyses from 110 grains from 16 Canary Island lavas) to suggest that δ18Ool is weakly correlated (R 2 = 0.291) with the parameter used by Gurenko et al. (Earth Planet Sci Lett 277:514–524, 2009) to describe the estimated weight fraction of pyroxenite-derived melt (Xpx). With this relationship, end-member δ18O values for HIMU-peridotite (δ18O = 5.3 ± 0.3 ‰) and depleted pyroxenite (δ18O = 5.9 ± 0.3 ‰) were defined. Although the model proposed by Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) implicates similar pyroxenite-peridotite mantle sources to those proposed by Day et al. (Geology 37:555–558, 2009, Geochim Cosmochim Acta 74:6565–6589, 2010) and Day and Hilton (Earth Planet Sci Lett 305:226–234, 2011), there are significant differences in the predicted δ18O values of end member components in the two models. In particular, Day et al. (Geochim Cosmochim Acta 74:6565–6589, 2010) proposed a mantle source for La Palma lavas with low-δ18O (<5 ‰), rather than higher-δ18O (c.f. the HIMU-peridotite composition of Gurenko et al. in Contrib Mineral Petrol 162:349–363, 2011). Here we question the approach of using weakly correlated variations in δ18Ool and the Xpx parameter to define mantle source oxygen isotope compositions, and provide examples of why this approach appears flawed. We also provide reasons why the LF datasets previously published for Canary Island lavas remain robust and discuss why LF and SIMS data may provide complementary information on oxygen isotope variations in ocean island basalts (OIB), despite unresolved small-scale uncertainties associated with both techniques. 相似文献
7.
This paper presents a computer tool that automatically predicts mining subsidence using the generalized n-k-g influence function detailed in (González Nicieza et al. Int J Rock Mech Min Sci 42(3):372–387, 2005). This function depends on two physical concepts: the first is gravity, which characterizes the forces acting on the ground,
and the second, the convergence of the roof and floor of the mine workings due to the stress state of the ground. The developed
tool also allows other influence functions to be used to predict subsidence, namely the spatial influence function (Ramírez
Oyanguren et al. 2000) and the normal-type classical (Knothe, Arch Gór Hut 1, 1952) and modified (González Nicieza et al. Bull Eng Geol Environ 66(3):319–329, 2007) time functions. Moreover, the inputting and periodic updating of data from subsidence monitoring surveys is controlled by
one of the tool’s modules using a method that minimizes errors resulting from time discontinuities in landmarks measurements.
In addition, when actual landmarks measurements exist, the developed tool allows calibration of the subsidence parameters,
minimizing the errors between actual measurements and those obtained by prediction. The tool includes a viewer, developed
using OpenGL, which enables the results of the calculations carried out to be viewed, allowing the point of view to be varied.
It also includes the option of viewing and saving the results of the calculations carried out over the original topographic
plane defined in the AutoCAD DXF data file format. The efficacy of the tool is demonstrated via its application to a real
case of mining work carried out in a village in the Principality of Asturias, Spain. 相似文献
8.
Łukasz Gągała 《International Journal of Earth Sciences》2009,98(2):461-479
In the course of numerical experiments selected algorithms for stress tensor inversion and separation of heterogeneous populations
of calcite twins and striated faults were tested. Artificial data sets were created in a manner simulating natural processes.
They were composed of data, dynamically compatible with one or two stress tensors and chaotic “noise” imitating natural imperfections.
For calcite twins the classical inversion procedure is considered valid, with restrictions regarding a high proportion of
chaotic data, when shape ratio of the stress tensor Φ is poorly constrained. The algorithm of Etchecopar (1984 fide Tourneret and Laurent in Tectonophysics 180:287–302, 1990) devised originally for calcite twins has been modified and applied to fault/slip data, facilitating a rejection of incompatible
outliers. Two main classes of data separation procedures were tested: separation contemporary with inversion and separation
prior to inversion, utilising hierarchical clustering. The separation contemporary with inversion performs moderately but
often fails with complex calcite twin sets. The performance of hierarchical clustering is high, but only with a σ
1 orientation as a similarity criterion—the new strategy introduced in this contribution. For fault/slip data the hierarchical
clustering with the right-dihedra construction as the similarity criterion (Nemcok et al. 1999) is satisfactory. Additionally, a new approach is proposed for fault/slip data, utilising principles of the classical algorithm
for heterogeneous populations of calcite twins. Validated algorithms for striated faults were successfully applied to a natural
data set from the Holy Cross Mts (central Poland). 相似文献
9.
David M. Jenkins Juan Carlos Corona William A. Bassett Kenji Mibe Zhongwu Wang 《Physics and Chemistry of Minerals》2010,37(4):219-226
The compressibilities of two synthetic glaucophane samples were measured over the range of 0–10 GPa at ambient temperature
in a diamond-anvil cell at the Cornell High-Energy Synchrotron Source (CHESS). The pressure–volume data were fitted to the
Birch–Murnaghan equation of state taking care to include only data with a minimum of deviatoric stress. When using a second-order
truncation, both samples yielded essentially identical values of the bulk modulus K
0, which had an average value of 91.8 ± 1.3 GPa. Maximum compression was observed approximately along the a* axis as shown by the strain ellipsoid and supported by the a axis showing the highest compressibility. These results agree closely with the earlier study of a natural glaucophane single-crystal
by Comodi et al. (Eur J Mineral 3:485–499, 1991), suggesting that the substitution of about 20–30 mol.% of Fe for Mg and Al in the structure may not significantly change
its compressibility. 相似文献
10.
Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps 总被引:1,自引:0,他引:1
Thomas J. Lapen Clark M. Johnson Lukas P. Baumgartner Giorgio V. Dal Piaz Susanne Skora Brian L. Beard 《Contributions to Mineralogy and Petrology》2007,153(2):139-157
High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite
and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic
conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed
inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white
mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist.
Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based
on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the
Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore,
the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally
overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic
and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental
crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role
in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental
crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle. 相似文献
11.
Abidin Kaya 《Geotechnical and Geological Engineering》2009,27(2):281-288
A backpropagation artificial neural network (ANN) model is developed to predict the secant friction angle of residual and
fully softened soils, using data reported by Stark et al. (J Geotech Geoenviron Eng ASCE 131:575–588, 2005). In the ANN model, index properties such as liquid limit, plastic limit, activity, clay fraction and effective normal stress
are used as input variables while secant residual friction angle is used as output variable. The model is verified using data
that were not used for model training and testing. The results also indicate that the secant residual friction angle of cohesive
soils can be predicted quite accurately using liquid limit, clay fraction and effective normal stress as input variables with
R
2 = 0.93. The sensitivity analysis results indicate that plastic limit and activity have no appreciable effect on ANN predicted
secant friction angles. The secant friction angle predictions of the ANN model were also compared with those of Stark’s et
al. (2005) curves and the empirical formulas suggested for the same data sets by Wright (Evaluation of soil shear strengths for slope
and retaining wall stability with emphasis on high plasticity clays, 2005). The comparison shows that the ANN model predictions are very close to those suggested by the Stark et al. (2005) curves but much better than the prediction of Wright’s (2005) empirical equations. The results also show that ANN is an alternative powerful tool to predict the secant friction angle
of soils. 相似文献
12.
Asok K. Sen 《Mathematical Geosciences》2009,41(1):43-49
Sedimentary records of Lake Edward in Central Africa from the late Holocene era exhibit submillennial-scale periodicities
in magnesium (Mg) and stable isotope compositions of endogenic calcite. Using multitaper spectral analysis, Russell et al. (Geology
31(8):677–680, 2003) detected a 725-yr cycle in the Mg data. We have analyzed the Mg data using a continuous wavelet transform and observed temporal
variations in the submillennial periodicities. These temporal variations can be discerned from a time-period representation
of the wavelet power spectrum by visual inspection. The multi-taper spectral analysis is based on the traditional Fourier
transform, which is a purely frequency domain technique, and therefore cannot detect temporal variability of the spectrum,
if any. In contrast, wavelet analysis offers a spectral-temporal approach by which both the dominant periodicities and their
time variations can be identified. In this regard, the results of our wavelet analysis extend those of Russell et al. (Geology
31(8):677–680, 2003). Our analysis reveals dominant periodicities around the 785-yr and 660-yr cycles, but these cycles persist over different
time spans within the late Holocene era. The 725-yr period identified by Russell et al. (Geology 31(8):677–680, 2003) with multitaper spectral analysis is very close to the average of the periods of these two cycles. For the purpose of accurately
reconstructing the climate history in Central Africa using Mg as a proxy, it would be important to take into consideration
the temporal variations of the submillennial periodicities. 相似文献
13.
The paper presents a closed-form solution for the convergence curve of a circular tunnel in an elasto-brittle-plastic rock
mass with both the Hoek–Brown and generalized Hoek–Brown failure criteria, and a linear flow rule, i.e., the ratio between
the minor and major plastic strain increments is constant. The improvement over the original solution of Brown et al. (J Geotech
Eng ASCE 109(1):15–39, 1983) consists of taking into account the elastic strain variation in the plastic annulus, which was assumed to be fixed in the
original solution by Brown et al. The improvement over Carranza-Torres’ solution (Int J Rock Mech Min Sci 41(Suppl 1):629–639,
2004) consists of providing a closed-form solution, rather than resorting to numerical integration of an ordinary differential
equation. The presented solution, by rigorously following the theory of plasticity, takes into account that the elastic strain
components change with radial and circumferential stress changes within the plastic annulus. For the original Hoek–Brown failure
criterion, disregarding the elastic strain change leads to underestimate the convergence by up to 55%. For a rock mass failing
according to the generalized Hoek–Brown failure criterion, using the original failure criterion leads to a high probability
(97%) of underestimating the convergence by up to 100%. As a consequence, the onset or degree of squeezing may be underestimated,
and the loading on the support/reinforcement calculated with the convergence/confinement method may be largely underestimated. 相似文献
14.
Zr-in-rutile thermometry in HP/UHP eclogites from Western China 总被引:5,自引:0,他引:5
Guibin Zhang David J. Ellis Andrew G. Christy Lifei Zhang Shuguang Song 《Contributions to Mineralogy and Petrology》2010,160(3):427-439
Four Zr-in-rutile thermometry calibrations are applied to eclogites from Western China. Here, we show that if rutile grows
in equilibrium with Qtz and Zrn, and is isolated inside garnet, it preserves its Zr composition and does not undergo compositional
change due to cation exchange with the host garnet. It thus preserves the composition for the P–T conditions of its formation and the growth zoning of the host garnet. For the HP/UHP metamorphic temperature, the Tomkins
et al. (J Metamorph Geol 25:703–713, 2007) calibration yields temperatures that agree well with previous studies, whereas the other three calibrations (Zack et al.
in Contrib Mineral Petrol 148:471–488, 2004; Watson et al. in Contrib Mineral Petrol 151:413–433, 2006; Ferry and Watson in Contrib Mineral Petrol in 154:429–437, 2007), which do not include a pressure correction, give systematically lower temperatures. Zr contents of rutile inclusions within
garnet show systematic decrease from garnet core to rim. The rutile inclusions in garnet rims contain the lowest Zr content,
similar to that in the matrix. Analyses confirm that the pressure plays a significant role in modifying the primary temperature
dependence of the Zr content of rutile. Rutiles trapped in garnets are unable to re-equilibrate easily during retrogression,
but those in the matrix can do so, providing retrograde P–T path information. 相似文献
15.
Dmytro M. Trots Alexander Kurnosov Leonid Vasylechko Marek Berkowski Tiziana Boffa Ballaran Daniel J. Frost 《Physics and Chemistry of Minerals》2011,38(7):561-567
A single crystal X-ray diffraction study on lithium tetraborate Li2B4O7 (diomignite, space group I41
cd) has been performed under pressure up to 8.3 GPa. No phase transitions were found in the pressure range investigated, and
hence the pressure evolution of the unit-cell volume of the I41
cd structure has been described using a third-order Birch–Murnaghan equation of state (BM-EoS) with the following parameters:
V
0
= 923.21(6) Å3, K
0
= 45.6(6) GPa, and K′ = 7.3(3). A linearized BM-EoS was fitted to the axial compressibilities resulting in the following parameters a
0
= 9.4747(3) Å, K
0a
= 73.3(9) GPa, K′
a
= 5.1(3) and c
0
= 10.2838(4) Å, K
0c
= 24.6(3) GPa, K′
c
= 7.5(2) for the a and c axes, respectively. The elastic anisotropy of Li2B4O7 is very large with the zero-pressure compressibility ratio β
0c
/β
0a
= 3.0(1). The large elastic anisotropy is consistent with the crystal structure: A three-dimensional arrangement of relatively
rigid tetraborate groups [B4O7]2− forms channels occupied by lithium along the polar c–axis, and hence compression along the c axis requires the shrinkage of the lithium channels, whereas compression in the a direction depends mainly on the contraction of the most rigid [B4O7]2− units. Finally, the isothermal bulk modulus obtained in this work is in general agreement with that derived from ultrasonic
(Adachi et al. in Proceedings-IEEE Ultrasonic Symposium, 228–232, 1985; Shorrocks et al. in Proceedings-IEEE Ultrasonic Symposium, 337–340, 1981) and Brillouin scattering measurements (Takagi et al. in Ferroelectrics, 137:337–342, 1992). 相似文献
16.
Mingbin Huang D. G. Fredlund M. D. Fredlund 《Geotechnical and Geological Engineering》2010,28(2):105-117
There are significant advantages in using indirect pedo-transfer functions, (PTFs) for the estimation of unsaturated soil
properties. The pedo-transfer functions can be used for the estimation of the soil–water characteristic curve (SWCC) which
in turn is used for the estimation of other unsaturated soil properties. The accuracy of the indirect pedo-transfer function
method for the estimation of the SWCC depends on the PTF and the equation used to best-fit the particle-size distribution
(PSD) data. The objectives of this study are to: (1) evaluate the performance of the Fredlund et al. (Can Geotech J 37:817–827,
2000) equation for best-fitting the particle-size distribution, (PSD) data, and, (2) compare the predictions made by two of the
commonly used PTFs; namely, Arya and Paris (Soil Sci Soc Am J 45:1023–1030, 1981) and Fredlund et al. (Can Geotech J 39:1103–1117, 2002), for estimating the SWCC from the PSD. The authors used 258 measured PSDs and SWCC datasets from the Loess Plateau, China,
for this study. The dataset consisted of 187 silt–loam soils, 41 loam soils, 11 silt–clay–loam soils, 10 sand–loam soils,
6 silt–clay soils, and 3 loam–sand soils. The SWCC and PSD datasets were measured using a Pressure Plate apparatus and the
pipette method, respectively. The comparison between the estimated and measured particle-size distribution curves showed that
the Fredlund et al. (Can Geotech J 37:817–827, 2000) equation closely prepresented the PSD for all soils in the Loess Plateau, with a lower root mean square error (RMSE) of
0.869%. The comparison between the estimated and measured water contents at the same suction showed that the Fredlund et al.
(Can Geotech J 39:1103–1117, 2002) PTF performed somewhat better than the Arya and Paris (Soil Sci Soc Am J 45:1023–1030, 1981) function. The Fredlund et al. method had RMSE value of 0.039 cm3 cm−3 as opposed to 0.046 cm3 cm−3 for the Arya and Paris (Soil Sci Soc Am J 45:1023–1030, 1981) method. The Fredlund et al. (Can Geotech J 39:1103–1117, 2002) PTF produced the closest predictions for sand–loam, loam–sand, and loam soils, with a lower RMSE for gravimetric water content
ranging from 0.006 to 0.036 cm3 cm−3. There were consistent over-estimations observed for silt–loam, silt–clay–loam, and slit–clay soils with RMSE values for
gravimetric water content ranging from 0.037 to 0.043 cm3 cm−3. The measured and estimated air-entry values were closest when using the Fredlund et al. (Can Geotech J 39:1103–1117, 2002) PTF. The measured and estimated maximum slopes on the SWCC were closest when using the Arya and Paris (Soil Sci Soc Am J
45:1023–1030, 1981) PTF. 相似文献
17.
Andrey A. Gurenko Ilya N. Bindeman Marc Chaussidon 《Contributions to Mineralogy and Petrology》2012,164(1):185-189
The comment by Day et al. (Contrib Mineral Petrol, 2012) (1) discusses the validity of the previously obtained oxygen isotope data for El Hierro and La Palma (Canary Island) olivines,
(2) questions the approach by Gurenko et al. (Contrib Mineral Petrol 162:349–363, 2011) of using weakly correlated variations of δ18Oolivine values with X
px
(proportion of pyroxenite-derived melt in the parental magma), and (3) provides reasons why oxygen isotope data by secondary
ion mass spectrometry (SIMS) “offer sensitive means for detecting melt-crust interactions.” We respond these comments and
report a new set of oxygen isotope measurements performed by SIMS and single-grain laser fluorination methods. These measurements
confirm our previous data and conclusions and demonstrate the ability of the SIMS technique to analyze O isotopes in terrestrial
samples with 2-sigma uncertainty better than ±0.25 ‰. 相似文献
18.
Zr diffusion in titanite 总被引:2,自引:0,他引:2
D. J. Cherniak 《Contributions to Mineralogy and Petrology》2006,152(5):639-647
Chemical diffusion of Zr under anhydrous, pO2-buffered conditions has been measured in natural titanite. The source of diffusant was either zircon powder or a ZrO2–Al2O3–titanite mixture. Experiments were run in sealed silica glass capsules with solid buffers (to buffer at NNO or QFM). Rutherford Backscattering Spectrometry (RBS) was used to measure diffusion profiles. The following Arrhenius parameters were obtained for Zr diffusion parallel to c over the temperature range 753–1,100°C under NNO-buffered conditions: D
Zr = 5.33 × 10−7 exp(−325 ± 30 kJ mol−1/RT) m2 s−1 Diffusivities are similar for experiments buffered at QFM. These data suggest that titanite should be moderately retentive of Zr chemical signatures, with diffusivities slower than those for O and Pb in titanite, but faster than those for Sr and the REE. When applied in evaluation of the relative robustness of the recently developed Zr-in-titanite geothermometer (Hayden and Watson, Abstract, 16th V.M. Goldschmidt Conference 2006), these findings suggest that Zr concentrations in titanite will be less likely to be affected by later thermal disturbance than the geothermometer based on Zr concentrations in rutile (Zack et al. in Contrib Mineral Petrol 148:471–488, 2004; Watson et al. in Contrib Mineral. Petrol, 2006), but much less resistant to diffusional alteration subsequent to crystallization than the Ti-in-Zircon geothermometer (Watson and Harrison in Science 308:841–844, 2005). 相似文献
19.
T. W. Sisson J.-I. Kimura M. L. Coombs 《Contributions to Mineralogy and Petrology》2009,158(6):803-829
A basanite–nephelinite glass suite from early submarine Kilauea defines a continuous compositional array marked by increasing
concentrations of incompatible components with decreasing SiO2, MgO, and Al2O3. Like peripheral and post-shield strongly alkalic Hawaiian localities (Clague et al. in J Volcanol Geotherm Res 151:279–307,
2006; Dixon et al. in J Pet 38:911–939, 1997), the early Kilauea basanite–nephelinite glasses are interpreted as olivine fractionation products from primary magnesian
alkalic liquids. For early Kilauea, these were saturated with a garnet–phlogopite–sulfide peridotite assemblage, with elevated
dissolved CO2 contents responsible for the liquids’ distinctly low-SiO2 concentrations. Reconstructed primitive liquids for early Kilauea and other Hawaiian strongly alkalic localities are similar
to experimental 3 GPa low-degree melts of moderately carbonated garnet lherzolite, and estimated parent magma temperatures
of 1,350–1,400°C (olivine–liquid geothermometry) match the ambient upper mantle geotherm shortly beneath the base of the lithosphere.
The ~3 GPa source regions were too hot for stable crystalline carbonate and may have consisted of ambient upper mantle peridotite
containing interstitial carbonate–silicate or carbonatitic liquid, possibly (Dixon et al. in Geochem Geophys Geosyst 9(9):Q09005,
2008), although not necessarily, from the Hawaiian mantle plume. Carbonate-enriched domains were particularly susceptible to further
melting upon modest decompression during upward lithospheric flexure beneath the advancing Hawaiian Arch, or by conductive
heating or upward drag by the Hawaiian mantle plume. The early Kilauea basanite–nephelinite suite has a HIMU-influenced isotopic
character unlike other Hawaiian magmas (Shimizu et al. in EOS Tran Amer Geophys Union 82(47): abstr V12B-0962, 2001; Shimizu et al. in Geochim Cosmochim Acta 66(15A):710, 2002) but consistent with oceanic carbonatite involvement (Hoernle et al. in Contrib Mineral Petrol 142:520–542, 2002). It may represent the melting products of a fertile domain in the ambient upper mantle impinged upon and perturbed by the
sustained plume source that feeds later shield-stage magmatism. 相似文献
20.
The comment of Martin Oczlon contains some significant contributions to the topics discussed in the article of Huckriede et
al. (Int J Earth Sci 93:414–431, 2004). Contrary to Oczlon’s comment, the central results of Huckriede et al. (Int J Earth Sci 93:414–431, 2004) are clearly different from the tectonic model of Oczlon (Geol Rundsch 83:20–31, 1994). Additionally, there is no reason for a new interpretation of the 40K/40Ar muscovite cooling-ages from allochthonous units. 相似文献