Laboratory simulation of rock weathering by salt crystallization and hydration processes in hot,arid environments

The results of a series of experiments are reported in this paper which were designed to differentiate between the forces of crystal growth and hydration in salt weathering, using a single salt-hydrate system (sodium sulphate), five contrasting rock types, and several diurnal temperature-relative humidity cycles which permitted or inhibited these processes and simulated ground surface climates in hot, arid environments. It was shown that hydration of sodium sulphate is an effective mechanism of rock disintegration but that it is significantly less destructive than crystal growth pressure. Crystallization of thenardite (Na₂SO₄) is, in turn, more effective in rock weathering than the crystal growth of mirabilite (Na₂SO₄.10H₂O). In general, rates of disintegration were most rapid where the diurnal temperature range was extreme and relative humidity lowest.     

Spatial characterization of salt accumulation in early stage limestone weathering using probe permeametry

This research characterizes the weathering of natural building stone using an unsteady‐state portable probe permeameter. Variations between the permeability properties of fresh rock and the same rocks after the early stages of a salt weathering simulation are used to examine the effects of salt accumulation on spatial variations in surface rock permeability properties in two limestones from Spain. The Fraga and Tudela limestones are from the Ebro basin and are of Miocene age. Both stone types figure largely in the architectural heritage of Spain and, in common with many other building limestones, they are prone to physical damage from salt crystallization in pore spaces. To examine feedbacks associated with salt accumulation during the early stages of this weathering process, samples of the two stone types were subjected to simulated salt weathering under laboratory conditions using magnesium sulphate and sodium chloride at concentrations of 5% and 15%. Permeability mapping and statistical analysis (aspatial statistics and spatial prediction) before and after salt accumulation are used to assess changes in the spatial variability of permeability and to correlate these changes with salt movement, porosity change, potential rock deterioration and textural characteristics. Statistical analyses of small‐scale permeability measurements are used to evaluate the drivers for decay and hence aid the prediction of the weathering behaviour of the two limestones. Copyright © 2010 John Wiley & Sons, Ltd.     

Salt fretting in the valley cliff of the Asama volcano region,Japan

On the pumice flow deposits of the Asama volcano, Japan, many salts such as halite (NaCl), gypsum (CaSO₄·2H₂O), hexahydrite (MgSO₄·6H₂O) and mirabilite (Na₂SO₄·10H₂O) crystallize at the base of south-facing valley cliffs. The zone of salt efflorescence and of resulting polygonal rind correspond to the zones of notch formation and high water content. The main conditions for salt crystallization and polygonal rind formation are: (1) the existence of groundwater containing a high concentration of Cl^?, SO, Ca²⁺, Mg²⁺, and Na⁺; (2) a valley cliff material with a high capillary action and small tensile strength; and (3) low humidity and a high ground-surface temperature derived from the direct incidence of sunshine. Given the right conditions, salt weathering can occur not only in the arid regions but also in humid, temperate inland regions.     

Experimental frost and salt weathering of chalk—II

Experiments are described in which chalk cubes were soaked in solutions of either sodium chloride, sodium sulphate, or magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, or in a mixed solution of sodium chloride and sodium sulphate or in distilled water. After removal of excess liquid, the cubes were subjected to six freeze–thaw cycles with temperatures ranging from either +15 to ?10°C or +15 to ?30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the extent of weathering was much less than that previously reported for samples frozen totally immersed in the same liquids. Evidence is presented which suggests that salt crystallization is the major weathering process operative when non–immersed samples are frozen but a combination of frost and salt weathering operates when fully immersed samples are frozen.     

Weathering of sandstone by the combined action of frost and salt

Preliminary results from a continuing series of laboratory experiments designed to examine the combined effects of salt and frost weathering indicate that some salts greatly enhance the breakdown of rocks by frost. Samples of Ardingly Sandstone from southeast England were soaked in saturated solutions of sodium chloride or sodium sulphate and subjected to alternating cycles of freezing and thawing. Rapid disintegration of the sandstone occurred within twenty cycles, in each of the salt solutions. In contrast, samples subjected to freezing and thawing in deionized water suffered very little damage unless they were saturated under vacuum. When samples were subjected to twenty cycles of wetting and drying at temperatures above 0°C, those soaked in deionised water or sodium chloride suffered no appreciable damage but those soaked in sodium sulphate rapidly disintegrated. Tentative explanations of these results are offered. The enhancement of frost weathering by salt appears to have been overlooked by many writers yet it is likely to be an important geomorphological process in those areas of mid and high latitudes where rocks are saturated with sodium salts.     

Laboratory simulation of ‘the wick effect’ in salt weathering of rock

‘The wick effect’ is the upward migration of saline solutions into rocks and their subsequent crystallization. Lower Carboniferous sandstone blocks of rectangular shape have been subjected to this process in the laboratory using a range of salt types, a range of salt concentrations, and various mixtures of salts. Some treatments produced severe disintegration, notably sodium carbonate and a mixture of sodium carbonate with magnesium sulphate, whereas other salts (including sodium chloride and gypsum) were much less effective. The debris produced by this experimental salt weathering included appreciable quantities of silt-sized material, which were analysed with a laser granulometer. Such material could provide a source for desert loess.     

Complex relationships between salt type and rock properties in a durability experiment of multiple salt–rock treatments

A laboratory salt weathering experiment was performed using five salts to attack eight types of rocks to determine the relative significance of rock durability and salt aggressivity to salt crystallization damage. The influence of individual rock properties on the salt susceptibility of the rocks was also evaluated. To study the relation between pore characteristics, salt uptake, and damage, the pre‐ and post‐experiment pore size distributions of the rocks were also examined. It is observed that both salt type and rock properties influenced the damage pattern. The durability ranking of the rocks became significantly altered with the salt type while the variation in salt efficacy ranking with rock type was less pronounced. Of the five salts used, sodium chloride and aluminium sulfate were invariably ineffective with all rock types while sodium carbonate, sodium sulfate, and magnesium sulfate, were markedly more effective in damaging most types of rock used. Of the rock properties investigated, the microporosity (of pores smaller than 0·05 or 0·1 µm) showed the most significant influence on deterioration of the rocks associated with salt crystallization, whereas microporosity of pores smaller than 5 µm played a more important role in salt uptake. Pore size distribution was thus the key factor controlling salt uptake and damage. Rocks with a large number of pores (<5 µm) and a high proportion of pores (<0·05 or 0·1 µm) were particularly susceptible to salt crystallization damage. However, anomalies arose that could not be explained in terms of rock properties or salt efficacy alone. Overall, the relative influences of salt type/efficacy and rock type/properties on salt damage propensity were not clear enough to draw a reasonable conclusion. Salt crystallization damage appears to be influenced by the individual interactions between salts and rocks, which could explain the anomalous results. Copyright © 2009 John Wiley & Sons, Ltd.     

Experimental frost and salt weathering of chalk—I

To try to resolve the conflicts surrounding the influence of salts on frost weathering, chalk cubes were immersed, separately, in solutions of sodium chloride, sodium sulphate, and magnesium sulphate at concentrations of 5·5 per cent and 12·5 per cent, in a mixed solution of sodium chloride and sodium sulphate, and in distilled water. The cubes were subjected to six freeze-thaw cycles with temperatures ranging from either +15 to — 10°C or + 15 to — 30°C. The results confirm that frost weathering can be enhanced by the presence of certain salts, but the degree of enhancement depends both on the concentration and type of salt and on the intensity of the freeze-thaw regime. Some, but not all, of the results can be explained by the phase changes that occur during the freezing of the salt solutions.     

A multi‐method investigation of temperature,moisture and salt dynamics in tafoni (Tafraoute,Morocco)

Despite numerous investigations and theoretical models, tafoni weathering is still not fully understood largely because of limited data available on temperature, moisture and salt regimes. We investigated tafoni developed in granite in the Tafraoute region, Morocco, through an exploratory, two‐week multi‐method field campaign. Temperatures were measured with iButtons and by means of infrared thermography; moisture distribution and progress were captured with handheld moisture sensors and with drilled‐in iButtons. Salts were analysed in drill dust samples from different positions and rock depths. The results derived from very different techniques mutually support one another. Salts and moisture are concentrated near the base of the investigated tafoni, probably due to a saturated pore water body around the base of rock tors. Salts are accumulated close to the rock surface in tafoni, but not on the surrounding rock surfaces. A clear correlation was found between moisture and salt contents. Within a tafone, areas of higher humidity also display increased salt concentration near the surface. The temperature/humidity records allied with ionic analyses suggest that sodium sulfate dominates and is likely to undergo frequent phase changes from thenardite to mirabilite and vice versa. Two pathways of salt transport in and around tafoni are assumed based on the data: infiltration with rainfall on the top and around tors and boulders, and capillary rise from saturated pore water bodies to the surface. Copyright © 2015 John Wiley & Sons, Ltd.     

Sodium sulphate weathering and the disintegration of Mohenjo-Daro,Pakistan

In Pakistan various brick building structures are currently disintegrating in the Indus Valley. These include the Harappan site of Mohenjo-Daro. The environment of this site is described, the nature and speed of the disintegration problem is outlined, and the cause of disintegration is discussed Weathering occurs in association with the development of salt efflorescences and some bricks disintegrate only a few years after being laid down. Chemical and X-ray diffraction analyses show that the predominant salt is the sodium sulphate mineral thenardite. The reasons for its effectiveness are discussed. They include its high solubility, the rapid change of solubility with temperature, and its hydration characteristics.     

Chemical textures on quartz grains: An experimental approach using salts

Two groups of fresh crushed Brazilian quartz grains (0.4–0.6 mm) were placed in 10 ml of various saturated salt solutions (sodium sulphate, sodium chloride, magnesium sulphate, sodium carbonate, and sodium carbonate and soil). One group was placed in an environmental cabinet programmed to simulate summer diurnal temperature and relative humidity values recorded in Wheeler Valley, a dry valley in southern Victoria Land, Antarctica. The other group was allowed to remain at normal laboratory conditions. Quartz grains from both groups were removed at pre-selected intervals for examination using the scanning electron microscope. After 50 hours chemical surface textures were formed on the quartz grains in all but the sodium sulphate solution. At the 140 hour interval all the salt solutions used were producing chemical surface textures on the quartz grains. This paper demonstrates that chemical surface textures can be produced on quartz grain surfaces by saturated salt solutions in a short period of time and may prove to be representative of chemical surface textures produced in a saturated saline environment.     

Sandstone response to salt weathering following simulated fire damage: a comparison of the effects of furnace heating and fire

Fire has long been recognized as an agent of rock weathering. Our understanding of the impact of fire on stone comes either from early anecdotal evidence, or from more recent laboratory simulation studies, using furnaces to simulate the effects of fire. This paper suggests that knowledge derived from simulated heating experiments is based on the pre‐conceptions of the experiment designer – when using a furnace to simulate fire, the operator decides on the maximum temperature and the duration of the experiment. These are key factors in determining the response of the stone to fire, and if these are removed from real‐world observations then knowledge based on these simulations must be questioned. To explore the differences between heating sandstone in a furnace and a real fire, sample blocks of Peakmoor Sandstone were subjected to different stress histories in combination (lime rendering and removal, furnace heating or fire, frost and salt weathering). Block response to furnace heating and fire is discussed, with emphasis placed on the non‐uniformity of the fire and of block response to fire in contrast to the uniform response to surface heating in a furnace. Subsequent response to salt weathering (by a 10% solution of sodium chloride and magnesium sulphate) was then monitored by weight loss. Blocks that had experienced fire showed a more unpredictable response to salt weathering than those that had undergone furnace heating – spalling of corners and rapid catastrophic weight loss were evidenced in blocks that had been subjected to fire, after periods of relative quiescence. An important physical side‐effect of the fire was soot accumulation, which created a waxy, relatively impermeable layer on some blocks. This layer repelled water and hindered salt ingress, but eventually detached when salt, able to enter the substrate through more permeable areas, concentrated and crystallized behind it, resulting in rapid weight loss and accelerated decay. Copyright © 2007 John Wiley & Sons, Ltd.     

Effect of salt types on salt precipitation and water transport in saline sandy soil

Salt precipitation on the surface of porous media significantly affects water transport processes. Most studies on salt precipitation mainly focused on single salts, but in nature, salt precipitation usually occurs as mixtures. Consequently, information on the crystallization of salt mixtures and its effect on water transport remains scarce. This study investigated the precipitation of mixtures (the mass ratios of NaCl:Na₂SO₄ were 3:7, 5:5, and 7:3, respectively) of NaCl (typical efflorescence) and Na₂SO₄ (typical subflorescence) in the initially saturated sandy soil columns and its effect on evaporation and compared it with the cases of the two salts individually. The results showed that salt mixtures exhibited a mixed pattern of crystals including both efflorescence and subflorescence, and the efflorescence showed granular aggregation, unlike the mono-salts. The crystallization coverage of the salt mixtures was smaller than that of NaCl mono-salt; high (7:3) and low (5:5 and 3:7) proportions of NaCl led to larger and smaller crystallization coverage than that of Na₂SO₄ mono-salt, respectively. While the salt mixtures had less crystallization coverage than the mono-salts, they showed lower evaporation because the salt mixtures formed a denser crystallization structure of efflorescence-subflorescence-soil layer, this crystallization structure exhibited greater inhibition of water vapour diffusion, thus reducing evaporation. In addition, the crystallization of the salt mixtures with higher NaCl proportion afforded greater resistance of evaporation. The mixed crystallization pattern formed by the salt mixtures significantly enhances the crystallization resistance to evaporation.     

Hydrogeochemistry,contaminant transport and tectonic effects in the Okposi-Uburu salt lake area of Imo State,Nigeria

ABSTRACT

Hydrogeochemical data of groundwater samples from 35 boreholes drilled in the Okposi-Uburu salt lake area are analysed. The data reveal that concentrations of dissolved geochemical constituents such as calcium (Ca²⁺), manganese (Mn²⁺), magnesium (Mg²⁺), chloride (C1^?), and sulphate (SO²⁺ ₄) ions show significant areal variations. Dissolved solids, chloride and manganese ions have concentrations up to and above the objectionable limits for drinking water in the salt lake area. Concentrations of dissolved solids in this zone are about 1200 mg 1^?1. Concentrations of chloride and manganese ions are 350 mg 1^?1 and 1.0 mg 1^?1 respectively. These geochemical constituents and groundwater flow patterns show that transport of contaminants away from the source zone has been greatly influenced by advection, while in areas of high velocity dispersion is the controlling factor. Temperatures for the Okposi and Uburu salt springs are 34.4 and 37.5°C respectively. Bomb tritium indicated water of pre-1953 age. Deuterium and oxygen-18 showed high isotopic enrichment. The high concentrations of dissolved salts resulted from the combined effects of migration of dissolved salts through fractures at the lake floor and evaporation from the lake surface. These findings are related to the tectonic history of the Okposi-Uburu area.     

FIELD EXPERIMENTS ON PHYSICAL WEATHERING AND WIND EROSION IN AN ANTARCTIC COLD DESERT

Field experiments were carried out over a five year period with the aim of understanding contemporary weathering and erosional environments in the Sør Rondane Mountains, an Antarctic cold desert region. These include observations of (1) scaling from rockwalls, (2) disintegration of tuff blocks with or without saline solutions, and (3) abrasion of artificial walls by wind. Monitoring was also made of rock surface temperature and wind speed. Despite frequent temperature oscillations across 0°C, rock scaling due to frost action was generally very slow because of low moisture content in the rockwalls. Exposure to the cold, dry climate led to the rapid disintegration of porous tuff blocks including soluble salts like halite and thenardite. This indicates that rates of weathering are increased greatly with the accumulation of such salts in the bedrock. Although gypsum did not cause any visible damage over four years, its widespread occurrence in heavily damaged rocks demonstrates that increasing gypsum contents may also intensify rock breakdown. The snow-laden katabatic wind resulted in rapid wearing of the windward face of an asbestos board with the peak erosion at 30–40 cm above the ground. Nonetheless, the landforms expected from the unidirectional wind characteristics are by no means common features because of lack of abrasive materials, such as snow and sand particles. These experiments suggest that frost weathering and wind erosion are only locally effective where plenty of moisture or an abrasive material is available, whilst salt weathering and removal of the waste by wind play a major role in constructing erosional landforms over the mountains.     

Contour scaling of a sandstone by salt weathering under simulated hot desert conditions

A laboratory study has been used to investigate relationships between salts and contour scaling—a weathering feature commonly observed on rock surfaces in salt-rich environments. Surface disaggregation and essentially surface-parallel cracks were produced in sandstone blocks using 10 per cent solutions of sodium sulphate and magnesium sulphate applied daily to single exposed surfaces for sixty days. A control block soaked once in saturated magnesium sulphate and subsequently wetted daily with distilled water showed extensive surface disaggregation, but no cracking. Both surface disaggregation and subsurface cracking were associated with relative concentrations of microcrystalline salt. A tentative model of contour scaling is proposed, which involves linking together potential cracks by salt-induced fracturing of intervening, crack-stopping grains. Further control blocks treated respectively with 10 per cent and saturated sodium chloride showed no evidence of subsurface cracking and only limited surface disaggregation of the ‘saturated’ block.     

Experimental salt weathering of limestones in relation to rock properties

A total of 21 different types of British and European Mesozoic limestones have been subjected to simulated salt weathering using sodium sulphate (Na₂SO₄) with the following aims: assessment of the relative durabilities of different types of limestone; assessment of the importance of modulus of elasticity and other factors in affecting durability; and assessment of the use of impulse excitation techniques to monitor changes in rock modulus of elasticity. The rocks showed a wide spectrum of durabilities; while rocks with high values of modulus of elasticity, lower water absorption capacities, high densities and low salt uptakes tended to be durable, there were anomalies, the explanation for which probably lies in their pore structures. Non-destructive testing techniques showed that, although the more durable rocks failed to lose weight or to show visual signs of disintegration, their modulus of elasticity values did tend to decline, indicating a loss in strength. Copyright © 1999 John Wiley & Sons, Ltd.     

柴达本盆地沙下盐湖的卤水化学及矿物沉积特征——以察尔汗盐湖区北部外围地带为例

对柴达木盆地察尔汗盐湖区外围沙下盐湖的卤水及沉积进行了综合研究。沙下盐湖卤水化学组成与地表径流和开放性盐湖卤水之间存在明显的差异性,具有高Na⁺+Cl^-、低Mg²⁺+Ca²⁺+SO₄^2-、贫K⁺+CO₃^2-+HCO₃^-等特征。沙下盐湖析盐层位含有新生矿物并夹带碎屑矿物,其盐类矿物组合为:石盐+羟氯镁铝石+光卤石。25℃等温蒸发相图表明,其卤水演化方向往光卤石析出区迁移,在穿越上覆盖层通道中卤水发生的物理化学反应与独特的沉积特征,可以作为继续寻找沙下盐湖的指导。     

Application of geochemical and stable isotopic tracers to investigate groundwater salinity in the Ochi-Narkwa Basin,Ghana

Rainwater, groundwater and soil-water samples were analysed to assess groundwater geochemistry and the origin of salinity in the Ochi-Narkwa basin of the Central Region of Ghana. The samples were measured for major ions and stable isotopes (δ¹⁸O, δ²H and δ¹³C). The Cl^? content in rainwater decreased with distance from the coast. The major hydrochemical facies were Na-Cl for the shallow groundwaters and Ca-Mg-HCO₃, Na-Cl and Ca-Mg-Cl-SO₄ for the deep groundwaters. Groundwater salinization is caused largely by halite dissolution and to a minor extent by silicate weathering and seawater intrusion. Stable isotope composition of the groundwaters followed a slope of 3.44, suggesting a mixing line. Chloride profiles in the soil zone revealed the existence of salt crusts, which support halite dissolution in the study area. A conceptual flow model developed to explain the mechanism of salinization showed principal groundwater flow in the NW–SE direction.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal     

Laboratory simulation of salt weathering under moderate ageing conditions: Implications for the deterioration of sandstone heritage in temperate climates

Salt weathering is a significant process affecting the deterioration and conservation of stone-built heritage in many locations and environments. While much research has focused on the impact of salt weathering under arid or coastal conditions with characteristic climatic conditions and salt types, many sites found to be experiencing salt-induced deterioration, such as sandstone rock-hewn cave temples in Gansu Province, China and sandstone buildings in the northern UK, experience high humidities, moderate temperature ranges, and different salt types. To evaluate the impact of salt weathering on sandstone-built heritage under such mild humid environmental conditions, a lab simulation experiment was designed. The experiment was carried out on three types of sandstone (used in the northern UK and Gansu Province, China) and utilized a realistic diurnal humidity and temperature cycle (85% RH/16°C + 60% RH/22°C), and three widespread damaging salts, that is, Na₂SO₄, MgSO₄, and the mixture of Na₂SO₄–MgSO₄. The nature and extent of deterioration was monitored by photography, weight loss, and the changes in petrophysical properties measured using hardness, ultrasonic pulse velocity (P-wave velocity), water absorption coefficient by capillarity, open porosity, and apparent density. All three sandstones were found to be susceptible to MgSO₄ and the mixture of Na₂SO₄–MgSO₄, but weakly affected by Na₂SO₄ under mild humid environmental conditions.