Physical and Mechanical Properties of Serpentinized Ultrabasic Rocks in NW Turkey

Serpentinized ultrabasic rocks crop out at various places in the northwestern part of Turkey. They are the foundation rocks of some architecture and the ground under road bases in many areas. They are also frequently used for indoor work such as tables, shafts, pilasters, jambs for chimney pieces and ornaments of different kinds. Owing to their economic importance, in situ geophysical and geotechnical studies were conducted to determine their dynamic engineering parameters such as: P- and S-wave velocities, Poisson’s ratio, rigidity modulus, elasticity modulus, bulk modulus, natural period, safe bearing capacity, and bearing coefficient. Geophysical and geotechnical laboratory tests were performed on cylindrical specimens cored across and along the foliation planes: ultrasonic measurements of compressional pulse velocity (UPV), uniaxial compressive strength (UCS), point load index (Is₍₅₀₎), and static elasticity modulus (Es); effective porosity (n), dry unit weight (DUW), and saturated unit weight (?_s) sets of the rock specimens were determined. Finally, statistical correlations were performed by regression analysis to evaluate the relationships between UCS and Is₍₅₀₎, UPV, Es; UPV and Is₍₅₀₎, DUW, ?_s, n, and Es.     

Laboratory simulation of salt weathering processes in arid environments

The equipment and techniques being used at Bedford College, London to simulate salt weathering processes in deserts are described in the context of a general discussion of the nature of salt weathering processes and approaches to studying them. An experiment based on the equipment and techniques is described: it is designed to test the durability of three building stones in the presence of several different saline solutions under conditions of surface temperature and relative humidity that are considered typical of hot deserts. The experiment, the first of a series, shows that Na₂SO₄ is the most effective of the salts used, and that susceptibility of the rocks to weathering is related to such rock properties as porosity, microporosity and water absorption capacity.     

Rift Valley in the Atlantic Ocean near 36°50′N: petrology and geochemistry of basaltic rocks

Dredged rocks from an area of about 15 km² within the inner floor and on the adjacent walls of the Rift Valley were collected. Based on petrographic and chemical data, four types of basaltic rocks were recognized: (1) picritic basalts with olivine xenocrysts, TiO₂ < 0.6%, K₂O < 0.1%, (2) olivine basalts with olivine megacrysts, TiO₂ = 0.8–1.5%,K₂O = 0.1–0.2%, (3) highly phyric and moderately phyric plagioclase basalts with megacrystic plagioclase, TiO₂ < 1.3%, K₂O < 0.3%, and (4) pyroxene basalts with pyroxene > plagioclase, TiO₂ = 0.8–1%,K₂O = 0.2–0.4%. The Cr and Ni having high partition coefficients show different variation trends for each type of rock and their values decrease continuously as crystallization proceeds within each type of basalt. It is speculated that two different magmas have given rise to the above-mentioned rocks. One has yielded the picritic basalts and subsequently the olivine basalts after a separation of the olivine cumulates; the other gave rise to the plagioclase basalts.     

Mechanical behavior of magma reservoir envelopes: Elasticity of the olivine tholeiite solidus

A study of the elasticity of the solidus of igneous rocks provides a means of evaluating several high temperature mechanical characteristics of the zone that forms the transition region between solid rock and rock with a small fraction of partial melt — that is, the magma reservoirenvelope. This type of study has been performed for Hawaiian olivine tholeiite, by employing the theoretical treatment ofWalsh (1969). The effective aggregate bulk modulus (K*), aggregate rigidity (μ*), aggregate Young’s modulus (E*) and the aggregate Poisson’s ratio (n*) have been used to characterize the range in elastic behavior expected for this partially molten envelope. The details of mineralogy, mineral crystal chemistry and microstructure for a tholeiitic basalt from a deep-ponded flow unit (the Boiling Pots), as well as the geometry of melt pocket aspect ratios have been used to provide a basis for computing the elasticity for a shallow reservoir solidus. For a broad range in modal mineralogy, the internal 0–1% melt represents a transition region from an aggregate elasticity controlled by mineral composition, to an elastic behavior dominated by the melt phase (evaluated at a melt pocket aspect ratio ofε=0.001). For vesicular rocks in a low pressure environment, the internal 0–1% melt represents a transition from porosity-controlled elasticity to melt-controlled elasticity, evaluated at a prevalent aspect ratio ofε=0.001, and over the porosity range Φ=0.0?0.20 (20%). Thin melt films found to separate plagioclase microlites (0.0001=ε) are capable of effecting a 94.7% reduction in Young’s modulus, E*, over the 0–1% melt range, and suggest that the reservoir envelope may be critically weakened by rather small volume fractions of liquid, if dispersed in such narrow packets.     

Modeling of mineralogical composition,density and elastic wave velocities in anhydrous magmatic rocks

We use the technique of direct minimization of the Gibbs free energy of the 8-component (K₂O-Na₂O-Fe₂O₃-FeO-CaO-MgO-Al₂O₃-SiO₂) multiphase system in order to determine the equilibrium mineral assemblages of rocks of different bulk chemical compositions equilibrated at various P-T conditions. The calculated modal compositions of rocks and experimental data on elastic moduli of single crystals are then used to calculate densities and isotropic elastic wave velocities of rocks together with their pressure and temperature derivatives. Sufficient accuracy of the calculations is confirmed by comparison with experimental data on the gabbro-eclogite transformation and precise ultrasonic measurements of elastic wave velocities in a number of magmatic and metamorphic rocks.We present calculated phase diagrams with isolines of density, elastic wave velocities, and their pressure and temperature derivatives for several anhydrous magmatic rocks, from granite to lherzolite. Density and elastic properties of rocks are controlled by their chemical compositions, especially the SiO₂ content, and by P-T of equilibration, and they increase with pressure due to mineral reactions changing mineral assemblages from plagioclase-bearing and garnet-free to garnetbearing and plagioclase-free. TheV _p -density correlation is high, and shows two clear trends: one for iron-poor ultramafic rocks and another for all the other rocks considered. Mineral reactions, which occur at high pressures, changeV _p and density of anhydrous magmatic rocks following the well-known Birch (or a similar) law.Felsic, intermediate and mafic rocks can be well distinguished in theV _p -V _p /V _s - diagram, although their values ofV _p can be close to one another. TheV _p -V _p /V _s -density diagrams together with calculated phase diagrams can serve as efficient instruments for petrologic interpretation of seismic velocities.     

Velocity and Density Heterogeneities of the Tien-Shan Lithosphere

—The Tien-Shan orogene is a region in which the earth’s crust undergoes considerable thickening and tangential compression. Under these conditions the lithosphere heterogeneities (composi tion, rheological) create the prerequisites for the development of various phenomena of tectonic layering (lateral shearing, different deformation of layers). To study the distribution of velocity, density and other elastic parameters, the results from a seismic tomography study on P-wave as well as S-wave velocities were used. Using empirical as well as theoretical formulas on the relationship between velocity, density and silica content in rocks, their distribution in the Tien-Shan’s lithosphere has been calculated. In addition, other elastic parameters, such as Young’s modulus, shear modulus, Poisson’s ratio and coefficient of general compressions have been determined. Zoning of different types of crust was carried out for the region investigated. The characteristics of the "crust-mantle" transition have been investi gated. Large blocks with different types of the earth’s crust were distinguished. Layers with inverse values of velocity, density and shear and Young modulus are revealed in the Tien-Shan lithosphere. All of the above described features open new ways to solve geodynamics problems.     

Distribution and geological significance of 17α(H)-diahopanes from different hydrocarbon source rocks of Yanchang Formation in Ordos Basin

Based on GC-MS testing data of many saturated hydrocarbon samples, 17α(H)-C₃₀ diahopanes (C₃₀ ^*) are extensively distributed in the lacustrine hydrocarbon source rocks of the Yanchang Formation in Ordos Basin, but show remarkable differences in relative abundance among various source rocks. Generally, Chang 7 high-quality source rock (oil shale) developed in deep lake anoxic environment shows lower C₃₀ ^* content, whereas Chang 6–9 dark mudstone developed in shallow to semi-deep lake, sub-oxidizing environment shows relatively high to high C₃₀ ^* value. Particularly, Chang 7 and Chang 9 black mudstones in Zhidan region in the northeast of the lake basin show extremely high C₃₀ ^* value. A comparative analysis was made based on lithology, organic types and various geochemical parameters indicative of redox environment, and the results indicate that environmental factors such as redox settings and lithology are key factors that control the C₃₀ ^* relative abundance, while organic types and maturity may be minor factors. High to extremely high C₃₀ ^* values are indicative of sub-oxidizing environment of fresh-brackish water and shallow to semi-deep lake. Therefore, research on C₃₀ ^* relative content and distribution in lacustrine hydrocarbon source rocks in the Yanchang Formation, especially on the difference in C₃₀ ^* between Chang 7 high-quality source rocks (oil shale) and Chang 6–9₁ source rocks (dark mudstone), will provide an important approach for classification of Mesozoic lacustrine crudes and detailed oil-source correlation in the basin. Supported by National Natural Science Foundation of China (Grant No. 40773028)     

The relations between modulus of elasticity and temperature in the context of the experimental simulation of rock weathering by fire

Fires occur frequently in many biomes and generate high temperatures on the ground surface. There are many field examples of fire causing rock disintegration. The simulation of fire in the laboratory (using a furnace) and the monitoring of changes in rock modulus of elasticity (with a Grindosonic apparatus), reveal that different rocks respond differently to heating. Significant decreases in elasticity occur at temperatures as low as 200°C and granites display particularly marked reductions. Extended periods of heating are not required for significant reductions to occur. It is postulated that the degree of change in elasticity as a result of simulated fire is such that rock outcrops subjected to real fires are likely to be sufficiently modified as to increase their susceptibility to erosion and weathering processes.     

NMR Measurements in Carbonate Rocks: Problems and an Approach to a Solution

Carbonate rocks are well known for their complex petrophysical behavior where, in contrast to siliciclastic rocks, different parameters, including porosity and permeability, usually are not directly related. This behavior is the result of thorough reorganization of porosity during diagenesis, and it turns prediction of reservoir quality of carbonate rocks into a challenge. The study presented here deals with the problem of utilizing NMR techniques in prediction of petrophysical properties in carbonates.We employ a visual porosity classification as a priori knowledge for better interpreting NMR data for prediction purposes. This allows for choice of suitable T₂ cutoff values to differentiate movable from bound fluids adapted for the specific carbonate rock, thus resulting in better interpretation of NMR data. The approach of using a genetic pore type classification for adapting the conventional method for T₂ cutoff determination, which originally was developed for siliciclastic rocks, is promising. Similarly, for permeability determination on the basis of NMR measurements, the classification of carbonate rocks based on porosity types also shows potential. The approach implemented here has the promise to provide a basis of standardized interpretation of NMR data from carbonate rocks.Acknowledgment We are grateful to Baker Hughes INTEQ, Celle, for permission to publish the results of this work. This study was part of I.S.s Masters Thesis at Hannover University that was carried out in collaboration with Baker Hughes INTEQ, Celle, Germany. We appreciate comments of an anonymous referee and PAGEOPH editor Brian J. Mitchell.     

Comprehensive geochemical identification of highly evolved marine carbonate rocks as hydrocarbon-source rocks as exemplified by the Ordos Basin

China’s widespread marine carbonate rock series are mostly characterized by intensive thermal evolu- tion and low abundance of organic matter, especially the Lower Paleozoic carbonate rocks have experienced multi-episodes of tectonics and prolonged history of thermal evolution, thus making it more complicatedethe development and distribution of hydrocar- bon-source rocks reflected in the sedimentary, bio- logical and geochemical facies. Consequently, it seems much less powerful to assess the …     

Petrology,geochemistry and Sr-isotope characteristics of lavas from the area of Commenda (Mts. Vulsini,Italy)

Major, trace element and Sr-isotope compositions are reported for a suite of lavas coming from the area of Commenda in the SE Vulsinian district. The analyzed samples have all low silica contents and variable but generally high CaO, MgO and FeO_t. Based on K₂O% and K₂O/Na₂O ratio, the rocks from Commenda can be classified as belonging to the Potassic Series (KS) and the High-potassium Series (HKS). The HKS rocks appear to have derived by cristal/liquid fractionation from the most mafic types with separation of olivine and clinopyroxene and then of clinopyroxene + leucite. The most primitive HKS rocks have aphyric texture and high Mg-values, Cr and Ni contents which are close or within the range of values of magmas formed by partial melting of periodititic mantle sources. The KS rocks have lower incompatible element contents as the HKS rocks with similar degree of evolution.The variations of Sr-isotopic ratios of the analyzed rocks and of other Vulsinian lavas, indicate that the basic HKS Vulsinian rocks did not interact significantly with the continental crust. Instead, the KS appears to have evolved by combined crystal fractionation and assimilation processes, starting from parental magmas which had⁸⁷Sr/⁸⁶Sr ratio not significantly lower than that found in the less evolved rocks of the suite.The most primitive HKS rocks from Commenda have hygromagmatophile element distribution pattern characterized by high ratio of LILE/HFSE with negative anomalies of Ta and Ti, resembling closely those of other Roman mafic volcanics. The primitive geochemical characteristics of the Commenda rocks exclude that these features are the products of interaction with the crust and provide a further support to the hypothesis of a genesis within a subduction-modified mantle source.     

Rock anelasticity by complex modulus apparatus

Summary An attempt has been made to study the mechanical response of rocks to stress waves using the Complex Modulus Apparatus. Natural resonant frequencies and the half-power relative band widths are determined experimentally in the frequency range 50–5000 c/s for a few igneous, metamorphic and sedimentary rock samples. Elastic and anelastic parameters, like the real part of the elastic modulus, loss factor, complex modulus of elasticity and percentage anelasticity, are evaluated and the interrelationships between them shown. Data on four synthetic materials like perspex, ebonite and laminated sheeting are reported besides the results on different rock types.RM-9/73.     

新疆艾比湖干涸湖底不同景观单元蒸发盐分布与变化特征

盐尘暴是由干旱、半干旱区尾闾湖干涸湖底及其附近盐质荒漠风蚀所导致的一种灾害性极强的天气现象.盐尘主要来自风蚀过程中干涸湖底盐分的释放.由于干涸湖底不同的植被覆盖状况,导致风蚀过程中盐分损失不同.为了解风蚀过程中不同景观单元下盐分分布与变化特征,选择艾比湖干涸湖底自然状态下典型的6种景观单元(胡杨林带(Landscape 1,简写为L1)、乔本结合带(L2)、草本结合带(L3)、芦苇荒漠带(L4)、梭梭荒漠带(L5)、无植被覆盖(L6)),于2011年6月初和10月初2次采集沉积物样品,运用方差分析方法,研究各个景观单元下盐分的分布与季节变化特征.结果表明:1)2次采样不同景观单元0~30 cm和30~60 cm处阳离子Na⁺、K⁺、Mg²⁺含量均存在显著差异,其中Na⁺含量存在极显著差异且含量最高,而不同景观单元0~30 cm和30~60 cm处阴离子Cl^-、SO₄^2-含量均存在显著差异,CO₃^2-、HCO₃^-含量甚微;2)干涸湖底沉积物的主要盐分类型是NaCl,其次是CaSO₄,其它盐分含量较小,且不同景观单元相同深度沉积物盐分含量存在显著差异.无论是盐分离子组成还是含量,L5均最高,其次是L6,而L2均最低.随着深度的增加,不同景观单元沉积物中的盐分含量均呈现降低的趋势.随着时间变化,景观单元L2、L3、L4、L5、L6盐分含量有不同程度的增加,而L1盐分含量减少;3)在小尺度范围内,局地气候条件相对均一,地下水矿化度、地下水埋深及沉积物性质差别不大,不同景观类型是影响盐分表聚的主要因素.     

Petrology and geochemistry of clastic sedimentary rocks as evidences for provenance of the Late Palaeozoic Madzaringwe Formation,Tshipise-Pafuri Basin,South Africa

Petrography and geochemistry(major, trace and rare earth elements) of clastic rocks from the Late Palaeozoic Madzaringwe Formation, in the Tshipise-Pafuri Basin, Northern South Africa, have been investigated to understand their provenance. Sandstone petrography and detrital modes indicates that the Late Palaeozoic succession was derived from craton interior and recycled orogen provenance. Sandstones in the Madzaringwe Formation are sub-arkosic to sub-litharenite. The sediments may represent a recycled to craton interior provenance. The geochemical data of major elements show that sandstone and shales have the same source. The study of paleoweathering conditions based on modal composition, chemical index of alteration(CIA) and A-CN-K(Al2O3-Ca O+Na2O-K2O) relationships indicate that probably chemical weathering in the source area and recycling processes have been more important in shale and sandstone rocks. The relatively high CIA values(70–90%) indicates moderate to high weathering conditions of the samples and the paleoclimate of the source area was warm. K2O/Na2 O versus Si O2 and Na2O-Ca O-K2 O tectonic setting discrimination plots, suggest a passive continental margin. In the study of trace elements, triangular Th-Sc-Zr/10 and La-Th-Sc plots both suggest a passive margin setting of the basin. Petrographic and geochemical results of the samples suggest uplifted basement source areas dominated by sedimentary rocks and/or granite-gneiss rocks. The source rocks might have been the recycled pre-Soutpansberg Karoo Supergroup rocks and the metasedimentary rocks of the Soutpansberg Group. Other source rocks may have been the pre-Beit-Bridge basement rocks(granites and gneisses).     

A method of estimating the stress exponent in the flow law for rocks using fold shape

On the basis of experiment and theory, we expect rocks to deform in a linear fashion when diffusive processes control deformation, and nonlinearly in most other situations. The geometric characteristics of buckle folds in layered materials are dependent on rheological parameters, and in particular depend strongly on the stress exponent,n _L , of the stiff layers involved. Thus, information about the deformation rocks have undergone and their rheological state during deformation can be obtained by studying fold shapes and strain distributions. This is important because there is uncertainty in extrapolating laboratory-derived flow laws to the very slow natural strain rates and large strains found in nature.We have studied the development of buckle folds in linear and nonlinear materials using finite-element modeling, and interpolated the numerical results to construct plots relating several geometric parameters to variations in power-law exponent,n _L , and viscosity ratio,m, of layer to matrix. Such plots allow for a comparison of the results of numerical models with data for many natural and experimentally-produced folds, and there is consistency among the data for folds produced in physical models, using both linear and nonlinear materials and the numerical simulations. data for folds from the Appalachian Mountains, the Alps and elsewhere, however, suggest high values ofn _L in the flow laws for a number of rock types. The unexpectedly high estimates ofn _L suggest that other factors, such as strain softening or anisotropy, may influence fold shape, and thus complicate the estimation of the rheological properties of rocks.     

Geochemistry of Cenozoic volcanic rocks in Tengchong,SW China: relationship with the uplift of the Tibetan Plateau

There are wide spread Cenozoic volcanic rocks in Tengchong (CVRT), Yunnan province, SW China. These rocks comprise three rock types: basalt, andesite (dominant type) and dacite. Most samples are sub‐alkaline, and among the sub‐alkaline rocks, most are high‐K calc‐alkaline. These rocks have a SiO₂ range of 49.1 wt.% to 66.9 wt.%. TiO₂ contents are not high and have a variation of 0.7 wt.%–1.6 wt.%. Trace element concentrations and element ratios (such as Nb/U, Ce/Pb, Nb/La, etc.) of these rocks have a large variation. ⁸⁷Sr/⁸⁶Sr values fall in the range of 0.7057–0.7093 and ¹⁴³Nd/¹⁴⁴Nd values change from 0.5120 to 0.5125. ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, and ²⁰⁸Pb/²⁰⁴Pb ratios are in the range of 17.936–19.039, 15.614–15.810, and 38.894–39.735, respectively. These geochemical characteristics of CVRT make them resemble island‐arc volcanic rocks. We suggest that the magmas were generated in the lithospheric mantle that had already been metasomatized by previous subduction processes. By the study of the uplift history of the Tibetan Plateau, we found that the beginning of the geotectonic processes to the eruption of CVRT was coeval with one uplift event. Therefore, we propose that the uplift of the Tibetan Plateau caused collapse of the collisional orogeny in Tengchong, which further triggered the generation and eruption of the CVRT magmas.     

Energy of acoustic signals in a borehole

In the present article, the dependencies of the acoustic signal total energy and the energies of the wave packets of different types of the waves on the elastic parameters and permeability of rocks have been studied. We have considered traditional logging tools containing acoustical monopole source. Calculations were performed in a frequency range of dozens of kilohertz, typical for acoustic well logging. It was shown that in a typical high-velocity formation (v_s > v_f, where v_s and v_f are the velocities of the shear wave in the rock and of the compressional wave in the borehole fluid, respectively), the pseudo-Rayleigh waves, whose elastic properties depend mainly on the shear modulus of the rock, contributed significant energy to the total signal energy in the borehole. The energies of different wave packets depend on the permeability in different ways. The greatest sensitivity to permeability change has been shown by the acoustic signal total energy and the energy of the low-velocity part of the pseudo-Rayleigh wave packet. The theoretical analysis was illustrated by real sonic log data.     

Relation of fracture resistance to fabric for granitic rocks

Double-torsion specimens of two granitic rocks were prepared in several directions with reference to microcracks fabric. Even for the same rock and at the same stress levels, the observed crack velocities in two granitic rocks were dependent on both the propagation direction and the opening direction. The maximum difference by several orders of magnitude was found for both rocks. The highest crack velocity was observed when the subcritical crack was parallel to most of the preexisting cracks. The maximum critical stress intensity factor was about twice as high as the minimum one in different directions. An analysis for a thin plate having anisotropic elasticity under torsional load showed that the observed difference in the crack velocity and the critical stress intensity factor was not an error due to conventional equations derived on the assumption of isotropic elasticity but the true material's property. As the preferred orientation of microcracks has been pointed out for many granitic rocks, we can conclude that the anisotropic nature of the fracture resistance of the two granitic rocks used in this study was not exceptional. A region of a transport-limited velocity was not found for rocks, even at the velocity of 10^–2 m/s, that is almost equal to the theoretical limit of the stress corrosion cracking.     

Ultrasonic measurements of Vp and Qp: relaxation spectrum of complex modulus on basalt melts

Ultrasonic compressional wave velocity V_p and quality factor Q_p have been measured in alkali basalt, olivine basalt and basic andesite melts in the frequency range of 3.4–22 MHz and in the temperature range of 1100–1400°C. Velocity and attenuation of the melts depend on frequency and temperature, showing that there are relaxation mechanisms in the melts. Complex moduli are calculated from the ultrasonic data. The results fit well a complex modulus of Arrhenius temperature dependence with log-normal Gaussian distribution in relaxation times of attenuation. The analysis yields average relaxation time, its activation energy, relaxed modulus, unrelaxed modulus and width of Gaussian distribution in relaxation times. Relaxed modulus is smaller (17.5 GPa) for basic andesite melt of high silica and high alumina contents than for the other two basalt melts (18.1–18.4 GPa). The most probable relaxation times decrease from ～ 3 × 10^?10 s for basic andesite to ～ 10^?11 s for alkali basalt at 1400°C. Activation energies of attenuation, ranging from 270 to 340 kJ mol^?1 in the three melts, are highest in basic andesite. Longitudinal viscosity values and their temperature dependences are also calculated from V_p and Q_p data. The volume viscosity values are estimated from the data using the shear viscosity values. Longitudinal, volume and shear viscosities and their activation energies are highest in the basic andesite melt of the most polymerized structure.     

Laboratory simulation of salt weathering under moderate ageing conditions: Implications for the deterioration of sandstone heritage in temperate climates

Salt weathering is a significant process affecting the deterioration and conservation of stone-built heritage in many locations and environments. While much research has focused on the impact of salt weathering under arid or coastal conditions with characteristic climatic conditions and salt types, many sites found to be experiencing salt-induced deterioration, such as sandstone rock-hewn cave temples in Gansu Province, China and sandstone buildings in the northern UK, experience high humidities, moderate temperature ranges, and different salt types. To evaluate the impact of salt weathering on sandstone-built heritage under such mild humid environmental conditions, a lab simulation experiment was designed. The experiment was carried out on three types of sandstone (used in the northern UK and Gansu Province, China) and utilized a realistic diurnal humidity and temperature cycle (85% RH/16°C + 60% RH/22°C), and three widespread damaging salts, that is, Na₂SO₄, MgSO₄, and the mixture of Na₂SO₄–MgSO₄. The nature and extent of deterioration was monitored by photography, weight loss, and the changes in petrophysical properties measured using hardness, ultrasonic pulse velocity (P-wave velocity), water absorption coefficient by capillarity, open porosity, and apparent density. All three sandstones were found to be susceptible to MgSO₄ and the mixture of Na₂SO₄–MgSO₄, but weakly affected by Na₂SO₄ under mild humid environmental conditions.