The influence of coupled physical swelling and chemical reactions on deformable geomaterials

Coupled thermo‐hydro‐mechanical‐chemical modelling has attracted attention in past decades due to many contemporary geotechnical engineering applications (e.g., waste disposal, carbon capture and storage). However, molecular‐scale interactions within geomaterials (e.g., swelling and dissolution/precipitation) have a significant influence on the mechanical behaviour, yet are rarely incorporated into existing Thermal‐Hydro‐Mechanical‐Chemical (THMC) frameworks. This paper presents a new coupled hydro‐mechanical‐chemical constitutive model to bridge molecular‐scale interactions with macro‐physical deformation by combining the swelling and dissolution/precipitation through an extension of the new mixture‐coupling theory. Entropy analysis of the geomaterial system provides dissipation energy, and Helmholtz free energy gives the relationship between solids and fluids. Numerical simulation is used to compare with the selected recognized models, which demonstrates that the swelling and dissolution/precipitation processes may have a significant influence on the mechanical deformation of the geomaterials.     

Analysis of the hydration of a bentonite seal in a deep radioactive waste repository

A deep geological repository for nuclear waste requires the backfilling and sealing of shafts and galleries to block any preferential path for radioactive contaminants. The paper presents the coupled hydromechanical analyses of an in situ test carried out in the HADES underground laboratory in Mol, Belgium. The test examines the effectiveness of an expansive clay seal in a horizontal borehole specifically drilled for this purpose. The analysis covers the phase of seal hydration up to saturation and subsequent pore pressure equilibration. Hydraulic and mechanical constitutive laws suited to expansive clay materials have been chosen for the analyses with all the parameters determined independently of the in situ test. A quite good agreement has been found between test observations and computed results suggesting that the numerical formulation employed is able to reproduce the main features of a real sealing system.