Steady-state observations of geomagnetically trapped energetic heavy ions and their implications for theory

Measurements of energetic heavy ions using the Explorer 45 and ATS-6 satellites are reviewed and the resulting implications for theory are evaluated. The measured ions are basically protons and helium ions in the energy range from 0.1 to 1 MeV/nucleon. The equatorial energetic ion distributions inside L = 4.5 are found to be very stable for extended periods of time. These ions are very closely confined to the equatorial plane and are sharply peaked as a function of L around a value designated as L_max. Beyond L = 5.0 the fluxes of these ions are more variable with order of magnitude variations being observed at L = 6.6 on the time scales of minutes, hours, or days. The region inside L = 4.5 appears to be well described by radial diffusive transport driven by fluctuations in the geomagnetic field coupled with losses due to charge exchange and Coulomb interactions with ambient hydrogen geocorona and terrestrial plasma environment. From an analysis relating the position in L-value of the maximum intensity, L_max, observed for a given ion species and energy, it is argued that the influence of fluctuations in the convection electric field as discussed by Cornwall (1972) are not effective in radially diffusing in L ions with energies greater than a few hundred kiloelectron volts per nucleon. The source of these ions remains basically undetermined and its determination must await further measurements.     

Mass spectrometric measurements of fractional ion abundances in the stratosphere—Negative ions

Fractional abundances of stratospheric negative ions are for the first time explicitly reported. The measurements made by balloon-borne ion mass spectrometers also rely on recent studies of electric field induced collisional dissociation of negative cluster ions conducted at our laboratory. These indicate that the negative ion composition measurements around 36 km conducted by our group do not suffer from any significant dissociation. The new composition data support ion identifications NO₃^?(HNO₃)_b and HSO₄^?(H₂SO₄)_c(HNO₃)_d and the underlying ion reactions propo previously. Moreover, it is found that HSO₄^?(H₂SO₄)_g-ions appear to be particularly stable and that H₂SO₄-association is very fast. Implications of the ion composition data for ion processes are discussed.     

Ultraviolet photolysis and proton irradiation of astrophysical ice analogs containing hydrogen cyanide

Hydrogen cyanide (HCN) has been identified in the gas phase of the interstellar medium as well as in the comae of several comets. Terrestrially, HCN is a key component in the synthesis of biologically important molecules such as amino acids. In this paper, we report the results of low-temperature (18 K) ice energetic processing experiments involving pure HCN and mixtures of HCN with H₂O and NH₃. Ice films, 0.1 to several microns in thickness, were exposed to either ultraviolet photons (110-250 nm) or 0.8-MeV protons to simulate the effects of space environments. Observed products include HCNO (isocyanic acid), NH₄⁺ (ammonium ion), CN⁻ (cyanide ion), OCN⁻ (cyanate ion), HCONH₂ (formamide), and species spectrally similar to HCN polymers. Product formation rates and HCN destruction rates were determined where possible. Results are discussed in terms of astrophysical situations in the ISM and the Solar System where HCN would likely play an important role in prebiotic chemistry. These results imply that if HCN is present in icy mixtures representative of the ISM or in comets, it will be quickly converted into other species in energetic environments; pure HCN seems to be polymerized by incident radiation.     

Interaction of particles with ion cyclotron waves and magnetosonic waves. Observations from GEOS 1 and GEOS 2

Coordinated observations involving ion composition, thermal plasma, energetic particle, and ULF magnetic field data from GEOS 1 and 2 often reveal the presence of electromagnetic ion cyclotron and magnetosonic waves, which are distinguished by their respective polarization characteristics and frequency spectra. The ion cyclotron waves are identified by a magnetic field perturbation that lies in a plane perpendicular to the Earth's magnetic field B₀ and propagate along B₀. They are associated with the abundance of cold He⁺ in the presence of anisotropic pitch angle distributions of ions having energies E > 20 keV, and were observed at frequencies near the He⁺ gyrofrequency. The magnetosonic waves are characterized by a magnetic field perturbation parallel to B₀ and thus seem to be propagating perpendicular to the Earth's magnetic field. They often occur at harmonics (not always including the fundamental) at the proton gyrofrequency and are associated with phase-space-density distributions that peak at energies E ～ 5–30 keV and at a pitch angle of 90°. Such a ring-like distribution is shown to excite instability in the magnetosonic mode near harmonics of the proton gyrofrequency. Magnetosonic waves are associated in other cases with sharp spatial gradients in energetic ion intensity. Such gradients are encountered in the early afternoon sector (as a consequence of the drift shell distortion caused by the convection electric field) and could likewise constitute a source of free energy for plasma instabilities.     

Production and imaging of energetic neutral atoms from Titan’s exosphere: a 3-D model

Energetic Neutral Atoms (ENAs) are formed when singly charged magnetospheric ions undergo charge exchange collisions with exospheric neutral atoms. The energy of the incident ions is almost entirely transferred to the charge exchange produced ENAs, which then propagate along nearly rectilinear ballistic trajectories. Thus the ENAs can be used like photons in order to form an image of the energetic ion distribution. The Cassini spacecraft is equipped with the Ion and Neutral Camera (INCA), a magnetospheric imaging ENA camera which is part of MIMI (Magnetospheric Imaging Instrument) [Mitchell, D.G., Cheng, A.F., Krimigis, S.M., Keath, E.P., Jaskulek, S.E., Mauk, B.H., McEntire, R.W., Roelof, E.C., Williams, D.J., Hsieh, K.C., Drake, V.A., 1993. INCA: the ion neutral camera for energetic neutral imaging of the Saturnian magnetosphere. Opt. Eng. 32, 3096; Krimigis, S.M., Mitchell, D.G., Hamilton, D.C. et al., 1998. Magnetospheric Imaging Instrument (MIMI) on the Cassini Mission to Saturn/Titan, Space Sci. Rev., submitted]. In this paper we study the production of energetic neutral atoms resulting from the interaction of Titan’s inner exosphere with Saturn’s magnetosphere. We then simulate the ENA images of this interaction, that we anticipate to get from INCA, by using a 3-D model of the ENA production. This first necessitated the development of a model for the altitude density profile and composition of the Titan exosphere [Amsif, A., Dandouras, J., Roelof, E.C., 1997. Modeling the production and the imaging of energetic neutral atoms from Titan’s exosphere. J. Geophys. Res. 102, 22,169]. We thus used the Chamberlain model [Chamberlain, J.W., 1963. Planetary corona and atmospheric evaporation. Planet. Space Sci. 11, 901] and included the five major species: H, H₂, N, N₂ and CH₄. The density and composition profiles obtained were then used to calculate the ENA production, considering a proton spectrum measured by Voyager in the Saturnian magnetosphere as the parent ion population. In order to generate simulated ENA images of the interaction of Titan’s exosphere with Saturn’s magnetosphere, we developed a model based on 3-D trajectory tracing techniques for the parent ions. Since the parent ions (E>10 keV) have gyroradii comparable with the Titan diameter, the screening effect of Titan on the parent ion population was also taken into account. This effect results in highly anisotropic ion distributions, which produce ‘shadows’ in the ENA fluxes, in certain directions. These shadows depend on the ENA energy and on the relative geometry of Titan, the magnetic field and the Cassini spacecraft position. The INCA images will thus enable us to remotely sense the ion fluxes and spectra. They are also expected to give information about the magnetic field in the vicinity of Titan and thus to Titan’s interaction with the magnetosphere of Saturn.     

ACE Observations of the Bastille Day 2000 Interplanetary Disturbances

We present ACE observations for the six-day period encompassing the Bastille Day 2000 solar activity. A high level of transient activity at 1 AU, including ICME-driven shocks, magnetic clouds, shock-accelerated energetic particle populations, and solar energetic ions and electrons, are described. We present thermal ion composition signatures for ICMEs and magnetic clouds from which we derive electron temperatures at the source of the disturbances and we describe additional enhancements in some ion species that are clearly related to the transient source. We describe shock acceleration of 0.3–2.0 MeV nucl⁻¹ protons and minor ions and the relative inability of some of the shocks to accelerate significant energetic ion populations near 1 AU. We report the characteristics of < 20 MeV nucl⁻¹ solar energetic ions and < 0.32 MeV electrons and attempt to relate the release of energetic electrons to particular source regions.     

Ulysses observations of anti-sunward flow on Jovian polar cap field lines

We examine the energetic (MeV) ion data obtained by the Anisotropy Telescopes instrument of the Ulysses COSPIN package during two northern high-latitude excursions prior to closest approach to Jupiter, when the spacecraft left the region of trapped fluxes on closed magnetic field lines at lower latitudes and entered a region of open field lines which we term the polar cap. During these intervals the ion fluxes dropped by 4–5 orders of magnitude to low but very steady values, and the ion spectrum was consistent with the observation of an essentially unprocessed interplanetary population. Ion anisotropies observed at these distances (within 16R_J, of Jupiter) indicate that in the low-latitude, high-flux regions the flows are principally azimuthail and in the sense of corotation, with speeds which are within a factor of 2 (in either direction) of rigid corotation. In the higher latitude trapped flux regions the flows rotate to become northward as the polar cap is approached, while in the polar cap itself the flows rotate further to become anti-corotational (and anti-sunward in the morning sector) and northward. These results provide primary evidence of the existence of solar wind-driven flows in the outer Jovian magnetosphere mapping to the high-latitude ionosphere. Investigation of concurrent magnetic data for the signatures of related field-aligned currents reveals only weak signatures with an amplitude of order 1 nT. The implication is that the height-integrated Pedersen conductivity of the ionosphere to which the spacecraft was connected was low, of order 0.01 mho or less. We also examine the ion observations during the two northern high-latitude excursions previous to those discussed above. These data indicate that the spacecraft approached but did not penetrate the open flux region during these intervals.     

A near‐infrared/optical/X‐ray survey in the centre of σ Orionis

Because of the intense brightness of the OB‐type multiple star system σ Ori, the low‐mass stellar and substellar populations close to the centre of the very young σ Orionis cluster is poorly know. I present an IJHK_s survey in the cluster centre, able to detect from the massive early‐type stars down to cluster members below the deuterium burning mass limit. The near‐infrared and optical data have been complemented with X‐ray imaging. Ten objects have been found for the first time to display high‐energy emission. Previously known stars with clear spectroscopic youth indicators and/or X‐ray emission define a clear sequence in the I vs. I – K_s diagram. I have found six new candidate cluster members that follow this sequence. One of them, in the magnitude interval of the brown dwarfs in the cluster, displays X‐ray emission and a very red J – K_s colour, indicative of a disc. Other three low‐mass stars have excesses in the K_s band as well. The frequency of X‐ray emitters in the area is 80±20 %. The spatial density of stars is very high, of up to 1.6±0.1 arcmin^–2. There is no indication of lower abundance of substellar objects in the cluster centre. Finally, I also report two cluster stars with X‐ray emission located at only 8000–11000 AU to σ Ori AB, two sources with peculiar colours and an object with X‐ray emission and near‐infrared magnitudes similar to those of previously‐known substellar objects in the cluster. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Model-data comparisons for Titan's nightside ionosphere

Solar and X-ray radiation and energetic plasma from Saturn's magnetosphere interact with the upper atmosphere producing an ionosphere at Titan. The highly coupled ionosphere and upper atmosphere system mediates the interaction between Titan and the external environment. A model of Titan's nightside ionosphere will be described and the results compared with data from the Ion and Neutral Mass Spectrometer (INMS) and the Langmuir probe (LP) part of the Radio and Plasma Wave (RPWS) experiment for the T5 and T21 nightside encounters of the Cassini Orbiter with Titan. Electron impact ionization associated with the precipitation of magnetospheric electrons into the upper atmosphere is assumed to be the source of the nightside ionosphere, at least for altitudes above 1000 km. Magnetospheric electron fluxes measured by the Cassini electron spectrometer (CAPS ELS) are used as an input for the model. The model is used to interpret the observed composition and structure of the T5 and T21 ionospheres. The densities of many ion species (e.g., CH⁺₅ and C₂H⁺₅) measured during T5 exhibit temporal and/or spatial variations apparently associated with variations in the fluxes of energetic electrons that precipitate into the atmosphere from Saturn's magnetosphere.     

Temperature and solar zenith angle control of D-region positive ion chemistry

A numerical model is utilized to investigate the temperature (T) and solar zenith angle (χ) control of D-region positive ion chemistry between 75 and 90 km. It is assumed that NO^? is the precursor ion in a chain which involves three-body formation of the intermediary cluster ions NO⁺(H₂O)_m?1(X) (m = 1–3), where X can be N₂,O₂, H₂O, or CO₂, switching reactions which convert these weakly bound clusters to hydrates of NO⁺ and reaction of the third hydrate of NO⁺ with H₂O to initiate the chain to form H⁺(H₂O)_n (n = 1–7). Zonal mean and tidal temperatures from rocket observations and theory are synthesized to obtain the best available estimate of mean latitudinal, seasonal and local time variations of temperature in this height region. Relative compositions of NO⁺(H₂O)_m and H⁺(H₂O)_n are found to vary widely over the complete range of realistic conditions; however, the relative ion populations are entirely explicable in terms of the effects of χ and T on the relative life-times of the intermediary ion clusters with respect to recombination, switching and thermal decomposition. For instance, as χ increases (and electron production decreases) beyond 60° for a given temperature, the recombination times of the intermediate ion cluster species lengthen with respect to the formation time of the H⁺ water clusters, causing the relative H⁺ water cluster population to increase and thus raise the level where the cluster ion and NO⁺ concentrations are equal from about 85 km (normal midday) to 90 km. For a given χ the concentrations of NO⁺H₂O and H⁺(H₂O)₄ increase (decrease) for temperatures less than (greater than) 190 and 205 K, respectively. The transition occurs when the temperature becomes sufficiently high that the lifetimes of intermediary ion clusters with respect to thermal decomposition become less than their lifetimes with respect to H₂O switching (which ultimately leads to the third hydrate of NO⁺ and entry into the water chain). At this point, the formation time of H⁺(H₂O)₄ becomes long compared with its lifetime with respect to thermal decomposition and its relative concentration decreases also. Implications of these results with respect to studies of the D-region are discussed.     

Upper stratosphere negative ion composition measurements and inferred trace gas abundances

In situ composition measurements of atmospheric negative ions were made at 40.8 km altitude using a balloon-borne mass spectrometer with large mass range and improved mass resolution. The data obtained show marked differences compared to previous data obtained mostly around or below 33 km.It appears that these differences are mostly due to a higher atmospheric temperature, a lower nitric acid vapour abundance and a larger HSO₃-vapour abundance prevailing at the higher altitude.A particularly striking feature is the relatively large fractional abundance of HSO₃-containing cluster ions.Another interesting result is that nitric acid vapour abundances can be inferred from the negative ion composition data with better accuracy than is possible for lower altitudes. The reason being that collisional ion dissociation occurring during ion sampling is less disturbing.The inferred nitric acid vapour abundance for 40.8 km altitude is consistent with current 2-dimensional model calculations.     

Implications for atmospheric negative ion composition measurements of laboratory ECA studies of sulfuric acid cluster ions

Laboratory studies of electric field-induced collisional activation (ECA) of HSO₄⁻(H₂SO₄)_n cluster ions were made revealing fragmentation via two channels: HSO₄⁻ + H₂SO₄ and HSO₄⁻SO₃ + H₂O. This result suggests that mixed cluster ions of the type HSO₄⁻(H₂SO₄)₁ X with X having a mass of 81±1 amu which were recently detected in the stratosphere may not represent true ambient ions but are fragments formed by ECA of ambient HSO₄⁻(H₂SO₄)_n clusters during ion sampling into the mass spectrometer. Implications for stratospheric negative ion composition measurements are discussed.     

Radiation Products in Processed Ices Relevant to Edgeworth-Kuiper-Belt Objects

Near the inner edge of the Edgeworth-Kuiper Belt (EKB) are Pluto and Charon, which are known to have N₂- and H₂O-dominated surface ices, respectively. Such non-polar and polar ices, and perhaps mixtures of them, also may be present on other trans-Neptunian objects. Pluto, Charon, and all EKB objects reside in a weak, but constant UV-photon and energetic ion radiation environment that drives chemical reactions in their surface ices. Effects of photon and ion processing include changes in ice composition, volatility, spectra, and albedo, and these have been studied in a number of laboratories. This paper focuses on ice processing by ion irradiation and is aimed at understanding the volatiles, ions, and residues that may exist on outer solar system objects. We summarize radiation chemical products of N₂-rich and H₂O-rich ices containing CO or CH₄, including possible volatiles such as alcohols, acids, and bases. Less-volatile products that could accumulate on EKB objects are observed to form in the laboratory from acid-base reactions, reactions promoted by warming, or reactions due to radiation processing of a relatively pure ice (e.g., CO → C₃O₂). New IR spectra are reported for the 1–5 mu;m region, along with band strengths for the stronger features of carbon suboxide, carbonic acid, the ammonium and cyanate ions, polyoxymethylene, and ethylene glycol. These six materials are possible contributors to EKB surfaces, and will be of interest to observers and future missions.     

Sources and losses of energetic protons in Saturn's magnetosphere

We present Cassini data revealing that protons between a few keV and about 100 keV energy are not stably trapped in Saturn's inner magnetosphere. Instead these ions are present only for relatively short times following injections. Injected protons are lost principally because the neutral gas cloud converts these particles to energetic neutral atoms via charge exchange. At higher energies, in the MeV to GeV range, protons are stably trapped between the orbits of the principal moons because the proton cross-section for charge exchange is very small at such energies. These protons likely result from cosmic ray albedo neutron decay (CRAND) and are lost principally to interactions with satellite surfaces and ring particles during magnetospheric radial diffusion. A main result of this work is to show that the dominant energetic proton loss and source processes are a function of proton energy. Surface sputtering by keV ions is revisited based on the reduced ion intensities observed. Relatively speaking, MeV ion and electron weathering is most important closer to Saturn, e.g. at Janus and Mimas, whereas keV ion weathering is most important farther out, at Dione and Rhea.     

Monitoring of energy spectra of particle bursts in the plasma sheet and magnetosheath

Energetic ion (E ? 290 keV) and electron (E_e ? 220 keV) burst intensities were simultaneously monitored at various regions of the plasma sheet and magnetosheath by the CPME JHU/APL instruments on board the IMP-7 and 8 s/c during an extended period from day 250, 1975 to day 250, 1976 when the two spacecraft were closely trailing each other in crossing the geomagnetotail. The energy spectra of the energetic particle populations of different regions in the magnetotail were also computed and monitored simultaneously at the positions of the two spacecraft. The results indicate that the energetic particle intensities are higher and the energy spectra in general considerably softer inside the plasma sheet than the adjacent magnetosheath. The spectral index γ of a power law fit in the computed energy spectrum inside the plasma sheet occasionally exceeds γ > 10 for the ions and γ > 6 for the electrons. Furthermore simultaneous monitoring of particle intensities in the vicinity of the neutral sheet and the high latitude plasma sheet shows higher intensities in the former region. The observations suggest that the energetic particles escape to the magnetosheath from their source inside the plasma sheet by a rigidity dependent process. A dawn-dusk asymmetry in the particle acceleration and escape processes is implied in the observations and discussed in detail.     

Photometry of Galaxies in the Field of the Galaxy Cluster aBELL 1781

A method for determing the brightness and diameter of galaxies in a large field on Schmidt plates by automatic scanning with a microphotometer is described and applied to the ABELL cluster A 1781. The accuracy of this method is tested. The overall errors (r.m.s.) of brightness and diameter are 0.16 mag and 0″.44. The cluster A 1781 has been prooved to be a very poor cluster of about 10 members up to m_B ≈ 19^m.5.     

Mass spectrometric measurements of fractional ion abundances in the stratosphere—Positive ions

Measured fractional abundances for stratospheric positive ions are reported for the first time. The measurements which were obtained from balloon-borne ion mass spectrometer experiments relied on recent simulation studies of electric field induced cluster ion dissociation conducted at our laboratory.The ion abundance data provide strong support for identifications of the observed ions as H⁺(H₂O)_n and Hx⁺x_L(H₂O)_m proposed previously. Moreover, it is found that x most likely cannot be identified as NaOH or MgOH which implies that gaseous metal compounds do not exist in the middle stratosphere in significant abundances.Implications of the present findings for the composition and chemistry of stratospheric ions as well as for stratospheric aerosols are discussed.     

Observed composition of the ionosphere of Venus: Implications for the ionization peak and the maintenance of the nightside ionosphere

Across the nightside of Venus, daily measurements from the PV Orbiter Ion Mass Spectrometer often indicate an ionosphere of relatively abundant concentration, with a composition characteristic of the dayside ionosphere. Such conditions are interspersed by other days on which the ionosphere appears to largely “disappear” down to about 200 km, with ion concentrations at lower heights also much reduced. These characteristics, coupled with observations of strong day to night flows of O⁺ in the upper ionosphere, support arguments that ion transport from the dayside is important for the maintenance of the nightside ionosphere. Also, U.S. and Soviet observations of nightside energetic electron fluxes have prompted consideration of impact ionization as an additional nightside ion source. The details of the ion and neutral composition at low altitudes on the nightside provide an important input for further analysis of the maintenance process. In the range 140–160 km, strong concentrations of O₂⁺ and NO⁺ indicate that the ionization peak is at times composed of at least two prominent ion species. Nightside concentrations of O₂⁺ and NO⁺ as large as 10⁵ and 10⁴/cm³, respectively, appear to require sources in addition to that provided by transport. The most probable sources are considered briefly, and no satisfactory explanation is yet found for the observed NO⁺ concentrations. Further analysis beyond the scope of this paper is required to resolve this issue.     

The Orbits of Cluster Galaxy Populations as Evolutionary Constraints

We determine the mass profile of a synthetic cluster built from the combination of 59 nearby clusters observed in the ESO Nearby Abell Cluster Survey (ENACS). We use ellipticals and S0s as tracers of the cluster potential, and solve the Jeans equation assuming isotropic orbits. Such an assumption is justified by the analysis of the shape of the velocity distribution of ellipticals and S0s. We find that the cluster mass profile is consistent with the Navarro, Frenk and White(NFW) model. We use this cluster mass profile to search for equilibrium solutions for the other cluster galaxy populations: very bright ellipticals (M _R ≤–22+5 log h),early-type spirals (Sa-Sb), and late-type spirals and irregulars (Sbc-Ir), together with emission-line galaxies. We find equilibrium solutions for both the early- and the late-spirals, but not for the very bright ellipticals. The dynamics of very bright ellipticals is probably affected by dissipative processes which invalidate the use of the collisionless Jeans equation. The equilibrium solution found for the early-spirals implies them to move on nearly-isotropic orbits. Late-spirals are instead found to be on mildly radial orbits, with the radial anisotropy increasing outwards. We discuss the implications of these results for the evolutionary histories of the different populations of cluster galaxies. This revised version was published online in July 2006 with corrections to the Cover Date.