A new matrix for multiphase couplings in a membrane porous medium

The empirical Darcy's law of water transport in porous media, Fick's law of chemical diffusion, and Fourier's law of thermal transport have been widely used in geophysics/geochemistry for over 150 years. However, the strong couplings between water, temperature, and chemicals in a membrane porous medium have made these laws inapplicable and present a significant hurdle to the understanding of multiphase flow in such a material. Extensive experiments over the past century have observed chemical osmosis and thermal osmosis, but a model for understanding their underlying physicochemical basis has remained unavailable, because of the highly cross‐disciplinary and multiscale‐multiphase nature of the coupling. Based on the fundamental principles of nonequilibrium thermodynamics and mixture coupling theory, a rigorously theoretical and mathematical framework is proposed and a general model accounting for all of the coupled influences is developed. This leads to a simple and robust mathematical matrix for studying multiphase couplings in a membrane porous medium when all chemical components are electrically neutral.     

孔隙介质毛细滞回简化模型研究

土-水特征曲线的研究是非饱和孔隙介质研究的重要部分。完整的土-水特征曲线包括初始脱湿曲线（IDC）、主吸湿线(MWC)和主脱湿线(MDC)3部分。传统的土-水特征曲线实验需要花费较长的时间和精力。以文献中的试验数据为依据,对非饱和土土-水特征关系和岩石的汞注入抽出试验的滞回现象进行了深入研究,提出一个经验模型来模拟MDC曲线。如果已根据试验得到了孔隙介质的IDC和MWC,此模型只需要一个参数,即可得到增量形式的MDC。通过与试验结果相比较,验证了模型对MDC模拟的有效性。     

基于SPH方法的非饱和多孔介质相变耦合研究

在考虑相变的热能平衡方程和非饱和水分迁移质量控制方程的基础上,建立温度场-水分场的耦合模型,并采用一种无网格粒子算法（SPH）进行数值求解。其中,耦合方程中考虑了水流传热以及温度势对水流的直接驱动,在不考虑相变的情况下,该耦合模型可退化为常温下的水-热耦合模型,故可用于模拟冻融循环的相关问题。从求解热能平衡方程中的含冰量出发,实现解耦并对半无限单向冻结条件下介质内非稳态温度场和体积含水率分布场进行模拟,将耦合作用下的温度场与不耦合的解析解进行对比,反映出水分迁移对温度场存在较大影响。最后,求解了路基边坡在季节性周期温度边界下,温度场、水分场分布的演变规律,并评估了边坡阴阳面受热不均对水热两场分布的影响。计算结果基本能反映土冻结相变的实际物理过程,光滑粒子算法可以用于尝试解决冻土领域的其他相关问题。     

Time‐scale analysis in unsaturated porous media under external wave loads

Extreme waves caused by tsunamis and storm surges can lead to soil failures in the near‐shore region, which may have severe impact on coastal environments and communities. Multiphase flows in deformable porous media involve several coupled processes and multiple time scales, which are challenging for numerical simulations. The objective of this study is to investigate the roles of the various processes and their interactions in multiphase flows in unsaturated soils under external wave loading, via theoretical time‐scale analysis and numerical simulations. A coupled geomechanics–multiphase flow model based on conservation laws is used. Theoretical analysis based on coupled and decoupled models demonstrates that transient and steady‐state responses are governed by pore pressure diffusion and saturation front propagation, respectively, and that the two processes are essentially decoupled. Numerical simulations suggest that the compressibility of the pore fluids and the deformation of the soil skeleton are important when the transient responses of the media are of concern, while the steady‐state responses are not sensitive to these factors. The responses obtained from the fully coupled numerical simulations are explained by a simplified time‐scale analysis based on coupled and decoupled models. Copyright © 2010 John Wiley & Sons, Ltd.     

考虑毛细滞回效应的非饱和多孔介质渗流与变形耦合本构模型

在Wheeler本构模型框架的基础上,提出了一个水力与力学耦合的本构模型。该模型中的土-水特征曲线采用毛细滞回内变量模型,能够更好地描述水力历史变化下毛细滞回现象对非饱和多孔介质变形的影响,同时也可描述非饱和多孔介质变形对渗流的影响。非饱和土的强度不仅与吸力有关,而且受到饱和度的影响。相同的吸力下,土样经过吸湿和脱湿路径的饱和度不同,因此,非饱和土的强度也不同。此模型以体积含水率的塑性变化和体变的塑性变化为硬化参数,不仅能描述基质吸力对非饱和土的强化作用,而且考虑了饱和度对强度及变形的影响。试验结果与模型预测基本吻合,证明该模型能够模拟非饱和土的主要特性。为了简化,此模型是在各向同性荷载下推得的,有待于推广到一般的应力状态     

Micromechanics of saturated and unsaturated porous media

The homogenization method is used to determine the formulation of the behaviour of both saturated and unsaturated porous media. This approach makes it possible to assess the validity of the effective stress concept as a function of the properties of the porous media at the microscopic scale. Furthermore, the influence of the morphologies of the solid and fluid phases on the macroscopic behaviour is studied. The strain induced by drying is examined as a function of the morphological properties. Copyright © 2002 John Wiley & Sons, Ltd.     

Weak discontinuity in porous media: an enriched EFG method for fully coupled layered porous media

In this paper, a series of multimaterial benchmark problems in saturated and partially saturated two‐phase and three‐phase deforming porous media are addressed. To solve the process of fluid flow in partially saturated porous media, a fully coupled three‐phase formulation is developed on the basis of available experimental relations for updating saturation and permeabilities during the analysis. The well‐known element free Galerkin mesh‐free method is adopted. The partition of unity property of MLS shape functions allows for the field variables to be extrinsically enriched by appropriate functions that introduce existing discontinuities in the solution field. Enrichment of the main unknowns including solid displacement, water phase pressure, and gas phase pressure are accounted for, and a suitable enrichment strategy for different discontinuity types are discussed. In the case of weak discontinuity, the enrichment technique previously used by Krongauz and Belytschko [Int. J. Numer. Meth. Engng., 1998; 41:1215–1233] is selected. As these functions possess discontinuity in their first derivatives, they can be used for modeling material interfaces, generating only minor oscillations in derivative fields (strain and pressure gradients for multiphase porous media), as opposed to unenriched and constrained mesh‐free methods. Different problems of multimaterial poro‐elasticity including fully saturated, partially saturated one, and two‐phase flows under the assumption of fully coupled extended formulation of Biot are examined. As a further development, problems involved with both material interface and impermeable discontinuities, where no fluid exchange is permitted across the discontinuity, are considered and numerically discussed. Copyright © 2014 John Wiley & Sons, Ltd.     

Analysis of the solid phase stress tensor in multiphase porous media

Conservation equations for mass, momentum, energy, and entropy are formulated for the phases and interfaces of a three‐phase system consisting of a solid and two immiscible fluids. The microscale equations are averaged to the macroscale by integration over a representative elementary volume. Thermodynamic statements for each of the phases and interface entities are also formulated at the microscale and then averaged to the macroscale. This departure from most uses of thermodynamics in macroscale analysis ensures consistency between models and parameters at the two scales. The expressions for the macroscale rates of change of internal energy are obtained by differentiating the derived forms for energy and making use of averaging theorems. These thermodynamic expressions, along with the conservation equations, serve as constraints on the entropy inequality. A linearization of the resulting equations is employed to investigate the theoretical origins of the Biot coefficient that relates the hydrostatic part of the total stress tensor to the normal force applied at the solid surface by the pore fluids. The results here are placed in the context of other formulations and expressions that appear in the literature. Copyright © 2006 John Wiley & Sons, Ltd.     

Transient bifurcation condition of partially saturated porous media at finite strain

Bifurcation of unsaturated soils into a localized shear band is a ubiquitous failure mode of partially saturated soils. The density and degree of saturation have major impacts on the inception of localized deformations in unsaturated soils. Unsaturated fluid flow may dramatically change the density and degree of fluid saturation of unsaturated soils. Therefore, the unsaturated fluid flow is a potential trigger for shear banding in such materials. In this paper, we derive a simplified bifurcation condition of localized deformation in unsaturated soils under the local transient condition at finite strain. This transient bifurcation condition is implemented into a nonlinear finite element code to study the inception of localized deformation in unsaturated soil specimens. Numerical simulations are conducted to study the impact of soil fabrics of density, a ‘bonding’ variable, and intrinsic permeability on the inception of localized failures via the transient bifurcation criterion. Mesh sensitivity analysis is performed to demonstrate the viscosity effect of unsaturated fluid flow on the localized deformation. Numerical simulations demonstrate that the transient bifurcation condition can detect the localized deformation triggered by the internal unsaturated fluid flow process in unsaturated soils. Copyright © 2016 John Wiley & Sons, Ltd.     

多孔介质非饱和导水率预测的分形模型

多孔介质非饱和导水率是地下水污染预测与评价的重要参数。根据分形几何的基本原理和方法,推导出了与Campbell经验公式在形式上完全一致的多孔介质非饱和导水率的预测公式。公式中的幂指数为介质孔隙分维和随机行走分维的函数,分别体现了多孔介质的静态性质与动态性质对其中水分运动的影响,但静态性质的影响是主要的,即导水率主要受多孔介质的结构控制。根据文献中报道的大量数据,利用笔者推导的预测公式计算得到的幂指数的统计值与试验测定的幂指数的统计值基本一致,说明推导的理论公式预测多孔介质非饱和导水率是较为可靠的。     

近饱和条件下非饱和多孔介质渗流过程的数值分析

在非饱和多孔介质渗流分析中,近饱和条件下物理模型与数值模型之间的差异会导致数值不稳定问题。为解决这一问题,并保证模拟结果的可靠性,提出了3种方法,并在有限元分析程序U-DYSAC2中分别进行了程序代码的实施。通过数值试验与试验数据的比较,证实了在近饱和条件下土-水特征曲线和水力传导函数的高非线性可引起数值收敛性、稳定性和精度问题,而且在不同条件下含水率和基质吸力的预测结果差异明显。在3种方法中,修正的Van Genuchten模型（MVGM）方法对含水率的预测较为准确,而Line方法对基质吸力的预测较为合理。因此,解决在分析近饱和条件下非饱和多孔介质渗流问题时,为获得接近真实的模拟结果,采用合适的数值方法进行预测是非常关键的。     

Hydro‐mechanical modeling of cohesive crack propagation in multiphase porous media using the extended finite element method

In this paper, a numerical model is developed for the fully coupled hydro‐mechanical analysis of deformable, progressively fracturing porous media interacting with the flow of two immiscible, compressible wetting and non‐wetting pore fluids, in which the coupling between various processes is taken into account. The governing equations involving the coupled solid skeleton deformation and two‐phase fluid flow in partially saturated porous media including cohesive cracks are derived within the framework of the generalized Biot theory. The fluid flow within the crack is simulated using the Darcy law in which the permeability variation with porosity because of the cracking of the solid skeleton is accounted. The cohesive crack model is integrated into the numerical modeling by means of which the nonlinear fracture processes occurring along the fracture process zone are simulated. The solid phase displacement, the wetting phase pressure and the capillary pressure are taken as the primary variables of the three‐phase formulation. The other variables are incorporated into the model via the experimentally determined functions, which specify the relationship between the hydraulic properties of the fracturing porous medium, that is saturation, permeability and capillary pressure. The spatial discretization is implemented by employing the extended finite element method, and the time domain discretization is performed using the generalized Newmark scheme to derive the final system of fully coupled nonlinear equations of the hydro‐mechanical problem. It is illustrated that by allowing for the interaction between various processes, that is the solid skeleton deformation, the wetting and the non‐wetting pore fluid flow and the cohesive crack propagation, the effect of the presence of the geomechanical discontinuity can be completely captured. Copyright © 2012 John Wiley & Sons, Ltd.     

单层非饱和多孔介质一维瞬态响应半解析解

基于Zienkiewicz提出的非饱和多孔介质波动理论,考虑两相流体和固体颗粒的压缩性以及惯性、黏滞和机械耦合作用,采用半解析的方法获得了一类典型边界条件下单层非饱和多孔介质一维瞬态响应解。首先推导出无量纲化后以位移表示的控制方程,并将其写成矩阵形式;然后,将边界条件齐次化,求解控制方程所对应的特征值问题,得到了满足齐次边界条件的特征值和相对应的特征函数。根据变异系数法并利用特征函数的正交性,得到了一系列仅黏滞耦合的关于时间的二阶常微分方程及相应的初始条件。在此基础上,运用精细时程积分法给出了常微分方程组的数值解。最后,通过若干算例验证了结果的正确性并探讨了单层非饱和多孔介质一维瞬态动力响应的特点。该方法可推广应用于其他典型的边界条件。     

A random solid‐porous model to simulate the retention curves of soils

This paper describes a random solid‐porous model capable of simulating the structure of porous materials. To this purpose, the grain and pore size distributions as well as the void ratio of the material are required. Solids and pores are distributed at random in the model's space according to a size strategy. Herein, the model is used to simulate the retention curves of soils. The Laplace equation is used to determine the size of the pores able to saturate or dry during a wetting or drying process, respectively. The continuous path principle is used to define those elements that effectively saturate or dry during these processes. With this procedure, it is possible to simulate the main retention curves as well as the scanning curves during wetting–drying cycles. Some experimental results reported in the international literature have been used to test the model. This model can be enhanced to study the mechanical behavior of unsaturated soils. Copyright © 2012 John Wiley & Sons, Ltd.     

Analytical solutions for advective–dispersive solute transport in double‐layered finite porous media

Analytical solutions for advection and dispersion of a conservative solute in a one‐dimensional double‐layered finite porous media are presented. The solutions are applicable to five scenarios that have various combinations of fixed concentration, fixed flux and zero concentration gradient conditions at the inlet and outlet boundaries that provide a wide number of options. Arbitrary initial solute concentration distributions throughout the media can be considered via explicit formulations or numerical integration. The analytical solutions presented have been verified against numerical solutions from a finite‐element‐based approach and an existing closed‐form solution for double‐layered media with an excellent correlation being found in both cases. A practical application pertaining to advective transport induced by consolidation of underlying sediment layers on contaminant movement within a capped contaminated sediment system is presented. Comparison of the calculated concentrations and fluxes with alternative approaches clearly illustrates the need to consider advection processes. Consideration of the different features of contaminant transport due to varying pore‐water velocity fields in primary consolidation and secondary consolidation stages is achieved via the use of non‐uniform initial concentration distributions within the proposed analytical solutions. Copyright © 2010 John Wiley & Sons, Ltd.     

A model for moisture and heat flow in fractured unsaturated porous media

The present study investigates propagation of a cohesive crack in non‐isothermal unsaturated porous medium under mode I conditions. Basic points of skeleton deformation, moisture, and heat transfer for unsaturated porous medium are presented. Boundary conditions on the crack surface that consist of mechanical interaction of the crack and the porous medium, water, and heat flows through the crack are taken into consideration. For spatial discretization, the extended finite element method is used. This method uses enriched shape functions in addition to ordinary shape functions for approximation of displacement, pressure, and temperature fields. The Heaviside step function and the distance function are exploited as enrichment functions for representing the crack surfaces displacement and the discontinuous vertical gradients of the pressure and temperature fields along the crack, respectively. For temporal discretization, backward finite difference scheme is applied. Problems solved from the literature show the validity of the model as well as the dependency of structural response on the material properties and loading. Copyright © 2016 John Wiley & Sons, Ltd.     

非饱和土广义有效应力原理

综述了非饱和土有效应力的沿革,并就非饱和土有效应力的研究和发展中存在的问题进行了讨论。基于多相孔隙介质理论推导得到的变形功的表达式,提出了非饱和土广义有效应力原理。该原理认为,由非饱和土中的单应力变量的有效应力或双应力变量理论很难唯一地确定非饱和土的变形和强度。广义有效应力原理实质上就是要综合考虑影响非饱和土变形和强度的三种广义应力以及与其对偶的广义变形,给出考虑因素更为全面、理论基础更为坚实的广义有效应力原理。它为非饱和土基本性质的研究和本构方程的建立奠定了坚实而科学的理论基础。     

多孔介质固液耦合相似材料的研制

为研究地下结构与富水多孔岩体的相互作用问题,根据模型试验相似理论,研制出了一种多孔介质固-液耦合相似材料,该材料由中粗砂、水泥、透水混凝土增强剂合水按一定配比均匀拌和压制而成。运用正交试验设计原理进行配比试验,制作模型小试件,进行了单轴抗压强度、渗透系数、重度、弹性模量、泊松比等参数测试,找出了相似材料各成分对配比试件的影响特征,可根据需要在物理模拟试验中选取不同配比。该配方力学指标稳定,满足一次性浇筑大尺寸模型试件的要求,适用于进行结构与围岩体耦合失效破坏模式的大型物理模拟试验,为富水条件下地下结构风险评估提供了相似试验材料     

A three‐phase model for unsaturated soils

A comprehensive framework to define the constitutive behaviour of unsaturated soils is developed within the theory of mixtures applied to three‐phase porous media. Each of the three phases is endowed with its own strain and stress. Elastic and elastic–plastic constitutive equations are developed. Particular emphasis is laid on the interactions between the phases both in the elastic and plastic regimes. Nevertheless, the clear structure of the constitutive equations requires a minimal number of material parameters. Their identification is provided: in particular, it incorporates directly the soil–water characteristic curve. Crucial to the formulation is an appropriate definition of the effective stress. The coupled influence of this effective stress and of suction makes it possible to describe qualitatively many of the characteristic features observed in experiments, e.g. for normally consolidated soils, a plastic behaviour up to air entry followed by an elastic behaviour at increasing suctions, and, on the way back, an elastic behaviour, unless compression is applied in which case plastic collapse occurs. Copyright © 2000 John Wiley & Sons, Ltd.