Deformation mechanisms in experimentally and naturally deformed amphiboles

Experimental deformation of an igneous hornblendite at 600–750°C, 10 kbars confining pressure and a strain rate of 10 ^?5 sec^?1 results in kink bands whose normals cluster about [001] and axes of external rotation subparallel to [010]. This is consistent with glide on the system T = (100), t = [001]. At temperatures of 800°C to the breakdown temperature of the hornblende, external rotation axes spread along the (100) plane although kink band boundary poles remain subparallel to [001]. This indicates glide on the (100) plane in variable directions. Analysis of bend zones in a naturally deformed actinolite indicates glide on the (100), [001] system. Mechanical (101) twinning was not observed in any of the samples, and we suggest that in these amphiboles the critical resolved shear stress for glide is lower than that for twinning.     

Rare earth elements in garnets and clinopyroxenes from garnet lherzolite nodules in kimberlites

Six pairs of coexisting garnets and clinopyroxenes were separated from the sheared and granular garnet lherzolite nodules in kimberlites and analyzed for rare earth elements (REE). The sheared and granular nodules can be distinguished in terms of REE pattern of both clinopyroxene and garnet. However, there are no significant differences in REE partitioning between clinopyroxene and garnet, indicating that the partitioning may be insensitive toP, T and composition. REE partition coefficients between garnet and liquid were estimated by using clinopyroxene-liquid partition coefficients found in the literature and clinopyroxene-garnet partitioning reported here. The estimated values agree with those reported by Philpotts et al. (1972). The estimated whole-rock REE pattern for the sheared nodules is similar to a chondritic pattern suggesting that the sheared nodules appear to be close to the primary mantle material. The REE data suggest that the granular nodules were originally garnet-free assemblages equilibrated with kimberlitic or nepheline-melilite basalt-like liquid, and later recrystallized as a garnet lherzolite assemblage.     

位错理论在西安地面沉降模拟中的应用

介绍了用位错理论研究地面变形的基本理论和方法.根据西安地面变形的地质模型,利用位错理论对西安市11条地裂缝活动与地面垂直变形的综合影响进行了数值模拟计算,并将计算结果与精密水准实测结果进行了对比分析.结果表明:位错理论模型数值模拟结果与实测的水准结果在空间分布具有很好的一致性.从理论上分析了西安地区的地面地面沉降除与抽取地下水,地面负荷等有关外,还与西安地区的地质构造特征有密切的关系.     

Deformation-induced microstructures in soils affected by mass movements

The soil deformation produced by mass movements gives rise to specific microscopic features. The study of some markers of deformation, such as the orientation of rigid clasts and the morphology of fine-grained intercalations, indicates that, in most cases, mass movements can be related to simple shear. The development of these features varies according mainly to the type of mass movement (solifluction, debris flow or earth slide). Different factors play a significant role in their formation: intrinsic soil characteristics such as the grain size of the matrix, water content and matrix/element viscosity ratios, and external factors such as the intensity and homogeneity of deformation. A careful study of the microscopic features leads to a better understanding of the dynamics of mass deposits.     

Exsolution microstructures in titanomagnetites and their magnetic significance

A survey, carried out using transmission electron microscopy, of exsolution-derived microstructures developed in titanomagnetites is presented. Microstructures, probably produced by spinodal decomposition, consist of a three-dimensional lamellar framework of ulvospinel, separating magnetite-enriched blocks. In coarser textures the magnetite-enriched regions have a plate morphology, and the ulvospinel-enriched lamellae develop secondary exsolution textures. The implications of exsolution for the magnetic properties of titanomagnetites are discussed. The coarsening of exsolution textures will cause the blocking temperature of the magnetite-enriched regions to increase with time. The development of magnetite-enriched plates may alter the magnetic properties of the titanomagnetite, as may the stress associated with some of the small scale, coherent microstructures.     

Metal/silicate fractionation in the solar system

Fractionation between the metal and silicate components of objects in the inner solar system has long been recognized as a necessity in order to explain the observed density variations of the terrestrial planets and the H-group, L-group dichotomy of the ordinary chondrites. This paper discusses the densities of the terrestrial planets in light of current physical and chemical models of processes in the solar nebula. It is shown that the observed density trends in the inner solar system need not be the result of special fractionation processes, and that the densities of the planets may be direct results of simultaneous application of both physical and chemical restraints on the structure of the nebula, most notably the variation of temperature with heliocentric distance. The density of Mercury is easily attributed to accretion at temperatures so high that MgSiO₃ is only partially retained but Fe metal is condensed. The densities of the other terrestrial planets are shown to be due to different degrees of retention of S, O and H as FeS, FeO and hydrous silicates produced in chemical equilibrium between condensates and solar-composition gases. It is proposed that Mercury and Venus Have cores of Fe⁰, Earth has a core of Fe⁰ containing substantial amounts of FeS, and Mars has a quite small core of FeS with more FeO in its mantle than in Earth's. Geophysical and geochemical consequences of these conclusions are discussed.     

Co-existing fluid and silicate inclusions in mantle diamond

We document the compositions of co-existing silicate macro-inclusions and fluid micro-inclusions in the fibrous coats of eight coated diamonds from the Panda kimberlite (Canada). The mineral inclusions in the diamond coats come from either the peridotite suite (Cr-pyrope, orthopyroxene, olivine and Cr-diopside) or the eclogite suite (omphacite). Therefore, fibrous diamonds grow in the same paragenetic environments as octahedral diamonds. The inclusions document a more fertile source composition (lower Mg# and higher CaO) than for equivalent phases in octahedral diamonds from Panda and worldwide. However, moderate to high Cr₂O₃ contents in garnet and clinopyroxene inclusions suggest that this apparent fertility is due to a secondary process. Geothermometry of the silicate inclusions yields low equilibration temperatures of 930 to 1010 °C. The co-existing fluid micro-inclusions are dominated by H₂O, carbonate and KCl. Fluid inclusions in both the peridotitic and eclogitic samples fall along linear arrays between Fe–Ca–Mg carbonate and KCl. Inclusions in the one eclogitic sample also contain quartz. We suggest that the diamonds have trapped both metasomatised minerals and the metasomatic fluid, and so provide a snap shot of a metasomatic event in the mantle.     

On plane waves in thermo-viscoelastic solids deformed by magnetic fields

Summary In the present paper,Maxwell's electromagnetic equations together with the equation of motion of two types of viscoelastic solids have been used to deal with the propagation of magneto-thermoviscoelastic plane waves.     

Trace-element zoning patterns in porphyroblastic garnets in low-T eclogites: Parameter optimization of the diffusion-limited REE-uptake model

Compositional zoning patterns of the major elements and REEs in prograde-zoned garnets whose Mg/(Mg + Fe) atomic ratios increase rimward have been widely used to understand the metamorphic P–T–t trajectories, and the diffusion-limited REE-uptake model is a promising way to interpret their growth rates and the REE diffusion kinetics in the low-temperature eclogite. In order to elucidate their growth kinetics with Skora et al.'s (2006) diffusion-limited REE uptake model for prograde-zoned garnets, we examine the trace-element zoning patterns of two prograde-zoned porphyroblastic garnets (~6 mm in size) in low-temperature eclogites from two different localities. Core-to-rim trace-element profiles in a garnet (prp_5–9alm_61–67sps_1–3grs_24–30) of a glaucophane-bearing epidote eclogite of Syros (Cyclades, Greece) are characterized by the presence of Y + HREE peaks in the mantle, which might be attributed to a continuous breakdown of the titanite to form rutile during the garnet growth. In contrast, those in a garnet (prp_4–7alm_61–68sps_3–10grs_23–24) extracted from a lawsonite-eclogite of the South Motagua Mélange (SMM) (Guatemala) have prominent central peaks of Y + HREEs. Although the REE profiles of both the garnets can be explained by the diffusion-limited uptake, their Mn profiles suggest that their growth-rate laws are different: i.e., diffusion-controlled (Syros) and interface-controlled (SMM). Prior to the model application, we optimize the number of the parameters as the garnet grows with the interface-controlled processes based on the growth Péclet number. In particular, we propose the ratio of the REE diffusivity in the eclogitic matrix to the garnet growth rate as the new parameter. Visualizing the values of the new parameters allows to readily understand the relationship between the REE profiles and the REE-diffusion/garnet-growth kinetics in low-T eclogite. Our model refinement leads to the simple quantitative characterization of core-to-rim REE profiles in garnet in low-temperature eclogites.     

Compositions of Jurassic detrital garnets in Hefei Basin and its implication to provenance reconstruction and stratigraphic correlation

The compositions of Jurassic detrital garnets in Hefei Basin are complicated. Contents of the end member are from zero to 43% for pyrope, from less than 1% to 50% for grossular, from 2% to 92% for almandine, and from zero to 88% for spessartine. Part of relatively pyrope-rich detrital garnets might be originated from high pressure-ultrahigh pressure metamorphic rocks. Contents of spessartine in garnets from the present metamorphic rocks of the Dabie Mountains, including the greenschists of Foziling Group, are lower than 30%. Therefore, they would not be the source of the spessartine-rich detrital garnets in the Jurassic sedimentary rocks of the Hefei Basin. Chemical compositions of the Jurassic detrital garnets in the Hefei Basin have some characteristics in the distribution with strata, which can be applied to study of the sedimentary filling sequence and stratigraphic correlation.     

Chemical fractionation in the silicate vapor atmosphere of the Earth

Despite its importance to questions of lunar origin, the chemical composition of the Moon is not precisely known. In recent years, however, the isotopic composition of lunar samples has been determined to high precision and found to be indistinguishable from the terrestrial mantle despite widespread isotopic heterogeneity in the Solar System. In the context of the giant-impact hypothesis, this level of isotopic homogeneity can evolve if the proto-lunar disk and post-impact Earth undergo turbulent mixing into a single uniform reservoir while the system is extensively molten and partially vaporized. In the absence of liquid–vapor separation, such a model leads to the lunar inheritance of the chemical composition of the terrestrial magma ocean. Hence, the turbulent mixing model raises the question of how chemical differences arose between the silicate Earth and Moon. Here we explore the consequences of liquid–vapor separation in one of the settings relevant to the lunar composition: the silicate vapor atmosphere of the post-giant-impact Earth. We use a model atmosphere to quantify the extent to which rainout can generate chemical differences by enriching the upper atmosphere in the vapor, and show that plausible parameters can generate the postulated enhancement in the FeO/MgO ratio of the silicate Moon relative to the Earth's mantle. Moreover, we show that liquid–vapor separation also generates measurable mass-dependent isotopic offsets between the silicate Earth and Moon and that precise silicon isotope measurements can be used to constrain the degree of chemical fractionation during this earliest period of lunar history. An approach of this kind has the potential to resolve long-standing questions on the lunar chemical composition.     

Contrasting zoning profiles in high-grade garnets: evidence for the allochthonous nature of a Grenville province terrane

In the central part of the Grenville Province, Proterozoic metasediments of the Réservoir Cabonga Terrane arc underlain by gently dipping Archean migmatites. A major mylonite zone, located within the migmatites, is the base of a large thrust sheet made up of the Réservoir Cabonga Terrane and a migmatitic sole. Garnets from meta-aluminous assemblages in Proterozoic metasediments, mylonites and migmatites display contrasting types of Ca zoning patterns. Garnets with Ca-rich cores are found along the western edge of the Réservoir Cabonga Terrane, whereas garnets with flat Ca profiles are found in the remaining Proterozoic metapelites, in the mylonites and in the Archean migmatites. Considering samples in which an infinite reservoir of Ca ions is warranted by abundant plagioclase in the matrix, pressures well in excess of 1200 MPa, at temperatures between 700° and 800°C are indicated for a metamorphic event recorded in the cores of garnets from the western edge of the Réservoir Cabonga Terrane. The inner rim of garnet records pressures of around 1000 MPa for the same temperature range. In homogeneous garnets, a single P-T set, around 800 MPa and 750°C, is recorded in the migmatites. Some of the mylonites initiate their recrystallization under relatively high pressures, which is continued during decompression, and record the lowest P-T values. These metamorphic signatures suggest that the Proterozoic metapelites were already metamorphosed under relatively high pressure when emplaced on to Archean migmatites and that the entire area was subsequently subjected to metamorphism at a lower pressure.     

Zircon saturation model in silicate melts:a review and update

Zircon stability in silicate melts—which can be quantitatively constrained by laboratory measurements of zircon saturation—is important for understanding the evolution of magma.Although the original zircon saturation model proposed by Watson and Harrison(Earth Planet Sci Lett 64(2):295-304,1983) is widely cited and has been updated recently,the three main models currently in use may generate large uncertainties due to extrapolation beyond their respective calibrated ranges.This paper reviews and updates zircon saturation models developed with temperature and compositional parameters.All available data on zircon saturation ranging in composition from mafic to silicic(and/or peralkaline to peraluminous)at temperatures from 750 to 1400℃ were collected to develop two refined models(1 and 2) that may be applied to the wider range of compositions.Model 1 is given by lnC_(Zr)(melt)=(14.297±0.308)+(0.964 ± 0.066).M-(11113±374)/r,and model 2 given by lnC_(Zr)(melt)=(18.99±0.423)-(1.069±0.102)·lnG-(12288±593)/T,where C_(Zr)(melt) is the Zr concentration of the melt in ppm and parameters M [=(Na+K+2 Ca)/(Al·Si)](cation ratios) and G [=(3·Al_2 O_3+SiO_2)/(Na_(2-)O+K_2 O+CaO+MgO+FeO)](molar proportions)represent the melt composition.The errors are at one sigma,and T is the temperature in Kelvin.Before applying these models to natural rocks,it is necessary to ensure that the zircon used to date is crystallized from the host magmatic rock.Assessment of the application of both new and old models to natural rocks suggests that model 1 may be the best for magmatic temperature estimates of metaluminous to peraluminous rocks and that model 2 may be the best for estimating magmatic temperatures of alkaline to peralkaline rocks.     

High-P/T experimental studies and water in the silicate mantle

Water (or H) in the silicate mantle is a key element in influencing Earth’s climate, habitability, geochemical evolution, geophysical properties and geodynamical processes, and has received increasing attention in the past decades. Experimental work under simulated high-pressure and high-temperature conditions is a powerful tool in characterizing the species, distribution, storage capacity and various physicochemical impacts of water in the mantle. In recent years, significant approaches have been acquired about some key physical, chemical and dynamical properties of water in the mantle and their various impacts, as a result of extensive studies by high-pressure and temperature experiments, and our knowledge of Earth’s water cycle, especially the deep water cycle, on both temporal and spatial scales has been greatly enhanced. In this paper, a brief review based mainly on experimental studies is presented concerning the current understanding and some recent approaches of water in the silicate mantle, such as the possible origin, amount, storage and the effect on mantle properties.     

Dynamics of phosphorus in sediments of a naturally acidic lake

The mechanisms which controls the fixation and/or release of P in sediment of an extremely acidic lake（pH = 2.0 to 3.0） and its response to the influence of eutrophic urban waste water were investigated.The results,in the chemical composition,in the mineralogy of the sediment and in the material as obtained from sediment traps,show that the lake sediments are mainly volcanic material reflecting volcanic features of the basin.The sedimentation rate calculated for the lake(2.5×10^-2 mg m^-2 day^-1) was higher than that observed in other similar glacial lakes in both Andean Patagonia and also elsewhere in the world.The Total Phosphorus concentration in sediments was higher than figures reported by other authors for mining acid lakes,and the main fraction of P was found associated with organic matter.There was no control by Fe or Al on P,because both are in solution at pH < 3.0.It was concluded that changes in the natural input of nutrients（derivatives of Copahue volcano fluid,the discharge of sewage,or basin run-off） are responsible for a high concentration of SRP and N-NH₄⁺ in the lake.Laboratory experiments showed that sediments have no ability to retain phosphorus and a continuous release of P from the sediments into the water column was observed.The assays where the pH was artificially increased showed that the P still remains in solution until at least pH 7.0.It was concluded that changes in the natural input of nutrients due to:1) the volcanic fluids,2) the increase in sewage charges,or 3) surface runoff upstream,maintain a high trophic state with high concentrations of dissolved P and N-NH₄⁺,although the threshold of neutral pH in the lake is exceeded.This study will enable a better understanding about of the mechanism of release/fixation of phosphorus in acidic sediments in order to assist in making decisions regarding the conservation and management of this natural environment.     

互层胶结土中正断层地震地表破裂位错特征研究

为了解决采用Trimble GX 3D地面激光三维扫描仪分析互层胶结土中正断层地震地表破裂位错特征时,未有效模拟地表垂直和水平位移的基本特征,获取的地表破裂位错特征结果不准确的问题。提出新的互层胶结土中正断层地震地表破裂位错特征研究方法,先构建地震地表弹性位错模型,分析互层胶结土正断层的地表三维断裂特征,得到地表在受到走滑、逆冲和张开错动导致的地表错位变化情况;再通过正断层地震地表破裂离心机试验,获得互层胶结土中正断层地震地表破裂位错特征。试验结果说明,所提方法可有效分析互层胶结土中正断层地震地表破裂位错特征,且破裂点在土体模型中部和中下部的裂缝深度分别为22.4 m和33.4 m,裂缝上的破裂点处于土体模型的中下部时,裂缝的深度越深。     

Plagioclase weathering in the groundwater system of a sandy,silicate aquifer

The weathering rate of plagioclase was estimated in the groundwater system of a sandy, silicate aquifer formed after the Wisconsin Glacial Stage. The study area is an isthmus lying between Crystal and Big Muskellunge Lakes in northern Wisconsin, USA. Plagioclase occupies 3% of the quartz and K‐feldspar dominated sediments. Groundwater in the study area is recharged in part by precipitation through the isthmus soils and in part by seepage from Crystal Lake, which is of low ionic strength and chemically in steady state. Water analysis revealed that the chemistry of groundwater recharged from Crystal Lake is regulated by mineral dissolution reactions. The rate constant for plagioclase was estimated using mass balances for sodium concentrations along a groundwater flowline from Crystal Lake. For this calculation, various kinds of hydrological/mineralogical information were used: groundwater flow path from oxygen isotope analysis, groundwater travel times from flow modelling, mineral composition from microprobe analysis and surface area of minerals from BET (Brunauer–Emmett–Teller) analysis. The overall range of the estimation was less than an order of magnitude (3·5 × 10^?16 to 3·4 × 10^?15 mol/m²/s). The result is up to three orders of magnitude slower than the previous field estimates, which applied geometric methods in measuring mineral surface areas. However, this result is somewhat higher than the estimates reported by other BET area‐based studies, which were undertaken on soil profiles having different hydrological conditions. This rate difference is interpreted as a result of higher mineral reactivity owing to younger sediment age. The rate difference is smaller when this result is compared with the estimates from the soils of similar age, indicating that the differences in hydrological condition are not sufficient to explain the weathering rate discrepancy between the laboratory and field studies, which is up to five orders of magnitude. Copyright © 2002 John Wiley & Sons, Ltd.