The physico-chemical conditions of Turkwel Gorge Reservoir, a new man made lake in Northern Kenya

Variations in some physical, chemical, and nutrient conditions were investigated at Turkwel Gorge Reservoir and its inflowing river, Suam between 1994 and 1995. Seasonal changes in inflow volume had the greatest impact on the reservoir and river conditions investigated. A wide fluctuation in inflow volume combined with a regulated outflow independent of season resulted in a draw down of over 10 m in each year. Flood inflows during the wet season resulted in the lowest values of Secchi depth (range, 0.09–2.16 m), electrical conductivity (EC, range = 140–200 mS cm⁻¹) and total alkalinity (TA, range = 75–111 mg l⁻¹) while the highest values were measured during the dry season. A functional relation between EC and TA (TA = 0.529 mg l⁻¹, EC: R² = 0.876) suggests a predominance of carbonates among the anions. Vertical profiles of temperature and dissolved oxygen (DO) revealed that the reservoir is monomictic with a wide variation in the depth of the daily mixed layer. High values of pH (range = 6.7–8.9) and DO (range = 4.9–9.2 mg l⁻¹) were associated with periods of peak phytoplankton photosynthesis while the lowest values followed reservoir mixing. Peak total nitrogen (TN, range = 119–526 μg l⁻¹) and total phosphorus (TP, range = 8.9–71.6 μg l⁻¹) levels during the wet season resulted from increased river loading. Values of dissolved reactive silica (DRS, range = 0.41–9.77 mg l⁻¹) showed a wet season decline which was related to diatom depletion during the wet season. Annual reservoir areal loading rates of 27.38, 10.90 and 408.5 mg m⁻² were computed for TN, TP and DRS respectively based on estimates of inflowing river loads in 1994.

At the inflowing river Suam, low levels of EC (range = 107–210 μS cm⁻¹) and TA (range = 62–125 mg l⁻¹) occurred during the wet season while the highest levels occurred shortly before the river dried up. The first flood water at the resumption of river inflow in March was characterized by very low levels of DO (range = 1.8–8.2 mg l⁻¹) and high levels of TN (range = 205–3354 μg l⁻¹) and TP (102–1259 μg l⁻¹). River pII (6.9–7.7) and DRs (range = 9.01–19.93 mg l⁻¹) varied irregularly throughout the year.     

In situ cosmogenic Be in olivines and pyroxenes

This study proposes an efficient new cleaning procedure for measuring in situ cosmogenic ¹⁰Be in olivines and pyroxenes. This chemical routine is specially designed to decontaminate the abundant meteoric ¹⁰Be from these minerals. The method was tested on mafic minerals from basaltic flows of Mt. Etna volcano and from Hawaiian flows and moraines. A sequential dissolution test shows that ¹⁰Be concentrations decrease with the number of cleaning steps until reaching a constant value. This is a necessary condition to demonstrate the efficiency of the method in properly decontaminating samples of meteoric ¹⁰Be. Moreover, cross-calibration with cosmogenic ³He measured within the same samples yielded a sea level high-latitude production rate of 4.5±0.4 at g⁻¹ a⁻¹ for cosmogenic ¹⁰Be in mafic minerals. This rate is within 1σ uncertainty of empirically or model-derived rates for ¹⁰Be on the same targets. Such concordance supports the consistency of the new method.     

Melting rates beneath Hawaii: Evidence from uranium series isotopes in recent lavas

²³⁸U, ²³²Th, ²³⁰Th and ²²⁶Ra abundances have been measured in six samples of recent Hawaiian basalt by high precision mass spectrometry, in an attempt to compare the melting process in plumes and at spreading ridges. The data reveal a very small range in (²³⁰Th/²³⁸U) activity ratio up to a maximum value of 1.02 ± 0.01, and (²²⁶Ra/²³⁰Th) activity ratios which lie between 1.10 ± 0.015 and 1.19 ± 0.02. UTh and RaTh abundances are linearly correlated demonstrating that the disequilibria predate crystallisation and differentiation. Using recently published estimates for the bulk partition coefficients of U and Th, the results are consistent with melting rates > 10⁻³ kg m⁻³ a⁻¹ at porosities < 10⁻³ for dynamic fractional melting in the garnet stability field.     

Implanted radiogenic and other noble gases in crustal diamonds from Northern Kazakhstan

Noble gases were extracted in steps from grain size fractions of microdiamonds ( < 100 μm) from the Kokchetav Massif, Northern Kazakhstan, by pyrolysis and combustion. The concentration of ⁴He in the diamonds proper (liberated by combustion) shows a 1/r dependence on grain size. For grain diameters > 15 μm the concentration also decreases with the combustion step. Both results are clear evidence that ⁴He has been implanted into the diamonds from -decaying elements in the surrounding matrix. The saturation concentration of ⁴He(5.6 × 10⁻⁴ cm³ STP/g) is among the very highest observed in any terrestrial diamonds. Fission xenon from the spontaneous fission of ²³⁸U accompanies the radiogenic ⁴He; the ¹³⁶Xe_f/⁴He ratio of (2.5 ± 0.3) × 10⁻⁹ agrees well with the production ratio of 2.3 × 10⁻⁹ expected in a reservoir where Th/U 3.3. Radiogenic ⁴⁰Ar is predominantly ( > 90%) set free upon combustion; it also resides in the diamonds and appears to have been incorporated into the diamonds upon their formation.

³He, on the other hand is mainly released during pyrolysis and hence is apparently carried by ‘contaminants’. The concentration in the diamonds proper is of the order of 4 × 10⁻¹² cm³ STP/g, with a ³He/⁴He ratio of 1 × 10⁻⁸. Excess ²¹Ne, similarly, appears to be present in contaminants as well as in diamonds proper. These two nuclides in the contaminants must have a nucleogenic origin, but it is difficult to explain their high concentrations.     

Al depth profile in Apollo 15 drill core

Cosmic-ray-produced²⁶Al (t_1/2 = 7.05 × 10⁵ years) has been measured in the Apollo 15 long core (surface to 390 g/cm²—218 cm) for study of galactic cosmic ray production profiles, using accelerator mass spectrometry. The results are in general accord with non-destructive counting data obtained earlier, but systematically lower, and significantly higher precision. From this experiment the half-attenuation length for²⁶Al production can be calculated to be 122 g/cm² (150–400 g/cm² region) after normalizing the data to average chemical composition. The⁵³Mn (t_1/2 = 3.7 × 10⁶ years) production profile in deep cores was also compiled to date. The half-attenuation length for⁵³Mn production was calculated to be 123 g/cm² (150–400 g/cm² region).     

Correlation of cyclic preloading with the liquefaction resistance

The compactivity of sand due to cyclic loading with a high number (N>10³) of small cycles (ε^ampl≤10⁻³) cannot be described by void ratio and stress alone. It depends strongly on the soil fabric usually described as ‘cyclic preloading’. The cyclic preloading cannot be measured directly in situ but correlates well with the liquefaction resistance. This paper demonstrates this correlation on the basis of laboratory tests. Practical applications can be derived from this work.     

The ground-state conductivity profile of the core-mantle system of the Earth

The ground state of the core-mantle conductivity system is defined as a step function transition from the constant non-zero conductivity of the core to zero conductivity in the mantle. This ground state is reached by letting the thickness of a transition region Δ → 0, where Δ appears as a parameter in the model conductivity of the system. By a transformation of the equation governing the behavior of the electrostatic potential φ, it is shown that the function V(x) = (1/σ^1/2)(d²σ^1/2/dx²) acts as a potential barrier in the quantum mechanical sense, and that for certain conductivity profiles σ(x), where x is the usual Cartesian coordinate, the electrostatic potential is screened out in regions where σ(x) → 0 as Δ → 0. Consequently, E = −φ also vanishes in these regions. The results generalize to the time-dependent case. Conditions that the conductivity function σ(x) must satisfy to qualify as the ground-state conductivity are defined and an example is provided.     

Origin and age of thermal waters in Cieplice Spa, Sudeten, Poland, inferred from isotope, chemical and noble gas data

Isotope and hydrochemical data of the thermal water system in Cieplice laskie Zdrój (Spa) indicate the existence of two subsystems that greatly differ in volume and which meet at the fault zones of a granitic horst, where they discharge at an altitude of about 340m. One of the subsystems is very small (about 4 × 10³ m³) as indicated by the tritium age of the order of 10 years and a low outflow rate. Its recharge area found from the δ¹⁸O and δD values, is about 200m above the springs, most probably on the slopes of the foothills of the Karkonosze Mountains south-southwest of the spa. The large subsystem contains water which is free of tritium and whose ¹⁴C content is from 1 to 8 pmc with δ¹³C = −8.0 to −9.2‰. The isotopic composition of this water reflects either the climatic effect (low-altitude recharge during a cooler pre-Holocene climate) or the altitude effect (recharge in the early Holocene period at about 1000m at the heights of the Karkonosze assuming that the ¹⁴C concentration is strongly reduced by exchange with calcite in veins). For the former hypothesis, the recharge area of this water is probably either at the foot of the southeastern slopes of the Kaczawa Mountains or/and at the foot of the Rudawy Janowickie Mountains, to the east of Cieplice. The noble gas temperatures are more consistent with the pre-Holocene recharge. Similarly, the ⁴He excess and ⁴⁰Ar/³⁶Ar ratio support the hypothesis of a pre-Holecene age. The constant ³He/⁴He ratio of 26 × 10⁻⁸ for highly different helium contents indicates crustal origin of helium. For the pre-Holocene age of water its volume is calculated at >- 10⁹m³ (stagnant water in micropores and mobile water in fractures) and the hydraulic conductivity of the host granite massif is estimated at about 7 × 10⁻⁸ ms⁻¹. Two outflows from this subsystem have different and variable fractions of a modern water component (bomb age), most probably originating from the bank infiltration of a nearby stream.     

Impacts of domestic sewage effluent on phytoplankton from Bedford Basin, eastern Canada

The impact of domestic sewage effluent (SE) on the dynamics of phytoplankton assemblages from Bedford Basin was evaluated in the laboratory. Phytoplankton production and chlorophyll a increased proportionally with SE enrichment. Phytoplankton species composition also changed. The potentially harmful diatoms, Pseudonitzschia spp., present initially in small numbers (600 cells 1⁻¹) in Bedford Basin seawater, and became dominant (3–5×10⁶ cells 1⁻¹) when the seawater was enriched with 0.5–5% untreated SE. With higher proportions of SE, other harmful species such as Fragilaria spp. and Euglena spp. became dominant (7−15×10⁶ and 2.2×10⁴ cells 1⁻¹, respectively). Treatment of SE with UV light or activated charcoal seems to favour growth of benign species, such as Chaetoceros socialis, Skeletonema costatum and Thalassiosira spp., but not harmful species such as Pseudonitzschia spp. Further research on UV treatment of domestic sewage is recommended.     

AMS analysis of I in Japanese soil samples collected from background areas far from nuclear facilities

Analytical procedures in the determination of iodine-129 (half-life: 1.6×10⁷ y) have been studied using accelerator mass spectrometry (AMS), with special references to the separation procedures of iodine from soil samples for the AMS measurement. Iodine was successfully volatilized from soil samples by pyrohydrolysis at 1000 °C and collected in a trap solution. Iodine was purified from the matrix by solvent extraction. Finally, it was precipitated as silver iodide to make a target for AMS. In order to obtain information on the ¹²⁹I/¹²⁷I ratio in a chemical blank (or iodine carrier), we have determined the ratios in several iodine reagents and found that the ratios fell in a narrow range around 1.7×10⁻¹³. The detection limit for soil sample (1 g material) by the present method was about 0.01 mBq/kg or 4×10⁻¹¹ as the ratio of stable iodine (¹²⁹I/¹²⁷I ratio), i.e. these values were much better than that by neutron activation analysis (NAA) used in our previous studies. We have applied this method in the analysis of soil samples collected from different places in Japan. We could successfully determine ¹²⁹I in soil samples with low ¹²⁹I concentrations, which could not be detected by NAA. Sample size necessary for the soil analysis by AMS was only about 0.5 g or less, whereas about 100 g of the sample were required for NAA [Muramatsu, Y., Ohmomo, Y., 1986. Iodine-129 and iodine-127 in environmental samples collected from Tokaimura/ Ibaraki, Japan. Sci. Total Environ. 48, 33-43]. Using this method, new data were obtained for the ¹²⁹I levels in 20 soil samples collected from background areas far from nuclear facilities, and the ranges were 1.4×10⁻⁵−4.5×10⁻³ Bq/kg as ¹²⁹I concentrations and 3.9×10⁻¹¹−2.2×10⁻⁸ as ¹²⁹I/¹²⁷I ratios. These values are useful in understanding the ¹²⁹I levels in Japanese environments. Higher ¹²⁹I concentrations were observed in forest soils than those in field and rice paddy soils should be related to the interception effect of atmospheric ¹²⁹I due to tree canopies. Relatively high ¹²⁹I/¹²⁷I ratios found in rice paddy soils could be explained by their low stable iodine concentrations which were caused by the desorption of stable iodine from the rice paddies during the cultivation.     

U,U andTh in seawater

We have developed techniques to determine²³⁸U,²³⁴U and²³²Th concentrations in seawater by isotope dilution mass spectrometry. U measurements are made using a²³³U²³⁶U double spike to correct for instrumental fractionation. Measurements on uranium standards demonstrate that²³⁴U/²³⁸U ratios can be measured accurately and reproducibly.²³⁴U/²³⁸U can be measured routinely to ± 5‰ (2σ) for a sample of 5 × 10⁹ atoms of²³⁴U (3 × 10⁻⁸ g of total U, 10 ml of seawater). Data acquisition time is 1 hour. The small sample size, high precision and short data acquisition time are superior to-counting techniques.²³⁸U is measured to ± 2‰ (2σ) for a sample of 8 × 10¹² atoms of²³⁸U ( 3 × 10⁻⁹ g of U, 1 ml of seawater).²³²Th is measured to ± 20‰ with 3 × 10¹¹²³²Th atoms (10⁻¹⁰ g²³²Th, 1 1 of seawater). This small sample size will greatly facilitate investigation of the²³²Th concentration in the oceans. Using these techniques, we have measured²³⁸U,²³⁴U and²³²Th in vertical profiles of unfiltered, acidified seawater from the Atlantic and²³⁸U and²³⁴U in vertical profiles from the Pacific. Determinations of²³⁴U/²³⁸U at depths ranging from 0 to 4900 m in the Atlantic (7°44′N, 40°43′W) and the Pacific (14°41′N, 160°01′W) Oceans are the same within experimental error (± 5‰,2σ). The average of these²³⁴U/²³⁸U measurements is 144 ± 2‰ (2σ) higher than the equilibrium ratio of 5.472 × 10⁻⁵. U concentrations, normalized to 35‰ salinity, range from 3.162 to 3.281 ng/g, a range of 3.8%. The average concentration of the Pacific samples (31°4′N, 159°1′W) is 1% higher than that of the Atlantic (7°44′N, 40°43′W and 31°49′N, 64°6′W).²³²Th concentrations from an Atlantic profile range from 0.092 to 0.145 pg/g. The observed constancy of the²³⁴U/²³⁸U ratio is consistent with the predicted range of²³⁴U/²³⁸U using a simple two-☐ model and the residence time of deep water in the ocean determined from¹⁴C. The variation in salinity-normalized U concentrations suggests that U may be much more reactive in the marine environment than previously thought.     

Iodine-129 concentrations in marginal seas of the north Pacific and Pacific-influenced waters of the Arctic Ocean

Water sampling during the 1993 IV Russian–US Joint Expedition to the Bering and Chukchi Seas (BERPAC) indicates that Pacific Ocean burdens of the long-lived radionuclide ¹²⁹I are relatively low in the Pacific-influenced Arctic, particularly compared to high latitude waters influenced by the North Atlantic. These low concentrations occur despite the presence of potential submerged anthropogenic sources in the East Sea (Sea of Japan), and in the northwest Pacific Ocean, east of the Kamchatka Peninsula. The concentration of ¹²⁹I entering the Arctic Ocean through Bering Strait, 0.7×10⁸ atoms kg⁻¹, is only slightly higher than observed in deep Pacific waters. Similar concentrations (0.44–0.76×10⁸ atoms kg⁻¹) measured in Long Strait indicate no significant transfer of ¹²⁹I eastward into the Chukchi Sea in the Siberian Coastal Current from the Siberian marginal seas to the west. However, the concentrations reported here are more than an order of magnitude higher than the Bering Strait input concentration estimated (1.0×10⁶ atoms kg⁻¹) from bomb fallout mass balances, which supports other existing evidence for a significant atmospheric deposition term for this radionuclide in surface ocean waters. Near-bottom water samples collected in productive waters of the Bering and Chukchi Seas also suggest that sediment regeneration may locally elevate ¹²⁹I concentrations, and impact its utility as a water mass tracer. As part of this study, two deep ¹²⁹I profiles were also measured in the East Sea in 1993–1994. The near-surface concentration of ¹²⁹I ranged from 0.12 to 0.31×10⁸ atoms kg⁻¹. The ¹²⁹I concentration showed a steady decrease with depth, although because of active deep water ventilation, the entire 3000 m water column exceeded natural concentrations of the radionuclide. Atom ratios of ¹²⁹I/¹³⁷Cs in the East Sea also suggest an excess of ¹²⁹I above bomb fallout estimates, also possibly resulting from atmospheric deposition ultimately originating from nuclear facilities.     

REE diffusion in calcite

Chemical diffusion of four rare-earth elements (La, Nd, Dy and Yb) has been measured in natural calcite under anhydrous conditions, using rare-earth carbonate powders as the source of diffusants. Experiments were run in sealed silica capsules along with finely ground calcite to ensure stability of the single-crystal samples during diffusion anneals. Rutherford backscattering spectroscopy (RBS) was used to measure diffusion profiles. The following Arrhenius relations were obtained over the temperature range 600–850°C: D_La =2.6×10⁻¹⁴ exp(−147±14 kJ mol⁻¹/RT) m² s⁻¹, D_Nd =2.4×10⁻¹⁴ exp(−150±13 kJ mol⁻¹/RT) m² s⁻¹, D_Dy =2.9×10⁻¹⁴ exp(−145±25 kJ mol⁻¹/RT) m² s⁻¹, D_Yb =3.9×10⁻¹² exp(−186±23 kJ mol⁻¹/RT) m² s⁻¹. In contrast to previous findings for refractory silicates (e.g. zircon), differences in transport rates among the REE are not pronounced over the range of temperature conditions investigated in this study. Diffusion of the REE is significantly slower than diffusion of the divalent cations Sr and Pb and slower than transport of Ca and C at temperatures above 650°C. Fine-scale zoning and isotopic and REE chemical signatures may be retained in calcites under many conditions if diffusion is the dominant process affecting alteration.     

Accretion, core formation, H and C evolution of the Earth and Mars

Recent understandings of planetary accretion have suggested that accumulation of a small number of large planetesimals dominates intermediate to final growth stages of the terrestrial planets, with impact velocity high enough to induce extensive melting of the planetesimal and target materials, resulting in formation of a large molten region in which gravitational segregation of silicate and metal, that is, core formation proceeds. In case of homogeneous accretion, volatiles contained in each planetesimal are likely subjected to partitioning among gas, silicate melt, and molten metallic iron at significantly high temperatures and pressures in such a massive molten region. Each phase would subsequently form the proto-atmosphere, -mantle, or-core, respectively. Such chemical reprocessing of H and C associated with core formation, which is followed by both degassing from mantle and atmospheric escape, may result in a diverse range of H₂O/CO₂ in planetary surface environments, which mainly depends on the H and C content relative to metallic iron in planetary building stones. This may explain inferred difference in volatile distribution between the Earth's (relatively H₂O-rich, CO₂-poor) and the martian (H₂O-poor, CO₂-rich) surface environments. Such volatile redistribution may be systematically described by using the retentivity of H₂O, ξ, defined as follows: ξ = 1 − ([CO]⁰ + 2[CH₄]⁰ + 2[C(gr)]⁰)/[H₂O]⁰, where [i]⁰ represents mol number of species i partitioned into non-metallic phases, that is, gas and silicate melt in impact-induced molten region. When ξ > 0.5, relatively H₂O-rich and CO₂-poor surface environment may eventually evolve, although a small portion of H₂O partitioned into the NON=metallic phases are possibly consumed by subsequent chemical reactions with reduced C-species with producing CO₂ and H₂. When ξ< 0.5, on the contrary, H₂O consumption by the above reactions and selective loss of H₂ to space may result in relative H₂O-depleted and CO₂-rich surface environment. Given the building stone composition by the two-component model by Ringwood (1977) and Wänke (1981), ξ is found to decrease with increasing the mixing fraction of the volatile-rich component: ξ > 0.5 for the mixing fraction smaller than about 15–20% and ξ < 0 for the mixing fraction larger than about 20–30%. This is not significantly dependent on temperature and pressure in molten region and H/C ratio in the building stone. The estimated mixing fraction of the volatile-rich component, about 10% for the Earth and 35% for Mars, is consistent with the observed difference in volatile distribution between the surfaces of both planets.     

Distribution of Cs and Pu in the surface waters of the East Sea (Sea of Japan)

Surface and subsurface water samples for ¹³⁷Cs and ^239,240Pu analysis were collected in the East Sea (Sea of Japan) during August 1993. The ¹³⁷Cs levels of the surface waters are quite homogeneous in the East Sea (average = 3.1±0.2 mBq kg⁻¹). The ^239,240Pu levels vary from 6 to 10 μBq kg⁻¹ in the surface. ^239,240Pu to ¹³⁷Cs ratios in the surface water are within 0.002 to 0.003. The East Sea may be regarded as a part of the North Pacific Ocean in terms of ¹³⁷Cs dispersal in the surface, where the ¹³⁷Cs contents of the surface seawater seem to be controlled primarily by the atmospheric input. However, since our sampling was made just two months prior to the widely publicized Russian dumping incident on the 17th October 1993, our measurements may provide background data to assess the immediate impact of the Russian dumping on the levels of ¹³⁷Cs and ^239,240Pu in the East Sea.     

Temporal–compositional trends over short and long time-scales in basalts of the Big Pine Volcanic Field, California

Primitive basaltic single eruptions in the Big Pine Volcanic Field (BPVF) of Owens Valley, California show systematic temporal–compositional variation that cannot be described by simple models of fractional crystallization, partial melting of a single source, or crustal contamination. We targeted five monogenetic eruption sequences in the BPVF for detailed chemical and isotopic measurements and ⁴⁰Ar/³⁹Ar dating, focusing primarily on the Papoose Canyon sequence. The vent of the primitive (Mg# = 69) Papoose Canyon sequence (760.8 ± 22.8 ka) produced magmas with systematically decreasing (up to a factor of two) incompatible element concentrations, at roughly constant MgO (9.8 ± 0.3 (1σ) wt.%) and Na₂O. SiO₂ and compatible elements (Cr and Ni) show systematic increases, while ⁸⁷Sr/⁸⁶Sr systematically decreases (0.7063–0.7055) and ε_Nd increases (− 3.4 to − 1.1). ¹⁸⁷Os/¹⁸⁸Os is highly radiogenic (0.20–0.31), but variations among four samples do not correlate with other chemical or isotopic indices, are not systematic with respect to eruption order, and thus the Os system appears to be decoupled from the dominant trends. The single eruption trends likely result from coupled melting and mixing of two isotopically distinct sources, either through melt-rock interaction or melting of a lithologically heterogeneous source. The other four sequences, Jalopy Cone (469.4 ± 9.2 ka), Quarry Cone (90.5 ±17.6 ka), Volcanic Bomb Cone (61.6 ± 23.4 ka), and Goodale Bee Cone (31.8 ± 12.1 ka) show similar systematic temporal decreases in incompatible elements. Monogenetic volcanic fields are often used to decipher tectonic changes on the order of 10⁵–10⁶ yr through long-term changes in lava chemistry. However, the systematic variation found in Papoose Canyon (10⁰–10² yr) nearly spans that of the entire volcanic field, and straddles cutoffs for models of changing tectonic regime over much longer time-scales. Moreover, ten new ⁴⁰Ar/³⁹Ar ages combined with chemistry from all BPVF single eruption sequences show the long-term trend of BPVF evolution comprises the overlapping, temporal–compositional trends of the monogenetic vents. This suggests that the single eruption sequences contain the bulk of the systematic chemical variation, whereas their aggregate compositions define the long-term trend of volcanic field evolution.     

A metamorphic history from micron-scale Pb/Pb chronometry of Archean monazite

Ion microprobe measurements of Pb isotope ratios in monazites have been obtained, in situ, from thin sections using the Cambridge ISOLAB 120. Molecular interferences are sufficiently resolved at an RP of 6500 to allow ²⁰⁷Pb/²⁰⁶Pb dating of monazite with precisions as low as 4–5 Ma (2σ). The results presented here provide important information on the chronological history of the Late Archean metamorphism of the Wind River Range, Wyoming (USA).

Matrix monazites and monazite inclusions in garnets from a metapelite from the northern Wind River Range have been analysed by SIMS. In a previous study peak metamorphic conditions (T = 800°C; P = 8 ± 1 kb^*) were estimated using inclusion assemblages in garnets from this same sample. Isolated monazite inclusions in garnet yield ²⁰⁷Pb/²⁰⁶Pb age estimates of 2781 ± 6 to 2809 ± 10 Ma. Those along fractures yield lower ages (2603–2687 Ma) which are similar to TIMS and SIMS ages of matrix monazites. A single large (500 μm) monazite grain locally preserves growth zoning, but has a recrystallised core and a resorbed (recrystallised?) rim. Age estimates for these three regions are 2788 ± 9 Ma, 2663 ± 4 and 2523 ± 6 Ma, respectively. Thus the inclusion assemblages of Sharp and Essene^* may record peak metamorphic conditions at ca. 2.8 Ga, and indicate a phase of metamorphism that predates by over 100 Ma the emplacement of the Bridger Batholith, the major lithologic component of the northern Wind River Range.

The analysed monazite grains appear to preserve ca. 300 Ma history, even within a single grain. Monazite inclusions in garnet that are fully armoured may provide estimates for the time of garnet growth, even in high grade terranes where most chronometers are reset. The age pattern preserved by the large monazite grain cannot be simply related to diffusion controlled closure. Instead, a chronology is preserved which can be related to the petrographic setting of indicidual grains through in situ analysis.     

Entrainment from a bed of particles by thermal convection

Differentiation in magma chambers, in the Earth's core and in the partially molten early Earth is a competitive process between sedimentation and re-entrainment of crystals in the presence of convection. Previous studies show that the particles suspended in convective layers eventually settle and do so almost as fast as in the absence of convection. However, the nature and magnitude of the competing entrainment has remained unclear. Here we provide a simple theory and experimental evidence showing that entrainment occurs at the crests of dunes created in the particle bed at the base of a convecting fluid. In both laminar and turbulent regimes, the dune formation and entrainment are driven by viscous stresses produced by thermal plumes. At sufficiently high Rayleigh numbers the particles are probably entrained by Reynolds stresses. Entrainment in the Earth's core is hardly possible because it requires unreasonably small crystals. Entrainment of 10⁻²–10⁻¹ cm diameter crystals is very likely in magma oceans. For magma chambers entrainment requires large viscosities (> 10⁶ P) and even when it occurs, the total amount of the suspended solid fraction is very small.     

Tin and organotin in water, sediments, and benthic organisms of Poole Harbour

Tributyltin (TBT) concentrations in waters of Poole Harbour ranged between 2–139 ng l⁻¹ (as Sn) and increased to 234–646 ng l⁻¹ within marinas. Seasonal trends in contamination coincided with boat usage patterns and peaked during summer months. A combination of poor tidal flushing and removal of TBT to particulates restricts high levels of contamination to areas closest to marinas and moorings; TBT concentrations in benthic sediments decreased from 0.52 μg g⁻¹ near such sites to 0.02 μg g⁻¹ at the harbour mouth. Organotin accumulations in several benthic invertebrates including polychaetes (Nereis diversicolor), snails (Littorina littorea) and clams (Scrobicularia plana, Mya arenaria) reflect the distribution of contamination in the environment, though concentration factors (relative to water) vary considerably between species and were highest in sediment dwelling clams, notably Mya (1.3×10⁵). Compared to organotins, biological availability of inorganic tin is low.

Levels of TBT in parts of Poole Harbour exceed Environmental Quality Targets designed to protect marine life and may be responsible for poor recruitment, particularly in bivalves, at heavily contaminated sites.     

Pu, Cs and excess Pb in Russian Arctic sediments

The activity ratios of Pu and radiocesium isotopes have been used to delineate the major sources (such as global and close-in (debris) fallout, nuclear fuel reprocessing and fabrication plant effluents) in the environment. We have measured ²³⁸Pu, ^239,240Pu, ¹³⁷Cs, and excess ²¹⁰Pb concentrations in 107 surficial sediments as well as in 5 sediment cores collected in the summer months of 1993 and 1994 from the Ob and Yenisey Rivers (Russia) and the Kara sea. A comparison of the sediment core inventories of ^239,240Pu and ¹³⁷Cs, along with the ²³⁸Pu/^239,240Pu activity ratios, with those expected from global fallout allows us to estimate the relative amounts, if any, of reactor-derived ²³⁸Pu and ^239,240Pu from the dumped reactor sites in the study area.

In surficial sediment samples collected in 1993 and 1994, the ^239,240Pu concentrations varied between 4.2 and 856 mBq kg⁻¹, with a mean of 239 mBq kg⁻¹. In samples with a measurable ²³⁸Pu, the ²³⁸Pu/^239,240Pu activity ratios varied between 0.010 and 0.069, with an average value of 0.035 ± 0.014. This range can be compared to the average ²³⁸Pu/^239,240Pu activity ratio of 0.030 for the year 1993 from nuclear weapons testing and SNAP fallout obtained from soil studies, indicating very little (≤ 5%) additional sources of ²³⁸Pu to the sediments in the study area. The inventories of Pu in the 5 sediment cores from the study area varied between 2.67 ± 0.67 and 24.5 ± 2.2 Bq m⁻² with a mean value of 8.83 Bq m⁻². The ¹³⁷Cs concentrations in the upper 3 cm of the sediments varied between below detection limit to 71.4 Bq kg⁻¹, with a mean of 14.9 Bq kg⁻¹. The ¹³⁷Cs inventories in the 5 sediment cores varied between 156.7 ± 28.3 and 1600 ± 153.3 Bq m⁻², with a mean value of 583.3 Bq m⁻². The mean ratio of inventories of Pu to that of ¹³⁷Cs, 0.015, is comparable to the values in other places in the Arctic region. There is a significant correlation between total organic carbon and concentrations of ¹³⁷Cs, ^239,240Pu and ²¹⁰Pb, suggesting that organic matter-enriched fine particles are a likely carrier phase for these nuclides. The ratio of ¹³⁷Cs/^239,240Pu also suggests that most of these nuclides are derived from global fallout.