拉萨地体北部永珠地区早白垩世岩浆岩地球化学、锆石U-Pb年代学、Hf同位素组成及其地质意义

拉萨地体北部出露大面积早白垩世岩浆岩,对它们的成因和形成机制的研究,有助于揭示拉萨地块白垩纪时期的岩浆作用过程及动力学背景.通过岩石学、地球化学和同位素地质学方法对拉萨地体北带永珠地区早白垩世中-酸性岩浆岩进行了研究.结果显示黑云母二长花岗岩、流纹岩和安山岩的锆石LA-ICP-MS U-Pb年龄分别为118±1.0 Ma、121±0.8 Ma和115±0.8 Ma,代表了其侵入和喷出时代.黑云母二长花岗岩、花岗斑岩和流纹岩为高钾钙碱性过铝质-强过铝质岩浆岩（A/CNK=1.01~1.35）,亏损高场强元素Nb、P、Ti和大离子亲石元素Ba、Sr,富集大离子亲石元素Rb、K和放射性元素U、Th;稀土配分图显示LREE富集,HREE近平坦,Eu明显负异常,为形成于大陆边缘的岛弧岩浆岩特征.黑云母二长花岗岩和流纹岩的锆石Hf初始比值ε_Hf（t）分别为-1.21~3.01和-0.68~5.35,对应的两阶段模式年龄分别为0.99~1.26 Ga和0.84~1.22 Ga,为壳幔混源岩浆.安山岩为高钾钙碱性,亏损Nb、Ta、P、Ti、U和Sr,富集Rb、K和Th,稀土配分图显示LREE富集,HREE近平坦,Eu轻微负异常,为形成于大陆边缘弧的岩浆岩.结合前人研究成果,分析认为永珠地区早白垩世岩浆岩形成于班公湖-怒江特提斯洋壳南向俯冲作用下的大陆边缘弧环境,由俯冲的班公湖-怒江中特提斯洋板片在深部脱水熔融,进而诱发上覆地幔楔部分熔融形成基性岩浆上涌,导致下地壳物质发生部分熔融形成酸性岩浆,它们在上升过程中按不同比例混合,形成中性和酸性岩浆侵入到地下或喷出地表,形成侵入岩和火山岩.      

Petrogenesis and tectonic implications of the late Carboniferous calc-alkaline and shoshonitic magmatic rocks in the Awulale mountain,western Tianshan

The widespread late Carboniferous calc-alkaline and shoshonitic magmatic rocks in the Awulale mountain provide crucial constraints on the tectonic evolution of the western Tianshan. Here, we perform detailed petrological investigations as well as zircon U-Pb chronological, whole-rock geochemical and Sr-Nd isotopic analyses on these magmatic rocks from two geological sections along the Duku road. Magmatic rocks in the section I with zircon SHRIMP U-Pb ages of 306.8 Ma and 306.4 Ma are composed of medium-K calc-alkaline to shoshonitic basalt, trachy-andesite and trachyte, while those in the section II consist of shoshonitic trachy-andesite, trachyte with a U-Pb age of 308.1 Ma, and monzonite with a U-Pb age of 309.6 Ma. All these magmatic rocks are characterized by strong enrichments in large iron lithophile elements with depletions of Nb, Ta and Ti, indicating the origination from subduction-modified lithospheric mantle. The ε_Nd(t) values of the rock samples collected from the section I (2.80–5.45) and section II (3.34–5.37) are generally higher than those of the Devonian to early Carboniferous arc-type magmatic rocks in the Yili-central Tianshan, suggesting that depleted asthenosphere might also be involved in their generation. Based on these geochemical data and petrological observations, we suggest that the early-stage (308.1–309.6 Ma) shoshonitic monzonite, trachy-andesite and trachyte in the section II were generated by mixing between mafic magmas and trachytic melts, while the late-stage (306.4–306.8 Ma) medium-K calc-alkaline to shoshonitic basalt, trachy-andesite and trachyte in the section I were produced by partial melting of depleted asthenospheric and metasomatized lithospheric mantle, followed by the processes of fractional crystallization and crustal contamination. Taking into account the available regional geological data, the subduction of south Tianshan ocean was probably ceased at ∼310 Ma, and these calc-alkaline and shoshonitic magmatic rocks in the Awulale mountain formed in a post-collisional setting subsequent to slab break-off.     

西藏北部拉萨地块那曲地区约113Ma安山岩岩石成因与意义

西藏北部拉萨地块广泛分布着早白垩世岩浆岩,由于缺少高质量的年代学和地球化学数据,其岩浆源区和岩石成因迄今未能很好约束。本文报道了北部拉萨地块那曲地区安山岩的锆石U-Pb定年、地球化学和Sr-Nd-Hf同位素数据。那曲安山岩锆石U-Pb年龄为112.7±0.7Ma。岩石为高钾钙碱性系列,富集大离子亲石元素、Th、U和轻稀土元素[(La/Yb)N=6.62～11.68],亏损Nb、Ta、P和Ti等高场强元素。样品具有较高的(87Sr/86Sr)i值(0.7100～0.7126)、负的全岩εNd(t)值(-10.5～-7.8)和负的锆石εHf(t)值(-9.9～-4.7),对应于古老的Nd同位素二阶段模式年龄(1.5～1.8Ga)和锆石Hf同位素地幔模式年龄(1.0～1.6Ga)。综合岩石学、地球化学和区域构造背景研究认为,那曲地区安山岩形成于南向俯冲的班公湖-怒江洋壳岩石圈板片断离的背景,很可能是受早期流体/沉积物熔体交代富集的安多微陆块古老岩石圈地幔物质部分熔融的产物,并经历了不同程度的分离结晶。     

Petrogenesis and geochronology of Mishao peraluminous I-type granites,Shalair valley area,NE Iraq

The Shalair area, which is located in northeastern Iraq, is considered to be part of the northern Sanandaj-Sirjan Zone (SaSZ) and contains several granitoid bodies. One of these bodies, the Mishao porphyritic-granite (MG), was crystallized at 111.6?±?2.4 Ma, based on its zircon U-Pb age. Its geochemical characteristics suggest that the MG rocks are calc-alkaline, peraluminous, I-type granites with microgranular mafic enclaves. They are enriched in SiO₂, Na₂O, Al₂O₃ and Zr and depleted in MgO, Fe₂O₃, Nb and Ti; in contrast, the enclave sample records lower SiO₂ content and higher contents of MgO and Fe₂O₃. These rocks show an enrichment of LREE relative to HREE, and pronounced negative Eu anomalies implying feldspar fractionation. The isotopic and geochemical characteristics of the MG samples suggest that these rocks are evolved through fractional crystallization. In the La/Nb-Nb diagram and Sm/Nd ratios, the MG rocks and the enclave samples exhibit strong evidence for crustal contamination. The MG rocks record high initial ⁸⁷Sr/⁸⁶Sr (0.70625–0.70740) and low ¹⁴³Nd/¹⁴⁴Nd(i) (0.51235–0.51274) ratios. These Sr-Nd isotopic data, combined with the presence of high Th/U and Rb/Sr ratios and significant depletions of Nb, Ta and Ti, show a relation of these bodies to an active continental margin regime. Based on the age and geochemical data of the MG, this study presents new information about the occurrence of Middle Cretaceous magmatic activities, which are related to the active continental margins in the SaSZ that run parallel to the Zagros Fold-Thrust Belt.     

西藏措勤麦嘎岩基的锆石U-Pb年代学、地球化学和锆石Hf同位素:对中部拉萨地块早白垩世花岗岩类岩石成因的约束

西藏中部拉萨地块大规模早白垩世花岗岩类的岩浆源区和岩石成因迄今尚未得到很好约束,对这些问题的深入理解将有助于揭示拉萨地块白垩纪时期的岩浆作用过程及成矿背景。本文报道了中部拉萨地块代表性花岗岩基——措勤麦嘎岩基的锆石U-Pb年代学、全岩元素地球化学、Sr-Nd同位素和锆石Hf同位素数据。本文锆石U-Pb定年结果表明,麦嘎岩基花岗质岩主要侵位于122±1Ma和113±2Ma,闪长质包体与后者同期(113±2Ma)。122±1Ma花岗质岩属I型弱过铝质高钾钙碱性系列,(87Sr/86Sr)i值高(0.7147),全岩εNd(t)(-12.0)和锆石εHf(t)(-15.7～-11.1)为较大的负值,表明其很可能来源于古老下地壳物质的重熔。113±2Ma寄主花岗质岩为I型偏铝质-弱过铝质高钾钙碱性系列,相对于122±1Ma花岗质岩石,其(87Sr/86Sr)i比值偏低(0.7094～0.7156)、全岩εNd(t)值(-12.1～-7.3)和锆石εHf(t)值(-11.1～0.1)较高,很可能来源于古老下地壳物质的部分熔融,并含有更多幔源物质。闪长质包体(113±2Ma)为偏铝质中-高钾钙碱性系列,以变化范围大的(87Sr/86Sr)i(0.7058～0.7105)、负的全岩εNd(t)值(-10.7～-9.8)及负的锆石εHf(t)值(-14.0～-5.6)为特征,可能是古老富集岩石圈地幔物质部分熔融的产物或亏损地幔物质经历强烈地壳混染作用的结果。在目前已有资料条件下(缺乏同期基性岩石的相关数据),本文暂将麦嘎岩基113±2Ma寄主花岗质岩及同期闪长质包体解释为镁铁质岩浆与长英质岩浆发生不同程度岩浆混合作用的产物,这一解释可能对中部拉萨地块同期花岗类的岩石成因具普遍意义。麦嘎岩基及中部拉萨地块同期岩浆岩约113Ma幔源物质增加现象,可能是南向俯冲的班公湖-怒江洋壳岩石圈板片断离的结果。     

内蒙古赤峰南窝铺铀矿床英安岩的SHRIMP锆石U-Pb年龄、地球化学特征及地质意义

南窝铺铀矿床位于西拉木伦缝合带以南、康宝—围场—赤峰断裂带(华北北缘断裂带的一部分)以北的白乃庙加里东期岛弧带和华北古板块北缘海西期俯冲—碰撞带,属沽源—红山子铀成矿带北东段红山子—广兴铀成矿亚带的一个铀矿床,铀矿体赋存在额里图组安山岩—英安岩—流纹岩组合中.该组合中的英安岩SHRIMP锆石n(206Pb)/n(238...     

念青唐古拉中基性侵入岩年代学、地球化学及岩石成因

念青唐古拉早始新世中基性侵入岩由角闪辉长岩及二长闪长岩组成,其中角闪辉长岩锆石LA-MC-ICPMS U-Pb年龄为(49.92±0.24)Ma。中基性侵入岩属于高钾钙碱系列至钾玄岩系列;稀土总量较高且轻稀土富集;富集大离子亲石元素(Rb,Th,K),亏损高场强元素(Nb,Ta,Ti),具有弧岩浆岩的微量元素特征。中基性侵入岩具有较高的初始锶((87Sr/86Sr)i为0.708 77～0.713 71)、低的εNd值(-6.9～-6.1)、古老的亏损地幔模式年龄(TDM为1 329～1 995Ma),以及εNd、Nb/La与MgO无明显相关性,表明其源区为受古老地壳交代的富集地幔。稀土元素模拟表明中基性侵入岩的成岩过程受地幔中轻程度部分熔融作用所控制。动力学背景分析表明其与新特提斯洋板片的断离及软流圈物质的上涌密切相关。     

内蒙古狼山北部早古生代岩浆岩年代学、地球化学特征及构造意义

内蒙古狼山北部地区位于华北克拉通与兴蒙造山带交接部位,构造上隶属于华北克拉通北缘早古生代陆缘增生带.狼山北部巴音杭盖一带出露的早古生代岩浆岩,对确定华北北缘西段早古生代构造格局和造山带演化具有重要意义.本次研究采用LA-MC-ICP-MS锆石U-Pb测年法,获得了闪长岩、石英闪长岩206Pb/238U年龄为435.8±2.2 Ma~437.7±2.2 Ma,时代为早志留世.岩石为钙碱性系列,富集轻稀土元素,（La/Yb）_N=4.30~11.59,表现出不同程度地富集大离子亲石元素（LILE）Rb、Th、U、K、Ba、Sr等,亏损高场强元素（HFSE）,具有明显的Nb、Ta、Ti负异常,具有弱的负Eu异常（δEu=0.80~0.96）,具有俯冲带岩石的特征.在同位素组成上,早志留世闪长岩体具有明显亏损的特点,ε_Hf（t）=+5.2~+12.6,（87Sr/86Sr）_i=0.704 665~0.706 174,ε_Nd（t）=+1.84~+2.00.上述年代学、岩石地球化学、Sr-Nd-Hf同位素数据结合区域地质资料分析表明,狼山北部早志留世闪长质岩体形成于早古生代温都尔庙洋沿温都尔庙-乌德-索伦山南一线南向俯冲背景下,为经历了俯冲洋板片析出流体交代作用的新生下地壳部分熔融的产物.志留纪岛弧岩浆岩的确定,明确了狼山北部地区属于华北克拉通北缘早古生代活动大陆边缘,为白乃庙岛弧带向西延展的部分,同时为华北北缘西段早古生代"沟-弧-盆"体系的确定提供了重要素材.      

Geochronological and geochemical constraints on Late Cryogenian to Early Ediacaran magmatic rocks on the northern Tarim Craton: implications for tectonic setting and affinity with Gondwana

ABSTRACT

The Tarim Craton provides a geologic record of both the fragmentation of the Rodinian supercontinent and the subsequent assembly of Gondwana. However, the timing and interactions of these radically different tectonic processes remain contested. A critical part of this debate revolves around the Late Cryogenian-Ediacaran igneous rocks along the Craton’s northern margin, specifically, whether they record super-plume related Rodinian breakup or Gondwanan orogeny. To address this issue, we present zircon U-Pb-Hf isotopic data and whole rock geochemistry from Late Cryogenian to Early Ediacaran granitoids of the northern Tarim Craton. U-Pb zircon ages reveal three magmatic periods along the northern Tarim margin: ca. 660–640 Ma, 635–625 Ma and 620–600 Ma, associated with small scale felsic and mafic magmas. These granitoids have an A2-type affinity and are enriched in alkalines, but are depleted in Nb, Ta, Sr, P and Ti. Elemental data and generally negative εHf(t) values (?13.96 to 1.65) suggest that they were mainly derived from partial melting of enriched, subduction-modified lithospheric mantle triggered by upwelling of the asthenospheric mantle along the active continental margin of northern Tarim. We suggest that the Tarim Craton travelled as an isolated plate for much of the Late Neoproterozoic, near the outer part of Rodinia and subsequently Gondwana. During this time it was affected by localized and periodic subduction-related intrusion and eruption. However, within the samples of this study, there is no U-Pb-Hf isotopic and whole-rock geochemical evidence to support either super-plume-related rifting (i.e. Rodinian breakup) or Pan-African orogeny (i.e. Gondwanan assembly).     

皖南屯溪盆地火山岩的地球化学、年代学及其构造意义

安徽南部侏罗至白垩纪屯溪盆地位于NE向中下扬子火山岩带和NNE向中国东南部火山岩带的交接部位,其火山岩的年代学和成因研究可以提供华南晚中生代构造演化的信息。4个火山岩样品的LA-ICP-MS锆石U-Pb年龄及其岩石地球化学数据指示屯溪盆地发育两期火山岩:早期火山岩形成于156~152 Ma,为中、高钾钙碱性系列,稀土元素分布型式为轻稀土元素富集的右倾型,铕负异常不明显,富集轻稀土元素和大离子亲石元素,亏损高场强元素Nb、Ti、P;晚期火山岩形成于136~130 Ma,具有双峰式火山岩特征,其酸性组分属中钾钙碱性系列,稀土元素分布型式为右倾斜的"V"型,铕负异常明显,同样具有富集轻稀土元素、大离子亲石元素及亏损高场强元素Nb、Ti、P的特征。皖南屯溪盆地晚侏罗世-早白垩世火山活动类似于中国东南部火山岩带。结合前人资料,认为屯溪盆地晚侏罗世火山岩形成于挤压构造环境,而早白垩世火山岩形成于伸展环境,其成因与晚侏罗至早白垩世古太平洋板块俯冲角度变化和俯冲板片后撤作用有关。     

华北克拉通南缘小秦岭地区新太古代晚期-古元古代晚期岩浆构造热事件:锆石U-Pb-Hf同位素和地球化学证据

为了探讨华北克拉通南缘早前寒武纪形成演化,对华北克拉通南缘小秦岭地区早前寒武纪变质基底花岗质片麻岩开展了SHRIMP U-Pb锆石定年、Hf同位素组成及地球化学组成研究,获得了2个TTG片麻岩样品~2.50 Ga的岩浆锆石年龄和时代相近的变质锆石年龄,岩浆锆石ε_Hf（t）值为0.71~4.37;1个花岗质片麻岩样品的岩浆锆石年龄为~2.30 Ga,ε_Hf（t）值为－1.21~0.11.它们也记录了古元古代晚期变质锆石年龄或显示古元古代晚期构造热事件影响的存在.岩石以轻重稀土强烈分异为特征,大离子亲石元素相对富集,Nb、P、Ti相对亏损.在小秦岭地区首次发现新太古代晚期TTG岩石,并识别出新太古代晚期构造热事件.现有资料支持华北克拉通南缘与华北克拉通其他地区具有类似的早前寒武纪形成演化历史的认识.但是,华北克拉通南缘以2.3 Ga左右岩浆作用十分发育而显示出独特性.      

内蒙古赤峰大西营子金矿区赋矿火山岩年代学与岩石地球化学特征

大西营子金矿区位于内蒙古赤峰地区,金矿赋存在玛尼吐组火山岩中。对大西营子金矿区赋矿围岩进行了岩石学、锆石U-Pb年代学和岩石地球化学研究。矿区火山岩主要包括安山岩、粗安岩、粗面岩和火山碎屑岩。通过锆石LA-ICP-MS U-Pb定年,获得安山岩和粗安岩年龄分别为(157.8±6.2)Ma和(156.9±7.4)Ma,应代表其形成年龄。岩石地球化学数据显示该套火山岩具有相对富碱、富铝的特征,属于高钾钙碱性和碱性岩石系列。岩石富集轻稀土元素和大离子亲石元素(Th、U、Zr、Hf),亏损重稀土元素和Nb、Ta、Ti等高场强元素。这些特征显示岩浆来自被俯冲流体交代富集的岩石圈地幔,且经历了以单斜辉石为主的结晶分异过程。结合区域地质资料,认为在大西营子金矿区火山岩形成于造山后伸展环境,与蒙古—鄂霍茨克洋闭合作用有关。     

西藏南木林县格张地区早白垩世火山岩岩石成因

西藏南木林县格张地区在构造上位于中冈底斯带南部(即中拉萨地块南部)的革吉—申扎弧后盆地。以格张地区出露的火山岩为研究对象,进行岩石学、LA-ICP-MS锆石U-Pb定年、元素地球化学和Lu-Hf同位素地球化学分析研究。结果显示,格张地区火山岩主要为一套酸性火山碎屑岩夹少量的火山熔岩,岩石组合为流纹质含角砾晶屑凝灰岩和流纹质(含角砾)晶屑熔结凝灰岩夹少量流纹岩和玄武岩。火山岩中发育典型的岩浆锆石。对1件流纹岩和1件流纹质晶屑熔结凝灰岩样品中的锆石进行U-Pb LA-ICP-MS定年分析,分别获得的年龄为(133±1.7) Ma和(128±1.5) Ma,表明火山岩形成于早白垩世(K1)时期。火山岩主量元素在质量分数上表现为高SiO2(69.4%~75.8%)、高K2O(2.93%~5.58%)、富Al2O3(12.7%~14.6%)、低TiO2(0.20%~0.34%)、低Na2O(0.05%~2.5%)、弱过铝质过铝质(A/NK为0.92~1.83,A/CNK为1.06~3.59)、高钾钙碱性系列的钾质火山岩特征。稀土元素配分模式呈现为轻稀土元素强烈富集的右陡倾斜型,其(La/Yb)N为12.3~22.0,具明显的负铕异常(Eu/Eu*=0.47~0.62)。微量元素普遍表现出Rb、Th、K等元素的正异常和Ba、Ta、Nb、Sr、P、Ti等元素的负异常。火山岩的εHf(t)值主要集中在-12.4~-7.2,两阶段地壳Hf模式年龄tDM2主要为1.5~1.7 Ga,相当于念青唐古拉群(AnZNq)的地质时代。格张地区早白垩世火山岩应为中部拉萨地块基底的念青唐古拉群(AnZNq)部分熔融的结果,并伴有少量幔源物质的加入,形成于因班怒洋板片南向俯冲所产生的陆缘弧构造环境。     

大兴安岭北部兴隆地区寒武纪侵入岩锆石U-Pb年代学、地球化学及其构造意义

大兴安岭北部兴隆地区位于新林-喜桂图缝合带北部,额尔古纳地块南缘,在大地构造上属于兴蒙造山带北段.然而,由于资料有限,前人对该区寒武纪侵入岩的构造产出环境仍存有争议,从而制约了人们对于新林-喜桂图洋早期构造演化的正确认识.选取兴隆地区出露的寒武纪内河岩体为研究对象,通过岩相学、锆石U-Pb年代学及地球化学研究,以期限定其形成时限,探讨其岩石成因和构造背景,进而为解决上述问题提供新的证据.内河岩体中石英二长岩及侵入其中的辉石闪长岩的LA-ICP-MS锆石U-Pb年龄分别为508±3 Ma和507±5 Ma,证明其形成时代均为中寒武世.石英二长岩和辉石闪长岩样品为高钾钙碱性和钙碱性系列,同时表现出轻稀土元素富集和不同程度的亏损Nb、Ta和Ti.两组样品的Nb/Ta平均值分别为22.41和17.12,较高于原始地幔平均值,MgO的含量（< 8%）和Mg#（42~70）值较低.上述地球化学特征为典型俯冲带岩石的特征,暗示内河岩体为经历了俯冲板片析出流体交代作用的原始地幔部分熔融的产物.结合区域已有近同时代侵入岩、蛇绿混杂岩和蓝片岩资料,推测内河岩体可能形成于活动大陆边缘构造环境,为寒武纪期间新林-喜桂图洋向北俯冲的弧岩浆作用的产物.研究结果为兴蒙造山带北段在寒武纪期间仍处于俯冲构造环境提供了重要依据.      

Geochemistry, Nd Isotopic Characteristics of Metamorphic Complexes in Northern Hebei： Implications for Crustal Accretion

The middle segment of the northern margin of the North China Craton （NCC） consists mainly of metamorphosed Archean Dantazi Complex, Paleoproterozoic Hongqiyingzi Complex and unmetamorphosed gabbro-anorthosite-meta-alkaline granite, as well as metamorphosed Late Paleozoic mafic to granitoid rocks in the Damiao-Changshaoying area. The -2.49 Ga Dantazi Complex comprises dioritic-trondhjemitic-granodoritic-monzogranitic gneisses metamorphosed in amphibolite to granulite facies. Petrochemical characteristics reveal that most of the rocks belong to a medium- to high-potassium calc-alkaline series, and display Mg^# less than 40, right-declined REE patterns with no to obviously positive Eu anomalies, evidently negative Th, Nb, Ta and Ti anomalies in primitive mantlenormalized spider diagrams, εNd（t）=＋0.65 to -0.03, and depleted mantle model ages TDM=2.78-2.71 Ga. Study in petrogenesis indicates that the rocks were formed from magmatic mixing between mafic magma from the depleted mantle and granitoid magma from partial melting of recycled crustal mafic rocks in a continental margin setting. The 2.44-2.41 Ga Hongqiyingzi Complex is dominated by metamorphic mafic-granodioritic-monzogranitic gneisses, displaying similar petrochemical features to the Dantazi Complex, namely medium to high potassium calc-alkaline series, and the mafic rocks show evident change in LILEs, negative Th, Nb, Ta, Zr anomalies and positive P anomalies. And the other granitiod samples also exhibit negative Th, Nb, Ta, P and Ti anomalies. All rocks in the Hongqiyingzi Complex show right-declined REE patterns without Eu anomaly. The metamorphic mafic rocks with εNd（t） = -1.64 may not be an identical magmatic evolution series with granitoids that have εNd（t） values of ＋3.19 to ＋1.94 and TDM ages of 2.55-2.52 Ga. These granitic rocks originated from hybrid between mafic magma from the depleted mantle and magma from partial melting of juvenile crustal mafic rocks in an island arc setting. All the -311 Ma Late Paleozoic metamorphic mafic rocks and related granitic rocks show a medium-potassium calc-alkaline magmatic evolution series, characterized by high Mg^#, obviously negative Th, Nb, Ta anomalies and positive Sr anomalies, from no to strongly negative Ti anomalies and flat REE patterns with εNd（t） = ＋8.42, implying that the maflc magma was derived from the depleted mantle. However the other granitic rocks are characterized by right-declined REE patterns with no to evidently positive Eu anomalies, significantly low εNd（t） = -13.37 to -14.04, and TDM=1.97-1.96 Ga, revealing that the granitoid magma was derived from hybrid between maflc magma that came from -311 Ma depleted mantle and granitoid magma from Archean to Early Paleoproterozoic ancient crustal recycling. The geochemistry and Nd isotopic characteristics as well as the above geological and geochronological results indicate that the middle segment of the northern margin of the NCC mainly experienced four crustal growth episodes from Archean to Late Paleozoic, which were dominated by three continental marginal arc accretions （-2.49, -2.44 and 311 Ma）, except the 1.76-1.68 Ga episode related to post-collisional extension, revealing that the crustal accretion of this segment was chiefly generated from arc accretion and amalgamation to the NCC continental block.     

Mid–Late Cretaceous igneous activity in South China: the Qianjia example,Hainan Island

ABSTRACT

Both Pacific and Neo-Tethys plates had major influences on the Cretaceous magmatisms in southeastern China. The subduction of the Neo-Tethys plate is, however, not well studied. This paper reports zircon U–Pb ages, Lu–Hf isotopes, whole-rock geochemistry, and Sr–Nd isotopes for the Qianjia intrusive rocks in Hainan Island, southeast China. LA-inductively coupled plasma mass spectrometry zircon U–Pb dating of granites and dark enclave monzonite in the area yield magmatic crystallization ages of ca. 100 Ma, which are consistent with other Late Cretaceous granites, e.g. Baocheng, Tunchang, and Yaliang. Both rocks show high-K calc-alkaline compositions and metaluminous to weakly peraluminous signatures belonging to I-type rocks. They are enriched in the alkalis, Rb, Th, U, K, and light rare earth elements, depleted in Nb, Ta, Ti, and P, and characterized by high Al₂O₃ contents (14–15 wt%) and high Mg^# values (50–53). Among them, some of granodiorites have geochemical affinities of adakitic rocks. Zircon ε_Hf(t) values range from ?5.97 to ?1.18, with fairly constant whole-rock Sr–Nd isotopes (I_Sr = 0.7084–0.7086; ε_Nd(t) = ?4.97 to ?4.29) similar with those of the Cretaceous mafic dikes (136–81 Ma) in Hainan Island, which are the result of partial melting of subduction-related sub-continental lithospheric mantle. Combined with Sr–Nd isotopes and negative Hf isotope, Qianjia intrusive rocks were likely derived from hybrid melts of underplated continental crust-derived with mantle-derived, then experienced varied degrees of fractional crystallization. According to the latest geophysical, sedimentological, and geochemical data, previous authors identified a Cretaceous E–W-trend subduction zone in the northern margin of the South China Sea. Combined with the southern margin magmatisms (110–80 Ma) and magmatisms of ~120 Ma distributed east–west ward from the Philippines to the Vietnam, We preferred that the subduction of the E–W-trend Neo-Tethys plate was the main geodynamic mechanism which induced the Cretaceous large-scale magmatisms in the southern margin of South China Block.     

内蒙古锡林浩特小乌兰沟早白垩世二长花岗岩LA-ICP-MS锆石U-Pb年龄及其地质意义

通过1∶5万区域地质调查,对中亚造山带南缘内蒙古锡林浩特小乌兰沟地区发育的二长花岗岩进行了岩石学、锆石U-Pb同位素年代学、地球化学等研究。LA-ICP-MS锆石U-Pb测年表明,该花岗岩的侵位年龄为(121.29±0.63)Ma,其形成时代为早白垩世。岩石地球化学研究表明,二长花岗岩具有高硅、富钾、贫镁、贫钙、低磷和低钛的特征,属于高钾钙碱性、过铝质系列岩石;微量元素特征表现为富含大离子亲石元素Rb和高场强元素Th、Ta,而亏损Nb、Sr、Ba;稀土元素以略富集轻稀土、Eu亏损为特征。地球化学特征反映其为A型花岗岩,是陆壳岩石部分熔融的产物。构造环境判别图解表明该岩体具有典型的后造山A2型花岗岩特征,说明早白垩世期间锡林浩特小乌兰沟地区已经处于后造山岩石圈伸展构造环境。     

The Late Triassic Kataev volcanoplutonic association in western Transbaikalia,a fragment of the active continental margin of the Mongol-Okhotsk Ocean

The Kataev volcanoplutonic association has been recognized in western Transbaikalia. It unites the volcanosedimentary rocks of the Kataev Formation and associated granites localized within the lower plates of the Buteel-Nuur and Zagan metamorphic-core complexes. The rocks of the Kataev association are dynamometamorphosed to different degrees, which is due to the tectonic exposure of metamorphic-core complexes in the Early Cretaceous. The U-Pb zircon dating of the Kataev Formation rhyolites yielded an age of 226 ± 3 Ma. The U-Pb zircon age of the granites intruding the Kataev Formation rocks is 223.4 ± 5.0 Ma. The volcanics of the Kataev Formation belong to the subalkalic basalt-andesite-dacite-rhyolite series. The trachybasalts and trachyandesite-basalts of the Kataev Formation have geochemical characteristics of igneous rocks formed as a result of subduction, e.g., they show distinct negative Nb and Ti and positive Ba and Sr anomalies on multielemental patterns. The specific composition of mafic volcanics points to their formation through the melting of a mantle source resulted from the mixing of depleted mantle and subduction components. Trachyandesites have higher Th and U contents than basaltoids. They can result from the contamination of a mantle source, similar in composition to the Kataev Formation basaltoids, with crustal material. The felsic volcanics of the Kataev Formation and granites intruding them show nearly identical geochemical characteristics corresponding to both A-and I-type granites. These rocks might have formed through the melting of a moderately water-saturated magmatic source of diorite-tonalite composition at 742–833°C. We have established that the rocks of the Kataev volcanoplutonic association in western Transbaikalia and Northern Mongolia formed in the Late Triassic synchronously with the calc-alkaline granitoids of the Henteyn–Daurian batholith and the alkali granites and bimodal volcanic associations of the Kharitonovo and Tsagaan-Hurtey volcanoplutonic associations. The synchronous formation of volcanoplutonic associations of normal and high alkalinity agrees with the geodynamic setting of the Andean-type active continental margin existing in the area of present-day western Transbaikalia and Northern Mongolia in the Early Mesozoic. This setting was the result of the subduction of the Mongol-Okhotsk oceanic plate beneath the Siberian continent.     

新疆伊宁地块晚泥盆世火山岩的确认及其地质意义

最新发现的泥盆纪火山岩位于西天山伊犁地块北缘,主要岩石组成为流纹岩,英安岩夹少量安山岩。锆石LA-ICP-MS U-Pb定年结果显示,尼勒克北流纹岩类的形成时代一致,分别为369.7±4.9Ma,363.4±2.5Ma,均为晚泥盆世。岩石SiO₂含量较高且变化范围较宽,Al₂O₃含量较高,富碱,贫镁和钙,高FeO^T/MgO+FeO^T比值,低TiO₂,里特曼指数δ较小(1.09~2.88),A/CNK值变化较大(0.8~1.46),属于钙碱性过铝-准铝质低钛流纹岩类。稀土元素总量(∑REE)变化较大(80.66×10^-6~241.8×10^-6),稀土配分模式为轻稀土富集右倾((La/Yb)_N=5.96~7.82),铕负异常明显(Eu/Eu^*=0.47~0.86),相对富集Rb、Th、K等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素,较高的Rb/Sr、Nb/Ta和Th/Ta比值(分别为0.18~5.15,11.18~13.96,3.54~9.5),较低的Ti/Zr、Ti/Y及Ta/Yb比值(分别为4.95~25.79,43.7~295.5,0.45~1.29),这些地球化学特征表明其可能为上地壳部分熔融的产物,源区残留物组成可能为斜长石和角闪石,同时显示其具有大陆边缘弧亲缘性,这与西天山在早石炭世处于岛弧环境相匹配,即在晚泥盆世-早石炭世期间,准噶尔洋向伊犁-中天山地块之下发生俯冲,形成了伊犁地块北缘的大陆边缘弧岩浆带。尼勒克北晚泥盆世流纹岩类成岩时代的确定及构造环境分析为进一步认识伊犁地块北缘地区的构造演化提供了新的证据。     

铜陵舒家店地区中生代中酸性侵入岩锆石Hf同位素特征及其地质意义

通过锆石LA-MC-ICP-MS Lu-Hf同位素分析,结合前人地球化学资料对舒家店地区中酸性侵入岩进行了研究.主量、微量元素地球化学特征表明区内侵入岩为准铝质,具有岛弧岩浆岩的特征,区内岩浆的演化可能经历了同化混染与分离结晶（AFC）过程.通过分析,我们认为舒家店地区的早白垩世岩浆活动可能与早白垩世初太平洋板块的斜向俯冲相关,侵入岩的形成演化受到了区域构造应力场的制约.Hf同位素分析及计算结果表明,除两个继承性锆石核外,本区侵入岩锆石的ε_Hf（t）均为负值,橄榄安粗岩系列侵入岩的ε_Hf（t）值为-8.6~-4.1,高钾钙碱性系列ε_Hf（t）值为-13.4~-4.7.与高钾钙碱性系列相比,橄榄安粗岩系列侵入岩的ε_Hf（t）更接近球粒陨石演化线.从ε_Hf（t）值的变化特征来看,两个系列侵入岩均为来源于富集地幔,且在演化过程中混染了地壳物质,而高钾钙碱性系列在这个过程中混入了更多的地壳物质.