Organochlorine pesticides in sediments of Laizhou Bay and its adjacent rivers, North China

Organochlorine pesticides (HCHs, DDTs and HCB) have been investigated in sediments of Laizhou Bay and its adjacent rivers. The average concentrations of HCHs, DDTs and HCBs are 0.09 ng/g dw, 0.59 and 0.05 for marine sediments and 0.55, 8.6 and 1.1 for riverine sediments, respectively. Laizhou Bay is less contaminated by HCHs and DDTs in comparison with other coastal regions around the world, including the other two biggest bays in Bohai Sea. Fresh input of lindane and dicofol-type DDT were found in several riverine sites. Relatively strong TOC-dependence of HCB distribution in the entire studied area suggested no point source existed and/or water-sediment equilibrium achieved. No significant difference of α/γ-HCH ratios have been observed between marine and riverine sediments. However, o,p′-DDT/p,p′-DDT ratios varied largely between the two regions.     

Persistent organic pollutant, trace metal and radionuclide concentrations in bottom organisms of the Barents Sea and adjacent areas

On data of the Barents Sea and some regions of the Kara, White, Norwegian and Greenland Seas transregional study, carried out in 1991–1992, concentrations of various contaminants in benthic algae and invertebrates are defined. According to the results of two-way ANOVA the conclusion about the absence of spatial variability in concentrations of POP, TM and K-40 in the investigated shelf biota is done. Concentrations of the analysed substances in organisms and the differences in contaminant bioaccumulation by plants and animals of various taxons are presented in a form of a table. In spite of the discrepant information about the background level of contamination, given by different authors, the obtained data to a greater degree corresponds to the idea of the background concentration of contaminants in biota, than testify to the man-induced pollution of the investigated area.     

渤海、黄海及附近地区地震趋势分析

1999年11月29日的岫岩5.4级地震,发生在一直被列为年度重点地震危险区的北侧,此次地震是1979年以来该区发生的最大、具有前震性质的震群型地震。5.4级地震的发生,是该区地震危险程度的缓解,还是标志着地震危险性继续增强,或者说是标志着该区地震活动将进入一个新的阶段?本文选取渤海、北黄海及附近地区(36°～41°N,119°～124.5°E)为研究区,以中国地震局分析预报中心编制的中国地震目录和日报目录以历史地震目录为基础资料(中国地震简目汇编组,1988),对上述几个问题进行研究。1　与渤海、黄海及附近地区地震趋势关系1.1　历史地震活动时…     

Radiocaesium distribution in the bottom sediments of the Kara Sea

The article presents the results of radiogeochemical studies carried out by the Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, RAS (IGEM RAS), in the Kara Sea and the estuaries of the Ob and Yenisei rivers in 1995–2003. The studies were carried out onboard the Akademik Boris Petrov research vessel, belonging to the Institute of Geochemistry, RAS. Based on studies of circa 1500 samples of bottom sediments, taken from 172 marine and river stations, a map of ¹³⁷Cs distribution in the surface sediments has been compiled. Four zones of radiocesium overactivity (>15 Bk/kg) have been identified: Novaya Zemlya Zone, Vaigach Zone, Ob Zone, and Yenisei Zone. The zones have different radiocesium concentration levels, as well as different input sources, but all of them have formed under the influence of complex geochemical barriers. Data from 47 sectioned cores of bottom sediments, sampled in Ob and Yenisei overactivity zones, demonstrate distinct differences in the vertical radiocesium distribution. These differences have been shown to be due to many-year oscillations of suspended silt discharge, which are main transfer agents of solvable and poorly solvable radiocesium forms and to be independent of sedimentation conditions and the geochemical characteristics of the deposition environment.     

Organic carbon flow in the Ob, Yenisey Rivers and Kara Sea of the Arctic region

Stable carbon isotope and elemental C/N ratios of the organic fraction of a set of samples along a transect in the Ob and Yenisey Rivers into the Kara Sea in the Arctic were measured. Previously, the concentrations of 239,240Pu and 137Cs in these same samples had been determined. The coupled measurements were carried out to assess possible connectivity between organic carbon flow into the Kara Sea and transport of radioactive nuclides in this marine environment. Organic carbon flow into the Kara Sea is influenced significantly by terrigenous sources carried by the Ob and Yenisey Rivers. The carbon isotope-organic carbon relationship provides evidence that a rich source of terrigenous carbon exists in the riverine system. A weak, but significant relationship between stable carbon isotope ratio and 137Cs suggests that most of the 137Cs is derived from riverine particles, as compared to Pu which is also derived from in situ scavenging within the water column.     

黄海及邻区莫霍面起伏特征

针对地壳构造形成的动力学机制,在广泛收集区域地质、地质构造和地球物理等资料的基础上,着重对重力数据进行了数字化、坐标、重力公式、投影方式和比例尺的统一化处理,进而进行了网格化处理.为将区域异常和局部异常分离开来,以便以对深部构造的系统研究,笔者选取趋势分析法分别对研究区内预处理后的布格重力异常数据(Δg)进行了三维多项式迭代拟合计算,得到了区域布格重力异常二阶、五阶、十阶趋势分析结果.继而,利用二级近似公式迭代法对布格重力异常五阶趋势分析区域异常数据进行了三维运算处理,得到了黄海及周边地区的莫霍面埋深值.分析了黄海及邻区莫霍面起伏特征,并进行了深部构造区划,探讨了深部断裂构造与莫霍面起伏间的成因联系,为深部构造和活动断裂演化的地球动力学研究提供了依据.     

中国海及邻域岩石圈三维密度分布

利用中国海及邻域的 2 0× 2 0网格密度异常和 15′× 15′的网格平均布格重力异常 ,采用约束最小二乘方法反演 ,得到了中国海及邻域岩石圈内六个层面上 15′× 15′的密度分布结果 .反演结果表明 :(1)中国海及邻域岩石圈密度极不均匀 ,反映了区内强烈的构造活动特征 ;(2 )层内密度分布与大地构造有明显的相关性 ,不同的构造单元存在着密度差异 ,断裂带表现为密度异常梯级带 .     

视密度反演在东海及邻区重力异常解释中的应用

简要介绍了基于位场分离的视密度反演法的原理,并利用该技术对东海的重力异常进行处理并进行了区域地质解释应用.视密度反演的方法在对研究区内的区域性大断裂如郯庐断裂、江绍断裂以及东引—海礁隐伏断裂有很好的分辨能力.不同深度的视密度切片信息能够帮助我们了解这些大断裂的发育深度和规模.在沟弧盆等地形以及构造复杂地区利用视密度反演法研究深部地质构造,可以揭示不同深度上补偿质量分布情况,从而推测莫霍面的起伏情况.     

Trace metals in the North Sea

The distribution of zinc, manganese, nickel, copper and cadmium in water and biological material has been measured in the southern North Sea and Straits of Dover, and off the north-east coast of England. These investigations provide baseline values against which future pollution changes can be measured.     

Entrainment of fine-grained surface deposits into new ice in the southwestern Kara Sea,Siberian Arctic

The entrainment of bottom deposits (silt and clay) into newly formed ice was investigated in the Amderma/Vaygach flaw lead in the southwestern Kara Sea, Siberian Arctic. Fine-grained bottom deposits and sea ice sediments (SIS) were analyzed by granulometry, scanning electron microscopy and X-ray diffractometry. On average, SIS contain by a factor of four times more silt than the shelf deposits (66.7% vs. 16.3%), and the SIS clay percentage is more than three-fold of the bottom value (31.2% vs. 9.1%). Sand-sized particles are significantly less abundant in SIS compared to bottom sediment (2.1% vs. 74.6%). The preferred entrainment of silt into ice is underpinned by the enhanced silt-to-clay-ratio in SIS compared to bottom deposits. Though silt is preferably entrained into SIS, no evidence was found for preferential ice-entrainment of any silt sub-fraction (coarse, medium or fine). However, sub-angular- and angular-discoidal silt particles are favorably entrained into local sea ice. Clay mineral assemblages in SIS and shelf surface sediments match very well revealing that no individual clay mineral is preferably enriched in SIS or reduced at the bottom. The general textural, compositional and statistical match of fine-grained shelf surface deposits and SIS proves that bottom sediment is the principle source for ice-entrained material in the study area. We propose e.g. wave action and thermohaline convection to take sediment particles upward from the bottom nepheloid layer into the well-mixed 10–40 m deep water column of the Amderma/Vaygach flaw lead, and the turbulent process of suspension freezing to bring sediment particles and frazil crystals into contact, finally leading to the formation of sediment-laden ice. The role of SIS entrainment and export for local/regional shelf erosion and coastal retreat is of minor importance in the SW Kara Sea compared to other circum-Arctic shelf seas. However, the characteristic clay mineral assemblage of local SIS and bottom deposits can help identify the origin of SIS both on regional and Arctic-wide scales.     

Radionuclide adsorption to sediments from nuclear waste dumping sites in the Kara Sea

Environmental parameters (salinity, sediment concentration, equilibration time) affecting radionuclide partitioning between sediment and seawater were experimentally investigated for Kara Sea sediments collected from nuclear waste dumping sites in Abrosimov and Stepovogo Bays off Novaya Zemlya. Adsorption kinetics were examined and the influence of salinity and sediment concentration were evaluated over the range of concentrations expected in the bays for the following radionuclides: ^{110 m}Ag; ²⁴¹Am; ¹⁰⁹Cd; ⁶⁰Co; ⁵⁷Co-cobalamine; ¹³⁴Cs; ¹⁵²Eu; ⁵⁴Mn; ¹³³Ba; ¹⁰⁶Ru; and ⁸⁵Sr. The major findings of this investigation are that 1. radionuclide distribution coefficients (K_ds) were most sensitive to variations in sediment character (²⁴¹Am, ⁶⁰Co, ¹⁰⁹Cd) and concentration (⁵⁷Co-cobalamine, ⁸⁵Sr, and ¹³³Ba), 2. distribution coefficients generally decreased with increasing sediment concentration and 3. fast adsorption kinetics (near equilibrium ≈1 day) were observed only for ¹³⁷Cs and ^{110 m}Ag. The observed differences in K_ds for sediments from the two dumpsites exemplifies the importance of undertaking site-specific determinations of K_ds. For purposes of confining radioactive wastes to the dumpsites in Stepovogo and Abrosimov Bays, the findings of this study indicate that based on sediment character alone, Stepovogo Bay will be more effective at retaining radionuclides than Abrosimov Bay. This is unfortunate since less radioactive waste resides in Stepovogo Bay (0.6 PBq) than in Abrosimov Bay (1.4 PBq).     

Trace metals in the northern North Sea

Cadmium, lead and copper have been determined in the dissolved and particulate phase for surface waters of the northern North Sea. Dissolved cadmium and copper show concentration gradients associated with salinity fronts which mark the boundary between coastal and ocean waters; lead does not. The particulate phase is shown to represent only a small fraction of the total metal concentration. Processes likely to be responsible for the observed distribution are discussed.     

Environment and biology of the Kara Sea: a general view for contamination studies

The recent revelation that over the past 30 years there has been a history of dumping waste including high-level radioactive wastes in the shallow Kara Sea has caused wide-spread concern. The potential impact of these contaminants and other non-nuclear pollutants in the Arctic ecosystem and on human health need to be assessed and, thus, a better insight gained on radioecological processes in cold waters. The present paper proposes a general view on the biology and the environment of the Kara Sea, as a basic tool for the experimental and modelling assessments of the impact of these contaminants.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea,Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06–168.21 mg kg⁻¹ for Zn, 8.91–46.94 mg kg⁻¹ for Cr, 2.69–49.39 mg kg⁻¹ for Cu, 32.46–185.54 mg kg⁻¹ for V, 0.09–0.92 mg kg⁻¹ for Cd, and 0.95–15.25 mg kg⁻¹ for Pb. The geoaccumulation index (I_geo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Trace metal concentrations and fluxes in Bermuda sediments

Concentrations and calculated fluxes of trace metals into Bermuda nearshore marine and lake sediments are presented. In areas affected by anthropogenic activity, metal profiles show surface sediment enrichments similar to those observed in North American and European lacustrine and estuarine sediments. Atmospheric fluxes of Cu, Zn and Pb into the lake sediments are higher than those of rural areas in North America. These high fluxes are assumed to be due to jet-fuel combustion. Sediment profiles in the Hamilton City area indicate increased anthropogenic input of Cu and Pb compared to other marine locations.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea, Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06-168.21 mg kg(-1) for Zn, 8.91-46.94 mg kg(-1) for Cr, 2.69-49.39 mg kg(-1) for Cu, 32.46-185.54 mg kg(-1) for V, 0.09-0.92 mg kg(-1) for Cd, and 0.95-15.25 mg kg(-1) for Pb. The geoaccumulation index (Igeo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

黄海及其邻近地区的Pn波速度与各向异性

利用中国东部地震台网和ISC 报告1980~2004年的地震走时数据,反演了黄海及其邻近地区的Pn波速度和各向异性,根据岩石层地幔的横向非均匀性分析了区域地质构造的深部特点.Pn波速度的变化与区域地质构造有一定的对应关系,黄海地区上地幔顶部的P波平均速度较高,没有发现明显的低速异常,表明上地幔顶部不存在大范围的地幔扰动.速度异常的分布表明,南黄海东部和西部有可能分属于不同的构造块体,其间的分界大致对应于南北走向的黄海东部断裂带,具有相对较低的Pn波速度.边界东、西两侧的Pn波各向异性存在明显的差异：南黄海西部Pn波的快波方向以北东—北北东方向为主,反映了海区内部扬子块体向北运动产生的构造变形;南黄海东部Pn波的快波方向为南北方向,与黄海东部断裂带的走向基本一致,说明黄海东部和西部之间存在一个深达岩石层地幔的南北向转换边界.结合相关资料估计黄海东部断裂带在中生代时期发生了右旋走滑运动,以响应中国东部郯庐断裂带的大规模左旋剪切以及南黄海扬子块体的向北嵌入.