The carbon isotopic response of algae, (cyano)bacteria, archaea and higher plants to the late Cenomanian perturbation of the global carbon cycle: Insights from biomarkers in black shales from the Cape Verde Basin (DSDP Site 367)

The stable carbon isotopic compositions of free and sulfur (S)-bound biomarkers derived from algae, (cyano)bacteria, archaea and higher plants and total organic carbon (TOC) during the first phase of the late Cenomanian/Turonian oceanic anoxic event (OAE) were measured in black shales deposited in the southern proto-Atlantic Ocean in the Cape Verde basin (DSDP Site 367) to determine the response of these organisms to this major perturbation of the global carbon cycle resulting from widespread burial of marine organic matter. The average positive isotope excursions of TOC and biomarkers varied from 5.1‰ to 8.3‰. The δ¹³C values were cross correlated to infer potential common sources of biomarkers. This revealed common sources for C₃₁ and C₃₂ hopanes but no 1:1 relationship for pristane and phytane. The correlation of δ¹³C_TOC with the δ¹³C value of sulfur (S)-bound phytane is the strongest. This is because S-bound phytane is derived from phytol that originates from all marine primary producers (algae and cyanobacteria) and thus represents a weighted average of their carbon isotopic compositions. The δ¹³C values of S-bound phytane and C₃₅ hopane were also used to estimate pCO₂ levels. Before the OAE burial event, pCO₂ levels are estimated to be ca. 1300 ppmv using both biomarkers and the independent maximum Rubisco fractionation factors. At times of maximum organic carbon burial rates during the OAE, reconstructed pCO₂ levels are estimated to be ca. 700 ppmv. However, compared to other C/T OAE sections the positive isotope excursion of S-bound phytane is also affected by an increased production during the OAE. When we compensate for this, we arrive at pCO₂ levels around 1000 ppmv, a reduction of ca. 25%. This indicates that burial of organic matter can have a large effect on atmospheric CO₂ levels.     

Micropaleontological evidence for redox changes in the OAE3 interval of the US Western Interior: Global vs. local processes

The Coniacian-Santonian interval has been proposed as the youngest of the Cretaceous ocean anoxic events (OAE3), but this designation has long been debated. OAE3 is associated with a long-lasting (∼3 myr) succession of black shales from the central and South Atlantic, Caribbean region, and the North American Western Interior; in the Western Interior it is characterized by an abrupt increase in total organic carbon (TOC) and corresponding trace metal indicators for anoxia. However, the modern concept of OAEs is predicated on detection of global carbon cycle perturbations as recorded by substantial carbon isotope excursions (CIE), and the protracted Coniacian-Santonian black shale interval does not have a large CIE. A more conservative definition of OAE3 might limit the event to the modest positive carbon isotope excursion restricted to the upper Coniacian Scaphites depressus Ammonite Zone. Trace metal proxies suggest that oxygen levels abruptly declined prior to the onset of this CIE in the Western Interior Sea (WIS), but it is unknown whether regional anoxic conditions were confined to sediments/pore waters, or how anoxia may have affected the biota. In an effort to characterize the oxygenation history of the WIS and to better understand the nature of the hypothesized OAE3, we present micropaleontological evidence of declining oxygen in bottom waters prior to the event using benthic foraminifera, which are sensitive to dissolved oxygen. Changes in benthic foraminiferal abundances suggest a decline in oxygen at least 1-myr prior to the CIE (including a nadir immediately below the start of the excursion), improving bottom water oxygen during the CIE, and re-establishment of persistent anoxia following the isotope excursion. Anoxia endured for nearly 3 myr in the central seaway, showing some signs of recovery toward the top of the Niobrara Formation. Our findings suggest that declining oxygen concentrations in the seaway eventually reached a tipping point, after which dissolved oxygen quickly dropped to zero.The late Coniacian CIE is an exception to the trend of declining oxygen in the WIS, and part of a larger pattern in the oxygenation history of the Niobrara Formation which suggests that it does not adhere to standard black shale models. Transgressive periods, including the Fort Hays Limestone and the lower limestone unit of the Smoky Hill Shale (which corresponds to the CIE) are relatively oxic, while periods of highstand (i.e., most of the Smoky Hill) correspond to deteriorating oxygen conditions. This contrasts with the standard black shale model for sea level and oxygen, where transgressions typically correlate with maximum TOC enrichment, interpreted to result from both sediment condensation and oxygen deficiency. The association of global carbon burial/anoxia (as indicated by carbon isotopes) with a regional increase in oxygen and decrease in organic matter preservation is reminiscent of the Cenomanian-Turonian Greenhorn Limestone, which contains OAE2. In both cases, the facies are not typical black shales, but instead have appreciable carbonate content. Western Interior redox trends support the rejection of the original concept of a protracted Coniacian-Santonian OAE3 because it is not a distinct “event.” Increasing local oxygen during the late Coniacian CIE also argues against a narrower OAE designation for this event, because the excursion can't be tied to anoxia here or anywhere else it has been described. Nevertheless, the Late Coniacian Event (as we prefer to call this CIE) still represents an important perturbation of the global carbon cycle. This is emblematic of the shift away from widespread, discrete anoxic events during the ongoing paleoceanographic reorganization of the Late Cretaceous, even as large carbon cycle perturbations continued.     

The response of two Tethyan carbonate platforms to the early Toarcian (Jurassic) oceanic anoxic event: environmental change and differential subsidence

Chemostratigraphic analyses (⁸⁷Sr/⁸⁶Sr, δ¹³C_carb) of limestones from two Jurassic platform‐carbonate sequences in Italy (Trento and Campania–Lucania Platforms) illustrate previously established trends found in pelagic sediments and skeletal carbonates from biostratigraphically well‐calibrated sections elsewhere in Europe. Chemostratigraphic correlations between the platform‐carbonate successions and appropriate intervals from well‐dated reference sections allow the application of high‐resolution stratigraphy to these shallow‐water peritidal carbonates and, furthermore, elucidate the facies response to the Early Toarcian Oceanic Anoxic Event (OAE). Lower Jurassic (Toarcian) levels of the western Trento Platform (Southern Alps, Northern Italy) contain spiculitic cherts that appear where rising carbon‐isotope values characterize the onset of the OAE: a palaeoceanographic phenomenon interpreted as driven by increased nutrient levels in near‐surface waters. There is a facies change to more clay‐rich facies at the level of the abrupt negative carbon‐isotope excursion, also characteristic of the OAE, higher in the section. The Campania–Lucania Platform (Southern Apennines, Southern Italy) records a change to more clay‐rich facies where carbon‐isotope values begin to rise at the beginning of the OAE but the negative excursion, higher in the section, occurs within oolitic facies. Although, in both examples, the Early Toarcian OAE can be recognized by a change to more clay‐rich lithologies, this facies development is diachronous and in neither case did the platform drown. Although the Trento Platform, in the south‐west sector studied here, was adversely affected by the OAE, it did not drown definitively until Late Aalenian time; the Campania–Lucania Platform persisted throughout the Jurassic and Cretaceous. Differential subsidence rates, which can be calculated using comparative chemostratigraphy, are identified as a crucial factor in the divergent behaviour of these two carbonate platforms: relatively fast in the case of the Trento Platform; relatively slow in the case of the Campania–Lucania Platform. It is proposed that where water depths remained as shallow as a few metres during the OAE (Campania–Lucania Platform), dissolved oxygen levels remained high, nutrient levels relatively low and conditions for carbonate secretion and precipitation remained relatively favourable, whereas more poorly ventilated and/or more nutrient‐rich waters (Trento Platform) adversely influenced platform growth where depths were in the tens of metres range. The stage was thus set for drowning on the more rapidly subsiding western margin of the Trento Plateau and a pulse of oolite deposition post‐dating the OAE was insufficient to revitalize the carbonate factory.     

白垩纪至早第三纪的极端气候事件

地球科学界正在将预测未来气候变化的研究重点放到地球过去突然发生的气候变暖事件。白垩纪至早第三纪发生的极端气候事件被认为是最接近于现今的地球系统,对其研究有利于理解现今地球系统过程在碳循环快速搅动时的响应。这些气候事件主要包括：古新世-始新世最热事件（PETM,～5 5 MaBP）、早阿普第晚期和森诺曼-土仑界线的大洋缺氧事件（OAE1a,～120 Ma;OAE2,～93．5 MaBP）。PETM事件是中白垩世以来一次突然变暖事件,在10 ka年以内深海温度增加～5 ℃,表层海水温度增加 4～8 ℃,而δ¹³C至少发生 3．0‰的负偏移。目前普遍认为PETM事件是由于海洋气水化合物（CH₄）的巨量释放造成的。大洋缺氧事件（OAEs）记录了海洋环境下有机质的大量埋藏,代表了碳循环和海洋生物系统的重大搅动事件。综合大洋钻探计划（IODP）将极端气候确定为优先研究领域,将采取特定的钻探策略,在世界大洋范围内获取最低限度蚀变的新生代至白垩纪沉积物,研究精度要求达到米兰柯维奇的天文调谐时间尺度,其最终目标是定量描述过去全球气候变化,并为未来气候变化预测提供依据。     

Lithology, landscape dissection and glaciation controls on catchment erosion as determined by cosmogenic nuclides in river sediment (the Wutach Gorge, Black Forest)

Cosmogenic nuclides, measured in quartz from recent river bedload, provide a novel tool to quantify catchment‐wide erosion rates at geologically meaningful time scales. Here we present an analysis of the geomorphological evolution of the 350 km² Wutach catchment in the uplands of the south‐west German Black Forest. The robustness of the method is demonstrated by the fact that, although the area was affected by river capture at 18 kyr bp , the formed gorge is so narrow that spatially averaged erosion rates were not resolvably perturbed. However, because cosmogenic nuclides preserve an erosion memory of several thousand years, the only perturbation introduced was detected in the minor areas that have been subject to the last maximum glaciation. In unglaciated areas, an important relationship between lithology and erosion can by quantified: sandstone lithologies erode at 12–18 mm kyr^?1, granite lithologies at 35–47 mm kyr^?1 and limestone lithologies (as deduced from river load gauging) at 70–90 mm kyr^?1.     

Sedimentary architecture and genesis of Holocene shallow-water mud-mounds, northern Belize

Abstract Cangrejo and Bulkhead Shoals are areally extensive, Holocene biodetrital mud‐mounds in northern Belize. They encompass areas of 20 km² and 35 km² in distal and proximal positions, respectively, on a wide and shallow‐water, microtidal carbonate shelf where storms are the major process affecting sediment dynamics. Sediments at each mound are primarily biodetrital and comprise part of a eustatically forced, dominantly subtidal cycle with a recognizable deepening‐upward transgressive systems tract, condensed section and shallowing‐upward highstand systems tract. Antecedent topographic relief on Pleistocene limestone bedrock also provided marine accommodation space for deposition of sediments that are a maximum of 7·6 m thick at Cangrejo and 4·5 m thick at Bulkhead. Despite differences in energy levels and location, facies and internal sedimentological architectures of the mud‐mounds are similar. On top of Pleistocene limestone or buried soil developed on it are mangrove peat and overlying to laterally correlative shelly gravels. Deposition of these basal transgressive, premound facies tracked the rapid rate of sea‐level rise from about 6400–6500 years BP to 4500 years BP, and the thin basal sedimentation unit of the overlying mound‐core appears to be a condensed section. Following this, the thick and complex facies mosaic comprising mound‐cores represents highstand systems tract sediments deposited in the last ≈ 4500 years during slow and decelerating sea‐level rise. Within these sections, there is an early phase of progradationally offlapping catch‐up deposition and a later (and current) phase of aggradational keep‐up deposition. The mound‐cores comprise stacked storm‐deposited autogenic sedimentation units, the upper bounding surfaces of which are mostly eroded former sediment–water interfaces below which depositional textures have largely been overprinted by biogenic processes associated with Thalassia‐colonized surfaces. Vertical stacking of these units imparts a quasi‐cyclic architecture to the section that superficially mimics metre‐scale parasequences in ancient rocks. The locations of the mud‐mounds and the tidal channels transecting them have apparently been stable over the last 50 years. Characteristics that might distinguish these mud‐mounds and those mudbanks deposited in more restricted settings such as Florida Bay are their broad areal extent, high proportion of sand‐size sediment fractions and relatively abundant biotic particles derived from adjoining open shelf areas.     

Geochemistry of the Batang Group in the Zhaokalong Area,Yushu, Qinghai: Implications for the Late Triassic Tectonism in the Northern Sanjiang Region,China

The Batang Group in the Zhaokalong area not only hosts an important Fe-Cu polymetallic deposit but also reveal important insights for the Late Triassic tectonism in the northern Sanjiang region. In order to delineate the tectonic setting and evolutionary process of the paleo arc-basin system, geochemical studies on the Batang Group strata have been carried out. The results suggest that andesite in the Zhaokalong area mainly belongs to the tholeiite series and is characterized by obvious fractionation of LREE and HREE, enrichment in LILE and depletion in HFSE, and a distinctly elevated δ~(34)SCDT average of 10.5‰. The sandstone is classified as lithic sandstone, which is also characterized by obvious fractionation of LREE and HREE, as well as weak negative Ce and Eu anomalies. The limestone displays positive Eu anomalies, with δ~(13)CPDB ranging from-1.3‰ to 4.4‰ and δ~(18) OSMOW ranging from 14.6‰ to 22.5‰. These results indicate that the andesite has a dual signature of both arc andesite and rift volcanic rocks, whereas the sandstone may be formed in an active continental margin, and the limestone could be deposited in a weak oxidizing shallow sea. The sandstone in the Zhaokalong area represents sedimentation in a platform slope facies, corresponding to the main stage of the Jinshajing oceanic basin subduction during the middle period of Late Triassic. The continental arc volcanic activity resulted from subsequent strengthened subduction, forming the andesite in the North Qiangtang backarc basin. Afterwards, the limestone was formed after the cessation of magmatic activity. The information gleaned from the Batang Group strata helped constrain the evolution of the paleo-Jomda island arc and Jinshajiang oceanic subduction in the Late Triassic.     

Syntectonic hydrothermal calcite in a faulted carbonate platform margin (Albian of Jorrios, northern Spain)

ABSTRACT A calcite mass more than 1·5 km long and 20 m wide crops outs along the faulted margin of the Albian carbonate platform of Jorrios in northern Spain. The mass contains abundant dissolution cavities up to 7 m long and 1 m high, filled with cross‐stratified quartz sandstone and alternating sandstone–calcite laminae. Similar cavities are also present in a 50‐m‐wide zone of platform limestones adjacent to the calcite mass that are filled with limestone breccias and sandstone. The calcite mass has mean δ¹⁸O values of 19·6‰ (SMOW), whereas platform limestones have mean δ¹⁸O values of 24·4‰ (SMOW). Synsedimentary faulting of the carbonate margin and circulation of heated fault‐related waters resulted in replacement of a band of limestone by calcite. Soon after this replacement, dissolution by undersaturated fluids affected both the calcite mass and the adjacent limestones. Percolating marine quartz sand filled all dissolution cavities, sometimes alternating with precipitating calcite. The resulting cavities and fills, which recall products of meteoric diagenesis, are attributed to a hydrothermal origin based on their geometry, occurrence along the profile and synsedimentary tectonic relationships. The early faulting and diagenesis are related to local extensional tectonism in a large‐scale strike‐slip setting. Movements occurred during the early dispar/appenninica zone of the Late Albian.     

Lacustrine sedimentary record of early Aptian carbon cycle perturbation in western Liaoning,China

The early Aptian abrupt carbon isotope excursion in marine carbonate and sedimentary organic matter reflects a major perturbation in the global carbon cycle. However, until now almost all the evidences of this event came from marine deposits. Here we present organic-carbon isotope (δ¹³C_org) data from the non-marine Jehol Group in western Liaoning, China. The lacustrine δ¹³C_org curve is marked by a relative long-lasting δ¹³C_org minimum followed by two stages of positive δ¹³C_org excursions that are well correlated with contemporaneous marine records. The carbon isotope correlation shows that the lacustrine strata of the Jehol Group were deposited at the same time of the early Aptian Oceanic Anoxic Event (OAE1a). The relative long-lasting δ¹³C_org minimum supports the hypothesis that volcanic CO₂ emission may have played the main role in triggering the negative δ¹³C excursion and global warming at the onset of this event. In addition, the onset of δ¹³C_org minimum is concomitant with the radiation of the Jehol Biota, implying that the evolutionary radiation of the Jehol Biota may have been closely related with the increase in atmospheric CO₂ and temperature.     

影响C4草本植物C/N比值变化的因素与土壤有机C积累的关系

文章对采自贵州从低海拔的东部到高海拔的西部且大致平行的石灰岩和砂岩两地带均生长的3种C₄草本植物,即巴茅(Miscanthusfloridulus)、白茅(Imperatacylindrica)和类芦(Neyraudiareynaudiana),以及相对应的土壤表层样品,进行了营养元素和C同位素组成分析;研究营养元素含量随着海拔的不同而出现的变化趋势,以及这些元素之间的相互协变作用,尤其是Ca和N之间的相互协变作用对植物的N含量、C/N比值和^δ13C值的影响,以了解植物的C/N比值(指示植物残留物质量的一种标志)与土壤有机C积累的关系。研究结果表明,植物的N含量和^δ13C值具有随海拔的上升而显著增大趋势,而植物的C/N比值在砂岩地区虽有减小的趋势,在石灰岩地带则没有。对所研究的C4草本植物来说,在土壤pH值为5.8的中性条件下显示出Ca的最大吸收,因此,Ca与其他营养元素之间的协变模式在两种土壤类型中表现出相反的倾向,并存在土壤交换性Ca的边界浓度:当土壤可交换性Ca的含量为2.24mg/g,相应土壤的pH值在5.8以下时,随着土壤可交换性Ca浓度的增大,植物的N含量上升,而植物的C/N比值会显著降低;当Ca在边界浓度以上时,随着土壤可交换性Ca浓度的增大,植物的N含量下降,而植物的C/N比值有增加的趋势。由此可见,植物残留物的N含量和C/N比值受Ca元素含量的相     

Tectonic control on third‐order sequences in a siliciclastic ramp‐style basin: An example from the Roper Superbasin (Mesoproterozoic), northern Australia

TThe Roper Group is a cyclic, predominantly marine, siliciclastic succession of Calymmian (Early Mesoproterozoic) age. It has a distribution of at least 145 000 km² and a maximum known thickness of ～5000 m. In the Roper River district the middle part of the Roper Group (～1300 m thick) is characterised by the cyclical alternation of mudstone and sandstone units, and can be divided into six third‐order depositional sequences. A typical sequence is broadly progradational in aspect, and comprises a lower, mudstone‐rich, storm‐dominated shelf succession (up to 330 m thick), and a sequence‐capping unit dominated by tidal‐platform cross‐bedded sandstone (up to 80 m thick); both are interpreted as highstand systems tracts. Transgressive strata are poorly represented but where present are characterised by paralic to fluvial redbed assemblages that include ooidal ironstone. Roper Group sequences lack a distinct condensed section and sequence boundaries are mostly conformable. Erosional contacts separate mud‐rich shelf facies from sequence‐capping sandstones. We infer that these erosion surfaces were generated by episodic flexural tectonism, which also generated the accommodation and sediment supply for Roper sequences.     

Tertiary stratigraphy of Western Australia

This paper is a summary of the present knowledge of the Tertiary stratigraphy of Western Australia. Also included is new information on the Cainozoic of the Carnarvon Basin, a result of petroleum exploration in the area.

Tertiary rocks formed during more than one cycle of deposition in three basins (Eucla, Perth, and Carnarvon), and also as thin units deposited in a single transgression along the south coast. The Tertiary stratigraphy of the Bonaparte Gulf Basin is not well known.

Drilling in the Eucla Basin has encountered up to 400 m of Tertiary in the south central part, with uniform thinning towards the margins. The section begins with a middle‐upper Eocene carbonate unit which represents the dominant event in the Tertiary sedimentation in this basin. More carbonates were deposited in the late Oligocene‐early Miocene and middle Miocene.

Along the south coast, the so‐called Bremer Basin, the Plantagenet Group (up to 100 m) of siltstone, sandstone, spongolite, and minor limestone, was deposited during the late Eocene.

The Perth Basin contains up to 700 m of Tertiary sediment, formed during at least two phases of sedimentation. The upper Paleocene‐lower Eocene Kings Park Formation consists of marine shale, sandstone, and minor limestone, with a thickness of up to 450 m. The Stark Bay Formation (200 m) includes limestone, dolomite, and chert formed during the early and middle Miocene. Events after deposition of the Stark Bay Formation are not well known.

The northern Carnarvon Basin and Northwest Shelf contain by far the most voluminous Tertiary sediment known from Western Australia: 3500 m is known from BOCAL's Scott Reef No. 1. A more usual maximum thickness is 2500 m. Most sediments were laid down in four episodes, separated by unconformities: late Paleocene‐early Eocene; middle‐late Eocene; late Oligocene‐middle Miocene; and late Miocene to Recent.

The Paleocene‐early Eocene cycle consists of about 100–200 m (up to 450 m in the north) of carbonate, shale, and marl of the Cardabia Group containing rich faunas of planktonic foraminifera.

The middle‐late Eocene sediments include diverse rock types. Marine and nonmarine sandstone formed in the Merlinleigh Trough. At the same time, the Giralia Calcarenite (fauna dominated by the large foraminifer Discocyclina) and unnamed, deeper water shale, marl, and carbonate (with rich planktonic foraminiferal faunas) formed in the ocean outside the embayment. Thickness is usually of the order of 100–200 m.

The main cycle of sedimentation is the late Oligocene‐middle Miocene, during which time the Cape Range Group of carbonates formed. This contains dominantly large foraminiferal faunas, of a wide variety of shallow‐water microfacies, but recent oil exploration farther offshore has recovered outer continental shelf facies with abundant planktonic foraminifera. A minor disconformity representing N7 and perhaps parts of N6 and N8 is now thought to be widespread within the Cape Range Group. The last part of this cycle resulted in sedimentation mainly of coarse calcareous marine sandstone (unnamed), and, in the Cape Range area, of the sandstone and calcareous conglomerate of the Pilgramunna Formation. Maximum thickness encountered in WAPET wells is 900 m.

After an unconformity representing almost all the late Miocene, sedimentation began again, forming an upper Miocene‐Recent carbonate unit which includes some excellent planktonic faunas. Thickness is up to 1100 m.

Thin marine sediments of the White Mountain Formation outcrop in the Bonaparte Gulf Basin. They contain some foraminifera and a Miocene age has been suggested.     

Paleocirculation and foraminiferal assemblages of the Cenomanian–Turonian Bridge Creek Limestone bedding couplets: Productivity vs. dilution during OAE2

The limestone–marlstone (or limestone–calcareous shale) bedding couplets of the lower Bridge Creek Member of the Greenhorn Formation coincide with Oceanic Anoxic Event 2 and the Cenomanian–Turonian stage boundary at 93.9 Ma, and are characterized by fluctuations in microfossil and macrofossil biofacies, and organic carbon. Since G.K. Gilbert (1895), these strongly alternating lithofacies have been attributed to climate and/or productivity cycles. Heretofore, only the calcareous shale and marlstone parts of the Bridge Creek bedding couplets have been quantitatively analyzed for planktic and benthic foraminiferal assemblages. In this study, foraminiferal assemblages extracted from the hard limestone beds are comparable with the muddier lithologies thereby allowing a quantitative evaluation of the foraminiferal response to cyclically changing conditions in the U.S. Western Interior Sea (WIS) that resulted in the deposition of these lithologic couplets. The results reveal a modest cyclical response of foraminiferal assemblages extracted from limestone beds compared to adjacent calcareous shale or marlstone. These include the absence of planktic planispiral morphotypes (Globigerinelloides), increase in the proportion of planktic biserial and triserial morphotypes (Heterohelix and Guembelitria, respectively), and an increase in the proportion of benthics relative to total foraminifera (decrease in percent planktics) in the limestone beds. Such conditions suggest that the limestones may have been more productive than the adjacent shales and marlstones. Reduced surface salinity and greater stratification of the upper water column may have also contributed to the differences in assemblages preserved in the marlstones and calcareous shales. The onset of OAE 2 in the late Cenomanian is marked by an abrupt benthic oxygenation event (‘Benthonic Zone’) as Tethyan waters were drawn well north into the WIS, and cool Boreal waters spread across northwest Europe, known as the Plenus Cold Event. At this time, the WIS became an important ocean gateway for surface ocean circulation with rising sea level that helped facilitate the development and spread of OAE 2. A cyclonic (counterclockwise) gyre circulation in the WIS during deposition of the lower part of the Bridge Creek was driven by the difference between precipitation in the north and evaporation in the south. The gyre is represented by two modes, strong and weak, responsible for deposition of the limestone and marlstone, respectively. For the middle and upper parts of the studied section representing the plateau of OAE 2 and subsequent peak transgression of the WIS, the counterclockwise gyre was driven less by E-P gradient but by the amount of surface runoff from both margins of the WIS with deposition of limestone beds during the wetter (strong) phase and marlstones during the drier (weak) phase. Highest levels of TOC redevelop after OAE 2 in the early Turonian with the incursion or development of an oxygen minimum zone at the time of peak transgression.     

The oceanic anoxic event 2 at Es Souabaa (Tebessa,NE Algeria): bio-events and stable isotope study

At the southern margin of the Tethys, the Es Souabaa area recorded traces of Oceanic Anoxic Event 2 (OAE2) around the Cenomanian-Turonian boundary (C/Tb). The dark, laminated, filament- and pyrite-bearing limestones represent the typical facies of this event. In terms of sedimentary environment, these features reflect a transgressive drowning that had induced hypoxia in these sedimentary environments. Such conditions favored the deposition and preservation of organic matter of marine origin, the distribution of which was controlled by paleogeography and halokinetic tectonics at that period. The OAE2 reached a climax between the last upper Cenomanian occurrence of Rotalipora cushmani and the lower Turonian occurrence of Whiteinella praehelvetica. Positive shift of the δ¹³C excursion along with relatively high total organic carbon (TOC) contents during OAE2 both indicate palaeo-environmental modifications enhanced by a significant change in primary marine productivity. Meanwhile, negative δ¹⁸O peaks in carbonates reflect increasing temperatures. Comparison of the data from this study with those from the neighboring Kalaat Senan section (Tunisia) suggests close similarities of events, although OAE2 is much more enhanced in Algeria.     

Upper Albian OAE 1d event in the Chihuahua Trough,New Mexico,U.S.A.

Oceanic anoxic events are clues to ocean processes and are correlation datums. In North America only OAE 1a and 2 are well documented. Based on a low-resolution sampling program, a multi-proxy geochemical approach constrained by a biostratigraphic framework was utilized to identify OAE 1d in the upper part of the upper Albian Mesilla Valley Formation near El Paso, Texas. Chronostratigraphic and biostratigraphic evidence indicate that the OAE 1d event in the Mesilla Valley section is located in the lower part of the upper Albian–Cenomanian Ovoidinium verrucosum zone, which correlates with the uppermost Albian Parathalmanninella appenninica and Stoliczkaia dispar zones. The chronostratigraphic age of the geochemical event in the Mesilla Valley Formation is uppermost Albian (97.39–97.30 Ma).The classic geochemical signatures for OAEs are enriched total organic carbon (TOC) concentrations and coupled positive δ¹³C excursions. OAE 1d at this location records TOC values ranging from 0.25 to 0.69 wt.% throughout the Mesilla Valley Formation, where TOC increases during the OAE (21.0–40.0 m) to more than 0.40 wt.%. Interestingly, the organic matter in the Mesilla Valley is dominantly type III, which indicates a pervasive terrigenous source. Although marine organic matter is abundant from the base into the middle of the proposed OAE interval, it is progressively replaced by terrestrial material above the OAE section during progradation. The δ¹³C_organic values record a positive δ¹³C shift of +1.6‰ from −26.41 to −24.80‰ across the stratigraphic interval from 21.0 to 40.0 m, which correlates with OAE 1d.Mn and Fe geochemistry suggest the depositional conditions of the Mesilla Valley Formation were dominated by anoxic and possibly Fe-rich bottom waters, specifically during the time period associated with the OAE 1d event. This interpretation is supported by the presence of Fe enrichment recorded by Fe_Total/Al and Fe_{Highly Reactive}/Fe_T with the lack of Fe_pyrite/Fe_{Highly Reactive} associated with Mn depletion.     

鲁西北西向断裂系晚中生代活动的几何学、运动学及年代学研究

鲁西隆起区发育有大量的北西向脆性断裂.依据野外断裂构造的几何学、运动学详细解析,认为北西向断裂系经历了早期的右行压剪、右行张剪,以及后期的左行压剪等不同性质的构造活动.由与北西向断裂活动相伴生的同期侵入岩体的 K-Ar测试结果分析,北西向断裂系在距今约160 Ma及距今130～110 Ma分别经历了右行压剪与右行张剪构造活动;通过分布在隆起区不同样品的磷灰石裂变径迹数据分析、冷却史反演,厘定鲁西地体在距今90～80 Ma存在一次区域性快速冷却构造事件,该构造事件与北西向断裂系的左行压剪构造活动相对应.     

鲁西北西向断裂系晚中生代活动的几何学、运动学及年代学研究

鲁西隆起区发育有大量的北西向脆性断裂。依据野外断裂构造的几何学、运动学详细解析认为,北西向断裂系经历了早期的右行压剪、右行张剪,以及后期的左行压剪等不同性质的构造活动。由与北西向断裂活动相伴生的同期侵入岩体的 K-Ar测试结果分析,北西向断裂系在距今约160 Ma及距今130~110 Ma分别经历了右行压剪与右行张剪构造活动;通过分布在隆起区不同样品的磷灰石裂变径迹数据分析、冷却史反演,厘定鲁西地体在距今90~80 Ma存在一次区域性快速冷却构造事件,该构造事件与北西向断裂系的左行压剪构造活动相对应。     

浙江长兴二叠系和三叠系界限地层的碳同位素

研究海相碳酸盐岩的碳和氧同位素已有三十多年,积累了数千个数据,其目的在于研究古海洋碳和氧同位素的演变。在此期间,一部分研究者认为,海相碳酸盐岩的δ¹³C值在0±2范围内变化,未表现出与地质时代相关的变化趋势(Clayton和Degens,1959;Degens和Epstein,1962;Keith和Weber,1964;Galimov,1965;Becker和Clayton,1972;Schidlowski等,1975)。但是,另一些学者,如Jeffery等(1955),Baertschi(1975),Compston(1960),Weber(1967),Garrels和Parry(1974)却认为,海相碳酸盐岩的δ¹³C值随地质时代而有规律地变化。     

中国南方表层岩溶系统的碳循环及其生态效应

表层岩溶系统因碳酸盐岩－水－CO²(气)三相的化学动态不平衡过程而产生特殊的碳循环环节,参加循环的碳包括碳酸盐岩中的碳、大气和土壤空气CO²部分。中国南方表层岩溶系统的碳循环非常活跃,并敏感地响应岩溶动力因素的变化,从而促进了地球化学过程和生物化学过程的结合,成为大气CO²汇的重要项。中国南方表层岩溶系统的碳循环通过驱动环境的元素迁移,促进土壤有机质的积累,并影响植物所需要的矿物质营养元素的全量和有效态,进而影响岩溶区的植物物种、特有性和作物的发育。     

Evaluation of bulk carbonate δ13C data from Triassic hemipelagites and the initial composition of carbonate mud

Bulk carbonate samples of hemipelagic limestone–marl alternations from the Middle and Upper Triassic of Italy are analysed for their isotopic compositions. Middle Triassic samples are representative of the Livinallongo Formation of the Dolomites, while Upper Triassic hemipelagites were sampled in the Pignola 2 section, within the Calcari con Selce Formation of the Southern Apennines in Southern Italy. Triassic hemipelagites occur either as nodular limestones with chert nodules or as plane‐bedded limestone–marl alternations which are locally silicified. In the Middle Triassic Livinallongo Formation, diagenetic alteration primarily affected the stable isotopic composition of sediment surrounding carbonate nodules, whereas the latter show almost pristine compositions. Diagenesis lowered the carbon and oxygen isotope values of bulk carbonate and introduced a strong correlation between δ¹³C and δ¹⁸O values. In the Middle Triassic successions of the Dolomites, bulk carbonate of nodular limestone facies is most commonly unaltered, whereas carbonate of the plane‐bedded facies is uniformly affected by diagenetic alteration. In contrast to carbonate nodules, plane‐bedded facies often show compaction features. Although both types of pelagic carbonate rocks show very similar petrographic characteristics, scanning electron microscopy studies reveal that nodular limestone consists of micrite (< 5 μm in diameter), whereas samples of the plane‐bedded facies are composed of calcite crystals ca 10 μm in size showing pitted, polished surfaces. These observations suggest that nodular and plane‐bedded facies underwent different diagenetic pathways determined by the prevailing mineralogy of the precursor sediment, i.e. probably high‐Mg calcite in the nodular facies and aragonite in the case of the plane‐bedded facies. Similar to Middle Triassic nodular facies, Upper Triassic nodular limestones of the Lagonegro Basin are also characterized by uncorrelated δ¹³C and δ¹⁸O values and exhibit small, less than 5 μm size, crystals. The alternation of calcitic and aragonitic precursors in the Middle Triassic of the Dolomites is thought to mirror rapid changes in the type of carbonate production of adjacent platforms. Bioturbation and dissolution of metastable carbonate grains played a key role during early lithification of nodular limestone beds, whereby early stabilization recorded the carbon isotopic composition of sea water. The bulk carbonate δ¹³C values of Middle and Upper Triassic hemipelagites from Italy agree with those of Tethyan low‐Mg calcite shells of articulate brachiopods, confirming that Triassic hemipelagites retained the primary carbon isotopic composition of the bottom sea water. A trend of increasing δ¹³C from the Late Anisian to the Early Carnian, partly seen in the data set presented here, is also recognized in successions from tropical palaeolatitudes elsewhere. The carbon isotopic composition of Middle and Upper Triassic nodular hemipelagic limestones can thus be used for chemostratigraphic correlation and palaeoenvironmental studies.