Pb and Sr isotopes in volcanic rocks from the Aleutian Islands and Pribilof Islands,Alaska

The Pb and Sr isotope ratios of Plio-Pleistocene volcanic rocks from the Aleutian volcanic arc are used as tracers of the lithospheric subduction process at the converging Pacific and Bering plates. Aleutian arc lavas do not have the same Pb isotopic compositions as volcanic rocks of the subducted Pacific ocean crust or the nearby Pribilof Islands, but appear to contain an ‘old continental crustal component’ with high ²⁰⁷Pb/²⁰⁴Pb ratio, as has been found in some other volcanic arcs.⁸⁷Sr/⁸⁶Sr ratios in the Aleutian volcanic arc rocks average 0.70322, slightly higher than fresh volcanic rocks from normal ridge segments, but within the range of values from ‘Icelandic’ ridge segments, oceanic islands and the Pribolof Islands. The Pb and Sr isotopic compositions of Aleutian lavas show a positive correlation and the range of values does not change for volcanoes distributed along strike in the arc, even though the crustal type in the hanging wall of the Benioff zone changes from oceanic in the west to continental in the east. Since the basement of the continental arc segment is older than the basement of the oceanic segment, and probably has a different isotopic character, the constancy of isotopic ratios along the arc argues against contamination by wall rocks of the type exposed in the arc.A sufficient explanation for the isotopic data is the mixture of several per cent of continent-derived sediment with melt derived from the underthrust oceanic crust and overlying mantle. This small amount of contaminant is difficult to document by geophysical observations. Such a model implies extensive recycling of Ba, Pb, K and Rb through volcanism at convergent plate margins like the Aleutians.     

Geochronology and evolution of quaternary volcanism at the Keli Highland,Greater Caucasus

The paper reports newly obtained stratigraphic, petrographic, and isotope-geochronological data on modern moderately acid lavas from the Keli Highland at the Greater Caucasus and presents a geological map of the territory, in which 35 volcanoes active in Late Quaternary time were documented by the authors. The total duration of volcanic activity at the highland was estimated at 250 ka. The volcanic activity was discrete and occurred in three phases: Middle Neopleistocene (245−170 ka), Late Neopleistocene (135−70 ka), and Late Neopleistocene-Holocene (<30 ka). Newly obtained lines of evidence indicate that certain volcanoes erupted in the latest Neopleistocene-Holocene. The first phase of volcanic activity was connected mainly with lava volcanoes, and eruptions during the later phases of volcanic activity in this part of the Greater Caucasus produced mainly lavas. The most significant eruptions are demonstrated to occur in the territory during the second phase. The major evolutionary trends of volcanic processes during the final phase in the Keli Highland are determined. It was also determined that the overwhelming majority of volcanoes that were active less than 30 ka B.P. are spatially restricted to long-liven local magmatic zones, which were active during either all three or only the final two phases of activity. These parts of the territory are, perhaps, the most hazardous in terms of volcanic activity.     

云南腾冲黑空山、马鞍山和打莺山火山粗安岩显微结构特征及其火山学意义

火山喷发物记录了岩浆的整个活动历史,对火山喷发物的研究可以了解大量的岩浆活动特征信息。本文对腾冲火山区的三座全新世火山——黑空山、马鞍山和打莺山火山熔岩进行了详细的研究,包括熔岩和斑晶的成分、显微结构特征和斑晶的晶体大小分布(CSD)分析。研究发现,黑空山、马鞍山和打莺山火山熔岩以粗安岩为主,三座火山粗安岩中的斑晶成分范围接近,但它们的显微结构特征具有一定的差异,反映了不同的岩浆环境,推测来自不同的岩浆囊。黑空山粗安岩中斜长石斑晶的CSD曲线呈微上凹形,反映了小规模的岩浆混合作用。马鞍山和打莺山粗安岩的微斑晶CSD曲线呈很好的线性关系,说明微斑晶形成时的环境相对稳定,推测这些微斑晶是在岩浆上升过程中,停留在地壳的某处并形成一个小型的岩浆囊后受围岩的冷却作用形成。根据以上的分析,认为腾冲火山区下在横向和纵向上均至少存在两个岩浆囊。     

Aleutian tholeiitic and calc-alkaline magma series I: The mafic phenocrysts

Diagnostic mafic silicate assemblages in a continuous spectrum of Aleutian volcanic rocks provide evidence for contrasts in magmatic processes in the Aleutian arc crust. Tectonic segmentation of the arc exerts a primary control on the variable mixing, fractional crystallization and possible assimilation undergone by the magmas. End members of the continuum are termed calc-alkaline (CA) and tholeiitic (TH). CA volcanic rocks (e.g., Buldir and Moffett volcanoes) have low FeO/MgO ratios and contain compositionally diverse phenocryst populations, indicating magma mixing. Their Ni and Cr-rich magnesian olivine and clinopyroxene come from mantle-derived mafic olivine basalts that have mixed with more fractionated magmas at mid-to lower-crustal levels immediately preceding eruption. High-Al amphibole is associated with the mafic end member. In contrast, TH lavas (e.g., Okmok and Westdahl volcanoes) have high FeO/MgO ratios and contain little evidence for mixing. Evolved lavas represent advanced stages of low pressure crystallization from a basaltic magma. These lavas contain groundmass olivine (FO 40–50) and lack Ca-poor pyroxene. Aleutian volcanic rocks with intermediate FeO/MgO ratios are termed transitional tholeiitic (TTH) and calc-alkaline (TCA). TCA magmas are common (e.g., Moffett, Adagdak, Great Sitkin, and Kasatochi volcanoes) and have resulted from mixing of high-Al basalt with more evolved magmas. They contain amphibole (high and low-Al) or orthopyroxene or both and are similar to the Japanese hypersthene-series. TTH magmas (e.g., Okmok and Westdahl) contain orthopyroxene or pigeonite or both, and show some indication of upper crustal mixing. They are mineralogically similar to the Japanese pigeonite-series. High-Al basalt lacks Mg-rich mafic phases and is a derivative magma produced by high pressure fractionation of an olivine tholeiite. The low pressure mineral assemblage of high-Al basalt results from crystallization at higher crustal levels.     

Petrogenesis of basalt-comendite and basalt-pantellerite suites,Terceira, Azores,and some implications for the origin of ocean-island rhyolites

Petrogenetic modeling of the Recent lava succession of Santa Barbara and Pico Alto volcanoes and associated basaltic lavas indicates that there are two discrete lava series present, one erupted from the axial rift linking the two central volcanoes and one associated with monogenetic cones scattered around the flanks of Santa Barbara. The felsic lavas of both volcanoes are peralkaline and appear to be derived from associated basalts by fractional crystallization of an assemblage including essential amphibole. Trace element abundances in the felsic lavas, particularly those of Sr and REE, cannot be reconciled with an origin through partial melting of basaltic material at the base of the volcanic pile. The difference between the comenditic and pantelleritic differentiation trends of Santa Barbara and Pico Alto is attributed primarily to FO₂ control of the crystallizing assemblage, probably related to thermal dissociation of magmatic water in the Santa Barbara magma chamber. This effect may be augmented by minor differences in parent basaltic compositions, the Pico Alto pantellerites being derived from the rift basalts whereas the Santa Barbara comendites are derived from the off-rift basalts. A compositional gap between 54 and 64% silica content in the lavas is not present if the suite is extended to include co-magmatic hypabyssal xenoliths, leading to the inference that the gap in this and other bimodal suites results solely from a relative inability of magma of intermediate composition to erupt.     

Geochemistry of Quaternary lavas from NE Sulawesi: transfer of subduction components into the mantle wedge

Major and trace element, and Sr-Nd isotope compositions were determined for Quaternary volcanic rocks from NE Sulawesi (the Sangihe are), Indonesia, in order to examine the origin of across-arc variation in lava and magma source chemistry. The arc is formed in an intraoceanic tectonic setting and is not associated with a backarc basin, thereby minimizing possible contributions from non-arc geochemical reservoirs. The geochemistry of these arc lavas is likely to provide essential information about the chemical characteristics of subduction components. All incompatible elements, except Pb, increase away from the volcancic front. Major element data for Mg-rich lavas together with available experimental data, suggest that primary magmas are produced at higher pressured by smaller degrees of partial melting beneath the backarc-side volcanoes. Rb/K and Ba/Pb are higher, and ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd are lower in backarc-side lavas. These variations may be attributed to generation of hydrous fluids in the downdragged hydrous peridotite layer at the base of the mantle wedge through the following reactions: decompositions of pargasitic amphibole to form phlogopite and breakdown of phlogopite to crystallize K-richterite, beneath the volcanic front and the backarc-side volcanoes, respectively.     

Cambrian–early Ordovician volcanism across the South Armorican and Occitan domains of the Variscan Belt in France: Continental break-up and rifting of the northern Gondwana margin

The Cambrian–lower Ordovician volcanic units of the South Armorican and Occitan domains are analysed in a tectonostratigraphic survey of the French Variscan Belt. The South Armorican lavas consist of continental tholeiites in middle Cambrian–Furongian sequences related to continental break-up. A significant volcanic activity occurred in the Tremadocian, dominated by crustal melted rhyolitic lavas and initial rifting tholeiites. The Occitan lavas are distributed into five volcanic phases: (1) basal Cambrian rhyolites, (2) upper lower Cambrian Mg-rich tholeiites close to N-MORBs but crustal contaminated, (3) upper lower–middle Cambrian continental tholeiites, (4) Tremadocian rhyolites, and (5) upper lower Ordovician initial rift tholeiites. A rifting event linked to asthenosphere upwelling took place in the late early Cambrian but did not evolve. It renewed in the Tremadocian with abundant crustal melting due to underplating of mixed asthenospheric and lithospheric magmas. This main tectono-magmatic continental rift is termed the “Tremadocian Tectonic Belt” underlined by a chain of rhyolitic volcanoes from Occitan and South Armorican domains to Central Iberia. It evolved with the setting of syn-rift coarse siliciclastic deposits overlain by post-rift deep water shales in a suite of sedimentary basins that forecasted the South Armorican–Medio-European Ocean as a part of the Palaeotethys Ocean.     

Subduction factory processes beneath the Guguan cross-chain, Mariana Arc: no role for sediments, are serpentinites important?

We need to understand chemical recycling at convergent margins and how chemical interactions between subducted slab and the overlying mantle wedge affect mantle evolution and magmagenesis. This requires distinguishing contributions from recycled individual subducted components as well as those contributed by the mantle. We do this by examining magmatic products generated at different depths above a subduction zone, in an intra-oceanic arc setting. The Guguan cross-chain in the intra-oceanic Mariana arc overlies subducted Jurassic Pacific plate lithosphere at depths of ~125--230 km and erupts mostly basalt. Basalts from rear-arc volcanoes are more primitive than those from the magmatic front, in spite of being derived by lower degrees of melting of less-depleted mantle. Rear-arc magmas also show higher temperatures and pressures of equilibration. Coexisting mineral compositions become more MORB- or OIB-like with increasing height above the subduction zone. Trace element and isotopic variations indicate that the subduction component in cross-chain lavas diminishes with increasing depth to the subduction zone, except for water contents. There is little support for the idea that melting beneath the Mariana Trough back-arc basin depleted the source region of arc magmas, but melting to form rear-arc volcanoes may have depleted the source of magmatic front volcanoes. Enrichments in rear-arc lavas were not caused by sediment melting; the data instead favor an OIB-type mantle that has been modestly affected by subduction zone fluids. Our most important conclusion is that sediment fluids or melts are not responsible for the K--h relationship and other cross-chain chemical and isotopic variations. We speculate that an increasing role for supercritical fluids released from serpentinites interacting with modestly enriched mantle might be responsible for cross-chain geochemical and isotopic variations. Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.     

A geochemical study of magmatism associated with the initial stages of back-arc spreading

Bransfield Strait is a narrow basin separating the South Shetland Islands from the Antarctic Peninsula and is attributed to recent back-arc extension behind the South Shetland volcanic arc. The volcanic islands of Deception and Bridgeman are situated close to the axis of spreading, whereas Penguin Island lies slightly to the north of this axis. The mineralogy, petrology and geochemistry of the lavas of the three volcanoes have been studied in order to provide information on the nature of magmatism associated with the initial stages of back-arc spreading.Deception Island lavas range from olivine basalt to dacite, and all are highly sodic, with high Na/K, K/Rb, Ba/Rb and Zr/Nb ratios and with Ce_N/Yb_N = 2. Incompatible elements increase systematically between basalt and rhyodacite, while Sr decreases, suggesting that fractional crystallisation is the dominant process relating lava compositions. The rhyodacites have high concentrations of Zr, Y and the REE and negative Eu anomalies and are compositionally similar to oceanic plagiogranite. Bridgeman Island lavas are mostly basaltic andesites, but the levels of many incompatible elements, including REE, are significantly lower than those of Deception lavas, although Ce_N/Yb_N ratios and ⁸⁷Sr/⁸⁶Sr ratios (0.7035) are the same. Penguin Island lavas are magnesian, mildly alkaline olivine basalts with a small range of composition that can be accommodated by fractional crystallisation of olivine, clinopyroxene and/or chromite. Penguin lavas have higher ⁸⁷Sr/⁸⁶Sr (0.7039) and Ce_N/ Yb_N (4) ratios than Deception and Bridgeman lavas. The Rb/Sr ratios of Deception and Penguin basalts (ca. 0.01) are much too low to account for their present ⁸⁷Sr/⁸⁶Sr ratios.Modelling suggests that the source regions of the lavas of the three volcanoes share many geochemical features, but there are also some significant differences, which probably reflects the complex nature of the mantle under an active island arc combined with complex melting relationships attending the initial stages of back-arc spreading. Favoured models suggest that Bridgeman lavas represent 10–20% melting and the more primitive Deception lavas 5–10% melting of spinel-peridotite, whereas Penguin lavas represent less then 5% melting of a garnet-peridotite source. The mantle source for Bridgeman lavas seems to have undergone short-term enrichment in K, Rb and Ba, possibly resulting from dewatering of the subducted slab. Hydrous melting conditions may also account for the more siliceous, high-alumina nature and low trace element contents of Bridgeman lavas.     

Petrology and geochemistry of the Banks Peninsula volcanoes,South Island,New Zealand

Within the volcanic sequence of the twin volcanoes of Lyttelton and Akaroa, Banks Peninsula, New Zealand a number of different magma series have been distinguished.An early series of hawaiites (McQueens Valley Formation) was erupted about 32 m.y. ago and is of transitional or mildly tholeiitic chemistry. Stratigraphically above the McQueens Valley Formation, but unconformably overlain by the main volcanic dome sequence, is a unit of rhyolite (Gebbies Pass Rhyolites) which is not directly related to the earlier or later basaltic volcanism. The rhyolite was probably formed during intracrustal melting which was related to the rise of basaltic magma into the crust.Between 12 and 9.7 m.y. a large volcanic dome, composed mainly of hawaiite, was built at Lyttelton. Dykes, which intrude the Lyttelton volcanic sequence, range in composition from basalt to trachyte. Late, mildly alkalic, basaltic flank flows (7.5–5.8 m.y.) occur in several areas and they, and the differentiated rocks of the dyke swarm can be related by a crystal fractionation model which has been quantitatively tested.Following construction of the Lyttelton dome a second larger dome was built at Akaroa between 9 and 7.5 m.y. The rocks of the Akaroa Volcano are principally hawaiites but rocks ranging in composition through to trachyte also occur. The differentiated rocks of the Akaroa volcano have derived from the basaltic rocks by a crystal fractionation controlled process, operating during ascent through the crust.None of the Banks Peninsula basalts appear to have derived from primitive (pyrolitic) mantle material, but progressive changes in the chemistry of the basalts with time implies that the mantle source regions were evolving geochemically as partial melting proceeded. Later lavas tend to be more alkalic and to have lower MgO/FeO ratios than earlier lavas. The volcanic rocks of the Banks Peninsula volcanoes were derived by fractional removal of olivine, plagioclase, clinopyroxene, magnetite and apatite from ascending basaltic magma batches. Variations between the suites reflect differences between the parental magma batches.     

Evolution of volcanism in graben and horst structures along the Cenozoic Cameroon Line (Africa): implications for tectonic evolution and mantle source composition

Tombel graben and Mounts Bambouto are two volcanic fields of the typical system of alternating graben and horst structure of the Cameroon Volcanic Line. Tombel graben is a young volcanic field, whereas Mounts Bambouto horst is an old stratovolcano with calderas. Volcanic products in both settings have a signature close to that of Ocean Island Basalt implying a major role of FOZO (focal zone) component and varied contribution of depleted mantle (DMM) and enriched mantle (EM) components. The Cameroon Volcanic Line is a hot line essentially resulting from passive rifting. Eocene to Recent intraplate basaltic volcanism in the study area was probably a result of mantle upwelling coupled with lithospheric extension. The olivine basaltic magma of horst volcanoes evolved in a large-scale, steady-state magmatic reservoir via crystal fractionation and limited contamination to highly differentiated alkaline lavas (trachyte and phonolite). Conversely, rapid ascent of lavas along multiple fault lines of graben structures produced less evolved lavas (hawaiite) within small reservoirs. This model, evaluated for the study area, involves mantle upwelling inside zones of weakness in the lithosphere after intra-continental extension. It can be applied to other parts of the Cameroon Volcanic Line as well, and is similar to that described in other intra-continental rift-related areas in Africa.     

Initiation of arc magmatism in an embryonic continental rifting zone of the southernmost part of Okinawa Trough

The Okinawa Trough is a young, intracontinental backarc basin that has formed behind the Ryukyu arc–trench system since late Miocene time. In the Southernmost Part of the Okinawa Trough (SPOT), a cluster of active submarine volcanoes delineates a volcanic belt, which is located only ∼100 km above the Wadati–Benioff zone. We report herein new major and trace element data for the SPOT volcanic rocks. These rocks show a compositional range from medium-K andesite to rhyolite. Their geochemical characteristics are similar to those of pre-backarc rifting volcanic rocks from the central Ryukyu arc, and different from those of backarc basin lavas from the Middle Okinawa Trough and the post-backarc rifting Ryukyu arc volcanics. Therefore, despite being topographically contiguous with the rest of the Trough, the SPOT that developed in the Quaternary is not a simple backarc basin but instead an embryonic rift zone in which early arc volcanism occurs as a result of the Ryukyu subduction.     

Trace element analyses of magnetites from andesitic and dacitic lavas from Bay of Plenty,New Zealand

Five magnetites from andesitic and dacitic lavas from the volcanoes Edgecumbe, Whale Island, and White Island were separated, and analysed for Mg, Ti, Cu, V, Ni, Co, Mn, and Cr. The vanadium contents provide difficulties for Osborn's (1962) hypothesis for the origin of calc-alkaline volcanic rocks.     

河床底部沙火山特征、演化及其研究意义

沉积后尚未固结的砂体在外部动力的干扰下容易发生液化,形成沙火山、液化砂岩脉等沉积构造,地震是触发液化的最常见动力.在河床现代沉积中发现大量的沙火山构造,其产生过程虽受人为活动影响,形成条件却在盆地特殊构造部位可以满足,分析其特征、演化及动力可以为震积岩及其他成因软沉积变形研究提供参考.研究结果显示,不同规模及对应特征的...     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

Geochemical evolution of Kohala Volcano,Hawaii

Kohala Volcano, the oldest of five shield volcanoes comprising the island of Hawaii, consists of a basalt shield dominated by tholeiitic basalt, Pololu Volcanics, overlain by alkalic lavas, Hawi Volcanics. In the upper Pololu Volcanics the lavas become more enriched in incompatible elements, and there is a transition from tholeiitic to alkalic basalt. In contrast, the Hawi volcanics consist of hawaiites, mugearites, and trachytes. ⁸⁷Sr/⁸⁶Sr ratios of 14 Pololu basalts and 5 Hawi lavas range from 0.70366 to 0.70392 and 0.70350 to 0.70355, respectively. This small but distinct difference in Sr isotopic composition of different lava types, especially the lower ⁸⁷Sr/⁸⁶Sr in the younger lavas with higher Rb/Sr, has been found at other Hawaiian volcanoes. Our data do not confirm previous data indicating Sr isotopic homogeneity among lavas from Kohala Volcano. Also some abundance trends, such as MgO-P₂O₅, are not consistent with a simple genetic relationship between Pololu and Hawi lavas. We conclude that all Kohala lavas were not produced by equilibrium partial melting of a compositionally homogeneous source.     

The Petrology of the Lavas of Grande Comore

The four volcanic islands comprising the Comores archipelagoform a linear rise across the northern end of the MozambiqueChannel. Volcanism migrated westward from the now deeply dissectedand partially submerged Mayotte to the active Kartala volcanoon Grande Comore. The volcanic rocks on all the islands consistof silica–undersaturated basalts and their derivatives. Grande Comore is formed of two coaleseing shield volcanoes,La Grille in the north and Kartala in the south. The lavas ofKartala are entirely alkali basalts, with abundant ankaramiticand oceanitic varieties, containing an average of 3.7 wt percent normative nepheline. They represent a series resultingfrom low–pressure (< 8kb) fractional crystallizationof alkali basalt parent magma. The formation of this parentmagma can be explained as resulting from more than 10 per centpartial melting of garnet lherzolite upper mantle at pressuresaround 30 kb, with some high–pressure (> 25 kb) fractionationof harzburgite, garnet harzburgite, and either garnet wehrliteor ecogite, followed by polybaric fractionation of olivine±clinopyroxene during ascent. They La Grille lavas are basanitie, with an average of 11–5wt per cent normative nepheline and some normative leucite,and contain only olivine as an important phenocryst phase. Theyare explicable as originating from less than 10 per cent partialmelting of garnet I herzolite upper mantle, with substantialhigh–pressure (> 25 kb) fractionation of garnet wehrliteor eclogite. Interuption of this high–pressure(> 25kb) fractionation at different stages resulted in one trendof chemical variation, on which was superimposed a second trendby polybaric fractionation of lherzolite, wehrlite, and dunite,now found as inclusions in the lavas.     

Late Ordovician island‐arc volcanic rocks,northern Capertee Zone,Lachlan Fold Belt,New South Wales

The Cape Hoskins volcanoes form part of the Quaternary volcanic island arc that extends from Rabaul in the east to the Schouten Islands in the west, and they overlie the northerly dipping New Britain Benioff Zone. The products of the volcanoes range in composition from basalt to rhyolite, and are normative in quartz and hypersthene. They contain phenocrysts of plagioclase and subordinate augite, hypersthene, and in most samples iron‐titanium oxides; some samples also contain olivine or quartz or both, and some pumice contains hornblende and, rarely, biotite.

Chemical analyses of 29 volcanic rocks are presented; 22 were also analysed for 17 minor elements — Rb, Ba, Sr, Pb, Zn, Cu, Zr, Y, Ni, Co, Sc, Cr, V, Ga, B, U, and Th.

Chemically the rocks have many of the characteristics of the ‘island arc tholeiitic series’, but do not show a pronounced relative enrichment in iron and appear to be relatively enriched in Sr. Compared with volcanic rocks from the northern part of the Willaumez Peninsula, they are lower in K (but not Na), Ti, Rb, Ba, Zr, Pb, Th, Ni, and probably also V, Cu, and Zn: these differences are attributed to the greater depth of the Benioff Zone beneath the Willaumez Peninsula. The more basic of the Cape Hoskins rocks are similar in most respects to lavas of comparable composition from Ulawun volcano to the east.     

Volcanic evolution of a long-lived Ordovician island-arc province in the Parkes region of the Lachlan Fold Belt,southeastern Australia

The Ordovician mafic volcanic rocks in the Parkes region of New South Wales occur as three distinct packages of volcaniclastic and coherent volcanic rocks and minor limestone that formed part of an oceanic island arc succession. The oldest package is the Early Ordovician Nelungaloo Volcanics and overlying Yarrimbah Formation. These formations consist of volcanic siltstone, sandstone, polymictic breccia, conglomerate facies interpreted as moderately deep-water turbidites and coarser grained debris-flow deposits emplaced in the medial to distal part of a subaqueous volcaniclastic apron flanking an active volcanic centre(s). Broadly conformable massive to brecciated andesites in the apron deposits are interpreted as synsedimentary sills and/or lava flows. A hiatus in volcanism occurred between the Bendigonian and early Darriwilian (ca 476 – 466 Ma). Deposition of the second package, which produced the Middle to Late Ordovician Goonumbla Volcanics, Billabong Creek Limestone and Gunningbland Formation, commenced with shallow-water limestones and minor volcaniclastic rocks. During an approximately 15 million years period, a thick sequence of bedded volcanic sandstone, limestone and minor siltstone and volcanic breccia were deposited in very shallow to moderate water depths. The top of this package is marked by thick volcanic conglomerate and sandstone mass-flow deposits and approximately coeval basaltic andesite lavas and sills sourced from a nearby volcano. The upper age limit of this package is constrained as approximately 450 Ma by Ea3/4 fossils and monzodiorite that intrudes the Goonumbla Volcanics. The lower limit of the third package, which constitutes the Wombin Volcanics, is poorly constrained and the duration of the hiatus that separates the Goonumbla and Wombin Volcanics is unknown but may be as long as 10 million years. The Wombin Volcanics record development of a thick, proximal volcaniclastic apron flanking a compositionally more evolved volcanic edifice in the immediate Parkes area. Thick crystal-rich turbiditic sandstones of mafic provenance are intercalated with polymictic volcanic breccias and megablock breccias that are interpreted as proximal subaqueous debris-flow and debris-avalanche deposits, respectively. The sequence also includes numerous trachyandesite bodies, many of which were emplaced within the volcaniclastic apron as synsedimentary sills. No evidence was found at Parkes to support the existence of a previously proposed 22 km diameter collapse caldera and the source volcanoes for the Ordovician are envisaged as complex stratovolcanoes.     

Chemical monitoring of volcanic gas using remote FT-IR spectroscopy at several active volcanoes in Japan

Chemical compositions of volcanic gases of several Japanese active volcanoes have been monitored from distant safe places since the beginning of the 1990s using an FT-IR spectral radiometer. For absorption measurements, an infrared light source behind volcanic gas emissions is necessary in a volcanic environment. In the early observations, infrared radiation from hot lava domes (Unzen volcano) and hot ground heated by high-temperature fumaroles (Usu, Aso, and Satsuma-Iwojima volcanoes) were used as infrared light sources. However, these sources were not available in many cases. This remote FT-IR method became more commonly applied to chemical monitoring of volcanic gases emitted from the summit or slopes of active volcanoes using scattered solar infrared light as infrared light sources (Sakurajima, Miyakejima, and Asama volcanoes). To date, eight species have been measured using this method: SO₂, HCl, HF, CO, CO₂, COS, SiF₄, and H₂O. The observations indicate that volcanic gases for each volcano have different chemical composition on a SO₂–HCl–HF ternary diagram in spite of similar tectonic settings, suggesting that vapor/melt volume ratios during volcanic gas formation differ among volcanoes. During more than 15 years of monitoring, chemical changes in volcanic gases attributable to ascent of magma were observed only at Asama, where HCl/SO₂ and HF/HCl ratios in the eruptive period were higher than those in non-eruptive period because of scrubbing of more soluble components in surface hydrothermal systems in the non-eruptive stage or solubility-controlled fractionation processes. Results show that these parameters are the most prospective ones among the various parameters measured using the remote FT-IR method to monitor volcanic activities.