黄河河流水体二氧化碳分压及其影响因素分析

根据2003年秋季黄河河流水体二氧化碳分压(p(CO2))的实测数据，结合水文、化学和生物等要素的同步观测资料，对河流水体p(CO2)的影响因素进行了探讨。研究结果表明：生物好氧呼吸作用不是影响河流水体p(CO2)的主要因素，黄河河流p(CO2)的高低主要受水体碳酸盐系统的控制。     

秋季北黄海表层海水CO_2分压分布及其影响因素探讨

根据2007年10月在北黄海走航连续观测所得pCO2数据,结合水文、化学和生物等要素的同步观测资料,对该海域pCO2分布及其影响因素进行了探讨.结果表明:秋季北黄海表层海水pCO2值在354～435 μatm之间,统计平均值为395 μatm.受河流输入影响的辽南沿岸流区域,山东半岛以北沿岸受渤海沿岸水输入影响的泥沙沉积区,是大气CO2的源区;在北黄海中部,黄海混合水范围内,由于强烈的生物活动,形成了较大范围的大气CO2汇区;而黄海混合水的其他区域仍然是大气CO2的源.总体来说,秋季北黄海表现出大气CO2弱源的性质.     

2011年3月胶州湾表层海水pCO2及海-气界面通量

依据2011年3月4日对胶州湾走航连续实测所得pCO2数据,结合水文、化学和生物等要素的同步实测资料,对胶州湾海域pCO2分布及其影响因素进行了初步探讨,并估算了3月海-气CO2通量。结果表明:3月胶州湾表层海水pCO2实测值在191～332μatm之间,平均值为278μatm,海-气CO2通量在-22.76～-7.13mmol·m-2·d-1,平均值为-14.2mmol·m-2·d-1,这一时期胶州湾从大气吸收约1.59×103t C,表现为大气CO2的强汇。生物活动是影响这一时期表层海水pCO2分布的主要原因。     

Dissolved inorganic carbon and CO2 fluxes across Jiaozhou Bay air-water interface

On the basis of data collected in the Jiaozhou Bay in June and July 2003, the DIC distribution in seawater is studied,and an average air-sea flux of CO2 is estimated. The results show that the content of DIC inside the bay is markedly higher than outside the bay in June, but the content of DIC outside the bay is markedly higher than inside the bay in July. The trend of DIC distribution inside the bay is similar, viz. the content is the maximum in the northeast, then decreases gradually toward the west, and the content is the minimum in the west. The total trend of vertical distribution is to increase gradually from surface to bottom. This characteristic of DIC distribution is determined by Jiaozhou Bay hydrology and there is a close relation between DIC and particulate N,P. Average CO2 flux across the source for atmospheric CO2 in June and July, and the total CO2 flux from seawater into atmosphere is about 740 t in June and 969 t in July.     

大洋海区海-气CO_2通量单参数遥感算法的适用性检验

利用卫星遥感技术的优势,基于LDEO数据库的全球海表二氧化碳分压（PCO2）及海表温度（SST）等实测数据,初步建立东太平洋海区PCO2与SST的单参数经验算法,并采用相同区域的独立实测数据检验.结果表明,单参数算法在寡营养大洋海区具有良好的适用性,反演值与实测值之间的均方根误差（RMS）为0.51 Pa（1 Pa=9.869μatm）,由此估算出2003年6月该海域CO2通量为-1.4 mmol/（m2.d）,与实测估算的碳通量基本相符,能够很好地反映出海区CO2源汇特征.将该遥感算法运用到西大西洋海域（15°~25°N,60°~75°W）,反演值与实测值之间均方根误差（RMS）为0.69 Pa.检验结果表明,在寡营养大洋海区,单参数遥感算法具有一定的适用性,在受相似因子调控的同纬度海区可以使用同一遥感算法.     

Oceanic iron fertilization: one of strategies for sequestration atmospheric CO2

Carbon cycle is connected with the most important environmental issue of Global Change.As one of the major carbon reservoirs, oceans play an important part in the carbon cycle. In recent years, iron seems to give us a good news that oceanic iron fertilization could stimulate biological productivity as CO2 sink of human-produced CO2. Oceanic iron fertilization experiments have verified that adding iron into high nutrient low chlorophyll (HNLC) seawaters can increase phytoplankton production and export organic carbon, and hence increase carbon sink of anthropogenic CO2, to reduce global warming. In sixty days, the export organic carbon could reach 10 000 times for adding iron by model prediction and in situ experiment, i.e. the atmospheric CO2 uptake and inorganic carbon drawdown in upper seawaters also have the same magnitude. Therefore, oceanic iron fertilization is one of the strategies for increasing carbon sink of anthropogenic CO2. The paper is focused on the iron fertilization, especially in situ o     

Dissolved inorganic carbon and CO2 fluxes across Jiaozhou Bay air-water interface

On the basis of data collected in the Jiaozhou Bay in June and July 2003, the DIC distribution in seawater is studied,and an average air-sea flux of CO2 is estimated. The results show that the content of DIC inside the bay is markedly higher than outside the bay in June, but the contem of DIC outside the bay is markedly higher than inside the bay in July. The trend of DIC distribution inside the bay is similar, viz. the content is the maximum in the northeast, then decreases gradually toward the west, and the content is the minimum in the west. The total trend of vertical distribution is to increase gradually from surface to bottom. This characteristic of DIC distribution is determined by Jiaozhou Bay hydrology and there is a close relation between DIC and particulate N.P. Average CO2 flux across the air-sea interface is 0.55 mol/(m^2.a) in June and 0.72 mol/(m^2.a) in July. Jiaozhou Bay is considered as a net annual source for atmospheric CO2 in June and July, and the total CO2 flux from seawater into atmosphere is about 740 t in June and 969 t in July.     

Ecophysiological characteristics of four intertidal marine macroalgae during emersion along Shantou coast of China, with a special reference to the relationship of photosynthesis and CO2

Intertidal marine macroalgae experience periodical exposures during low tide due to their zonational distribution. The duration of such emersion leads to different exposures of the plants to light and aerial CO2, which then affect the physiology of them to different extents.The ecophysiological responses to light and CO2 were investigated during emersion in two red algae Gloiopeltis furcata and Gigartina interrnedia, and two brown algae Petaloniafascia and Sargassum hemiphyllum, growing along the Shantou coast of China. The light-saturated net photosynthesis in G. furcata and P. fascia showed an increase followed by slightly desiccation, whereas that in G.interrnedia and S. hemiphyllum exhibited a continuous decrease with water loss. In addition, the upper-zonated G. furcata and P. fascia,exhibited higher photosynthetic tolerance to desiccation and required higher light level to saturate their photosynthesis than the lower-zonated G. interrnedia and S. hemiphyllum. Desiccation had less effect on dark respiration in these four algae compared with photosynthesis. The light-saturated net photosynthesis increased with increased CO2 concentrations, being saturated at CO2 concentrations higher than the present atmospheric level in G. furcata, G. intermedia and S. hemiphyllum during emersion. It was evident that the relative enhancement of photosynthesis by elevated CO2 in those three algae increased, though the absolute values of photosynthetic enhancement owing to CO2 increase were reduced when the desiccation statuses became more severe. However, in the case of desiccated P. fascia (water loss being greater than 20 %), light saturated net photosynthesis was saturated with current ambient atmospheric CO2 level. It is proposed that increasing atmospheric CO2 will enhance the daily photosynthetic production in intertidal macroalgae by varied extents that were related to the species and zonation.     

秋季东海和南黄海表层海水CO_2体系各参数分布及海-气界面通量

根据2007年11月在东海和南黄海海域表层海水测得的TCO2和TA数据,计算了表层海水pCO2,结合现场环境对表层海水CO2体系各参数的分布进行了讨论,探讨了pCO2与海水温度及叶绿素的相关性,利用Wanninkhof(1992)提出的通量模式并采用加权平均法估算了整个调查海域的海-气CO2的净通量。结果表明:观测海域表层海水CO2系统各参量的分布呈明显的不均匀性,在水团的混合处往往是各参量的高值或低值中心。由相关性分析可知,pCO2的分布主要受海水温度的影响,生物活动的影响较弱。受秋季较大风速的影响,调查海域表现为强的CO2源,秋季可向大气释放CO2约为556×104tC。     

Dark respiration in the light and in darkness of three marine macroalgal species grown under ambient and elevated CO2 concentrations

Dark respiration (non-photorespiratory mitochondrial respiration),which occurs both in the light and in darkness,is vital for growth and survival of algae and plays a critical role in modulating the carbon balance of them.In the present study,we have investigated dark respiration in the light (R L) and in darkness (R D) in three marine macroalgal species,Hizikia fusiformis (phaeophyta),Gracilaria lemaneiformis (Rhodophyta) and Ulva lactuca (Chlorophyta),cultured at 20℃ using aeration with two CO 2 conditions:current ambient (CO 2 concentration about 380 μl/L) and elevated CO 2 (approximately 720 μl/L) air.R L was estimated by using the Kok method,whereas R D was determined as the rate of O 2 influx at zero light.The results showed that both R L and R D were unchanged for the elevated CO 2-grown algae relative to ambient CO 2 concentration for all the algal species tested.However,R L was significantly lower than R D across all the algal species and growth CO 2 treatments,demonstrating that daytime respiration was partly depressed by the light.The percentage of inhibition of respiration by light was similar between ambient and elevated CO 2 grown algae.The ratio of respiration to photosynthesis,which tended to decrease when estimated using R L instead of R D,was not altered for the elevated relative to ambient CO 2 concentration.The results suggest that R L,rather than R D,is a more accurate estimate of nonphotorespiratory carbon loss in marine macroalgae during the daytime.It would not be anticipated that elevated atmospheric CO 2 would exert a substantial influence on respiratory flux either in the light or in darkness in these particular marine macroalgal species.     

Comparison of airsea fluxes of CO2 in the Southern Ocean and the western Arctic Ocean

The data were collected during Chinese Arctic and Antarctic Expeditions in the western Arctic Ocean and the marginal sea ice zone (MSIZ) of the Southern Ocean, respectively in the boreal summer from July to September of 1999 and in the austral summer from December of 1999 to January of 2000. The concentrations of CO2 in surface water of the survey regions would mostly present lower than those in the atmosphere. A significant biological driving force could also been observed in summer waters in both of the above oceans. Air to sea CO2 fluxes were also calculated to compare oceanic uptake capacity of CO2 in both oceans with the world oceans using Liss, Wanninkhof, and Jacobs‘s methods. The averaged CO2 fluxes of air to sea in the western Arctic Ocean or in the MSIZ of the Southern Ocean doubled that in the world oceans.     

The effects of enriched CO2 and enhanced UV-B radiation on ultra-structure of Dunaliella salina, singly and in combination

1 Introduction The amount of stratospheric ozone was being re duced due to anthropogenic emission of chlorofluoro carbons (CFCs) and nitrogen orides (Molina and Row land, 1974; Rowland, 1989; Yang et al., 1998; Xiao e al., 2005). This reduction of ozone r…     

正理庄高89-1区块CO2混相驱参数优化数值模拟研究

为了确保高89-1区块CO2混相驱项目的顺利实施,依据该区块的精细油藏描述成果,在优化适于CO2混相驱模型基础上,建立了符合油藏地质特点的三维地质模型。在此基础上对开发指标进行计算,对五个参数（井网、开发方式、压力水平、注入量和采油速度）进行优化,并提出了推荐方案,预测采收率可达23.10%,比弹性开采方式提高15.16%。     

2019年夏末长江口及其邻近海域走航pCO2变化及控制机制

利用2019年8月获得的长江口及其邻近海域表层海水pCO2的走航观测数据,结合温度、盐度、溶解氧等理化参数,初步探讨了该区域夏末表层海水pCO2的空间分布特点及控制因素.研究结果显示,整体上pCO2呈现近岸高而离岸低的特点,其中在长江冲淡水的中盐度区域出现了一个pCO2的极低值区.去除温度的影响,温度归一化后的pCO2...     

辽河三角洲滨海湿地生态系统CO_2释放机制

二氧化碳(CO2)是滨海湿地生态系统主要释放的温室气体,对其释放机制的研究是碳循环研究的重要内容。利用LI-8100A土壤呼吸速率检测系统,应用封闭系统的动态气室法,通过2012年5月对辽河三角洲光滩、翅碱蓬(Suaeda salsa)和芦苇(Phragmites australis)2种典型植被湿地类型的系统呼吸通量及其不同实验处理后的呼吸通量研究,探讨在这一季节条件下湿地生态系统的CO2释放途径与机制。研究表明,芦苇湿地呼吸通量[(3 041.59±320.66)mg·m-2·h-1]高于翅碱蓬湿地[(534.09±56.06)mg·m-2·h-1],且站立植物的呼吸量的贡献在翅碱蓬湿地仅占24%,在芦苇湿地占40%。特别地,当湿地植物被移除后,湿地系统所产生的CO2通量会显著增高,由此揭示了滨海湿地植物一旦被破坏,其生态系统在短时间内会向大气释放大量的CO2。     

东海冬、夏两季表层海水的二氧化碳分压

１９９７ 年冬、１９９８ 年夏在东海进行了两个航次的调查,采用气相色谱一喷洒式平衡器系统,现场测定了表层海水和大气的ＣＯ２ 分压。东海表层海水ＣＯ２ 分压受东海环流、生物活动、季节等因素影响而变化。冬季受垂直混合作用的影响,陆架区是ＣＯ２ 的源;黑潮水是ＣＯ２ 的汇,夏季受生物活动的影响,陆架区水系是ＣＯ２ 的汇;黑潮及影响区域是ＣＯ２ 的源。     

关对蓝藻CO2浓缩机制运转影响的模拟分析

通过数学模型模拟的方法，分析了蓝藻CO2浓缩机制（简称CCM）对光强变化的响应规律。CCM运转时的关键步骤－－无机碳（简称Ci)转运所需的能量来自于光系统，其活动强度与光强密切相关，以此为基础，本文建立了具外部Ci浓度和光强两个变量的数学模型，计算表明：（1）光合速率和浓缩效率随着光强的增加而增加；（2）Ci泵的特征光能利用率的变化对CCM的行为有显著的影响。     

基于聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解二氧化碳电极及其性能标定

深海探测溶解CO2气体异常.可以为寻找热液口提供一个很好的证据.本文设计的基于自制的聚二甲基硅氧烷胶与Zn-Al型水滑石复合膜为离子载体的溶解CO2探测电极属于电势型CO2电极,适用于对深海中溶解形式的CO2的测量,具有体积微小、便于与pH、盐度、温度、氧化还原电位等多种传感器集成在同一探头腔内,实施在线探测等优点.实验室条件下.将该溶解CO2探测电极与银,氯化银参比电极分别接在Keithley 6517A高阻抗电位计输入端进行测试,测试结果表明:该电极对不同浓度的碳酸氢钠溶液具有良好的响应信号,响应时间大约在30s-1 min.检测限在10-1-10-4mol·L-1.     

Enhanced photobiological H2 production by the addition of carbon monoxide and hydrogen cyanide in two unicellular N2-fixing cyanobacterial strains isolated from Korean coasts

Photobiological H₂ from marine cyanobacterial strains is widely accepted to be an ideal clean and renewable energy source. Using the two Korean N₂-fixing unicellular cyanobacterial strains (Cyanothece sp. KNU CB MAL-031 and Cyanothece sp. KNU CB MAL-058) and the Synechococcus sp. Miami strain BG043511 we performed flask-scale experiments to measure the effect of CO and HCN addition on photobiological H₂ production. For the test, 1, 5, 10 and 30% v/v of CO in the N₂ atmosphere was applied. Enhancement of H₂ production was remarkable at 1–5% concentration range of CO addition. At CO concentrations over 5% no further cost-effective enhancement of H₂ production was detectable, which suggests to us that 1–5% CO addition should be adopted for practical photobiological H₂ production by the cyanobacterial strains. Maximum enhancement of the photobiological H₂ production by CO additions was 2–6 times over the control flasks without CO. When 3 ppm of HCN was injected into the cell suspension of BG043511, the enhancement of hydrogen production was 50–60% of that under 5% CO. Present result implies the possible recycling of waste CO and HCN for the enhancement of the photobiological H₂ production using marine cyanobacterial strains.     

絮凝-CO2曝气-催化氧化处理制革废水研究

使用新型高效的絮凝剂MF,对制革废水进行絮凝吸附、CO2曝气、催化氧化回用处理试验,确定了絮凝剂MF的最佳使用条件、催化氧化时间和氧化剂用量.结果表明,制革废水经工艺处理后,对废水中主要污染物CODCr、S2-、Cr3+、SS、色度的去除率分别达到78.9%、97.5%、95.5%、91.4%、96.5%.处理后的废水基本达到鞣铬工艺用水要求和国家<污水综合排放标准>(GB8978-1996)限定的二级标准.