共查询到19条相似文献,搜索用时 46 毫秒
1.
众所周知,铀是一种最重要的核原料,不少国家正在研究用各种无机和有机吸附剂来提取海水中的痕量铀,一些小规模的试验工厂正在设计和建造中。然而,由于海水中铀的浓度极低(约为0.003毫克/升),要从含有常量浓度的Na,Mg,Ca,Cl,Br等离子 相似文献
2.
3.
稀土元素已越来越多地应用于示踪各类地球化学体系的物质来源与岩石矿物形成等演化过程。但在进行海水样品的稀土元素检测时,由于样品的高盐特征和稀土元素的痕量特征又使得分析具有相当的挑战性。本研究旨在从高盐的海水基质中有效分离并富集痕量的稀土元素,同时结合电感耦合等离子体质谱(Inductively Coupled Plasma Mass Spectrometry, ICP-MS)技术对海水中的稀土进行定量分析。通过对海水样品稀土元素的定量限分析、加标回收实验和梯度加标回收实验,验证了方法的准确性,评估方法的分离富集效率。通过共沉淀过程中的pH比较、氢氧化钠与氨水作为共沉淀剂的比较,确定了富集过程中共沉淀剂用量、种类等影响因素。通过稀土元素配分曲线的绘制与类似样品结果进行比对,以及标准海水的检测结果,验证了方法在实际样品中的可行性。本研究探索了共沉淀富集法在分离富集海水中稀土元素的实验条件,实现高盐背景下痕量稀土的准确定量,并将其用于近岸海水与孔隙水的实际检测。 相似文献
4.
5.
6.
8.
9.
Л.В.Рыжова等 《海洋科学》1982,6(2):69-70
由于海水中铀的浓度很低(3×10~(-6)克/升),必须预先富集铀。现有的提取铀的方法——用金属氢氧化物和难溶盐共沉淀、萃取和浮选,都要求预先制备样品:酸化,煮沸,将U还原到U(Ⅳ)等,这些步骤增加了分析时间。 本文研究应用纤维螯合吸附剂富集海水中的铀,然后试验用偶氮肿Ⅲ光度法测定铀的可能性。我们采用的吸附剂是用改性的纤维素重氮化并结合上偶氮胂工,其含有以下官能团: 相似文献
10.
11.
A number of dictating resins have been synthesized for extracting uranium from scawatcr. The feasibilities of extracting uranium directly from seawater by synthesizing chelating resins have been investigated by studying three factors:(1) the chelating ability of the resins for uranyl ion;(2) the competitive complex of calcium, magnesium and other cations with uranyl ion;(3) the competitive complex of carbonate ion with uranyl ion.It is suggested that the competitive complex of carbonate ion with uranyl ion should be the most important factor. 相似文献
12.
The adsorption behaviour for uranium of four kinds of amidoxime resinst RNH, RCH, RAH and RPH in seawater has been investigated. It has been found that all these resins are capable of adsorbing rapidly uranium from U-cnriched seawater with a high uranium uptake.RNH was able to adsorb uranium satisfactorily from natural seawater, and the uranium uptake of RNH with a degree of cross-linking of 3-5 mol % was above 200 μg/g-R (adsorption for 15 days). The uranium uptakes of RCH, RAH and RPH from natural seawater were much lower than the uranium uptake of RNH. The factors which caused the difference between resins RCH, RAH, RPH and resin RNH are discussed. 相似文献
13.
14.
A laser-induced fluorometric method for the rapid determination of trace level? of uranium in seawater with the Modified Anti-interference Fluorometric Reagent for uranium (MAFG) is described. Only a sample volume of 1.5-2.5 ml is used in each determination and no pre-scparation and concentration steps are required. The analysis rate is a sample per 5 min. The relative standard deviation of ten replicate determinations on 3.44 ppb U of the natural seawater is 4.7%. 相似文献
15.
海水中硼的快速测定方法 总被引:2,自引:2,他引:2
海水、卤水及废水等样品中微量硼的测定方法很多,其中姜黄素法是测硼灵敏度最高的一种,现已被列入美国《水和废水标准检验法》第13版中。我们以姜黄素-分光光度法测定海水中微量硼时,在标准曲线中加入了与海水样相当的无硼人工海水,消除了阴阳离子的干扰,在半年多的海水中硼的间断性测定试验方面,获得了较满意的结果,其相对标准偏差为3.1%,测一批样品仅需4小时,因此,该法是测定海水中硼的快速准确的较好方法。 相似文献
16.
Hydrous titanium oxide (HTO) is a better inorganic absorbent for the extractionof uranium from sea water. Although its structure has been proposed by some authors,little attention has been paid to the relation between the structure and the property ofuranium-untaking. Some relevant articles only concentrated their efforts on the in-terior structure and little was given to the investigation of its surface properties whichplay an important part in the property of uranium-uptaking. 相似文献
17.
18.