中国南部对流层中上层臭氧增加的气象场判识及臭氧变化的多尺度特征

副热带急流对中国南部地区对流层中上层臭氧浓度的影响程度及地理范围目前还研究较少,且缺乏综合使用常规气象资料及卫星资料来判识对流层中上层臭氧浓度增高的方法.本文利用NCEP再分析与最终分析资料、日本GMS-5地球静止卫星水汽云图资料,以2001年3月27~29日中国南部的临安、昆明、香港臭氧探测个例为基础,结合1996年3月29日香港与2001年4月13日临安对流层中上层高浓度臭氧分布个例对副热带急流对中国南部对流层中上层臭氧浓度的影响进行了详细分析,提出根据气象要素场判识春季中国南部对流层中上层臭氧浓度增高的充分条件为根据卫星水汽图像上的暗区、高空急流入口区的左侧辐合区、高空锋区、对流层中上层≥1 PVU的向下伸展的舌状高位涡区来综合判断.本文的分析结果表明,本文个例中对流层中上层高浓度臭氧来自平流层;香港对流层中上层低浓度臭氧来自热带海洋地区.不仅臭氧垂直廓线的多个极小与极大值表明臭氧垂直分布的多尺度变化特征,而且对流层中上层PV分布以及卫星水汽图像分析也表明大气中的多尺度运动对臭氧垂直分布特征有显著影响.本文的结果表明与副热带高空急流相联系的平流层空气侵入不仅发生在中国大陆的较高纬度地区,较低纬度的昆明与香港地区也有平流层空气侵入导致对流层中上层臭氧浓度升高.     

Numerical simulation of the influence of stationary mesoscale orographic waves on the meridional circulation and ozone fluxes in the middle atmosphere

The authors’ parameterization of the dynamic and thermal action of stationary orographic waves generated by the Earth’s surface relief is included into the model of general circulation of the middle and upper atmosphere. Numerical simulation of the general circulation in the troposphere and stratosphere was performed and the influence of stationary orographic waves propagating upward from the Earth’s surface on the meridional and vertical velocity was studied. It is shown that the allowance for the dynamic and thermal action of these waves in the numerical model leads to changes by up to 20–30% in the meridional circulation and ozone fluxes associated with it at heights of the ozone layer maximum.     

青藏高原上空UTLS区域一次地形重力波过程中的物质上传

利用美国航空航天局MERRA(Modern-Era Retrospective Analysis for Research and Applications)再分析资料和MODIS(Moderate-Resolution Imaging Spectroradiometer)卫星资料以及欧洲气象中心ECMWF-Interim(European Centre for Medium-Range Weather Forecasts)再分析资料,分析了发生于青藏高原北侧上空的一次地形重力波事件,并使用中尺度预报模式WRF-ARW.V3.0(Weather Research and Forecasting model,V3.0)对其进行了数值模拟.在此基础上,诊断分析了此次地形重力波在UTLS(Upper Troposphere and Lower Stratosphere)区域造成的物质和能量垂直传输特征.分析结果表明这一中尺度地形重力波信号的水平波长约为600km,与地形扰动水平尺度接近,重力波在对流层中传播的垂直波长约为3km,在垂直方向上随着高度的增加呈现出由东向西倾斜的结构特征.此次地形重力波上传进入平流层并在150hPa附近破碎,波破碎后动量通量在短时间内发生了强烈的衰减,重力波携带的能量在破碎高度附近释放.重力波破碎的同时垂直方向湍流混合变得异常强烈,湍流交换系数可在短时间内增加到背景值的8倍以上,剧烈湍流混合过程导致了对流层上层的空气进入平流层,使下平流层空气出现了位势涡度和臭氧的低值区,在浮力频率的垂直剖面中也可以看到由于地形重力波过程造成的平流层下层浮力频率异常低值区.     

UHF radar observation of strato-tropospheric transfers on the anticyclonic side of a jet streak

An observation by UHF ST radar of a subsidence pattern on the right side of the exit region of a jet streak is reported. The onset of the subsidence pattern occurred at 23:30 UTC on the 29 November 1991, when a downward motion was initiated above 14 km. The injections of stratospheric air in this region seem to have an intermittent nature; they occur during at least three intervals during the lifetime of the subsidence pattern. Comparison of these results with an ECMWF analysis suggests that it is an unfolding case. However, observation of turbulent intensities w’ greater than 60 cm s⁻¹ at the tropopause level also suggests the existence of a turbulent flux between the stratosphere and the troposphere. From the turbulence characteristics measured by the radar and the potential temperature profile obtained by radiosonde data, the eddy diffusivity at the tropopause level has been calculated. An eddy diffusion coefficient ranging between 5 and 7 m² s⁻¹ is found. From these values, and with the assumption of a climatological gradient of the volume mixing ratio of ozone in the lower stratosphere, it is possible to deduce a rough estimate of the amount of ozone injected from the stratosphere into the troposphere during this event. A rate of transfer of 1.5×10²⁰ molecules of ozone per day and per square meter is found.     

A distribution law for relative humidity in the upper troposphere and lower stratosphere derived from three years of MOZAIC measurements

Data from three years of MOZAIC measurements made it possible to determine a distribution law for the relative humidity in the upper troposphere and lower stratosphere. Data amounting to 13.5% of the total were obtained in regions with ice supersaturation. Troposphere and stratosphere are distinguished by an ozone concentration of 130 ppbv as threshold. The probability of measuring a certain amount of ice supersaturation in the troposphere decreases exponentially with the degree of ice supersaturation. The probability of measuring a certain relative humidity in the stratosphere (both with respect to water and ice) decreases exponentially with the relative humidity. A stochastic model that naturally leads to the exponential distribution is provided. Mean supersaturation in the troposphere is about 15%, whereas ice nucleation requires 30% supersaturation on the average. This explains the frequency of regions in which aircraft induce persistent contrails but which are otherwise free of clouds. Ice supersaturated regions are 3-4 K colder and contain more than 50% more vapour than other regions in the upper troposphere. The stratospheric air masses sampled are dry, as expected, having mean relative humidity over water of 12% and over ice of 23%, respectively. However, 2% of the stratospheric data indicate ice supersaturation. As the MOZAIC measurements have been obtained on commercial flights mainly between Europe and North America, the data do not provide a complete global picture, but the exponential character of the distribution laws found is probably valid globally. Since water vapour is the most important greenhouse gas and since it might enhance the anthropogenic greenhouse effects via positive feedback mechanisms, it is important to represent its distribution correctly in climate models. The discovery of the distribution law of the relative humidity makes possible simple tests to show whether the hydrological cycle in climate models is represented in an adequate way or not.     

Evidence for vertical ozone redistribution since 1967

Long-term measurements of the ozone concentration in the vicinity of the city of Berlin have been performed with ground based Dobson spectrophotometers and balloon borne systems. The respective experiments cover the past 24 years. All data have been reevaluated and corrected towards uniform calibration standards, leading to the longest European data set of total column density, altitude-dependent ozone partial pressures and the corresponding temperatures. Smoothing algorithms unravel significant long-term trends.The analysis shows an increase of ozone concentration within the middle stratosphere (below 31 km height) as well as in the troposphere over the past 24 years. On the contrary, ongoing ozone depletion in the lower stratosphere has been found.The large scale vertical redistribution of atmospheric ozone in the troposphere and the lower stratosphere seems to be in agreement with model calculations and trend predictions that have their roots in changes of the chemical composition and the ozone photochemistry due to anthropogenically induced trace gas concentrations.Deutscher Wetterdienst, Meteorologisches Observatorium Potsdam.Deutscher Wetterdienst, Meteorologisches Observatorium Lindenberg.     

Stratospheric ozone response to a solar proton event: Hemispheric asymmetries

Ozone depression in the polar stratosphere during the energetic solar proton event on 4 August 1972 was observed by the backscattered ultraviolet (BUV) experiment on the Nimbus 4 satellite. Distinct asymmetries in the columnar ozone content, the amount of ozone depressions and their temporal variations above 4 mb level (38 km) were observed between the two hemispheres. The ozone destroying solar particles precipitate rather symmetrically into the two polar atmospheres due to the geomagnetic dipole field These asymmetries can be therefore ascribed to the differences mainly in dynamics and partly in the solar illumination and the vertical temperature structure between the summer and the winter polar atmospheres. The polar stratosphere is less disturbed and warmer in the summer hemisphere than the winter hemisphere since the propagation of planetary wave from the troposphere is inhibited by the wind system in the upper troposphere, and the air is heated by the prolonged solar insolation. Correspondingly, the temporal variations of stratospheric ozone depletion and its recovery appear to be smooth functions of time in the (northern) summer hemisphere and the undisturbed ozone amount is slighily, less than that of its counterpart. On the other hand, the tempotal variation of the upper stratospheric ozone in the winter polar atmosphere (southern hemisphere) indicates large amplitudes and irregularities due to the disturbances produced by upward propagating waves which prevail in the polar winter atmosphere. These characteristic differences between the two polar atmospheres are also evident in the vertical distributions of temperature and wind observed by balloons and rocker soundings.     

亚洲夏季平流层-对流层水汽交换年际变化与亚洲夏季风的联系

亚洲地区是物质由对流层向平流层输送的主要通道,在平流层-对流层交换中扮演着积极的角色. 本文主要利用卫星资料和欧洲中心ERA40再分析资料,借助Wei诊断模式研究亚洲地区夏季上对流层-下平流层(UTLS)水汽分布和平流层-对流层水汽交换特征,重点着眼于水汽交换的年际变化,并探讨其与亚洲夏季风的联系. 结果表明,季风区UTLS水汽较赤道地区偏多,且通过磁带记录信号的传播,可穿越对流层顶影响下平流层水汽的多寡. 夏季平流层-对流层水汽交换表现出明显的年际特征,其年际变化与亚洲季风强弱变化有密切联系,尤其与南亚夏季风的关系更为显著. 在亚洲夏季风影响下,亚洲地区出现异常的大气环流和垂直运动,从而影响平流层-对流层之间水汽的交换. 这些结果对认识其它大气成分的输送过程也具有重要的指示意义.     

夏季青藏高原地区近地层水汽进入平流层的特征分析

青藏高原为亚洲季风区的典型代表区域,研究其水汽进入平流层的过程和机理对认识全球气候和大气环境变化具有一定的现实意义. 本文基于中尺度气象模式(WRF)的模拟输出结果(2006年8月20日至8月26)驱动拉格朗日大气输送模式FLEXPART,通过追踪并解析气块的三维轨迹以及温度、湿度等相关物理量的相关变化特征,初步分析了夏季青藏高原地区近地层-对流层-平流层的水汽输送特征. 研究结果表明,源于高原地区近地层的水汽在进入平流层的过程中受南亚高压影响下的大尺度环流和中小尺度对流的共同影响.首先,在对流抬升作用下,气块在短时间内(24 h)可抬升到9~12 km的高度,然后在南亚高压闭合环流影响下,相当部分气块在反气旋的东南侧穿越对流层顶进入平流层中,并继续向低纬热带平流层输送,进而参与全球对流层-平流层的水汽循环过程. 在对流抬升高度上气块位置位于高原的西北侧,然而气块拉格朗日温度最小值主要分布于高原南侧,两个位置上气块的平均位温差值可达15~35 K,这种显著的温度差异将导致气块进入平流层时"脱水". 比较而言,夏季青藏高原地区近地层水汽进入平流层的多寡主要和大尺度汽流的垂直输送有关,而深对流的作用相对较弱.     

Further ozone transport calculations and the spring maximum in ozone amount

Summary Calculations of the covariance between ozone amounts and meridional wind in the lower stratosphere are presented for all stations in the northern hemisphere for the IGY-IGC. Northward ozone transport occurs by large-scale quasi-horizontal transient and standing eddies and the transport is a maximum early in the year. It is suggested that the transport is governed by the exchange of energy between the troposphere and stratosphere and data are presented on the energy transformations within the lower stratosphere and the transfer of energy into the region which support this suggestion. The vertical flux of energy is also calculated from tropospheric data and its seasonal changes are seen to be in the correct phase to explain the spring maximum in ozone amount.The research reported in this article was sponsored by the Atomic Energy Commission under Contract AT (30-1)2241.     

夏季北极平流层大气基本结构特征

北极地区(60°N～90°N)平流层纬向风和气压场有明显的季节变化,不同高度层季节变化的时间有差异.北极平流层从冬至夏,季节转换从上向下推进,从夏至冬,季节转换从下向上推进.以20 hPa为例,平均而言,4月上旬以前,北极被极涡控制;4月中旬北极地区高压的势力开始超过低压,5月上旬,北极高压正式建立;7月份达到最强,8...     

Low ozone event at Madrid in November 1996

A sudden transient increase of the solar ultraviolet (UV) radiation was detected with a ground-based photometer in Madrid (Spain, 41°N, 3°W) on 25 November 1996 (Cordoba et al., 2000. UV-B irradiance at Madrid during 1996, 1997 and 1998. J. Geophys. Res. 105 (D4) (2000) 4903–4906). The data obtained by the TOMS satellite instrument revealed that this event was related to a reduction of the total ozone column values. This low ozone episode has been analysed. The ozone decrease was accompanied by a reduction of air temperature in the lower stratosphere. The anti-correlation between total ozone and air parcel height along the three-dimensional isentropic back-trajectories suggests that the adiabatic uplift of air contributed significantly to both the ozone and the temperature decreases observed. The uplift could be caused by the propagation into the lower stratosphere of the high-pressure cell located over the mid-Atlantic region.     

Studies of variations in the vertical ozone profiles over India

The latitudinal and temporal variations in the vertical profiles of ozone over the Indian subcontinent are discussed. In the equatorial atmosphere represented by Trivandrum (8°N) and Poona (18°N), while tropospheric ozone shows marked seasonal variations, the basic pattern of the vertical distribution of ozone in the stratosphere remains practically unchanged throughout the year, with a maximum at about 28 to 26 km and a minimum just below the tropopause. The maximum total ozone occurs over Trivandrum in the summer monsoon season and the latitudinal anomaly observed over the Indian monsoon area at this time is explained as arising from the horizontal transport of ozone-rich stratospheric air from over the thermal equator to the southern regions.In the higher latitudes represented by New Delhi (28°N), the maximum occurs at 23 km. Delhi, which lies in the temperate regime in winter, shows marked day-to-day variations in association with western disturbances and the strong westerly jet stream that lies over north and central India at this time.Although the basic pattern of the vertical distribution of ozone in the equatorial atmosphere is generally the same in all seasons, significant though small changes occur in the lower stratosphere and in the troposphere. There are small perturbations in the ozone and temperature structures, distinct ozone maxima being always associated with temperature inversions. There are also large perturbances not related to temperature, ozone-depleted regions normally reflecting a stratification of either destructive processes or materials such as dust layers or clouds at these levels. Particularly interesting are the upper tropospheric levels just below the tropopause where the ozone concentration is consistently the smallest, in all seasons and at all places where soundings have been made in India.     

The average tropospheric ozone content and its variation with season and latitude as a result of the global ozone circulation

Evaluations of radiosonde soundings over North America and Europe, measurements aboard commercial airlines, and permanent ozone registrations at nineteen ground-based stations between Tromsö, Norway, and Hermanus, South Africa, yield three belts of higher ozone intrusion from the stratosphera and maximum values of the annual means at about 30°N, at between 40°–45°N and at about 60°N. A marked decrease of the annual mean values of the tropospheric ozone is detected towards the equator and the pole, respectively.In the northen hemisphere the maximum of the annual cycle of the tropospheric ozone concentration occurs in spring at high latitudes and in summer at mid-latitudes.For the tropical region from 30°S to 30°N a strong asymmetry of the northern and southern hemisphere occurs. This fact is discussed in detail. The higher troposphere of the tropics seems to be a wellmixed reservoir and mainly supplied with ozone from the tropopause gap region in the northern hemisphere. The ozone distribution in the lower troposphere of the whole tropics seems to be controlled by the up and down movements of the Hadley cell. The features of large-scale and seasonal variation of tropospheric ozone are discussed in connection with the ozone circulation in the stratosphere, the dynamic processes near the tropopause and the destruction rate at the earth's surface.     

Two types of summertime heating over Asian large-scale orography and excitation of potential-vorticity forcing II. Sensible heating over Tibetan-Iranian Plateau

Based on analysis and simulation, the interaction of thermal forcing between the Tibetan Plateau (TP) and Iranian Plateau (IP) in summer is investigated. Associated influences on water vapor transport in the Asian subtropical monsoon region and the formation of a cold center in the lower stratosphere over Eurasia are also investigated. Results show that surface sensible heating (SH) over the two plateaus not only have mutual influences but also feedback to each other. SH over the IP can reduce the SH and increase the LH over the TP, whereas the SH over the TP can increase surface heating over the IP, thereby reaching quasi-equilibrium among the SH and LH over the TP, IP SH and atmosphere vertical motion. Therefore, the so-called Tibetan-Iranian Plateau coupling system (TIPS) is constructed, which influences atmosphere circulation. In the TIPS system, interaction between surface SH and LH over the TP plays a leading role. SH of the IP and TP influences on other regions not only have superimposed effects but also mutually offset. Accounting for contributions to the convergence of water vapor transport in the Asian subtropical monsoon region, TP SH contributes more than twice that of the IP. The combined influence of SH over TP and IP represents the major contribution to the convergence of water vapor transport in that region. In addition, the heating effect of TIPS increases the upper tropospheric temperature maximum and lifts the tropopause, cooling the lower stratosphere. Combined with large-scale thermal forcing of the Eurasian continent, the TIPS produces a strong anticyclonic circulation and the South Asian High that warms the upper troposphere and cools the lower stratosphere, thereby affecting regional and global weather and climate.     

Influence of the Precipitating Energetic Particles on Atmospheric Chemistry and Climate

We evaluate the influence of the galactic cosmic rays (GCR), solar proton events (SPE), and energetic electron precipitation (EEP) on chemical composition of the atmosphere, dynamics, and climate using the chemistry-climate model SOCOL. We have carried out two 46-year long runs. The reference run is driven by a widely employed forcing set and, for the experiment run, we have included additional sources of NO _x and HO _x caused by all considered energetic particles. The results show that the effects of the GCR, SPE, and EEP fluxes on the chemical composition are most pronounced in the polar mesosphere and upper stratosphere; however, they are also detectable and statistically significant in the lower atmosphere consisting of an ozone increase up to 3?% in the troposphere and ozone depletion up to 8?% in the middle stratosphere. The thermal effect of the ozone depletion in the stratosphere propagates down, leading to a warming by up to 1?K averaged over 46?years over Europe during the winter season. Our results suggest that the energetic particles are able to affect atmospheric chemical composition, dynamics, and climate.     

A simple numerical experiment concerning the general circulation in the lower stratosphere

Summary By means of highly truncated spherical harmonic expansions, an extended four-level quasi-geostrophic model with variable Coriolis parameter is transformed into a set of ordinary non-linear differential equations. Non-adiabatic effects, frictional dissipation, and boundary effects are approximately included in the equations. A numerical experiment made with the equations succeeds in producing many realistic statistical gross features, especially in the lower stratosphere, e. g., a poleward temperature incrase, the up-gradient horizontal transports of heat and momentum due to large-scale eddies, the upward energy flux of extra-long waves, and the trapping of the upward energy flux of tropospheric unstable waves near the tropopause. The mean energy flow in the lower stratosphere and in the troposphere are analyzed and compared with each other, indicating very clearly the baroclinical activness of the troposphere and the passiveness of the lower stratosphere. The dynamics in the lower stratosphere are discussed. the mean meridional circulation is also studied.     

A discussion of the chemistry of some minor constituents in the stratosphere and troposphere

A discussion is given of atmospheric reactions in the H₂O–CH₄–O₂–O₃–NO _x system. In the lower troposphere such reactions may lead to significant production of ozone. Their role in the odd hydrogen balance, especially of the troposphere and lower stratosphere, is discussed. CH₃OH may be an intermediate in the oxidation cycle of methane, especially in the cold stratosphere. Its photodissociation into H₂ and CH₂O may consequently provide an important source for stratospheric H₂. Catalytic photochemical chains of reactions involving NO _x and HO _x may also lead to tropospheric destruction of ozone. Due to lack of knowledge it is not possible at present to evaluate the importance of the before-mentioned reactions.With the aid of model calculations it is indicated that stratospheric ozone is most sensitive to changes in the adopted lower boundary values of N₂O and that an increase in water vapour concentrations in the lower stratosphere will indeed cause some increase in ozone as predicted.Fluctuations in the flux of solar radiation near 190 nm may cause significant variations in stratospheric ozone concentrations.     

Estimate of the effect of the 11-year solar activity cycle on the ozone content in the stratosphere

Using spectral, cross-spectral, and regression methods, we analyzed the effect of the 11-year cycle of solar activity on the ozone content in the stratosphere and lower mesosphere via satellite measurement data obtained with the help of SBUV/SBUV2 instruments in 1978–2003. We revealed a high coherence between the ozone content and solar activity level on the solar cycle scale. In much of this area, the ozone content varies approximately in phase with the solar cycle; however, in areas of significant gradients of ozone mixing ratio in the middle stratosphere, the phase shift between ozone and solar oscillations can be considerable, up to π/2. This can be caused by dynamical processes. The altitude maxima of ozone sensitivity to the 11-year solar cycle were found in the upper vicinity of the stratopause (50–55 km), in the middle stratosphere (35–40 km), and the lower stratosphere (below 25 km). Maximal changes in ozone content in the solar cycle (up to 10% and more) were found in winter and spring in polar regions.     

利用ERA-Interim资料对平流层Brewer-Dobson环流变化趋势的分析

选用每天12∶00UTC时次的逐日ERA-Interim再分析资料,根据transformed Eulerian-mean(TEM)方程通过积分剩余速度珔v*,研究了1979—2011年间Brewer-Dobson(BD)环流的时空演变规律.并将其与downward control(DC)原理研究的结果进行比较,同时还探讨了平流层温度与BD环流之间的相互联系.结果表明,由TEM方程通过积分剩余速度珔v*估算的BD环流与利用DC原理估算的环流相比较,在热带地区的形势更加明显.环流在热带对流层中上层上升至平流层中下层,最高可达1hPa等压面附近.然后在热带外向极向下运动,最后在中高纬度下沉回到对流层.BD环流的上升中心及质量通量均随季节的变化产生变动,环流在冬半球的形势显著地强于夏半球.在春季和秋季期间,环流呈现出南北两半球的对称形势.从全球尺度物质输送的角度来看,在过去的33a间平流层BD环流的长期变化趋势是减弱的,且在平流层中下层减弱是明显的.环流的减弱趋势与纬向平均温度的长期变化趋势相匹配.