Multiple temporal scale variability during the twentieth century in global carbon dynamics simulated by a coupled climate–terrestrial carbon cycle model

A coupled climate–carbon cycle model composed of a process-based terrestrial carbon cycle model, Sim-CYCLE, and the CCSR/NIES/FRCGC atmospheric general circulation model was developed. We examined the multiple temporal scale functions of terrestrial ecosystem carbon dynamics induced by human activities and natural processes and evaluated their contribution to fluctuations in the global carbon budget during the twentieth century. Global annual net primary production (NPP) and heterotrophic respiration (HR) increased gradually by 6.7 and 4.7%, respectively, from the 1900s to the 1990s. The difference between NPP and HR was the net carbon uptake by natural ecosystems, which was 0.6 Pg C year^?1 in the 1980s, whereas the carbon emission induced by human land-use changes was 0.5 Pg C year^?1, largely offsetting the natural terrestrial carbon sequestration. Our results indicate that monthly to interannual variation in atmospheric CO₂ growth rate anomalies show 2- and 6-month time lags behind anomalies in temperature and the NiNO₃ index, respectively. The simulated anomaly amplitude in monthly net carbon flux from terrestrial ecosystems to the atmosphere was much larger than in the prescribed air-to-sea carbon flux. Fluctuations in the global atmospheric CO₂ time series were dominated by the activity of terrestrial vegetation. These results suggest that terrestrial ecosystems have acted as a net neutral reservoir for atmospheric CO₂ concentrations during the twentieth century on an interdecadal timescale, but as the dominant driver for atmospheric CO₂ fluctuations on a monthly to interannual timescale.     

Estimating climate change effects on net primary production of rangelands in the United States

The potential effects of climate change on net primary productivity (NPP) of U.S. rangelands were evaluated using estimated climate regimes from the A1B, A2 and B2 global change scenarios imposed on the biogeochemical cycling model, Biome-BGC from 2001 to 2100. Temperature, precipitation, vapor pressure deficit, day length, solar radiation, CO₂ enrichment and nitrogen deposition were evaluated as drivers of NPP. Across all three scenarios, rangeland NPP increased by 0.26 % year^?1 (7 kg C ha^?1 year^?1) but increases were not apparent until after 2030 and significant regional variation in NPP was revealed. The Desert Southwest and Southwest assessment regions exhibited declines in NPP of about 7 % by 2100, while the Northern and Southern Great Plains, Interior West and Eastern Prairies all experienced increases over 25 %. Grasslands dominated by warm season (C4 photosynthetic pathway) species showed the greatest response to temperature while cool season (C3 photosynthetic pathway) dominated regions responded most strongly to CO₂ enrichment. Modeled NPP responses compared favorably with experimental results from CO₂ manipulation experiments and to NPP estimates from the Moderate Resolution Imaging Spectroradiometer (MODIS). Collectively, these results indicate significant and asymmetric changes in NPP for U.S. rangelands may be expected.     

Palaeoprecipitation reconstruction by inverse modelling using the isotopic signal of loess organic matter: application to the Nußloch loess sequence (Rhine Valley, Germany)

A modified version of the Biome4 vegetation model for simulation of the mean δ¹³C of plant communities is presented, and used to reconstruct palaeoprecipitation. We treat all fractionations by C3 and C4 plants in all coexistent Plant Functional Types, weighted by their respective net primary production. We constrain the range of variation in the intracellular versus atmospheric CO₂ concentration by fixing a lower limit. Finally, we replace some constant parameters by functions of external forcing to account for their responses to environmental variation. The new version of Biome4 was applied as an inverse model and tested on three modern data sets. The fit between observations and simulations is very close to the 1:1 relationship, with respective slopes of 0.90±0.02 (r ²=0.98, n=29) for δ¹³C and 0.97±0.06 (r ²=0.90, n=29) for precipitation. Inverse modelling was applied using the Metropolis-Hastings algorithm to the Nußloch loess sequence. Over the last glaciation, simulated palaeoprecipitation varies between 240 mm year^?1 and 400 mm year^?1. This study clearly demonstrates atmospheric teleconnections with the Greenland ice-sheet extension, by matching Dansgaard-Oeschger events with precipitation increase of ca. 100–200 mm year^?1.     

Effects of increased CO2 on land water balance from 1850 to 1989

Numerous studies have shown that increased atmospheric CO₂ concentration is one of the most important factors altering land water balance. In this study, we investigated the effects of increased CO₂ on global land water balance using the dataset released by the Coupled Model Intercomparison Project Phase 5 derived from the Canadian Centre for Climate Modelling and Analysis second-generation Earth System Model. The results suggested that the radiative effect of CO₂ was much greater than the physiological effect on the water balance. At the model experiment only integrating CO₂ radiative effect, the precipitation, evapotranspiration (ET) and runoff had significantly increased by 0.37, 0.12 and 0.31 mm year^?2, respectively. Increases of ET and runoff caused a significant decrease of soil water storage by 0.05 mm year^?2. However, the results showed increases of runoff and decreases of precipitation and ET in response to the CO₂ fertilisation effect, which resulted into a small, non-significant decrease in the land water budget. In the Northern Hemisphere, especially on the coasts of Greenland, Northern Asia and Alaska, there were obvious decreases of soil water responding to the CO₂ radiative effect. This trend could result from increased ice–snow melting as a consequence of warmer surface temperature. Although the evidence suggested that variations in soil moisture and snow cover and vegetation feedback made an important contribution to the variations in the land water budget, the effect of other factors, such as aerosols, should not be ignored, implying that more efforts are needed to investigate the effects of these factors on the hydrological cycle and land water balance.     

Phytomass carbon pool of trees and forests in India

The study reports estimates of above ground phytomass carbon pools in Indian forests for 1992 and 2002 using two different methodologies. The first estimate was derived from remote sensing based forest area and crown density estimates, and growing stock data for 1992 and 2002 and the estimated pool size was in the range 2,626–3,071 Tg C (41 to 48 Mg C ha^???1) and 2,660–3,180 Tg C (39 to 47 Mg C ha^???1) for 1992 and 2002, respectively. The second methodology followed IPCC 2006 guidelines and using an initial 1992 pool of carbon, the carbon pool for 2002 was estimated to be in the range of 2,668–3,112 Tg C (39 to 46 Mg C ha^???1), accounting for biomass increment and removals for the period concerned. The estimated total biomass increment was about 458 Tg over the period 1992–2002. Removals from forests include mainly timber and fuel wood, whereby the latter includes large uncertainty as reported extraction is lower than actual consumption. For the purpose of this study, the annual extraction values of 23 million m³ for timber and 126 million m³ for fuel wood were used. Out of the total area, 10 million ha are plantation forests with an average productivity (3.2 Mg ha^???1 year^???1) that is higher than natural forests, a correction of 408 Tg C for the 10 year period was incorporated in total estimated phytomass carbon pool of Indian forests. This results in an estimate for the net sink of 4 Tg C year^???1. Both approaches indicate Indian forests to be sequestering carbon and both the estimates are in agreement with recent studies. A major uncertainty in Indian phytomass carbon pool dynamics is associated with trees outside forests and with soil organic carbon dynamics. Using recent remote-sensing based estimates of tree cover and growing stock outside forests, the estimated phytomass carbon pool for trees outside forests for the year 2002, is 934 Tg C with a national average tree carbon density of 4 Mg C ha^???1 in non-forest area, in contrast to an average density of 43 Mg C ha^???1 in forests. Future studies will have to consider dynamics in both trees outside forests and soil for total terrestrial carbon dynamics.     

Influence of olive mill waste application on the role of soil as a carbon source or sink

Organic matter (OM) is involved in the enhancement of soil quality since it acts on soil structure, nutrient storage and biological activity. Organic carbon (OC), the dominant element constituent of OM, and related soil properties are probably the most widely acknowledged indicator of soil quality. The typically Mediterranean climate of the South of Spain promotes low yields on crops and low organic carbon in soil. The present work was carried out to evaluate the effect of the application of alperujo, olive oil waste difficult to eliminate, on the fixation or emission of carbon on soil in an olive grove situated in Montoro (Córdoba, Spain). In the study three treatments were considered: 15 kg (A), 7.5 kg (B), 0 kg (C) of alperujo per tree and the implementation of the amendment has been made for three consecutive years. The results confirm the benefits of the amendment on the carbon content organic soil with a fixation with respect to control of 4.8 and 6.1 t ha^???1 for the first year and 8.7 and 6.8 t ha^???1 for the second in treatments A and B, respectively. Of the different climatic agents considered in the study, it was the temperature which had a major influence on the emissions of CO₂ into the atmosphere and the flow of gas presented the highest values in soils treated with the highest dose.     

Seasonal variation of carbon dioxide fluxes over irrigated soybean (Glycine max L.)

In this study, variations in carbon dioxide (CO₂) fluxes resulting from gross primary production (GPP), net ecosystem exchange (NEE), and respiration (R _e) of soybean (Glycine max L.) were investigated by the Eddy Covariance method during the growing period from June to November 2005 on an irrigated sand field at the Arid Land Research Center, Tottori University in Tottori, Japan. Although climatic conditions were humid and temperate, the soybeans required frequent irrigation because of the low water holding capacity of the sandy soil at the field site. Finally, it has been found that the accumulated NEE, GPP, and R _e fluxes of soybean over 126 days amount to ?93, 319, and 226 gC m^?2, respectively. Furthermore, the average ratio of GPP to R _e was 1.4 and the average ratio of NEE to GPP was about ?0.29 for the growth period of soybean. Daily maximum NEE of ?3.8 gC m^?2 occurred when LAI was 1.1.     

Atmospheric stabilization and the timing of carbon mitigation

Stabilization of atmospheric CO₂ concentrations below a pre-industrial doubling (~550 ppm) is a commonly cited target in climate policy assessment. When the rate at which future emissions can fall is assumed to be fixed, the peak atmospheric concentration – or the stabilization “frontier” – is an increasing and convex function of the length of postponement. Here we find that a decline in emissions of 1% year^?1 beginning today would place the frontier near 475 ppm and that when mitigation is postponed, options disappear (on average) at the rate of ~9 ppm year^?1, meaning that delays of more than a decade will likely preclude stabilization below a doubling. When constraints on the future decline rate of emissions are relaxed, a particular atmospheric target can be realized in many ways, with scenarios that allow longer postponement of emissions reductions requiring greater increases in the intensity of future mitigation. However, the marginal rate of substitution between future mitigation and present delay becomes prohibitively large when the balance is shifted too far toward the future, meaning that some amount of postponement cannot be fully offset by simply increasing the intensity of future mitigation. Consequently, these results suggest that a practical transition path to a given stabilization target in the most commonly cited range can allow, at most, one or two decades of delay.     

Time-dependent uptake of NO3 by sea salt

Using a coated-insert flow tube reactor coupled to a low-energy electron-impact mass spectrometer with molecular beam sampling, we studied uptake of NO₃ by sea salt at room temperature and [NO₃]?=?8?10¹¹???4?10¹³ molecule cm^?3. The radical uptake coefficient γ(t) is time dependent: its initial value (γ _ini) decreases exponentially with the characteristic time (τ) to its steady-state value (γ _ss) at given [NO₃]. The parameters γ _ini, γ _ss and τ depend on [NO₃], whereas γ _ss is water vapor independent at [H₂O]?=?8?10¹²???1.6?10¹⁵ molecule cm^?3 and RH ≤ 0.5 %. HCl and NO₂ are uptake products detected in the gas phase. We used these findings to estimate γ values under tropospheric conditions for urban coastal and remote marine environments: at high NO₃ (~90 ppt), the time dependence becomes important, and the γ value averaged over the aerosol lifetime is 4?10^?3; at low NO₃ (~1 ppt), the radical uptake is time independent and proceeds faster with γ _ini?=?8?10^?3     

Potential for forest carbon plantings to offset greenhouse emissions in Australia: economics and constraints to implementation

The theoretical potential for carbon forests to off-set greenhouse gas emissions may be high but the achievable rate is influenced by a range of economic and social factors. Economic returns (net present value, NPV) were calculated spatially across the cleared land area in Australia for ‘environmental carbon plantings’. A total of 105 scenarios were run by varying discount rate, carbon price, rate of carbon sequestration and costs for plantation establishment licenses for water interception. The area for which NPV was positive ranged from zero ha for tightly constrained scenarios to almost the whole of the cleared land (104 M ha) for lower discount rate and highest carbon price. For the most plausible assumptions for cost of establishment and commercial discount rate, no areas were identified as profitable until a carbon price of AUD$40 t CO₂ ^?1 was reached. The many practical constraints to plantation establishment mean that it will likely take decades to have significant impact on emission reductions. Every 1 M ha of carbon forests established would offset about 1.4 % of Australia’s year 2000 emissions (or 7.4 Mt CO₂ year^?1) when an average rate of sequestration per ha was reached. All studies that predict large areas of potentially profitable land for carbon forestry need to be tempered by the realities that constrain land use change. In Australia and globally, carbon plantings can be a useful activity to help mitigate emissions and restore landscapes but it should be viewed as a long-term project in which co-benefits such as biodiversity enhancement can be realised.     

Interactive effects of elevated [CO2] and temperature on growth and development of a short- and long-season peanut cultivar

Temperature and CO₂ are two of the main environmental factors associated with climate change. It is generally expected that elevated [CO₂] will increase crop production. However, other environmental factors such as temperature along with management practices could further modify a crop’s response to CO₂. The goal of this study was to determine the interactive effects of elevated [CO₂] and above-optimum temperature on growth, development and yield of two peanut (Arachis hypogaea L.) cultivars, e.g., Pronto and Georgia Green. One of the objectives was to determine if there was any variation in response between these two cultivars with respect to possible adaptation to climate change. Peanut plants were grown in controlled environment chambers in the University of Georgia Envirotron under conditions of non-limiting water and nutrient supply. Plants were exposed to day/night air temperatures of 33/21°C (T _A), 35.5/23.5°C (T _A + 2.5°C), and 38/26°C (T _A + 5°C) along with CO₂ treatments of 400 and 700 μmol CO₂ mol^???1 air. The selected range of temperatures was based on the temperatures that are common for southwest Georgia during the summer months. The results showed that LAI of both cultivars responded positively, e.g., 28.3% for Pronto and 49.3% for Georgia Green to elevated [CO₂]. Overall, elevated [CO₂] alone resulted in a significant increase in total biomass at final harvest across all temperatures (P?< 0.0001), but decreased final seed yield (P?< 0.0005), except for Georgia Green at (T _A + 5°C). The higher temperatures compared to T _A reduced the relative response of total biomass to CO₂ for both cultivars. It can be concluded that final seed yield response to CO₂ depends on the sensitivity of individual cultivars to temperature, especially during the reproductive development stage.     

Combined effects of elevated [CO2] and high temperature on leaf mineral balance in Coffea spp. plants

Modelling studies predicted that climate change will have strong impacts on the coffee crop, although no information on the effective impact of elevated CO₂ on this plant exists. Here, we aim at providing a first glimpse on the effect of the combined impact of enhanced [CO₂] and high temperature on the leaf mineral content and balance on this important tropical crop. Potted plants from two genotypes of Coffea arabica (cv. Icatu and IPR 108) and one from C. canephora (cv. Conilon Clone 153) were grown under 380 or 700 μL CO₂ L^?1 air, for 1 year, after which were exposed to an stepwise increase in temperature from 25/20 °C (day/night) up to 42/34 °C, over 8 weeks. Leaf macro???(N, P, K, Ca, Mg, S) and micronutrients (B, Cu, Fe, Mn, Zn) concentrations were analyzed at 25/20 °C (control), 31/25 °C, 37/30 °C and 42/34 °C. At the control temperature, the 700 μL L^?1 grown plants showed a moderate dilution effect (between 7 % and 25 %) in CL 153 (for N, Mg, Ca, Fe) and Icatu (for N, K and Fe), but not in IPR 108 (except for Fe) when compared to the 380 μL L^?1 plants. For temperatures higher than control most nutrients tended to increase, frequently presenting maximal contents at 42/34 °C (or 37/30 °C), although the relation between [CO₂] treatments did not appreciably change. Such increases offset the few dilution effects observed under high growth [CO₂] at 25/20 °C. No clear species responses were found considering [CO₂] and temperature impacts, although IPR 108 seemed less sensitive to [CO₂]. Despite the changes promoted by [CO₂] and heat, the large majority of mineral ratios were kept within a range considered adequate, suggesting that this plant can maintain mineral balances in a context of climate changes and global warming.     

Methods for Estimating Air–Sea Fluxes of CO<Subscript>2</Subscript> Using High-Frequency Measurements

The most direct method for flux estimation uses eddy covariance, which is also the most commonly used method for land-based measurements of surface fluxes. Moving platforms are frequently used to make measurements over the sea, in which case motion can disturb the measurements. An alternative method for flux estimation should be considered if the effects of platform motion cannot be properly corrected for. Three methods for estimating CO₂ fluxes are studied here: the eddy-covariance, the inertial-dissipation, and the cospectral-peak methods. High-frequency measurements made at the land-based Östergarnsholm marine station in the Baltic Sea and measurements made from a ship during the Galathea 3 expedition are used. The Kolmogorov constant for CO₂, used in the inertial-dissipation method, is estimated to be 0.68 and is determined using direct flux measurements made at the Östergarnsholm site. The cospectral-peak method, originally developed for neutral stratification, is modified to be applicable in all stratifications. With these modifications, the CO₂ fluxes estimated using the three methods agree well. Using data from the Östergarnsholm site, the mean absolute error between the eddy-covariance and inertial-dissipation methods is 0.25 μmol  m^?2 s^?1. The corresponding mean absolute error between the eddy-covariance and cospectral-peak methods is 0.26 μmol m^?2 s^?1, while between the inertial-dissipation and cospectral-peak methods it is 0.14 μmol m^?2 s^?1.     

Effect of surface albedo, water vapour, and atmospheric aerosols on the cloud-free shortwave radiative budget in the Arctic

This study is based on ground-based measurements of downward surface shortwave irradiance (SW), columnar water vapour (wv), and aerosol optical depth (τ) obtained at Thule Air Base (Greenland) in 2007–2010, together with MODIS observations of the surface shortwave albedo (A). Radiative transfer model calculations are used in combination with measurements to separate the radiative effect of A (ΔSW_A), wv (ΔSW_wv), and aerosols (ΔSW_τ) in modulating SW in cloud-free conditions. The shortwave radiation at the surface is mainly affected by water vapour absorption, which produces a reduction of SW as low as ?100 Wm^?2 (?18%). The seasonal change of A produces an increase of SW by up to +25 Wm^?2 (+4.5%). The annual mean radiative effect is estimated to be ?(21–22) Wm^?2 for wv, and +(2–3) Wm^?2 for A. An increase by +0.065 cm in the annual mean wv, to which corresponds an absolute increase in ΔSW_wv by 0.93 Wm^?2 (4.3%), has been observed to occur between 2007 and 2010. In the same period, the annual mean A has decreased by ?0.027, with a corresponding decrease in ΔSW_A by 0.41 Wm^?2 (?14.9%). Atmospheric aerosols produce a reduction of SW as low as ?32 Wm^?2 (?6.7%). The instantaneous aerosol radiative forcing (RF_τ) reaches values of ?28 Wm^?2 and shows a strong dependency on surface albedo. The derived radiative forcing efficiency (FE_τ) for solar zenith angles between 55° and 70° is estimated to be (?120.6 ± 4.3) for 0.1 < A < 0.2, and (?41.2 ± 1.6) Wm^?2 for 0.5 < A < 0.6.     

Modeling to evaluate the response of savanna-derived cropland to warming–drying stress and nitrogen fertilizers

Many savannas in West Africa have been converted to croplands and are among the world’s regions most vulnerable to climate change due to deteriorating soil quality. We focused on the savanna-derived cropland in northern Ghana to simulate its sensitivity to projected climate change and nitrogen fertilization scenarios. Here we show that progressive warming–drying stress over the twenty-first century will enhance soil carbon emissions from all kinds of lands of which the natural ecosystems will be more vulnerable to variation in climate variables, particularly in annual precipitation. The carbon emissions from all croplands, however, could be mitigated by applying nitrogen fertilizer at 30–60 kg N ha^???1 year^???1. The uncertainties of soil organic carbon budgets and crop yields depend mainly on the nitrogen fertilization rate during the first 40 years and then are dominated by climate drying stress. The replenishment of soil nutrients, especially of nitrogen through fertilization, could be one of the priority options for policy makers and farm managers as they evaluate mitigation and adaptation strategies of cropping systems and management practices to sustain agriculture and ensure food security under a changing climate.     

Carbonaceous and inorganic species in PM<Subscript>10</Subscript> during wintertime over Giridih,Jharkhand (India)

Ambient concentrations of organic carbon (OC), elemental carbon (EC) and water soluble inorganic ionic components (WSIC) of PM₁₀ were studied at Giridih, Jharkhand, a sub-urban site near the Indo Gangatic Plain (IGP) of India during two consecutive winter seasons (November 2011–February 2012 and November 2012–February 2013). The abundance of carbonaceous and water soluble inorganic species of PM₁₀ was recorded at the study site of Giridih. During winter 2011–12, the average concentrations of PM₁₀, OC, EC and WSIC were 180.2?±?46.4; 37.2?±?6.2; 15.2?±?5.4 and 18.0?±?5.1 μg m^?3, respectively. Similar concentrations of PM₁₀, OC, EC and WSIC were also recorded during winter 2012–13. In the present case, a positive linear trend is observed between OC and EC at sampling site of Giridih indicates the coal burning, as well as dispersed coal powder and vehicular emissions may be the source of carbonaceous aerosols. The principal components analysis (PCA) also identifies the contribution of coal burning? +?soil dust, vehicular emissions?+?biomass burning and seconday aerosol to PM₁₀ mass concentration at the study site. Backward trajectoy and potential source contributing function (PSCF) analysis indicated that the aerosols being transported to Giridih from upwind IGP (Punjab, Haryana, Uttar Pradesh and Bihar) and surrounding region.     

Anthropogenic heat in the city of S?o Paulo, Brazil

The main goal of this work is to describe the anthropogenic energy flux (Q _F) in the city of S?o Paulo, Brazil. The hourly, monthly, and annual values of the anthropogenic energy flux are estimated using the inventory method, and the contributions of vehicular, stationary, and human metabolism sources from 2004 to 2007 are considered. The vehicular and stationary sources are evaluated using the primary consumption of energy based on fossil fuel, bio fuel, and electricity usage by the population. The diurnal evolution of the anthropogenic energy flux shows three relative maxima, with the largest maxima occurring early in the morning (??19.9 Wm^?2) and in the late afternoon (??20.3 Wm^?2). The relative maximum that occurs around noontime (??19.6 Wm^?2) reflects the diurnal pattern of vehicle traffic that seems to be specific to S?o Paulo. With respect to diurnal evolution, the energy flux released by vehicular sources (Q _FV) contributes approximately 50% of the total anthropogenic energy flux. Stationary sources (Q _FS) and human metabolism (Q _FM) represent about 41% and 9% of the anthropogenic energy flux, respectively. For 2007, the monthly values of Q _FV, Q _FS, Q _FM, and Q _F are, respectively, 16.8?±?0.25, 14.3?±?0.16, 3.5?±?0.03, and 34.6?±?0.41?MJ?m^?2?month^?1. The seasonal evolution monthly values of Q _FV, Q _FS, Q _FM, and Q _F show a relative minimum during the summer and winter vacations and a systematic and progressive increase associated with the seasonal evolution of the economic activity in S?o Paulo. The annual evolution of Q _F indicates that the city of S?o Paulo released 355.2?MJ?m^?2?year^?1 in 2004 and 415.5?MJ?m^?2?year^?1 in 2007 in association with an annual rate of increase of 19.6?MJ?m^?2?year^?1 (from 2004 to 2006) and 30.5?MJ?m^?2?year^?1 (from 2006 to 2007). The anthropogenic energy flux corresponds to about 9% of the net radiation at the surface in the summer and 15% in the winter. The amplitude of seasonal variation of the maximum hourly value of the diurnal variation increases exponentially with latitude.     

Temperature variations and rice yields in China: historical contributions and future trends

Temperature is the principal factor that determines rice growth, development and ultimately grain yield. In this study, normal growing-degree-days (NGDD) and killing growing-degree-days (KGDD) were used to capture the different effects of normal and extreme temperatures on rice yields, respectively. Based on these indexes, we assessed the contributions of temperature variations to county-level rice yields across China during the historical period (1980–2008), and estimated the potential exposure of rice to extreme temperature stress in the near future (2021–2050). The results showed that historical temperature variations had measurable impacts on rice yields with a distinct spatial pattern: for different regions, such variations had contributed much to the increased rice yields in Northeast China (Region I) (0.59 % yield year^?1) and some portions of the Yunnan-Guizhou Plateau (Region II) (0.34 % yield year^?1), but seriously hindered the improvements of rice yields in the Sichuan Basin (SB) (?0.29 % yield year^?1) and the southern cultivation areas (Region IV) (?0.17 % yield year^?1); for the entire country, half of the contributions were positive and the other half were negative, resulting in a balance pattern with an average of 0.01 % yield year^?1. Under the RCP8.5 scenario, climate warming during 2021–2050 would substantially reduce cold stress but increase heat stress in the rice planting areas across China. For the future period, Region I, II and eastern China would be continually exposed to more severe cold stress than the other regions; Region III (including SB and the mid-lower reaches of Yangtze River (MLRYR)) would be the hot spot of heat stress.     

Water-soluble inorganic ions of size-differentiated atmospheric particles from a suburban site of Mexico City

During the MILAGRO campaign, March 2006, eight-stage cut impactors were used to sample atmospheric particles at Tecámac (T1 supersite), towards the northeast edge of the Mexico City Metropolitan Area, collecting fresh local emissions and aged pollutants produced in Mexico City. Particle samples were analyzed to determine total mass concentrations of Ca²⁺, Mg²⁺, NH₄ ⁺, K⁺, Cl^?, SO₄ ^2?, and NO₃ ^?. Average concentrations were 22.1 ± 7.2 μg m^?3 for PM₁₀ and 18.3 ± 6.2 μg m^?3 for PM_1.8. A good correlation between PM₁₀ and PM_1.8, without influence from wind patterns, indicates that local emissions are more important than the city’s pollution transported to the site, despite the fact that Tecámac is just 40 km away from Mexico City. A lack of diurnal patterns in the PM_2.5/PM_1.8 ratio supports this conclusion. The inorganic composition of particles suggests that vehicles, soil resuspension, and industries are the main pollutant sources. Finally, the particles were found to be neutralized, in agreement with observations in the Mexico City Metropolitan Area.     

Continuous measurement of methane flux over a larch forest using a relaxed eddy accumulation method

We measured the methane flux of a forest canopy throughout a year using a relaxed eddy accumulation (REA) method. This sampling system was carefully validated against heat and CO₂ fluxes measured by the eddy covariance method. Although the sampling system was robust, there were large uncertainties in the measured methane fluxes because of the limited precision of the methane gas analyzer. Based on the spectral characteristics of signals from the methane analyzer and the diurnal variations in the standard deviation of the vertical wind velocity, we found the daytime and nighttime precision of half-hourly methane flux measurements to be approximately 1.2 and 0.7?μg?CH₄?m^?2?s^?1, respectively. Additional uncertainties caused by the dilution effect were estimated to affect the accuracy by as much as 0.21?μg?CH₄?m^?2?s^?1 on a half-hourly basis. Diurnal and seasonal variations were observed in the measured fluxes. The biological emission from plant leaves was not observed in our studies, and thus could be negligible at the canopy-scale exchange. The annual methane sink was 835?±?175?mg?CH₄?m^?2?year^?1 (8.35?kg?CH₄?ha^?1?year^?1), which was comparable to the flux range of 379–2,478?mg?CH₄?m^?2?year^?1 previously measured in other Japanese forest soils. This study indicated that the REA method could be a promising technique to measure canopy scale methane fluxes over forests, but further improvement of precision of the analyzer will be required.