A field experiment and numerical modeling of a tracer at a gravel beach in Prince William Sound,Alaska

Oil from the 1989 Exxon Valdez oil spill persists in many gravel beaches in Prince William Sound (Alaska, USA), despite great remedial efforts. A tracer study using lithium at a gravel beach on Knight Island, Prince William Sound, during the summer of 2008 is reported. The tracer injection and transport along a transect were simulated using the two-dimensional numerical model MARUN. Model results successfully reproduced the tracer concentrations observed at wells along the transect. A sensitivity analysis revealed that the estimated parameters are well determined. The simulated spatial distribution of tracer indicated that nutrients applied along the transect for bioremediation purposes would be washed to the sea very quickly (within a semi-diurnal tidal cycle) by virtue of the combination of the two-layered beach structure, the tidal fluctuation and the freshwater flow from inland. Thus, pore-water samples in the transect were found to be clean due to factors other than bioremediation. This may explain why the oil did not persist within the transect.     

Sulfide oxidation and distribution of metals near abandoned copper mines in coastal environments,Prince William Sound,Alaska, USA

The oxidation of sulfide-rich rocks, mostly leftover debris from Cu mining in the early 20th century, is contributing to metal contamination of local coastal environments in Prince William Sound, Alaska. Analyses of sulfide, water, sediment, precipitate and biological samples from the Beatson, Ellamar, and Threeman mine sites show that acidic surface waters generated from sulfide weathering are pathways for redistribution of environmentally important elements into and beyond the intertidal zone at each site. Volcanogenic massive sulfide deposits composed of pyrrhotite and (or) pyrite + chalcopyrite + sphalerite with subordinate galena, arsenopyrite, and cobaltite represent potent sources of Cu, Zn, Pb, As, Co, Cd, and Hg. The resistance to oxidation among the major sulfides increases in the order pyrrhotite ? sphalerite < chalcopyrite ? pyrite; thus, pyrrhotite-rich rocks are typically more oxidized than those dominated by pyrite. The pervasive alteration of pyrrhotite begins with rim replacement by marcasite followed by replacement of the core by sulfur, Fe sulfate, and Fe–Al sulfate. The oxi dation of chalcopyrite and pyrite involves an encroachment by colloform Fe oxyhydroxides at grain margins and along crosscutting cracks that gradually consumes the entire grain. The complete oxidation of sulfide-rich samples results in a porous aggregate of goethite, lepidocrocite and amorphous Fe-oxyhydroxide enclosing hydrothermal and sedimentary silicates. An inverse correlation between pH and metal concentrations is evident in water data from all three sites. Among all waters sampled, pore waters from Ellamar beach gravels have the lowest pH (∼3) and highest concentrations of base metals (to ∼25,000 μg/L), which result from oxidation of abundant sulfide-rich debris in the sediment. High levels of dissolved Hg (to 4100 ng/L) in the pore waters probably result from oxidation of sphalerite-rich rocks. The low-pH and high concentrations of dissolved Fe, Al, and SO₄ are conducive to precipitation of interstitial jarosite in the intertidal gravels. Although pore waters from the intertidal zone at the Threeman mine site have circumneutral pH values, small amounts of dissolved Fe²⁺ in the pore waters are oxidized during mixing with seawater, resulting in precipitation of Fe-oxyhydroxide flocs along the beach–seawater interface. At the Beatson site, surface waters funneled through the underground mine workings and discharged across the waste dumps have near-neutral pH (6.7–7.3) and a relatively small base-metal load; however, these streams probably play a role in the physical transport of metalliferous particulates into intertidal and offshore areas during storm events. Somewhat more acidic fluids, to pH 5.3, occur in stagnant seeps and small streams emerging from the Beatson waste dumps. Amorphous Fe precipitates in stagnant waters at Beatson have high Cu (5.2 wt%) and Zn (2.3 wt%) concentrations that probably reflect adsorption onto the extremely high surface area of colloidal particles. Conversely, crystalline precipitates composed of ferrihydrite and schwertmannite that formed in the active flow of small streams have lower metal contents, which are attributed to their smaller surface area and, therefore, fewer reactive sorption sites. Seeps containing precipitates with high metal contents may contribute contaminants to the marine environment during storm-induced periods of high runoff. Preliminary chemical data for mussels (Mytilus edulis) collected from Beatson, Ellamar, and Threeman indicate that bioaccumulation of base metals is occurring in the marine environment at all three sites.     

Temporal variation and the effect of rainfall on metals flux from the historic Beatson mine,Prince William Sound,Alaska, USA

Several abandoned Cu mines are located along the shore of Prince William Sound, AK, where the effect of mining-related discharge upon shoreline ecosystems is unknown. To determine the magnitude of this effect at the former Beatson mine, the largest Cu mine in the region and a Besshi-type massive sulfide ore deposit, trace metal concentration and flux were measured in surface run-off from remnant, mineralized workings and waste. Samples were collected from seepage waters; a remnant glory hole which is now a pit lake; a braided stream draining an area of mineralized rock, underground mine workings, and waste piles; and a background location upstream of the mine workings and mineralized rock. In the background stream pH averaged ∼7.3, specific conductivity (SC) was ∼40 μS/cm, and the aqueous components indicative of sulfide mineral weathering, SO₄ and trace metals, were at detection limits or lower. In the braided stream below the mine workings and waste piles, pH usually varied from 6.7 to 7.1, SC varied from 40 to 120 μS/cm, SO₄ had maximum concentrations of 32 mg/L, and the trace metals Cu, Ni, Pb, and Zn showed maximum total acid extractable concentrations of 186, 5.9, 6.2 and 343 μg/L, respectively.     

Holocene vegetation history of the Okanogan Valley,Washington

Haploxylon pine(s) and Artemisia dominated the initial vegetation in front of the receding Okanogan Lobe until ca. 10,000 yr B.P., as revealed by two pollen records in north-central Washington. After 10,000 yr B.P. the macroclimate became warmer throughout the Okanogan drainage as diploxylon pines and Artemisia increased. The Mount Mazama eruption at ca. 6700 yr B.P. is recorded as two stratigraphically separate and petrographically distinct tephra units at Bonaparte Meadows. While there are apparent short-term changes in the vegetation coincident with the ashfall(s), Artemisia continues to dominate the Okanogan Valley until ca. 5000 yr B.P. By 4700 yr B.P. the modern vegetation, dominated by Pseudotsuga menziesii, had become established around Bonaparte Meadows.     

PAH refractory index as a source discriminant of hydrocarbon input from crude oil and coal in Prince William Sound,Alaska

Geochemical correlation and differentiation of hydrocarbons from crude oils and coals is difficult. The complex mixture of the hydrocarbon constituents and the dynamic nature of these constituents in the environment as they weather contribute to this difficulty. A new parameter, the polycyclic aromatic hydrocarbon (PAH) refractory index, is defined here to help in this correlation. The PAH refractory index is a ratio of two of the most refractory constituents of most crude oils, namely triaromatic steranes and monomethylchrysenes. These are among the most persistent compounds in oil after deposition in the environment and thus retain reliably the signature of the original petroleum input. This index is utilized in Prince William Sound (PWS) to differentiate three different oils, as well as to provide evidence that coal, not oil, is the dominant source of the PAHs which are prominent constituents of marine sediments from PWS and the Gulf of Alaska.     

Relationships between microbial communities and environmental parameters at sites impacted by mining of volcanogenic massive sulfide deposits,Prince William Sound,Alaska

The relations among geochemical parameters and sediment microbial communities were examined at three shoreline sites in the Prince William Sound, Alaska, which display varying degrees of impact by acid-rock drainage (ARD) associated with historic mining of volcanogenic massive sulfide deposits. Microbial communities were examined using total fatty acid methyl esters (FAMEs), a class of compounds derived from lipids produced by eukaryotes and prokaryotes (bacteria and Archaea); standard extraction techniques detect FAMEs from both living (viable) and dead (non-viable) biomass, but do not detect Archaeal FAMEs. Biomass and diversity (as estimated by FAMEs) varied strongly as a function of position in the tidal zone, not by study site; subtidal muds, Fe oxyhydroxide undergoing biogenic reductive dissolution, and peat-rich intertidal sediment had the highest values. These estimates were lowest in acid-generating, intertidal zone sediment; if valid, the estimates suggest that only one or two bacterial species predominate in these communities, and/or that Archeal species are important members of the microbial community in this sediment.     

Structural evolution of the Port Wells gold mining district,Prince William Sound,south central Alaska: Implications for the origin of the gold lodes

Data collected in the Port Wells gold mining district, Alaska, indicate several stages in the structural history of the district. The first stage was the accretion and associated deformation of the Valdez group flysch sequence at the end of the Cretaceous. The deformation of the semilithified rocks included two folding phases forming isoclinal NE-SW-striking and SE-vergent folds during a D₁ phase, and minor open warps in NW-SE direction during a D₂ phase. Intrusion of early Oligocene (36 Ma) calc-alkaline granitoids followed deformation and was terminated by the emplacement of aplitic dikes. The major fracturing processes in both the granitoids and the country rocks occurred subsequently, probably during the uplift of the Chugach mountains in the late Tertiary. Several generations of epigenetic gold-bearing quartz veins were emplaced along the fractures at a later stage. Due to the significant time gap between peak metamorphism and mineralization, the metamorphic secretion model proposed for the vein formation is reconsidered.     

Holocene vegetation history in Romanian Subcarpathians

Pollen analysis from a peat core 7.0 m in length, taken from a bog near Bisoca, in a mid-altitude area of the Buzăului Subcarpathian mountains, is used to reconstruct the postglacial vegetation history of the region. The vegetation record, which is supported by twelve ¹⁴C dates, starts at the end of the Late Glacial period. At the Late Glacial/Holocene transition, open vegetation was replaced by forest, suggesting a fast response to climatic warming. The Holocene began with the expansion of Betula, Pinus and Ulmus, followed, after 11,000 cal yr BP, by Fraxinus, Quercus, Tilia and Picea. The rapid expansion of these taxa may be due to their existence in the area during the Late Glacial period. At ca. 9200 cal yr BP, Corylus expanded, reaching a maximum after 7600 cal yr BP. The establishment of Carpinus occurred at ca. 7200 cal yr BP, with a maximum at ca. 5700 cal yr BP. Fagus pollen is regularly recorded after 7800 cal yr BP and became dominant at ca. 2000 cal yr BP. The first indications of human activities appear around 3800 cal yr BP.     

Postglacial vegetation history of Mitkof Island, Alexander Archipelago, southeastern Alaska

An AMS radiocarbon-dated pollen record from a peat deposit on Mitkof Island, southeastern Alaska provides a vegetation history spanning ∼12,900 cal yr BP to the present. Late Wisconsin glaciers covered the entire island; deglaciation occurred > 15,400 cal yr BP. The earliest known vegetation to develop on the island (∼12,900 cal yr BP) was pine woodland (Pinus contorta) with alder (Alnus), sedges (Cyperaceae) and ferns (Polypodiaceae type). By ∼12,240 cal yr BP, Sitka spruce (Picea sitchensis) began to colonize the island while pine woodland declined. By ∼11,200 cal yr BP, mountain hemlock (Tsuga mertensiana) began to spread across the island. Sitka spruce-mountain hemlock forests dominated the lowland landscapes of the island until ∼10,180 cal yr BP, when western hemlock (Tsuga heterophylla) began to colonize, and soon became the dominant tree species. Rising percentages of pine, sedge, and sphagnum after ∼7100 cal yr BP may reflect an expansion of peat bog habitats as regional climate began to shift to cooler, wetter conditions. A decline in alders at that time suggests that coastal forests had spread into the island's uplands, replacing large areas of alder thickets. Cedars (Chamaecyparis nootkatensis, Thuja plicata) appeared on Mitkof Island during the late Holocene.     

The Holocene vegetation history of the Arfon Platform, North Wales, UK

Detailed pollen, charcoal and loss on ignition profiles were analysed from Llyn Cororion, North Wales, UK. The chronology was based on 11 radiocarbon dates. This site is particularly important for this region because its high-resolution record improves the spatial and temporal resolution of records of Holocene vegetation change in an area characterized by a highly variable environment. An early Holocene phase of Juniperus-Betula scrub was succeeded by Betula-Corylus woodland. Quercus and Ulmus were established by c. 8600 ¹⁴C yr BP, with Pinus dominating at c. 8430 ¹⁴C yr BP. Local disturbance then allowed the spread of Alnus; Tilia was a common component of the forest by 5650 ¹⁴C yr BP. Charcoal and pollen records suggest that by c. 2600 ¹⁴C yr BP there was progressive deforestation, increased use of fire and spread of grassland; the first cereal grain was recorded at c. 2900 ¹⁴C yr BP. Compared with data from upland Snowdonia, the results show that within a topographically diverse region there were significant local variations in forest composition. These variations developed as a response to interactions between many environmental parameters and were further complicated by the influence of human activity. In an area such as North Wales it is therefore unlikely that one site can be representative of regional Holocene vegetational development. The site is additionally important because it contributes to the data available for meta-analyses of environmental change in the North Atlantic region, particularly as detailed pollen diagrams from coastal lake sites around western Europe are rare.     

Late Pleistocene and Holocene vegetation history of the Bale Mountains,Ethiopia

A sediment core recovered from Garba Guracha, a glacial lake at 3950 m altitude in the Bale Mountains of Ethiopia, at the boundary of the Ericaceous and Afroalpine vegetation belts, provides a 16,700-year pollen record of vegetation response to climatic change. The earliest vegetation recorded was sparse and composed mainly of grasses, Amaranthaceae–Chenopodiaceae and Artemisia, indicating an arid climate. At 13,400 cal BP, Amaranthaceae–Chenopodiaceae pollen declined sharply and Cyperaceae increased, suggesting a change to moister conditions. The Younger Dryas interval is represented by a small increase in Artemisia and reduced Cyperaceae, indicating aridity. Just after the start of the Holocene (11,200 cal BP), the upper altitudinal limit of the Ericaceous belt rose, and woody Ericaceous vegetation extended across the Sanetti plateau, in response to increased moisture and temperature. The marked change from clastic to organic lake sedimentation at this time reflects the increase in woody vegetation cover in the lake catchment, accompanied by soil stabilisation, and increased leaf litter and soil humus content. From about 6000 cal BP, and especially after 4500 cal BP, mid-altitude dry Afromontane Juniper–Podocarpus forests developed on the northern slopes of the mountains in response to reduced rainfall in a shortened wet season. Erica shrub and forest decreased in area and altitude, and the Afroalpine ecosystem expanded on the plateau. Podocarpus declined from about 2000 cal BP, as Juniperus increased to its present dominance at 2500–3300 m altitude. Human impact on the high-altitude Afroalpine and Ericaceous vegetation has been relatively minor, confirming that the endemic biodiversity of the Ethiopian mountains is a legacy of natural Holocene vegetation change, following repeated expansion and contraction of the upland ecosystems during the Quaternary.     

Charcoal analysis and Holocene vegetation history in southern Syria

Charcoal analysis of three archaeological sites in southern Syria in the vicinity of the Jebel al Arab (formerly Jebel Druze) indicates that during the Early Bronze Age an association consisting predominately of Pistacia, deciduous oak and almond was exploited. During the Middle Bronze Age these taxa diminish and are partially replaced by more steppic species or introduced wood such as olive. During the Roman period evergreen oak appeared in the region and gradually replaced the deciduous oak which is now restricted to a small area. The gradual replacement of deciduous oaks by evergreen oaks has been observed in other areas of the Mediterranean basin during the Holocene. Conifer charcoal such as pine and cedar is present on the sites, but it is not clear whether these were local or imported from farther away, for example, the Lebanese highlands. During the Middle Bronze Age olive wood was also used as combustible but here also its exact origin is not known.     

Holocene vegetation, fire and climate history of the Sawtooth Range, central Idaho, USA

The paucity of low- and middle-elevation paleoecologic records in the Northern Rocky Mountains limits our ability to assess current environmental change in light of past conditions. A 10,500-yr-long vegetation, fire and climate history from Lower Decker Lake in the Sawtooth Range provides information from a new region. Initial forests dominated by pine and Douglas-fir were replaced by open Douglas-fir forest at 8420 cal yr BP, marking the onset of warmer conditions than present. Presence of closed Douglas-fir forest between 6000 and 2650 cal yr BP suggests heightened summer drought in the middle Holocene. Closed lodgepole pine forest developed at 2650 cal yr BP and fires became more frequent after 1450 cal yr BP. This shift from Douglas-fir to lodgepole pine forest was probably facilitated by a combination of cooler summers, cold winters, and more severe fires than before. Five drought episodes, including those at 8200 cal yr BP and during the Medieval Climate Anomaly, were registered by brief intervals of lodgepole pine decline, an increase in fire activity, and mistletoe infestation. The importance of a Holocene perspective when assessing the historical range of variability is illustrated by the striking difference between the modern forest and that which existed 3000 yr ago.     

贵州西部晚全新世植被演替、气候变化与火灾历史

贵州西部位于北亚热带云贵高原山地湿润-半湿润气候区,西南季风是该区域水汽来源的主要气候系统。贵州六盘水娘娘山有连片分布的垫状泥炭沼泽沉积,较完整记录了过去的植被和气候历史,是研究气候-植被-火灾-人类活动变化的理想场所。本研究以六盘水娘娘山1999 m海拔的一处泥炭湿地钻孔上部52 cm岩芯为研究材料,通过AMS ¹⁴C测年获得年代框架,采用孢粉和炭屑分析,重建了该地区晚全新世气候变化和人类活动叠加影响下的植被演替及火灾活动历史。结果表明：3500~3100 cal.a B.P. 期间,当地亚热带常绿阔叶林繁盛,火灾活动为气候控制为主的森林火灾,但火灾活动并未改变阔叶林的总体面貌;3100~600 cal.a B.P. 期间,气候呈变干趋势,阔叶类木本植物显著减少,当地植被从亚热带常绿阔叶林转变为疏林草地和针叶类疏林,极可能是趋于冷干的气候环境的结果;大约600 cal.a B.P. 之后,当地植被演变为开阔林,同时,出现大颗粒炭屑(>125 μm)以及伴人花粉的明显增加,表明人类农业活动高强度的刀耕火种已经扩张到较高海拔山区。区域对比显示,西南地区在3500 cal.a B.P. 以来,主要以区域性火灾为主,而3100 cal.a B.P. 以后的火灾活动受到气候变干和人类活动的双重影响,特别是600 cal.a B.P. 以来,人类活动(刀耕火种)成为局地火灾和植被更替的主要因素。

     

Holocene sea‐level reconstruction in the Young Sound region,Northeast Greenland

A relative sea‐level curve over the Holocene is constructed for the Young Sound region in northeastern Greenland. The reconstruction is derived by dating the heights of raised beach ridges in coastal plains using optically stimulated luminiscence (OSL), and by dating palaeoterrestrial surface levels now buried beneath the intertidal frame using the ¹⁴C technique. The relative sea‐level curve reveals a rapid fall of at least 10 mm a^?1 from ca. 9500 to 7500 a ago, which slowed to 2 mm a^?1 until it reached the present sea level ca. 3000 a ago. This part of the curve is based on the raised beach ridge data. Thereafter, relative sea level continued to fall, to reach a minimum level at about 0.5 m below the present sea level ca. 2300 a ago. Since then, relative sea level has experienced a slow rise of about 0.2 mm a^?1. This part of the curve uses the data from the palaeoterrestrial surfaces. The study supplements other estimates of Holocene relative sea‐level changes and supports the observations of a decreasing trend in the timing of the cross point and in minimum relative sea level from South to North Greenland. Copyright © 2011 John Wiley & Sons, Ltd.     

Climate and vegetation history from a 14,000-year peatland record, Kenai Peninsula, Alaska

Analysis of pollen, spores, macrofossils, and lithology of an AMS ¹⁴C-dated core from a subarctic fen on the Kenai Peninsula, Alaska reveals changes in vegetation and climate beginning 14,200 cal yr BP. Betula expansion and contraction of herb tundra vegetation characterize the Younger Dryas on the Kenai, suggesting increased winter snowfall concurrent with cool, sunny summers. Remarkable Polypodiaceae (fern) abundance between 11,500 and 8500 cal yr BP implies a significant change in climate. Enhanced peat preservation and the occurrence of wet meadow species suggest high moisture from 11,500 to 10,700 cal yr BP, in contrast to drier conditions in southeastern Alaska; this pattern may indicate an intensification and repositioning of the Aleutian Low (AL). Drier conditions on the Kenai Peninsula from 10,700 to 8500 cal yr BP may signify a weaker AL, but elevated fern abundance may have been sustained by high seasonality with substantial snowfall and enhanced glacial melt. Decreased insolation-induced seasonality resulted in climatic cooling after 8500 cal yr BP, with increased humidity from 8000 to 5000 cal yr BP. A dry interval punctuated by volcanic activity occurred between 5000 and 3500 cal yr BP, followed by cool, moist climate, coincident with Neoglaciation. Tsuga mertensiana expanded after ~ 1500 cal yr BP in response to the shift to cooler conditions.     

Holocene history of fire,vegetation and land use from the central Pyrenees (France)

Located on a mountain pass in the west-central Pyrenees, the Col d'Ech peat bog provides a Holocene fire and vegetation record based upon nine ¹⁴C (AMS) dates. We aim to compare climate-driven versus human-driven fire regimes in terms of frequency, fire episodes distribution, and impact on vegetation. Our results show the mid-Holocene (8500–5500 cal yr BP) to be characterized by high fire frequency linked with drier and warmer conditions. However, fire occurrences appear to have been rather stochastic as underlined by a scattered chronological distribution. Wetter and colder conditions at the mid-to-late Holocene transition (4000–3000 cal yr BP) led to a decrease in fire frequency, probably driven by both climate and a subsequent reduction in human land use. On the contrary, from 3000 cal yr BP, fire frequency seems to be driven by agro-pastoral activities with a very regular distribution of events. During this period fire was used as a prominent agent of landscape management.     

Late Pleistocene and Holocene glaciation of the Fish Lake valley,northeastern Alaska Range,Alaska

We reconstructed a chronology of glaciation spanning from the Late Pleistocene through the late Holocene for Fish Lake valley in the north‐eastern Alaska Range using ¹⁰Be surface exposure dating and lichenometry. After it attained its maximum late Wisconsin extent, the Fish Lake valley glacier began to retreat ca. 16.5 ka, and then experienced a readvance or standstill at 11.6 ± 0.3 ka. Evidence of the earliest Holocene glacial activity in the valley is a moraine immediately in front of Little Ice Age (LIA) moraines and is dated to 3.3–3.0 ka. A subsequent advance culminated at ca. AD 610–900 and several LIA moraine crests date to AD 1290, 1640, 1860 and 1910. Our results indicate that ¹⁰Be dating from high‐elevation sites can be used to help constrain late Holocene glacial histories in Alaska, even when other dating techniques are unavailable. Close agreement between ¹⁰Be and lichenometric ages reveal that ¹⁰Be ages on late Holocene moraines may be as accurate as other dating methods. Copyright © 2009 John Wiley & Sons, Ltd.     

Late-glacial and Holocene vegetation and climatic history of the Cass Basin, central South Island, New Zealand

Lithology, pollen, macrofossils, and stable carbon isotopes from an intermontane basin bog site in southern New Zealand provide a detailed late-glacial and early Holocene vegetation and climate record. Glacial retreat occurred before 17,000 cal yr B.P., and tundra-like grassland–shrubland occupied the basin shortly after. Between 16,500 and 14,600 cal yr B.P., a minor regional expansion of forest patches occurred in response to warming, but the basin remained in shrubland. Forest retreated between 14,600 and 13,600 cal yr B.P., at about the time of the Antarctic Cold Reversal. At 13,600 cal yr B.P., a steady progression from shrubland to tall podocarp forest began as the climate ameliorated. Tall, temperate podocarp trees replaced stress-tolerant shrubs and trees between 12,800 and 11,300 cal yr B.P., indicating sustained warming during the Younger Dryas Chronozone (YDC). Stable isotopes suggest increasing atmospheric humidity from 11,800 to 9300 cal yr B.P. Mild (annual temperatures at least 1°C higher than present), and moist conditions prevailed from 11,000 to 10,350 cal yr B.P. Cooler, more variable conditions followed, and podocarp forest was completely replaced by montane Nothofagus forest at around 7500 cal yr B.P. with the onset of the modern climate regime. The Cass Basin late-glacial climate record closely matches the Antarctic ice core records and is in approximate antiphase with the North Atlantic.