Cometary water on Venus: Impact modelling and possible evidence

The present small amount of water in the atmosphere of Venus, in connection with the estimated short time scale of water loss from this planet, has lead to the hypothesis that the water concentration in the Venusian atmosphere is in a dynamical equilibrium, where the losses are counter-balanced by a suitable water source. The main candidate water sources are: (a) outgassing from the Venusian surface, due to volcanic activity and (b) cometary impacts. The lack of observational evidence of cometary impacts is usually attributed either to the rarity of such events or to the fact that presently their observational signature is not well understood. In this paper we report on a photographic evidence of a short duration dark feature on Venus, which was observed on 18 May 1988. After eliminating the possibilities of a film defect and an interference from an artificial Earth satellite or an interplanetary object, we conclude that this feature was the signature of an event that took place on the upper haze layer of the Venusian atmosphere. We propose that this event was actually the impact of a small (~10¹⁰ gr) comet-like object, consisting mainly of water, on Venus. This impact caused the temporary evaporation ot the sol H₂SO₄ particles of the upper haze layer and, consequently, a decrease of the albedo of the region around the point of entrance of the comet in the Venusian cloud layers. This region of lower albedo appears as a dark feature in the reported photograph. Our model accounts for the short duration of the feature as well as for its shape.     

A layer of ozone detected in the nightside upper atmosphere of Venus

To date, ozone has only been identified in the atmospheres of Earth and Mars. This study reports the first detection of ozone in the atmosphere of Venus by the SPICAV ultraviolet instrument onboard the Venus Express spacecraft. Venusian ozone is characterized by a vertically confined and horizontally variable layer residing in the thermosphere at a mean altitude of 100 km, with local concentrations of the order of 10⁷–10⁸ molecules cm⁻³. The observed ozone concentrations are consistent with values expected for a chlorine-catalyzed destruction scheme, indicating that the key chemical reactions operating in Earth’s upper stratosphere may also operate on Venus.     

Hydroxyl airglow on Venus in comparison with Earth

Hydroxyl nightglow is intensively studied in the Earth atmosphere, due to its coupling to the ozone cycle. Recently, it was detected for the first time also in the Venus atmosphere, thanks to the VIRTIS-Venus Express observations. The main Δν=1, 2 emissions in the infrared spectral range, centred, respectively, at 2.81 and 1.46 μm (which correspond to the (1-0) and (2-0) transitions, respectively), were observed in limb geometry (Piccioni et al., 2008) with a mean emission rate of 880±90 and 100±40 kR (1R=10⁶ photon cm⁻² s⁻¹ (4πster)⁻¹), respectively, integrated along the line of sight. In this investigation, the Bates-Nicolet chemical reaction is reported to be the most probable mechanism for OH production on Venus, as in the case of Earth, but HO₂ and O may still be not negligible as mechanism of production for OH, differently than Earth. The nightglow emission from OH provides a method to quantify O₃, HO₂, H and O, and to infer the mechanism of transport of the key species involved in the production. Very recently, an ozone layer was detected in the upper atmosphere of Venus by the SPICAV (Spectroscopy for Investigation of Characteristics of the Atmosphere of Venus) instrument onboard Venus Express (Montmessin et al., 2009); this discovery enhances the importance of ozone to the OH production in the upper atmosphere of Venus through the Bates-Nicolet mechanism. On Venus, OH airglow is observed only in the night side and no evidence has been found whether a similar emission exists also in the day side. On Mars it is expected to exist both on the day and night sides of the planet, because of the presence of ozone, though OH airglow has not yet been detected.In this paper, we review and compare the OH nightglow on Venus and Earth. The case of Mars is also briefly discussed for the sake of completeness. Similarities from a chemical and a dynamical point of view are listed, though visible OH emissions on Earth and IR OH emissions on Venus are compared.     

Production of nitrogen and carbon species by thunderstorms on Venus

The effects of the newly discovered thunderstorms on Venus upon the nitrogen and carbon species in its atmosphere were calculated. An Earth-like lightning frequency of 100 sec^?1 was used for Venus, in accord with recent optical measurements by Pioneer-Venus (W. J. Borucki, J. W. Dyer, G. Z. Thomas, J. C. Jordon, and D. A. Comstock, submitted for publication). The rate of NO production by thunder shock waves, 2.5 × 10¹¹ g year^?1, is about an order of magnitude smaller than on the Earth. But on Venus, in the absence of precipitation, which is the major removal mechanism of odd nitrogen from the Earth's atmosphere, the mixing ratios of odd nitrogen species might be considerably higher. The global CO production is governed by CO₂ photolysis rather than by CO₂ pyrolysis by lightning. However, thunderstorms produce about 2.5 × 10¹¹ g year^?1 of CO in the cloud layer, far from the high altitude CO₂ photolysis region.     

Venus’ internal structure,temperature and core composition

The mass and radius of our closest neighbour Venus are only slightly smaller than those of the Earth indicating a similarity in composition. However, the lack of self-sustained internal magnetic field in Venus points to a difference in the core structure. The theory of tricritical phenomena has recently been used to study solidification at the high pressures and temperatures of the Earth, revealing how the Earth’s core works. This theoretical approach is here applied to Venus. While keeping Venus’ mantle density similar to the Earth’s, one obtains the gravitational acceleration g inside Venus, its moment of inertia factor, the size, pressure and density of its core, together with the planet’s temperature profile. Mainly due to the temperature difference between the core–mantle boundary and surface being 21% smaller than on the Earth, and the 11.5% smaller gravitational acceleration, Venus’ Rayleigh number Ra parameterizing mantle convection is only 54% of the Earth’s, offering a possible explanation for the present lack of plate tectonics on Venus. The theory as discussed predicts that Venus is molten at the centre, with temperature about 5200 K, and has 8 mol.% impurities there, slightly more impurities than in the Earth’s inner core boundary fluid. These impurities are likely to be a combination of MgO and MgSiO₃.     

Implications of36A excess on Venus

The finding of³⁶A excess on Venus by the mass-spectroscopic measurement of the Venus Pioneer appears to endorse the more rapid accretion theory of Venus than the Earth and the secondary origin of the terrestrial atmosphere.     

On the possibility of plate tectonics on Venus

Several arguments have been put forward suggesting that Venus has no place tectonics. We examine some of these arguments and suggest that because conditions on the surface of Venus are very different from those on Earth, the arguments should be reconsidered. We show that in the absence of an ocean, the differential hypsographic curve of Earth would probably have only one mode, like that for Venus. We show that the atmosphere of Venus is quite capable of erosion, provided that near-surface velocities are about 1 m · sec^?1 or more, and that therefore the “oceanic” areas on Venus, should they exist, are probably covered with some thickness of sediment. If sedimentation on Venus is at all rapid, it is likely that subduction zones could be filled up and made unrecognizable topographically. Because Venus does not have an ocean, and because its surface temperature is much greater than that on Earth, ridge crests on Venus have a much smaller topographic expression than those on Earth. If significant sedimentation occurs they would be completely unrecognizable topographically.     

Ion flow and momentum transfer in the Venus plasma environment

An analysis of ion data from 390 Venus Express, VEX, orbits demonstrates that the flow of solar wind- and ionospheric ions near Venus is characterized by a marked asymmetry. The flow asymmetry of solar wind H⁺ and ionospheric O⁺ points steadily in the opposite direction to the planet’s orbital motion, and is most pronounced near the Pole and in the tail/nightside region. The flow asymmetry is consistent with aberration forcing, here defined as lateral forcing induced by the planet’s orbital motion. In addition to solar wind forcing by the radial solar wind expansion, Venus is also subject a lateral/aberration forcing induced by the planet’s orbital motion transverse to the solar wind flow.The ionospheric response to lateral solar wind forcing is analyzed from altitude profiles of the ion density, ion velocity and ion mass-flux. The close connection between decreasing solar wind H⁺ mass-flux and increasing ionospheric O⁺ mass-flux, is suggestive of a direct/local solar wind energy and momentum transfer to ionospheric plasma. The bulk O⁺ ion flow is accelerated to velocities less than 10 km/s inside the dayside/flank Ionopause, and up to 6000 km in the tail. Consequently, the bulk O⁺ outflow does not escape, but remains near Venus as a fast (km/s) O⁺ zonal wind in the Venus polar and nightside upper ionosphere. Furthermore, the total O⁺ mass-flux in the Venus induced magnetosphere, increases steadily downward to a maximum of 2 × 10⁻¹⁴ kg/(m² s) at ≈400 km altitude, suggesting a downward transport of energy and momentum. The O⁺, and total mass-flux, decay rapidly below 400 km. With no other plasma mass-flux as replacement, we argue that the reduction of ion mass-flux is caused by ion-neutral drag, a transfer of ion energy and momentum to neutrals, implying that the O⁺ plasma wind is converted to a neutral (thermosphere) wind at Venus. Incidentally, such a neutral wind would go in the same direction as the Venus atmosphere superrotation.     

Aerial bursts in the terrestrial atmosphere

Impacts of cosmic bodies (stony and comet-like) are considered that “burn out” (or, more strictly, totally evaporate) in the atmosphere, which do not form craters but cause fires and destruction on the Earth’s surface. The heights of fragmentation, total evaporation, and deceleration of stony and comet-like meteoroids of different sizes, initial velocities, and impact angles are found from numerical simulations. The possible consequences of such falls are considered. The possible parameters of the Tunguska cosmic body are estimated.     

Noble gases in planetary atmospheres: Implications for the origin and evolution of atmospheres

The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of ⁴⁰Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of ⁴⁰Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H₂ resulting from efficient H₂O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in ²⁰Ne and ³⁶Ar from Venus to Earth to Mars; (2) a nearly constant ²⁰Ne/³⁶Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for ³⁶Ar/¹³²Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO₂ and N₂.     

Large-scale quasi-two-dimensional turbulence and a inverse spectral flux of energy in the atmosphere of Venus

The comparison of the theoretical inferences and the experimental data on large-scale turbulence in the atmospheres of the Earth and Venus, including those acquired with the Venus Express spacecraft, allows us to conclude that there is a inverse spectral flux of energy in the atmosphere of Venus, as in the terrestrial atmosphere, which participates in generating the superrotation of the atmosphere.     

Transient mantle layering and the episodic behaviour of Venus due to the ‘basalt barrier’ mechanism

Numerical models of mantle convection that include the ‘basalt barrier’ mechanism are explored for Venus. The ‘basalt barrier’ mechanism is due to the positive buoyancy of subducted basaltic crust between the mantle depths of 660 and 750 km. The inclusion of this mechanism in models of Earth’s evolution has been shown to cause episodic mantle layering early in Earth history and we explore whether it can also operate on Venus. The models presented here include a moderately mobile lithosphere, which is not representative of the current state of Venus, but this allows us to exclude the effects of episodic lithosphere mobility and thus to isolate the effect of the basalt barrier. This is a step in a systematic approach to models with a mostly-static lithosphere. We find the basalt barrier does yield episodically layered mantle convection in some Venus models. The likelihood of episodic layering is increased by Venus high surface temperature and by its less mobile or immobile lithosphere. Surprisingly, secondary differences from Earth, including the lower gravity, density and mantle depth also promote episodic layering. The models suggest that mantle layering and overturns may still be likely to occur in Venus. The breakdown of mantle layering and consequent mantle overturns would lead to dramatic episodes of volcanism, formation of large amounts of crust, and tectonic activity on the planet’s surface, as has been inferred to have happened on Venus around 500 Ma ago from surface morphology and cratering. These results thus suggest that a transient layering of the mantle by the ‘basalt barrier’ mechanism and mantle overturns may be part of the explanation for Venus’s recent resurfacing.     

Solar wind origin of 36Ar on Venus

A hypothesis is considered in which the ³⁶Ar found on Venus is of solar origin. This possibility is quantitatively discussed within the framework of present theories of planetary accumulation by sweep up of planetesimals under gas-free conditions. Solar wind implantation of ³⁶Ar would take place by irradiation of accumulating material during the first ≈10⁵ years of planetary growth, provided that the flux of solar wind was enhanced by a factor of ≈100 at that time. Enrichment of Venus in implanted gas would be a consequence of the irradiated material being initially confined to the innermost edge of the radially opaque circusolar planetesimal disk predicted by these theories. The observed atmospheric data require a Ne/Ar fractionation by a factor of ≈100 during the planetesimal stage. It is also necessary that there be very little mixing of irradiated planetesimals from the inner edge of disk to the distance (≈1 AU) at which the Earth formed. The hypothesis can be tested by measurement of the abundance of Kr and Xe in the Venus atmosphere. Venera data indicate a terrestrial ³⁶Ar/Kr ratio, in disagreement with the solar wind hypothesis. In contrast, the Pioneer experiments find a lower limit to this ratio, well above the terrestrial value, that is compatible with the hypothesis. These experiments also show that Venus' ³⁶Ar/Xe ratio does not correspond to the so-called “planetary” trapped inert gas composition. The inert of Venus could be related to result of admixture of gas with solar composition. The inert gas on Venus could be related to that found in enstatite chondrites.     

Deducing the age of the dense Venus atmosphere

We show how crater size-density counts may be used to help constrain the history of the Venus atmosphere, based on the predictions of simple but reasonable models for crater production, surface erosion, and the effects of atmospheric drag and breakup on incident meteors in the Venus atmosphere. If the atmosphere is old, we may also be able to determine the importance of breakup as a mechanism for destroying incident meteors in a dense fluid. In particular, if the atmosphere is young, the old (uneroded) surfaces will have crater densities upward of 10^?4 km^?2 and a ratio of small (4 km) craters to large (128 km) craters near 10³. If the atmosphere is old and the breakup mechanism is dominant, absolute crater densities on Venus surfaces will be diminished by several orders of magnitude relative to the young atmosphere case. If atmospheric drag is dominant and the atmosphere is old, the absolute crater density will be lowered by perhaps an order of magnitude relative to the young atmosphere case, and the ratio of small to large craters will be reduced to a value near 10^1.5 according to the models. The comparison of crater populations on young, as well as old, surfaces on Venus can help in distinguishing the young and old atmosphere scenarios, especially since the situation may be complicated by currently undetermined erosional and tectonic processes. Once a large fraction of Venus surface has been imaged at kilometer resolution, as the VOIR project promises to do, it could be possible to make an early determination of the age of the Venus atmosphere.     

On the problem of the Tunguska meteorite material

The approximate composition of the Tunguska meteorite remnants obtained by averaging the results of several measurements is presented. It is pointed out that the matter of the cosmic-body remnants was enriched with alkaline and alkaline-earth elements. The composition of the meteorite matter was extremely heterogeneous. The upper limit of the density of the Tunguska cosmic body has been estimated at 2.8 g/cm³. It is suggested that, due to interaction with the Earth’s atmosphere, the cosmic body disintegrated into fragments from 10^?7 to 10^?3 m in size, with the majority of the matter being ejected to the upper atmospheric layers. Calculations of the rate and the time of the sedimentation of particles in the atmosphere have shown that the change in atmosphere transparency is controlled by particles larger than 10^?5 m in radius.     

A comparison between Venus and the Earth

By means of the comparison between dynamical figures of Venus and the Earth, we confirmed that the nonhydrostatic moment difference ratios of the two celestial bodies are approximately equal. The hydrostatic flattening of the external equipotential surface of Venus according to the theory of internal field is equal to about 6 × 10^–8, but the observed value of Venusian equatorial flattening is equal to 6.8 × 10^–6. The latter is two orders of magnitude more than the former. These facts indicate that Venus itself is far from hydrostatic equilibrium.     

Venus Express—The first European mission to Venus

Venus Express is the first European mission to planet Venus. The mission aims at a comprehensive investigation of Venus atmosphere and plasma environment and will address some important aspects of the surface physics from orbit. In particular, Venus Express will focus on the structure, composition, and dynamics of the Venus atmosphere, escape processes and interaction of the atmosphere with the solar wind and so to provide answers to the many questions that still remain unanswered in these fields. Venus Express will enable a breakthrough in Venus science after a long period of silence since the period of intense exploration in the 1970s and the 1980s.The payload consists of seven instruments. Five of them were inherited from the Mars Express and Rosetta projects while two instruments were designed and built specifically for Venus Express. The suite of spectrometers and imaging instruments, together with the radio-science experiment, and the plasma package make up an optimised payload well capable of addressing the mission goals to sufficient depth. Several of the instruments will make specific use of the spectral windows at infrared wavelengths in order to study the atmosphere in three dimensions. The spacecraft is based on the Mars Express design with minor modifications mainly needed to cope with the thermal environment around Venus, and so a very cost-effective mission has been realised in an exceptionally short time.The spacecraft was launched on 9 November 2005 from Baikonur, Kazakhstan, by a Russian Soyuz-Fregat launcher and arrived at Venus on 11 April 2006. Venus Express will carry out observations of the planet from a highly elliptic polar orbit with a 24-h period. In 3 Earth years (4 Venus sidereal days) of operations, it will return about 2 Tbit of scientific data.Telecommunications with the Earth is performed by the new ESA ground station in Cebreros, Spain, while a nearly identical ground station in New Norcia, Australia, supports the radio-science investigations.     

Climatic change on the terrestrial planets

In this paper, we review the observational data on climatic change for the terrestrial planets, discuss the basic factors that influence climate, and examine the manner in which these factors may have been responsible for some of the known changes. Emphasis is placed on trying to understand the similarities and differences in both the basic factors and their climatic impacts on Venus, the Earth, and Mars. Climatic changes have occurred on the Earth over a broad spectrum of time scales that range from the elevated temperatures of Pre-Cambrian times (～10⁹ years ago), through the alternating glacial and interglacial epochs of the last few million years, to the small but significant decadal and centurial variations of the recent past. Evidence for climatic change on Mars is given by certain channel features, which suggest an early to intermediate aged epoch of warmer and wetter climate, and by layered polar deposits, which imply more recent periodic climate variations. No evidence for climatic change on Venus exists as yet, but comparison of its present climate state with that of outer terrestrial planets offers important clues on some of the mechanisms affecting climate. The important determinants of climate for a terrestrial planet include the Sun's output, astronomical perturbations of its orbital and axial characteristics, the gaseous and particulate content of its atmosphere, its land surface, volatile reservoirs, and its interior. All these factors appear to have played major roles in causing climatic changes on the terrestrial planets. Despite a lower solar luminosity in the past, the Earth and Mars have had warmer periods in their early history. In both cases, a more reducing atmosphere may have been the responsible agent through an enhanced greenhouse effect. In this paper, we present detailed calculations of the effect of atmospheric pressure and composition on the temperature state of Mars. We find that the higher temperature period is easier to explain with a reducing atmosphere than with the current fully oxidizing one. Both the very high surface temperature and massive atmosphere of Venus may be the result of the solar flux being a factor of two higher at its orbit than at the Earth's orbit. This difference may have led to a runaway greenhouse effect on Venus, i.e., the emplacement of volatiles entirely in the atmosphere rather than mostly in surface reservoirs. But if Venus formed with relatively little or no water, it may have always had an oxidizing atmosphere. In this case, a lower solar luminosity would have led to a moderate surface temperature in Venus' early history. Quasi-periodic variations in orbital eccentricity and axial obliquity may have contributed to the alternation between Pleistocene glacial and interglacial periods in the case of the Earth and to the formation of the layered polar deposits in the case of Mars. In this paper, we postulate that two mechanisms, acting jointly, account for the creation of the laminated terrain of Mars: dust particles serve as nucleation centers for the condensation of water vapor and carbon dioxide. The combined dust-H₂O-CO₂ particle is much larger and so has a much higher terminal velocity than either a dust-H₂O or a plain dust particle. As a result, dust and water ice are preferentially deposited in the polar regions. In addition, we postulate that the obliquity variations are key drivers of the periodic layering because of their impact on both atmospheric pressure and polar surface temperature, which, in turn, influence the amounts of dust and water ice in the atmosphere. But eccentricity and precessional changes probably also play important roles in creating the polar layers. The drifting of continents on the Earth has caused substantial climatic changes on individual continents and may have helped to set the stage for the Pleistocene ice ages through a positioning of the continents near the poles. While continental drift apparently has not occurred on Mars, tectonic distortions of its lithosphere may, in some circumstances, cause an alteration in the mean value of that planet's obliquity, which would significantly impact its climate. Atmospheric aerosols can influemce climate through their radiative effects. In the case of the Earth, volcanic aerosols appear to have contributed to past climatic changes, while consideration needs to be given to the future impact of man-generated aerosols. In the case of Mars, the atmospheric temperature structure and thereby atmospheric dynamics are greatly altered by suspended dust particles. The sulfuric acid clouds of Venus play a major role in its heat balance. Cometary impacts may have added substantial quantities of water vapor and sulfur gases to Venus' atmosphere and thus have indirectly affected its cloud properties. Calculations presented in this paper indicate substantial changes in surface temperature accompany these compositional changes.     

Effects of impacts on the atmospheric evolution: Comparison between Mars, Earth, and Venus

Classified as a terrestrial planet, Venus, Mars, and Earth are similar in several aspects such as bulk composition and density. Their atmospheres on the other hand have significant differences. Venus has the densest atmosphere, composed of CO₂ mainly, with atmospheric pressure at the planet's surface 92 times that of the Earth, while Mars has the thinnest atmosphere, composed also essentially of CO₂, with only several millibars of atmospheric surface pressure. In the past, both Mars and Venus could have possessed Earth-like climate permitting the presence of surface liquid water reservoirs. Impacts by asteroids and comets could have played a significant role in the evolution of the early atmospheres of the Earth, Mars, and Venus, not only by causing atmospheric erosion but also by delivering material and volatiles to the planets. Here we investigate the atmospheric loss and the delivery of volatiles for the three terrestrial planets using a parameterized model that takes into account the impact simulation results and the flux of impactors given in the literature. We show that the dimensions of the planets, the initial atmospheric surface pressures and the volatiles contents of the impactors are of high importance for the impact delivery and erosion, and that they might be responsible for the differences in the atmospheric evolution of Mars, Earth and Venus.     

Cosmic dust in modern ferromanganese nodules

This work is about the identification of modern cosmic dust that had survived heating during its high-velocity passage through the Earth’s atmosphere from ³He isotope concentrations in marine (Gulf of Finland) ferromanganese nodules (FMNs). The measured bulk composition of helium includes components of various origins, enabling the determination of the age (1800 years) of the shallow-water Baltic FMNs and the average time of exposure (8 × 10⁷ years) of cosmic dust particles during their existence in space. The concentration of cosmic dust per gram of FMN material is found to be 0.036 μg. The contribution of solar-wind helium to the Earth’s atmospheric helium is found to be small. The experiments are conducted by the stepheating method in vacuo with the subsequent mass-spectrometric analysis of the helium released from the samples.