Origins of Birimian (ca 2.2 Ga) mafic magmatism and the Paleoproterozoic ‘greenstone belt’ metallogeny: a review

The Birimian of the West African Craton is an important repository of Paleoproterozoic mafic magmatism, described by many workers as petrologically dominated by basaltic to andesitic rocks. In spite of extensive work done, opinions still differ on the origin and other salient features in these globally significant igneous rocks. Even less well understood is the relationship that may exist between the mafic rocks and prolific metalliferous deposits such as manganese and gold that are hosted in these rocks. This review suggests that the frequently observed association between mafic rocks and important mineral deposits may have far more genetic implications than previously envisaged.     

Subduction-related episodes of K-alkaline magmatism (15–0.1 Ma) and geodynamic implications in the north Tyrrhenian — central Italy region: a review

In the north Tyrrhenian region and adjoining shores of Alpine Corsica and central Italy, four magmatic phases (15–14; 8–6; 5–2; and 1.3–0.1 Ma) are present which consist prevailingly of either old acidic and lamproitic rocks or young (1.3–0.1 Ma) basic volcanics with potassic–ultrapotassic affinity (the rocks of the K and HK series of the Roman province, and the kamafugitic rocks). Composition, age and location of the igneous phases reveal a geochemical polarity oriented from west to east. The episodes of magmatic activity reflect the evolution of the geodynamic environment (ensialic plate convergence): backarc stretching and attenuation of an Alpine orogenic wedge were accompanied by the eastward roll-back and progressive steepening of the descending Adria plate. The latter process led to enhanced metasomatic modifications of the mantle wedge composition and to eruption of the large volumes of KS and HKS volcanic rocks in central Italy (0.6–0.1 Ma).     

Riparian alder fens — source or sink for nutrients and dissolved organic carbon? — 2. Major sources and sinks

Natural riparian forest wetlands are known to be effective in their ability to remove nitrate by denitrification and sediments with attached phosphorus via sedimentation. On the other hand, litter input and decomposition is a process of crucial importance in cycling of nitrogen and phosphorus in a forest ecosystem.In this study we investigated the amount of nitrogen and phosphorus entering the alder fen ecosystem through leaf litter and its decomposition and the removal capacity of nitrogen and phosphorus by measuring denitrification and sedimentation in the alder fen.We found an average input of leaf litter during fall 1998 of 226 g m⁻² yr⁻¹ DW with nutrient concentration of 0.17% P and 1.6% N. This means a yearly input of 0.4 g m⁻² yr⁻¹ P and 3.6 g m⁻² yr⁻¹ N. The decomposition of leaf litter using litter bags with small and large mesh size resulted in bags with macroinvertebrates (large mesh size) and without macroinvertebrates (small mesh size). After 57 days the litter bags with macroinvertebrates had a decomposition rate of 79%.Denitrification was measured in May and June of 1997 using the acetylene inhibition technique on intact soil cores and slurry-experiments. The average annual denitrification rate was 0.2 g m⁻² yr⁻¹ N using data from the core experiments. The denitrification rate was higher after addition of nitrate, indicating that denitrification in the riparian alder fen is mainly controlled by nitrate supply.The sedimentation rate in the investigated alder fen ranged from 0.47 kg m⁻² yr⁻¹ DW to 4.46 kg m⁻² yr⁻¹ DW in 1998 depending on the study site and method we used. Sedimentation rates were lower in newly designed plate traps than in cylinder traps. The alder fen also showed lower rates than the adjacent creek Briese. Average phosphorus removal rate was 0.33 g m⁻² yr⁻¹ P.Input sources for the surface water of the alder fen are sediment mineralization and decomposition of leaf litter; output sources are sedimentation and denitrification. This study showed that a nutrient input of 24.58 kg ha⁻¹ yr⁻¹ N, 8.8 kg ha⁻¹ yr⁻¹ P and 419 kg ha⁻¹ yr⁻¹ DOC into the surface water of the alder fen is possible. Alder fens cannot improve water quality of an adjacent river system. This is only true for a nearly pristine alder fen with the hydrology of 10 months flooded conditions and 2 months non-flooding conditions a year.     

Toxicity of Interactions of Zinc —Nickel,Copper —Nickel and Zinc —Nickel —Copper to a Freshwater Teleost,Lebistes reticulatus (PETERS)1

The lethal toxicity of mixtures of Zn²⁺ —Ni²⁺, Cu²⁺ —Ni²⁺ and Zn²⁺ —Cu²⁺ —Ni²⁺ to common guppy at 21£C in hard water (total hardness = 260 mg/l as CaCO₃) was studied under static bioassays test conditions with renewal of the test solutions every 24 h. The heavy metals were tested separately and in mixtures. The 48 h median lethal concentrations (LC₅₀) for individual salts were 75 mg/l Zn²⁺, 37 mg/l for Ni²⁺ and 2.5 mg/l for Cu²⁺. Concentrations were expressed in “toxic units” by taking them as proportions of LC₅₀ values. Experiments showed that in the Zn²⁺-Ni²⁺ mixture, when Ni²⁺ was more in proportion, the toxicity was more than additive. The 48 h LC₅₀ value and 95% confidence limits in the Ni²⁺-Cu²⁺ mixture were 0.684 (0.484 … 0.807) toxic units and the mixture produced more than the additive toxicity (synergism.). The LC₅₀ value and its 95% confidence limits in a Zn²⁺?Cu²⁺?Ni²⁺ mixture also suggested that the mixture was again strictly additive. The results indicate that heavy metallic mixtures would pose a greater toxicological danger to fish than the respective individual metals.     

The shoreface-connected ridges along the central Dutch coast — part 2: morphological modelling

The hydrodynamic and sediment transport processes on the Dutch inner-shelf were studied on the basis of short- and medium-term (days, month) field experiments during fair-weather and storm conditions. The primary goal of this study was to identify the mechanisms that may be responsible for the formation and maintenance of the shoreface-connected ridges in the study area. The hydrodynamic field observations do not consistently support existing theoretical models explaining the formation of such ridges. Instead, the water motion appears to be dominated by wind- and density-driven effects. A review of literature indicates that other field studies also fail to observe the flow response expected from theory. Sediment transport during fair-weather is very episodic, with bed load transport slightly dominant over suspended load transport. The sediment transport processes during storms are dominated by the mean fluxes, with waves acting as a stirring mechanism. The contribution of wave-oscillatory fluxes cannot be neglected and may be directed with and against the waves. Long-wave fluxes are present, but very small.     

Mantle source compositions of the Paraná Magmatic Province (southern Brazil): evidence from trace element and Sr–Nd–Pb isotope geochemistry

An integrated study based on incompatible trace elements and Sr–Nd–Pb isotopes is presented in order to assess the mantle sources involved in the genesis of the Paraná Magmatic Province (PMP) tholeiites. Particular emphasis is given to 33 new Pb isotope and concentration data obtained in representative samples of low-TiO₂ (LTiB) and high-TiO₂ (HTiB) flood basalts that occur in the province. Results show important differences with respect to type and location of these rocks. The LTiB and HTiB from northern PMP exhibit very similar initial Pb isotope ratios (average LTiB vs HTiB: ²⁰⁶Pb/²⁰⁴Pb_i=17.78±0.03 vs 17.65±0.02; ²⁰⁷Pb/²⁰⁴Pb_i=15.53±0.01 vs 15.52±0.01; ²⁰⁸Pb/²⁰⁴Pb_i=38.12±0.03 vs 38.05±0.04). The LTiB from southern PMP, with initial ⁸⁷Sr/⁸⁶Sr_i≤0.7060, show small variation in initial Pb isotope compositions (average ²⁰⁶Pb/²⁰⁴Pb_i=18.20±0.07; ²⁰⁷Pb/²⁰⁴Pb_i=15.61±0.01; ²⁰⁸Pb/²⁰⁴Pb_i=38.32±0.10), which are highly enriched in radiogenic Pb in comparison to the northern PMP analogues. The HTiB from southern PMP have initial Pb isotope ratios (average ²⁰⁶Pb/²⁰⁴Pb_i=17.45±0.09; ²⁰⁷Pb/²⁰⁴Pb_i=15.50±0.01; ²⁰⁸Pb/²⁰⁴Pb_i=37.89±0.03) slightly less radiogenic compared with the HTiB from northern PMP. The data cover a large range of isotope compositions, which are accompanied by systematic changes in incompatible trace element ratios and Sr–Nd isotopes, indicating contributions from different mantle sources. The remarkable chemical and isotope differences between PMP basalts, N-MORB and Tristan da Cunha least evolved volcanics indicate that these asthenospheric sources did not play a significant role in the basalt genesis, suggesting generation from the melting of heterogeneous lithospheric mantle sources. The close similarity between the radiogenic isotopes of the Cretaceous carbonatites that surround the PMP and those of the HTiB rock-types and the LTiB from the northern Paraná suggests the involvement of the same mantle components in their genesis: a dominant EMI end member and a radiogenic isotope enriched component of EMII-type, as some phlogopite-peridotite mantle xenoliths (Japecanga) from the Alto Paranaíba Igneous Province. The latter component seems also to have an important role in the origin of the LTiB from the southern Paraná, where the other end member is highly depleted in radiogenic lead similar to DMM.     

Streams in the Harz National Parks (Germany) — a hydrochemical and hydrobiological evaluation

Between 1995 and 2001, 16 measuring points at small and medium sized brooks in the Harz National Parks were sampled. The samples have been evaluated by means of hydrochemistry and macroinvertebrate biology. Although nearly all streams are largely uncontaminated by oxygen-consuming substances, they are settled only by a small number of macroinvertebrate species. There is a clear correlation between this number and pH. The reduction in species number with decrease of pH is mainly caused by the absence of most Ephemeroptera, some Coleoptera and Trichoptera. Comparing biological evaluation of acidity with physico-chemical measurements, a unacceptable underestimation was found. The reason could be that different sensitivities to acidification between regional populations seem to exist.

Despite of the low species number, there is a very specific macroinvertebrate fauna that emphasizes the conservation value of the Harz National Parks.     

Major- and trace-element systematics and isotope geochemistry of Cenozoic mafic volcanic rocks from the Vogelsberg (central Germany): Constraints on the origin of continental alkaline and tholeiitic basalts and their mantle sources

The Cenozoic basaltic province of the Vogelsberg area (central Germany) is mainly composed of intercalated olivine to quartz tholeiites and near-primary nephelinites to basanites. The inferred mantle source for the alkaline and tholeiitic rocks is asthenospheric metasomatized garnet peridotite containing some amphibole as the main hydrous phase. Trace element modelling indicates 2 to 3% partial melting for the alkaline rocks and 5 to 7% partial melting for the olivine tholeiites. Incompatible trace element abundances and ratios as well as Nd and Sr radiogenic isotope compositions lie between plume compositions and enriched mantle compositions and are similar to those measured in Ocean Island Basalts (OIB) and the Central European Volcanic Province elsewhere. The mafic olivine tholeiites have similar Ba/Nb, Ba/La and Nd–Sr isotope ratios to the alkaline rocks indicating derivation of both magma types from chemically comparable mantle sources. However, Zr/Nb ratios are slightly higher in olivine tholeiites than in basanites reflecting some fractionation of Zr relative to Nb during partial melting. Quartz tholeiites have higher Ba/Nb, Zr/Nb, La/Nb, but lower Ce/Pb ratios and lower Nd isotope compositions than the alkaline rocks which can be explained by interaction of the basaltic melt with lower (granulite facies) crustal material or partial melts thereof during stagnation within the lower crust. It appears most likely that upwelling of hot, asthenospheric material results in the generation of primitive alkaline rocks at the base of the lithosphere at depths of 75–90 km. Lithospheric extension together with minor plume activity and probably lower lithosphere erosion induced melting of shallower heterogenous upper mantle generating a spectrum of olivine tholeiitic melts. These olivine tholeiitic rocks evolved via crystal fractionation and probably limited contamination to quartz tholeiites.     

Deconstructing geomorphology: an appreciation of the contributions of Barbara A. Kennedy (1943–2014)

Barbara Kennedy has left only a small body of work, consisting principally of eight research papers, nine commentaries and two books. Its extent belies its importance. Read systematically, the work represents a sustained and important critique of the direction taken by mainstream geomorphology since the process‐focused reorientation of the mid‐twentieth century. Copyright © 2014 John Wiley & Sons, Ltd.     

History of faulting and magmatism in the Galilee (Israel) and across the Levant continental margin inferred from potential field data

The Galilee study area, northern Israel, is at present an uplifted, steep continental margin that formed mainly during the Jurassic and has a large positive isostatic anomaly. Since the Jurassic, it was modified by several tectonomagmatic events, which this study attempts to define and classify by updating, reprocessing and reinterpreting gravity, aeromagnetic and geological data. The prominent Rehovot-Carmel N–S positive reduced-to-pole (RTP) magnetic anomaly caused by the Gevim Volcanics, as well as the coexisting Helez-Gaash high Bouguer gravity and the Pleshet low Bouguer gravity, represent the deep (>5 km) Permo-Triassic dominant horst and graben structure of Israel. The Jonah Ridge and Beirut high SW–NE RTP magnetic anomalies in the Levant basin delineate the Levant continental edge that is marked by a deeply buried horst covered by a Late Cretaceous volcanic complex. The Asher and Devora Jurassic volcanics appear to be responcible for the Atlit and Galilee negative magnetic anomalies and for significant negative gravity anomalies which became clear after removing gravity effect of the upper (post-Turonian) light density sediments from the observed gravity. The volcanics extend along a SW–NE belt parallel to the strike of the Moho. It is suggested here that the Carmel-Gilboa fault propagated during the Late Cretaceous from the Levant basin across the Galilee area southeastward to form the Azraq-Sirhan graben in Jordan. As such, it forms a right-step, en echelon, dextral strike-slip fault with associated tectonic basins of various shapes. During the Oligocene and before formation of the Dead Sea transform (DST), the reactivation of the Azraq-Sirhan graben was accompanied by tectonic driven rift propagation in the opposite direction, from Azraq-Sirhan to northwest. It dispersed into many faults and terminated ∼10 km west of the present DST. During the Miocene it propagated in the same direction and includes internal volcanic activity. The numerous Miocene-Pliocene volcanic centers on the margins of the DST indicate that the preferred pathway for magmas at that time was not within the deep basins of the DST.     

The Oka Belt (Southern Siberia and Northern Mongolia): A Neoproterozoic analog of the Japanese Shimanto Belt?

Abstract   The Oka Belt, composed of clastic rocks and greenschists, extends for approximately 600 km in the South-Siberian Sayan region and adjacent northern Mongolia. For a long time the Oka Belt's age and tectonic setting were the most controversial problem in the region. We argue that the belt was formed in Late Neoproterozoic as an accretionary prism. The Oka Belt shows imbricated thrust structure, which had originally seaward vergence and reflected the Neoproterozoic accretion process. The Early Paleozoic orogeny had minor effect on its structural style. The belt contains tectonic slivers of mid-ocean ridge basalts, some oceanic-island basalts and possible pelagic sediments. In several localities they are associated with gabbro and serpentinite. All these rocks represent the oceanic lithosphere subducting beneath the Oka prism and trapped within it. In the inner zone of the Oka Belt are the blueschists exhumed from the deeper prism level. The northern Oka Belt includes mafic intrusions geochemically similar to normal mid-oceanic ridge basalt and felsic volcaniclastic rocks. This segment of the belt is very similar to the Tertiary portion of northern Shimanto Belt, in Japan, and has also experienced the subduction of orthogonal oceanic ridge beneath the prism. This event dates back to 753 ± 16 Ma (the U-Pb zircon discordia). The Oka prism started accreting in Mid-Neoproterozoic after the subduction had initiated under the Japan-like South-Siberian continental terrain. The prism existed through the second half of Neoproterozoic and accumulated a huge volume of sialic material to enlarge the nearby continent. Currently, the Oka Belt remains poorly studied and is very promising for further investigation and discoveries.     

Thermal history of the Rio Muni (West Africa)–NE Brazil margins during continental breakup

We document the thermal record of breakup of the conjugate Rio Muni (West Africa) and NE Brazil margins using apatite fission track analysis, vitrinite reflectance data and stratigraphic observations from both margins. These results permit determination of the timing of four cooling episodes, and the temperature of samples at the onset of each episode. All samples are interpreted to have experienced higher temperatures in the geological past due to i) elevated basal heatflow (palaeogeothermal gradient in Rio Muni-1 well decaying from 58 °C/km during the Mid Cretaceous to 21.5 °C/km in the Late Cenozoic) and ii) progressive exhumation from formerly greater burial depth. A well constrained history of changing palaeogeothermal gradient allows for much more precise quantification of the thickness of eroded section (exhumation) than if a constant heatflow is assumed. Cooling episodes identified from the palaeotemperature data at 110–95 Ma (both margins) and 85–70 Ma (Rio Muni only) coincide with major unconformities signifying, respectively, the cessation of rifting (breakup) and compressional shortening that affected the African continent following the establishment of post-rift sedimentation (drift). The interval between these separate unconformities is occupied by allochthonous rafts of shallow-water carbonates recording gravitational collapse of a marginal platform. The rift shoulder uplift that triggered this collapse was enhanced by local transpression associated with the obliquely divergent Ascension Fracture Zone, and thermal doming due to the coeval St Helena and Ascension Plumes. The data also reveal a c.45–35 Ma cooling episode, attributed to deep sea erosion at the onset of Eo-Oligocene ice growth, and a c.15–10 Ma episode interpreted as the record of Miocene exhumation of the West African continental margin related to continent-wide plume development. Integration of thermal history methods with traditional seismic- and stratigraphy-based observations yields a dynamic picture of kilometre-scale fluctuations in base level through the breakup and early drift phases of development of these margins. Major unconformities at ocean margins are likely to represent composite surfaces recording not only eustasy, but also regional plate margin-generated deformation, local ‘intra-basinal’ reorganization, and the amplifying effect of negative feedbacks between these processes.     

Coprecipitation with Cu(II)‐4‐(2‐Pyridylazo)‐resorcinol for Separation and Preconcentration of Fe(III) and Ni(II) in Water and Food Samples

The coprecipitation method is widely used for the preconcentration of trace metal ions prior to their determination by flame atomic absorption spectrometry (FAAS). A simple and sensitive method based on coprecipitation of Fe(III) and Ni(II) ions with Cu(II)‐4‐(2‐pyridylazo)‐resorcinol was developed. The analytical parameters including pH, amount of copper (II), amount of reagent, sample volume, etc., were examined. It was found that the metal ions studied were quantitatively coprecipitated in the pH range of 5.0–6.5. The detection limits (DL) (n = 10, 3s/b) were found to be 0.68 µg L^?1 for Fe(III) and 0.43 µg L^?1 for Ni(II) and the relative standard deviations (RSD) were ≤4.0%. The proposed method was validated by the analysis of three certified reference materials (TMDA 54.4 fortified lake water, SRM 1568a rice flour, and GBW07605 tea) and recovery tests. The method was successfully applied to sea water, lake water, and various food samples.     

The stratigraphy of the 3.5-3.2 Ga Barberton Greenstone Belt revisited: A single zircon ion microprobe study

Recent field and geochemical studies indicate a need to test the stratigraphy of the ca. 3.5 Ga Barberton Greenstone Belt as it is presently adopted [1,2]. This work uses the ion microprobe SHRIMP, to attempt such a test. Results show that: (1) Volcaniclastic sediments of the Theespruit Formation (< 3453 ± 6Ma) could be younger than the (structurally) overlying mafic and ultramafic volcanics of the Komati Formation (3482 ± 5Ma). A major structural discontinuity may therefore exist between the two formations. (2) An age of 3538 ± 6Ma established for a tectonic wedge of tonalitic gneiss within the Theespruit Formation confirms the presence of a sialic basement and deformed unconformity below that unit. The tonalitic gneiss is the oldest unit yet recorded within the greenstone belt, equal in age to the older components of the adjacent Ancient Gneiss Complex. (3) The interpreted ages of felsic volcanic rocks from both the Hooggenoeg (3445 ± 8Ma) and Theespruit Formations and the nearby Theespruit Pluton (3437 ± 6Ma) are essentially the same, and corroborate field and geochemical evidence that the felsic units were probably cogenetic and emplaced simultaneously as high-level equivalents of trondjhemite-tonalite plutons that intrude the greenstone belt at its southwestern extremity. (4) Felsic-intermediate volcanic-volcaniclastic rocks locally separating the two major groups (the Fig Tree and Moodies Groups) which overlie the Onverwacht Group record a second major peak of tonalitic magmatism in the Barberton terrain at about 3250 Ma. This is close to the age of the Kaap Valley tonalite pluton which intrudes the Barberton Greenstone Belt at ca. 3226 Ma along its northwestern margin. The present results indicate the Barberton Greenstone Belt is part of an allochthonous sequence containing major tectonic and stratigraphic breaks, with a protracted history; of which the last 200 million years, at least, evolved within a tectonically active convergent environment.