Spatial and temporal distribution patterns of suspended particulate matter and particulate organic carbon in the Saronikos Gulf (eastern Mediterranean, Greece)

In 1998–1999, beam attenuation coefficient (bac) profiles, suspended particulate matter (SPM) and particulate organic carbon (POC) concentrations were assessed during five cruises in the Saronikos Gulf, eastern Mediterranean, Greece. SPM and POC concentrations (0.05–1.84 mg l⁻¹ and 10.2–468.6 μg l⁻¹, respectively) exhibited strong spatial and temporal variations, related to the different environmental characteristics of various sectors of the gulf, including wind regime and biological productivity. The Elefsis and Keratsini bays, as well as the area around Psyttaleia Island, showed the highest POC concentrations. The vertical distribution of POC at stations in the western basin, as well as in the inner and outer Saronikos Gulf is characterised by higher POC concentrations in surface waters, associated with higher biological activity. The wastewater treatment plant effluents discharged south of the Psyttaleia Island are a major source of organic particles which directly influence the intermediate water layers, at least during the stratification period. Assessments of relationships between bac and SPM or POC concentrations revealed a relatively strong correlation between bac and POC. An equation converting bac readings to POC concentration was established which can be applied to historical and/or future bac measurements, independently of season. POC concentrations estimated from calibrated continuous transmissometer readings were used to estimate the standing stock of POC in the Saronikos Gulf, which varied between 6,110×10⁶ and 13,450×10⁶ g C during the period June 1998 to February 1999.     

Observed vs. predicted variability in non-algal suspended particulate matter concentration in the English Channel in relation to tides and waves

The study of water clarity is essential to understand variability in biological production, particularly in coastal seas. The spatial and temporal variability of non-algal suspended particulate matter (SPM) in surface waters of the English Channel was investigated and related to local forcing by means of a large satellite dataset covering the study area with a spatial resolution of 1.2 km and a daily temporal resolution. This analysed dataset is a time series of non-algal SPM images derived from MODIS and MERIS remote-sensing reflectance by application of an IFREMER semi-analytical algorithm over the period 2003–2009. In a first step, the variability of time series of MODIS images was analysed through temporal autocorrelation functions. Then, non-algal SPM concentrations were assessed in terms of site-specific explanatory variables such as tides, wind-generated surface-gravity wave amplitudes and chlorophyll-a (Chl-a), based on three statistical models with fitting parameters calibrated on a dataset of merged MERIS/MODIS images gathered from 2007 to 2009 over the whole English Channel. Correlogram analysis and the first model highlight the local patterns of the influence of the tide, especially the neap–spring cycle, on non-algal surface SPM. Its effect is particularly strong in the central and eastern English Channel and in the western coastal areas. The second model shows that waves prevail as driver at the entrance of the English Channel. The most sophisticated of the three statistical models, although involving only three explanatory variables—the tide, waves and Chl-a—is able to estimate non-algal surface SPM with a coefficient of determination reaching 70% at many locations.     

Hydro-meteorological influences and multimodal suspended particle size distributions in the Belgian nearshore area (southern North Sea)

Suspended particulate matter (SPM) concentration and particle size distribution (PSD) were assessed in a coastal turbidity maximum area (southern North Sea) during a composite period of 37 days in January–April 2008. PSDs were measured with a LISST 100X and classified using entropy analysis in terms of subtidal alongshore flow. The PSDs during tide-dominated conditions showed distinct multimodal behaviour due to flocculation, revealing that the building blocks of flocs consist of primary particles (<3 μm) and flocculi (15 μm). Flocculi comprise clusters of clay minerals, whereas primary particles have various compositions (calcite, clays). The PSDs during storms with a NE-directed alongshore subtidal current (NE storms) are typically unimodal and characterised by mainly granular material (silt, sand) resuspended from the seabed. During storms with a SW-directed alongshore subtidal current (SW storms), by contrast, mainly flocculated material can be identified in the PSDs. The findings emphasise the importance of wind-induced advection, alongshore subtidal flow and highly concentrated mud suspensions (HCMSs) as regulating mechanisms of SPM concentration, as well as other SPM characteristics (cohesiveness or composition of mixed sediment particles) and size distribution in a high-turbidity area. The direction of subtidal alongshore flow during SW storm events results in an increase in cohesive SPM concentration, HCMS formation, and the armouring of sand; by contrast, there is a decrease in cohesive SPM concentration, no HCMS formation, and an increase in sand and silt in suspension during NE storms.     

A mesocosm experiment coupled with optical measurements to assess the fate and sinking of atmospheric particles in clear oligotrophic waters

It has recently been postulated that lithogenic particles such as Saharan dust strongly influence particulate organic carbon export to the deep ocean by acting as mineral ballast. However, our understanding of the processes involved remains scant. In the present study, optical measurements were performed to monitor variations in the concentration, composition and size distribution of particles in suspension within the water column after simulating a Saharan dust event in very clear Mediterranean waters off Corsica in June 2010. A new methodology set up in large mesocosms proved very successful in this regard. Values obtained simultaneously from three instruments (WetLabs ECO-BB3, WetLabs ac-9, Sequoia Scientific LISST-100) provided evidence that (1) part of the Saharan dust pool has a rapid settling velocity (∼24–86 m day⁻¹), (2) particulate export following a dust event is a nonlinear multi-step process and (3) export is controlled in part by the formation of organic-mineral aggregates. This experimental study provides the first insight of the complex export processes occurring after a dust event involving both physical and biogeochemical forcings in clear oligotrophic waters.     

The radiative and thermal effects of smoke aerosol over the region of Moscow during the summer fires of 2010

The shortwave radiative forcings of smoke aerosol in the cloudless atmosphere during the summer fires of 2010 in European Russia were quantitatively estimated for the land surface and the atmospheric upper boundary from measurement data obtained at the Zvenigorod Scientific Station of the Obukhov Institute of Atmospheric Physics (OIAP ZSS), Russian Academy of Sciences. Variations in the temperature of the surface air layer due to the smoke-induced attenuation of incoming solar radiation were estimated. The most intensive smoke generation in the atmosphere was observed on August 7–9, 2010, when the maximum aerosol optical thickness amounted to more than 4.0 at a wavelength of 550 nm. In this case, the albedo of single aerosol scattering amounted to ∼0.95–0.96 and the asymmetry factor amounted to ∼0.69–0.70. The maximum shortwave radiative forcing of aerosol amounted to about −360 W/m² for the land surface and almost −150 W/m² for the atmospheric upper boundary. During the period of intensive smoke generation, the cooling of the atmospheric surface layer over daylight hours (12 h) amounted, on average, to ∼6°C. The power character of the dependence of the shortwave radiative forcing of aerosol for the land surface on aerosol optical thickness up to its values exceeding 4.0, which was revealed earlier on the basis of data on aerosol optical thickness (up to 1.5) obtained at the OIAP ZSS during the summer forest and peatbog fires of 2002 in the region of Moscow, was supported.     

Satellite monitoring of wildfires during the anomalous heat wave of 2010 in Russia

We describe the specific features of the summer 2010 emergency conditions in the European part of the Russian Federation, when an anomalous heat wave (the monthly mean temperatures in the summer months were 5–9°C higher than those for 2002–2009) and prolonged blocking anticyclones led to large wildfires. We analyze their causes and consequences. The features of the satellite system for operational fire monitoring (constructed at the Aerospace Scientific Center) and examples of its application in summer 2010 are presented. On the basis of the results of processing of satellite images of low (250–1000 m), medium (∼30–50 m), and high (∼6 m) resolutions, we found that the total area covered by fire from March to November of 2010 amounted to approximately 10.9 million hectares for the entire territory of the country and and 2.2 million hectares for its European part. Daily histograms of areas covered by fire in the summer months of 2010 were constructed. On the basis of these data and empirical models, we estimate the daily emissions of carbon monoxide (CO) from wildfires in the summer months of 2010 for the European part of Russia and Moscow oblast. On some days in August 2010, these emissions reached 15000–27000 t for the European part of Russia and 3000–7500 t for Moscow oblast. On the basis of analysis of data from the AIRS spectrometer (Aqua satellite), we derived the spatial distribution of CO concentrations at heights of 2 to 10 km above the territory of the Eastern and Central Europe. Moscow was shown to have been most severely affected by smoke from wildfires occurring on August 6–9, 2010, when the concentrations of harmful gases (CO₂, CO, CH₄, and O₃) and aerosols in the air significantly exceeded both the daily and the one-hour maximum allowable concentrations.     

Heliogeophysical and other natural processes,periods of their oscillations,and forecasts

Stable oscillations of heliogeophysical and other natural processes are generated within the solar system (SS) by interactions between the gravitational fields of the Sun, planets, and their satellites. The resonant periods of the SS are well described by a geometrical progression similar to a sound series with 32 notes in an octave. A comparison of the members of this geometrical progression to the orbital and rotational periods of the planets and the Moon and to the orbital periods of Jupiter’s satellites shows that the discovered regular pattern in the distribution of the motion periods of SS bodies holds with a 95% probability. Numerous natural periods of solar activity, interplanetary magnetic fields, the Earth’s magnetic field and rotational speed, movement of the Earth’s poles, seismic activity, and other terrestrial processes in the range of 10⁻⁴–10⁶ years are also consistent with the members of this geometrical progression. Heliogeophysical oscillations have a common external origin, and their periods often coincide with one another. The amplitudes of the oscillations of terrestrial processes depend on the oscillations in solar activity, lunar-solar tidal forces, and the Earth’s rotational speed, and on the interactions of geophysical processes. The existence of common external periods makes it possible to find significant correlations between terrestrial processes that appear to have no cause and effect relationships, e.g., between global air temperatures and magnitudes of regional earthquakes over a 600-year interval. These correlations testify to the influence of changes in the Earth’s rotational speed on tectonic and climatic processes and provide additional proof for the feasibility of the harmonic model of Northern Hemisphere temperatures. The parameters of stable oscillations that are components of global seismicity harmonic models and those of air temperatures and other natural processes are found from the respective simulated or observed time series. These models permit long-term forecasts of terrestrial and solar processes. The paper gives examples of successful forecasts of global seismicity in 2005–2010 and hazardous events of various origin in 1986, 1995, 2005, 2008, and 2010. Hazardous events are expected to intensify in 2011/2012, 2016/2017, 2024, and 2028/2029. The next economic crisis is expected in 2029 ± 1.     

Summer distribution and geochemical composition of suspended-particulate matter in the east china sea

The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The spatial variability of SPM distribution (0.3–6.5 mg l⁻¹) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water (mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations were highly significant. Particulate CaCO₃ distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total area of 0.45 × 10⁶ km² of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate that continental sources and cross-shelf transport modulate ECS particulate matter in summer.     

The concentration and composition of hydrocarbons in water,particulate matter,and bottom sediments of the Kara Sea

Data are presented on the content of aliphatic and polycyclic aromatic hydrocarbons (AHC and PAH, respectively) in the interstitial waters and bottom sediments of the Kara Sea compared to the distribution of the particulate matter and organic carbon. It was found that the AHC concentrations within the water mass (16 μg/l on average) are mainly formed by natural processes. The AHC distribution represents the variability of the hydrological and sedimentation processes in different regions of the sea. The widest ranges of the concentrations were registered in the Ob Bay-Kara Sea section: in the water (10–310 μg/l for the AHC and 0.4–7.2 ng/l for the PAH) and in the surface layer of the bottom sediments (8–42 μg/l for the AHC and 9–94 ng/g for the PAH). The differentiation of the hydrocarbons (HC) in the different media follows the marginal filter’s regularities; therefore, no oil and pyrogenic compounds are supplied to the open parts of the sea. In the sediment mass, the HC content is determined by the variations in the oxidative conditions in the sediment and its material’s composition.     

Mud transportation on a steep shelf,Rio de La Plata shelf,Puerto Rico

Hurricanes David (August 29–30, 1979) and Frederick (September 2–5, 1979) caused major flooding of the Rio de La Plata in northern Puerto Rico. A thin mud layer was deposited across the narrow insular shelf adjacent to the river mouth. Within 5 months, fair-weather shelf-winnowing processes moved the mud layer entirely from the shelf, 0.5 to 2 km to the shelf break at the 50-m contour and beyond. The process of mud movement is termed “mud hopping.”     

Decrease in anthropogenic nutrients and its effect on the C/N/P molar ratio of suspended particulate matter in hypertrophic Dokai Bay (Japan) in summer

Biologically important nutrient concentrations in Dokai Bay have declined as a result of reductions in anthropogenic inputs of total nitrogen and total phosphorus. A decrease in nutrient concentrations affects phytoplankton growth, thereby changing the biochemical characteristics of autochthonous particulate matter. We therefore investigated changes in the C/N/P molar ratio of suspended particulate matter (SPM) in the summer, when phytoplankton growth is vigorous, before environmental quality standards (EQSs) were attained (1995–1998) and afterward (2006–2009). We found that the ratio of particulate organic nitrogen (PON) to particulate phosphorus (PP) changed in conjunction with changes in the ratio of dissolved inorganic nitrogen to dissolved inorganic phosphorus (DIP) that resulted from reductions in nutrient loading. Furthermore, we suggest that because the DIP concentration in seawater was high before EQSs were attained, inorganic phosphorus was possibly adsorbed onto SPM. After the attainment of EQSs, however, the DIP concentration fell, and PON/PP was high. Phosphorus limitation of phytoplankton growth in the mouth of the bay may explain the high PON/PP ratios after EQS attainment.     

Grain-size composition of the suspended particulate matter in the marginal filter of the Severnaya Dvina River

The quantitative distribution and grain-size composition of the suspended particulate matter (SPM) in the marginal filter of the Severnaya Dvina River during the summer low-water periods of 2001–2005 were first analyzed in seawater on board of the vessel immediately after its sampling (without preliminary treatment) using a Coulter counter. This analysis revealed the main regularities in the transformation of the grain-size spectra at successive salinity steps of the marginal filter as well as the boundaries between these steps based on the data obtained by direct complex studies of the SPM dispersion. It is established that the water salinity is the main factor that controls the changes in the grain-size distribution and the composition of the particulate matter in the marginal filter. The concentrations of the pelitic fraction and the salinity demonstrate negative correlations between each other. It is shown that the areas characterized by the mass development of phytoplankton are located along the outer boundary of the marginal filter (at the biological step), where the salinity amounts to 23–24 psu. The content of the suspended forms of some chemical (lithogenic) elements and the C_org indicating the SPM’s genetic composition and their relations with the grain-size composition of the latter and the environments are studied.     

Greenhouse effect of the atmosphere and its influence on Earth’s climate (satellite data)

On the basis of the radiation-cloudiness model and the available long-term satellite data, we study the correlations of the greenhouse effect with the surface temperature of air and effective cloudiness equal to the product of the cloud amount by the conditional optical density of the clouds. We deduce the relations of satellite monitoring of the behavior of the anomalies of global air temperature caused by the excess amounts of volcanic products and greenhouse gases (formed as a result combustion of the fossil fuel) in the atmosphere. Realistic estimates of the processes of cooling and warming of the currently existing climate are obtained. Under the condition of preservation of the existing linear trends in the behaviors of the short-and long-wave flows of radiation into the outer space (observed according to satellite data for the last 20 yr), the global temperature in the second part of the current century can increase by 1.6–2.0°C. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 6, pp. 13–28, November–December, 2006.     

Characteristics of the ratio of dissolved cadmium to phosphate in subtropical coastal waters of Ishigaki Island,Okinawa, Japan

The ratio of dissolved cadmium (Cd) to phosphate (PO₄) in the subtropical coastal area of Ishigaki Island, Okinawa, Japan, was investigated. Twenty vertical seawater samplings were carried out once a month from May 2008 to January 2010. In order to examine how the Cd/PO₄ ratio in seawater varies with the oceanographic conditions (i.e., the water temperature–salinity characteristics), the water masses at the study sites were classified into two types: group 1 with a water temperature of >25°C and a salinity range of 34.0–34.4, and group 2 with a water temperature of <25°C and a salinity of >34.4. A different phytoplankton assemblage was observed in each water mass defined. Different Cd/PO₄ ratios were obtained for the two water mass types, due to the differences between the types in terms of the environmental conditions such as the water temperature–salinity (T–S) characteristics and phytoplankton assemblages, as well as possible variations in the concentrations of dissolved iron, zinc, manganese, and CO₂ in seawater in each water mass.     

Variations of the Earth’s magnetic field in the Phanerozoic

The global VDM database, which was later supplemented by new determinations published in the world literature (a total of 3194 determinations), is used as the basis for addressing the VDM behavior in the Phanerozoic (0–542 Ma) and up to 580 Ma. The results revealed a positive linear trend to higher VDM values from 3.5 × l0²² Am² to 5.7 × l0²² Am². Against this background, fluctuations of the mean VDMs occur with a periodicity of about 40 Myr. In the Phanerozoic, prominent minima of the intensity are found in the time intervals of 510–520, 420–460, 340–370, 290–300, 240–270, 190–210, 165–140 Ma (chrons M17–M43), 130–120 Ma (chrons M2–M10), 100–110 Ma (chron C34), 75–85 Ma (chrons C33 and the beginning of chron C34), 70–60 Ma (chrons C31–C27), and 40–15 Ma (chrons C18–C5AD). The distribution of the VDMs appears to reflect the paleomagnetic field behavior and may be taken into account in a magnetization model for the reversely magnetized oceanic crust.     

Benthic boundary layer processes in the Lower Florida Keys

 This special issue of Geo-Marine Letters, “Benthic Boundary Layer Processes in the Lower Florida Keys,” includes 12 papers that present preliminary results from the Key West Campaign. The Dry Tortugas and Marquesas Keys test sites were selected by a group of 115 scientists and technicians to study benthic boundary layer processes in a carbonate environment controlled by bioturbation and biogeochemical processes. Major activities included remote sediment classification; high-frequency acoustic scattering experiments; sediment sampling for radiological, geotechnical, biological, biogeochemical, physical, and geoacoustic studies; and hydrodynamic studies using an instrumented tetrapod. All these data are being used to improve our understanding of the effects of environmental processes on sediment structure and behavior.     

The rates of organic matter destruction in the central part of the Arctic Basin

The intensity of the processes of organic matter (OM) destruction in the deep-water part of the Arctic Basin is considered in terms of the activities of hydrolytic enzymes (alkaline phosphatase and proteases) and of redox enzymes of the electron transport system (ETS). High concentrations of mineral phosphorus are shown to cause low phosphatase activity (0.000–0.005 μM P/l h). The average time of the phosphate recycling amounted to about 240 h. The ranges of the total and specific activity of protease are 0.000–0.192 mg of azocasein/(l h) and 0.00–3.57 mg of azocasein/h mg of protein, respectively. It is found that the microplankton production of exo- and endopeptidase in the Arctic Basin is controlled by the concentration of nitrates in the water. The values of the total and the specific activities of the ETS enzymes vary within 0.27–8.96 μl O₂/(l h) and 8.4–583 μl O₂/mg of protein h, respectively. It is shown that the maximum values of the total activities of the hydrolytic and redox enzymes are characteristic for the photic layer. The vertical fluxes of organic carbon from the photic layer, being calculated by the activity of the ETS enzymes, amounted to 220–600 g of C_org/year m². The presence of ice intensifies the redox processes by factors of 2–15.     

Particulate organic carbon (POC) in surface sediments of the Baltic Sea

In this study, particulate organic carbon (POC) contents and their distribution pattern in surficial sediments of the Baltic Sea are presented for 1,471 sampling stations. POC contents range from approx. 0.1% in shallow sandy areas up to 16% in deep muddy basins (e.g. Gotland Basin). Some novel relationships were identified between sediment mass physical properties (dry bulk density (DBD), grain size) and POC levels. Notably, the highest POC concentrations (about 10–17 mg cm^–3) occur in sandy mud to mud (60–100% mud content) with intermediate POC contents of about 3–7% and DBDs of 0.1–0.4 g cm^–3. Areas with this range in values seem to represent the optimum conditions for POC accumulation in the Baltic Sea. The maximum POC contents (8–16%) are found in fluid mud of the central Baltic Sea characterized by extremely low DBDs (<0.1 g cm^–3) and moderate POC concentrations (4–7 mg cm^–3). Furthermore, sediment mass accumulation rates (MAR), based on ²¹⁰Pb and ¹³⁷Cs measurements and available for 303 sites of the Baltic Sea, were used for assessing the spatial distribution of POC burial rates. Overall, these vary between 14 and 35 g m^–2 year^–1 in the mud depositional areas and, in total, at least 3.5 (±2.9) Mt POC are buried annually. Distribution patterns of POC contents and burial rates are not identical for the central Baltic Sea because of the low MAR in this area. The presented data characterize Baltic Sea sediments as an important sink for organic carbon. Regional differences in organic carbon deposition can be explained by the origin and transport pathways of POC, as well as the environmental conditions prevailing at the seafloor (morphology, currents, redox conditions). These findings can serve to improve budget calculations and modelling of the carbon cycle in this large brackish-water marginal sea.     

Summer dynamics of phytoplankton pigments and its correlation with the optical parameters of shelf waters in the Black Sea (2001–2002)

We study the space and time variations of the concentration of chlorophyll in the Black-Sea coastal zone (near Katsiveli) in summer 2001–2002. Typical vertical profiles of the pigments are presented. The relations between the concentration of chlorophyll and the optical parameters of seawater (including the Secchi depth, sea reflectance, effective wavelength of the upwelling radiation, and the vertical attenuation coefficient of light) are analyzed. The equations for the biological parameters of seawater and its optical characteristics are presented. __________ Translated from Morskoi Gidrofizicheskii Zhurnal, No. 3, pp. 36–51, May–June, 2006.     

Mechanism of Nutrient Supply to Warm-Core Ring off Sanriku, Japan

The mechanism by which nutrient is supplied to a warm-core ring (WCR) was investigated in order to understand the greater productivity of WCR than that of the Kuroshio, where the WCR originattes. A single WCR was observed in January and May, 1997. The thermostad (a layer of isothermal and isohaline water) of the WCR had different properties from January to May, the differences: Δwater temperature: −0.698°C, Δsalinity: −0.048, Δsigma θ: +0.072, Δnitrite+nitrate-N: +1.83 μM, Δphosphate: +0.011 μM and Δsilicate: +3.2 μM. We examined three possible mechanisms for nutrient supply to WCR in winter, namely: 1) inflow of the Oyashio surface water into WCR; 2) isopycnal mixing with Oyashio water; 3) entrainment of the water below the WCR into the WCR. The results were as follows: 1) When the decrease of salinity was due to the inflow of the Oyashio surface water, the increase of nutrients (nitrite+nitrate-N, phosphate-P and silicate-Si) was estimated to be only 17–27% of the observed increase. 2) When the decrease of salinity was due to isopycnal mixing, the increase of nutrients was estimated to be 30–42% of the observed increase. 3) When the decrease of salinity in the WCR in May was due to entrainment of the water below the WCR in winter by convection, the mixing depth was calculated be 620 m according to the salt budget. The increase of nutrients in this case was calculated to be 82–95% of the observed increase. The main mechanism of nutrient supply to WCR was concluded to be due to the entrainment of the water below the WCR by winter mixing. This revised version was published online in August 2006 with corrections to the Cover Date.