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1.
分别采用硫酸过硫酸钾作为氧化剂进行高压消解和用浓度为1 mol/dm3盐酸浸泡提取,然后用磷钼蓝分光光度法测定海水悬浮颗粒物、沉积物中的总磷和无机磷,用差减法得到有机磷。悬浮颗粒物总磷(PTP)和无机磷(PIP)质量浓度分别为(632.4~651.7)×10-6和(436.6~452.6)×10-6时,其相对标准偏差小于1.44%。悬浮颗粒物总磷、无机磷和有机磷的回收率分别为97.2%~101.3%,97.8%~100.4%和97.3%~102.3%。所建立的分析方法可用于海水、河口水悬浮颗粒物及沉积物中不同形态磷的测定。 相似文献
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过硫酸盐氧化法测定海水中溶解总磷 总被引:6,自引:0,他引:6
实验研究在碱性和酸性条件下过二硫酸钾高温氧化四种不同类型含磷标准化合物在海水中的回收率和影响回收率的因素。结果表明 :在碱性条件下过二硫酸钾高温氧化可使海水中非聚磷类化合物完全回收 ,而聚磷类化合物回收率不高 ,延长消化时间聚磷类化合物的回收率有一定提高。除个别化合物外 ,各类含磷化合物在酸性条件下可被定量回收。依此 ,建立酸性过硫酸盐氧化法分解测定海水中溶解态总磷的方法。 相似文献
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Patrick Raimbault Wilfried Pouvesle Frdric Diaz Nicole Garcia Richard Sempr 《Marine Chemistry》1999,66(3-4)
We developed a simple and reliable method which allows simultaneous determination of organic forms of carbon (DOC), nitrogen (DON) and phosphorus (DOP) dissolved in seawater. Conversion of dissolved organic matter (DOM) to inorganic products (carbon dioxide, nitrate+nitrite and soluble reactive phosphate) is performed by a persulfate wet-oxidation in low alkaline condition. After oxidation, the concentration of the inorganic products dissolved in the sample was measured automatically by colorimetry using a 3-channel Technicon AutoAnalyzer system. A number of pure organic compounds were tested in the concentration range encountered in coastal and open ocean, indicating a high efficiency of the digestion procedure. The recovery range is similar to that obtained by other wet-oxidation procedures and by high-temperature catalytic oxidation techniques. Direct comparisons with usual methods used for separate determination of DOC, DON and DOP indicated a high efficiency of the procedure. Reproducibility tests demonstrated a very good precision (around 5%) for lagoonal and coastal waters, while precision was sometimes around 10–25% in oligotrophic oceanic waters, especially for DOP where values approached limits of detection for measuring phosphate. This method is highly suitable for routine analysis and especially appropriate for shipboard work. 相似文献
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A technique for the pH-controlled isolation and separation of dissolved copper—organic substances from large amounts of seawater is described. The method has been applied in two cruises in the Bothnian and Gotland Seas of the Baltic. In both areas the correlation between the amount of isolated dissolved organic material (DOM) and the concentration of organic copper in seawater has been found to be highly significant. Under the conditions established in our experiments, organic copper fractions detected in Baltic waters were in the range of about 5% of total copper. HPLC chromatograms and UV irradiation experiments from DOM extracts strongly indicate the existence of dissolved organic-copper compounds in Baltic waters. 相似文献
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The phosphorus cycle is studied during 2013–2014 in the Sanggou Bay(SGB), which is a typical aquaculture area in northern China. The forms of measured phosphorus include dissolved inorganic phosphorus(DIP), dissolved organic phosphorus(DOP), particulate inorganic phosphorus(PIP), and particulate organic phosphorus(POP).DIP and PIP are the major forms of total dissolved phosphorus(TDP) and total particulate phosphorus(TPP),representing 51%–75% and 53%–80%, respectively. The concentrations and distributions of phosphorus forms vary among seasons relative to aquaculture cycles, fluvial input, and hydrodynamic conditions. In autumn the concentration of DIP is significantly higher than in other seasons(P0.01), and higher concentrations are found in the west of the bay. In winter and spring the phosphorus concentrations are higher in the east of the bay than in the west. In summer, the distributions of phosphorus forms are uniform. A preliminary phosphorus budget is developed, and shows that SGB is a net sink of phosphorus. A total of 1.80×10~7 mol/a phosphorus is transported into the bay. The Yellow Sea is the major source of net input of phosphorus(61%), followed by submarine groundwater discharge(SGD)(27%), river input(11%), and atmospheric deposition(1%). The main phosphorus sink is the harvest of seaweeds(Saccharina japonica and Gracilaria lemaneiformis), bivalves(Chlamys farreri),and oysters(Crassostrea gigas), accounting for a total of 1.12×10~7 mol/a. Burial of phosphorus in sediment is another important sink, accounting for 7.00×10~6 mol/a. Biodeposition by bivalves is the major source of phosphorus in sediment, accounting for 54% of the total. 相似文献
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M. Falco M.N. Santos T. Drago D. Serpa C. Monteiro 《Estuarine, Coastal and Shelf Science》2009,83(4):451-459
The present study investigates the differences between nutrient fluxes and particulate organic matter within an artificial reef system (AR) deployed in August 2002 off Faro (Algarve, Southern Portugal) and in a non-reef area (NRA), and how fluxes and suspended material may be affected by the hydrodynamic regime. Surveys to collect sediment cores, suspended/settled particles and overlying water samples were carried out by divers, from March (2006) to October (2007) in AR and NRA. Sediment cores and settled particles were collected to determine grain size, organic and inorganic carbon, nitrogen and phosphorus content. Overlying water and pore water samples were analysed for ammonium, nitrite, nitrate, phosphate, silicate, dissolved organic nitrogen, dissolved organic phosphorus and chlorophyll a. Results from the period studied showed that: (1) the benthic export of dissolved N, P and Si was 2–3 times higher at AR; (2) the particulate organic carbon (POC), nitrogen (PON) and phosphorus (POP) in suspended/settled particles were about 1.5 times higher at AR; (3) at both AR and NRA, the benthic export of dissolved N, P and Si, during a calm weather period, was 2–4 times higher than during or immediately after a storm event; and (4) at both sites, particulate organic compounds (POC, PON and POP) increased about 20 times during a storm event. These findings suggest that both the nutrients transport from sediment to water column and the quantity/quality of suspended/settled particles were highly dependent on the existence of reef structures and on the hydrodynamic regime. 相似文献
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污水与九龙江河口水混合研究表明,COD的降解符合一级动力学模式,降解速率常数k在0.04-0.11d^-1之间,水体有机物的转移以降解作用为主;两种水体混合时,先产生磷的吸附,后释放,整个过程表现为颗业磷向溶解无机磷的转移。 相似文献
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Automatic determination of dissolved organic carbon in seawater in the sub-ppm range 总被引:1,自引:0,他引:1
G. Cauwet 《Marine Chemistry》1984,14(4):297-306
The improvement of a dissolved organic carbon (DOC) analysis technique is described. This continuous flow system, based on both persulfate and UV oxidations, allows the automatic determination of DOC in sea and estuarine waters. The use of FID detection gives a very high sensitivity, permitting the detection of small variations in carbon content. The efficiency of the method and its sensitivity are tested, together with the influence of initial pH and duration of nitrogen bubbling. The system can also be used to determine total or inorganic carbon. 相似文献
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采用超低本底液闪β计数的方法,测定了春季黄海、东海海水中溶解态、悬浮物、筛绢颗粒物和雨水中天然32P和33P的比活度.结果显示,上层海水各相33P,32P的比活度相当低,其中TDP的32P,33P比活度的浓度最高,悬浮物次之,筛绢颗粒物最低.海水各相中33P与32P活度比值从TDP到悬浮物、筛绢颗粒物逐渐增大,反映出食物链传递过程中磷的年龄逐渐增加.根据稳态模式的估算结果,海水各相中磷的停留时间具有明显的区域变化特征,其中近岸和内陆架溶解磷的停留时间比外陆架短,仅为3~4 d,意味着近岸和内陆架海区低浓度的磷也可能维持高生物生产力的运转.利用稳态模式还估算出浮游植物的碳同化通量为189~814 mg/(m2·d),浮游动物的碳摄食通量为10~161 mg/(m2·d).此外,通过比较雨水32P,33P的输入通量和海水32P,33P积存量,利用质量平衡方法估算出上层海水POC输出通量为102~972 mg/(m2·d). 相似文献
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根据1988年7月调查资料讨论了台湾海峡中北部海域夏季上升流区各种形态磷的分布特征。结果表明,上升流中心区(即海坛岛东侧一带水域)具有低温、高盐、低溶解氧;DIp,TDP,PP,TP较高;DOP较低(0.27);及DIP/DOP比值(约为1)较高的特性。DOP是该海域磷的主要形态(占TP的49.2%),其含量分布及其形态转化与生物活动直接相关,是该海域生物生产力高的体现。 相似文献
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LIU Sumei ZHAO Yingfei REN Jingling ZHANG Jing SUN San JIN Jie ZHANG Guiling 《海洋学报(英文版)》2010,29(1):42-51
Phosphorus (P) is an essential nutrient utilized by all organisms for energy transport and growth.
Both the conventional molybdenum-blue method and the magnesium-induced coprecipitation
(MAGIC) procedures were applied for the measurement of dissolved inorganic phosphorus (DIP)
and total dissolved phosphorus (TDP) in more than 840 water samples collected between 2003 and
2005, including seawater (the Huanghai Sea, the East China Sea, and the northern South China
Sea), water from rivers and estuaries (the Changjiang, the Huanghe, and the major rivers emptying
into the Jiaozhou Bay), groundwater (in the drainage basin surrounding the Jiaozhou Bay), rain-
water, and aquaculture water samples. The MAGIC method allows the investigation of phosphorus
distributions and cycling for systems in which DIP is below the detection limits of conventional
methods. Comparison between the two methods demonstrated that the concentrations obtained
with both methods were signiˉcantly correlated. The di?erences of DIP and TDP concentrations
measured with the two methods were higher when the concentrations of DIP and TDP were lower,
implying the lower reproducibility at low concentrations. The concentration di?erences increase
with the increase in the proportion of DOP in TDP, which indicates that the discrepancy of DIP
concentrations measured with the two methods increases when the DOP concentration is high. The
discrepancies indicated that the composition of P compounds di?ers depending on sample sources
and water type; it would be useful to infer the presence of di?erent phosphorus compound pools
from di?erences between the two methods. This study indicates the potential presence of a pool
of alkaline-labile compounds for samples from rainwater and rivers and estuaries surrounding the
Jiaozhou Bay; the potential presence of acid-labile compounds that were adsorbed by Mg(OH)2 for
samples from the Changjiang Estuary, Huanghai Sea, East China Sea, and groundwater; the po-
tential presence of a substantial pool of acid-labile compounds that were not adsorbed by Mg(OH)2
for samples from the Huanghe Estuary, aquaculture water, the East China Sea algal bloom water,
and the northern South China Sea. 相似文献
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Spatial distributions and seasonal variations of particulate phosphorus in the Jiaozhou Bay in North China 总被引:2,自引:0,他引:2
Based on the measurements of particulate phosphorus(PP) in the Jiaozhou Bay from May 2003 to April 2004,the spatial distribution,seasonal variation and biogeochemical characteristics of PP were investigated to understand the fates and roles of phosphorus in the Jiaozhou Bay ecosystem.The concentration of the total PP ranged from 0.07 to 2.09 μmol/dm3.The concentration of POP was from 0.01 to 1.83 μmol/dm3,with an average of 0.32 μmol/dm3,which accounted for 49.6% in total PP.The concentration of PIP was fro... 相似文献
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溶解态磷在海洋微藻碱性磷酸酶活力变化中的调控作用 总被引:17,自引:2,他引:17
在实验室批量培养条件下,测定了海洋微藻培养体系中碱性磷酸酶活力(APA)和各形态溶解磷的动态变化,分析了二者之间的关系.结果表明,在批量培养过程中,APA的动态变化呈"S"形曲线,各形态溶解磷在其变化过程中所起的调控作用不同,介质中溶解无机磷和小分子溶解有机磷的浓度是激发APA发生变化的主要调控因子,大分子溶解有机磷的浓度对APA的作用不明显,但APA的增大可加速微藻利用大分子溶解有机磷的速率.微藻的种类和丰度不影响APA的动态变化形式及其调控机理. 相似文献
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水-气平衡法被广泛地应用于海水CO2分压(partial pressure,pCO2)的测定。该方法采用水-气平衡器,使海水与平衡器上部顶空中的空气进行CO2交换,达到平衡后测定该顶空空气中CO2的浓度,再换算成海水pCO2。水-气平衡器是海水pCO2测量仪器的关键部件,其性能在很大程度上决定所获得的pCO2数据的准确度和可靠性。本文介绍了水-气平衡器的平衡原理、平衡器时间常数的测量方法及影响因素,归纳了现有的4种用于海水pCO2测量的水-气平衡器即喷淋式、鼓泡式、层流式及混合式平衡器的结构与特点,着重介绍了两种新型的水 气平衡器即基于射流器的鼓泡式平衡器和基于球形降膜的层流式平衡器,比较了不同水-气平衡器的尺寸、运行参数及时间常数,分析了设计和应用水-气平衡器时需考虑的因素。本文可为使用水-气平衡器测定海水pCO2的技术人员提供技术参考。 相似文献
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乳山湾外低氧海域沉积物中有机碳、氮、磷及其形态特征分析 总被引:3,自引:0,他引:3
根据2009年8月在乳山湾及其毗邻海域的综合调查,分析了该海域表层沉积物中有机碳、氮、磷含量及其组成形态的变化,初步探讨了影响底质理化参数变化的原因及对乳山湾外近岸底层低氧形成的影响.结果表明,乳山湾外近海为粉砂质岸滩,以细颗粒为主;底质中有机碳含量介于0.49% ~0.93%,平均值为0.69%;总氮含量介于382~1020 mg/kg,平均值为671 mg/kg;可溶性总氮含量介于23.0 ~ 60.0 mg/kg,平均值为44.0mg/kg,其中可溶性有机氮和氨氮分别占可溶性总氮的58.8%和38.8%;总磷含量介于138~769 mg/kg,平均值为356 mg/kg,有机磷是占有绝对优势的磷形态(62.5%).研究区域沉积物中总氮和湾内相当,有机碳、总磷含量普遍低于乳山湾内,但均明显高于南黄海区域,且呈还原性状态.调查区域内沉积物中相对较高的有机碳、氮、磷可能是在潮流作用下乳山湾与外海的物质交换所致,其耗氧过程是导致底层溶解氧亏损的重要原因,值得进一步关注. 相似文献
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Cycling of phosphorus in the Jiaozhou Bay 总被引:2,自引:1,他引:1
Dissolved inorganic phosphorus (DIP ),dissolved organic phosphorus (DOP ),particulate inorganic phosphorus (P IP ) and particulate organic phosphorus (P OP ) in the Jiaozhou Bay (JZB) and its adjacent major rivers were analyzed during 2001–2003.DIP was the major form of dissolved phosphorus in JZB,representing 62%–83% of the total dissolved phosphorus (T DP ),and the P IP concentration generally exceeded the P OP concentration.The concentrations of phosphorus were higher in the north than in the south of th... 相似文献