MODERN CLIMATIC SIGNALS DEDUCED FROM STABLE ISOTOPE IN SHELLS IN XINGCUO LAKE SEDIMENTS,EAST TIBETAN PLATEAU,CHINA

Ｉｔｉｓｏｎｅｏｆｔｈｅｆｒｏｎｔｉｅｒｆｏｃｕｓｅｓｉｎｔｈｅｆｉｅｌｄｏｆｇｌｏｂｌｅｅｎｖｉｒｏｎｍｅｎｔａｌｃｈａｎｇｅｓｔｏｅｘｔｒａｃｔｑｕａｎｔｉｔａｔｉｖｅｌｙｐａｓｔｃｌｉｍａｔｉｃｓｉｇｎａｌｓｆｒｏｍｌａｋｅｓｅｄｉｍｅｎｔｒｅｃｏｒｄｓ．Ｉｎｔｈｅｒｅ-ｃｅｎｔｄｅｃａｄｃｉｏｕｓｙｅａｒｓａｓｅｒｉｅｓｏｆａｃｈｉｅｖｅｍｅｎｔｓｏｎｒｅ-ｂｕｉｌｄｉｎｇｔｈｅｓｅｑｕｅｎｃｅｓｏｆｃｌｉｍａｔｉｃａｎｄｅｎｖｉｒｏｎｍｅｎｔａｌｅｖｏｌｕｔｉｏｎｓａｔｖａｒｉｏｕｓｓ…     

Isotopic evidence for holocene climatic changes in Bosten Lake, Southern Xinjiang, China

Based on the δ¹³C and δ¹⁸O fluctuation of lacustrine carbonate, CaCO₃ content and sporo-pollen data, a palaeoclimatic history of Bosten Lake during the Holocene has been outlined, several stages of climatic changes are divided, and the following result es are obtained: (1) Palaeoclimatic changes revealed by carbonate isotope around Bosten Lake are basically identical with that revealed by other geological records in Xinjiang. Environmental changes presented apparent Westlies Style model: during cold period, relative humidity increased, δ¹⁸O, δ¹³C and CaCO₃ appeared low; but in warm periods, the dry regime aggravated. (2) The temperature reflected by δ¹⁸O exist evident features being increase in the late period during the Holocene. Together with the δ¹³C, pollen and CaCO₃ analyses, several cold and warm phases which are of broad regional significance can be identified. The warm peaks occurred at about 11.0 ka B.P., 9.4 ka B.P., 7.5 ka B.P., 5.0 ka B.P., 3.0 ka B.P. and 2.0 ka B.P.; the cold peaks at 11.5 ka B.P., 10.5 ka B.P., 8.8 ka B.P., 5.5 ka B.P., 3.3 ka B.P., 2.2 ka B.P. and 1.5 ka B.P.. (3) Several climatic events with the nature of “abrupt climatic changes” are revealed in the periods of 11.0 ka B.P. −10.5 ka B.P., 9.4 ka B.P. −8.8 ka B.P., 5.5 ka B.P. −5.0 ka B.P. and 2.0 ka B.P. −1.5 ka B.P.. (4) The results show that carbonate isotopic record of lacustrine sediment in arid area is very sensitive to climatic changes, and may be play a very important role in understanding the features and mechanism of palaeoclimatic changes.     

VARIATIONS IN ISOTOPIC COMPOSITIONS OF CHLORINE IN EVAPORATION-CONTROLLED SALT LAKE BRINES OF QAIDAM BASIN，CHINA

ＩＮＴＲＯＤＵＣＴＩＯＮＣｈｌｏｒｉｎｅｈａｓｔｗｏｎａｔｕｒａｌｌｙｏｃｃｕｒｉｎｇｓｔａｂｌｅｉｓｏｔｏｐｅｓ,　35Ｃｌａｎｄ　37Ｃｌ.Ｓｅｖｅｒａｌｓｔｕｄｉｅｓｒｅｐｏｒｔｅｄｔｈｅｖａｒｉａｔｉｏｎｓｉｎｔｈｅｉｓｏｔｏｐｉｃｃｏｍｐｏｓｉｔｉｏｎｏｆｃｈｌｏｒｉｎｅｉｎｎａｔｕｒｅ.Ｈｏｗｅｖｅｒ,ｉｎｔｈｅｅａｒｌｙｙｅａｒｓＯｗｅｎａｎｄＳｃｈａｅｆｆｅｒ(1955)ｒｅｐｏｒｔｅｄｎｏｏｂｓｅｒｖａｂｌｅｄｉｆｆｅｒｅｎｃｅｉｎｔｈｅ　37Ｃｌ35Ｃｌｒａｔｉｏｓｉｎｔｅｎｓａｍｐｌｅｓｅｘ…     

Transformation pathway of carbonate pedofeatures based on their micromorhology and carbon isotope data in the Northern Caucasus region, Russia

Carbonate pedofeatures （CPs） in a chronosequence of paleosols buried under kurgans in the Northern Caucasus region of Russia in a period from the end of the 4th to the middle of the 5th centuries AD （It seams that there is no time left） were studied by using a set of morphological and isotopic methods. The CPs in chernozem-type soils of Russia are usually represented by crystallomorphic calcite whereas the non-segregated carbonates occurred at the same horizons - by collomorphic one. Those two morphotypes of calcite have the differences in elemental composition and isotopic composition of carbon and, hence, should have different origins - from true and colloidal solutions, respectively. The same differences including radiocarbon age have been revealed for pseudomycelium of the ABca horizon of the youngest paleosols as compared with the same CPs of other paleosols in the chronosequence studied. Our assumption is that it was succeeded in finding that the pseudomycelium right away after its precipitation from a colloidal solution migrated from the lower soil horizons to the surface horizons during the periods of climatic aridization. After a short time interval （not more than 25-50 years） collomorphic calcite in the pseudomicelium of the yongest paleosols mentioned above will likely become by ＂usual＂ acicular calcite.     

ORIGIN OF CARBONATE MATERIALS IN THE NORTHERN BASIN OF LAKE BAIKAL AND ITS RELATIONSHIP TO HOLOCENE PALEOCLIMATE

Fine-grained disseminated carbonate was found in Holocene sediments in a core taken from the northern basin of Lake Baikal. The core had two distinct facies. a terrigenous blue-clay overlain by a diatomaceous silt. Oxygen and carbon stable isotope analyses, combined with SEM , X-ray diffraction and .palynology, show that the carbonate in the blue-clay layer is pedogenic in origin, rather than biogenic or authigenic . The S C values in the blue clay suggest that the carbonate is derived from a single source , while the carbonate in the diatom-rich layer might be transported by winds from different sources. On the assumption that the carbonate was formed during the post-glacial age and was transported primarily by river runoff, the 18O isotopic values suggest that the annual temperature in the northern Baikal drainage area was about 3℃ warmer during the middle Holocene (8500-7000 a, B. P.) than during the early Holocene (11 000-8 500a, B.P.) when the blue clay was being deposited . This interpretation is     

Paleoclimatic Change Inferred from Carbon Isotope Composition of Organic Matter in Sediments of Dabusu Lake, Jilin Province, China

Study on the organic compounds and stable isotope composition of a sediment section in Dabusu Lake revealed that the organic materials in the sediments came mainly from terrestrial plants brought into the lake by rtmoff.The δ^13 C of the organic materials had high values during warm-dry climatic stages and decreased in cold-wet stages.Analysis of data on carbonate content and ^14C age showed that the lake basin had experienced several wet-cold and warm-dry climatic cycles since 15000 a BP. Since 6700 a BP, the climate reached a relatively stable warm-dry stage,so that the lake water was gradually condensed and finally a saline lake was formed.     

Geochemical characteristics of stable isotopes from hydrothermal chimneys in the Mariana Trough, West Pacific Ocean

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Episodes of volcanic activity and their environmental effects in the Okinawa Trough during the last 150 ka

1 INTRODUCTIONA large-scale volcanic eruption can injectenormous amount of ash and dust into the atmos-phere, leading to local and short cooling due toshielding incoming radiation. During the past 2 to 3decades, accumulated evidence indicated thatlarge-scale volcano eruptions or series of volcanicactivity appears to coincide with climatologicaltransitions. For example, Robock (1979) indicatedthat volcanic eruptions played a role in forcing "Lit-tle Ice Age". Well-dated high-resolution co…     

Compositions of δ18O and δ13C in various carbonates of core RM in the Zoigê Basin and climatic significance

The hole RM, the deepest one fully obtained core in the Qinghai-Xizang Plateau, situated in the depositional center of the Zoige Basin (33°57′N; 102° 21′E) in the northeastern Qinghai-Xizang Plateau with a depth of 310.46 m. From ¹⁴C dating and paleomagnetic stratigraphic study, the core RM can date back to 900 ka B.P.. In this paper we analyzed the compositions of δ¹⁸O and δ¹³C in various carbonates can date (snail, obstrode, chemical carbonate) in core RM and discussed preferably the paleoclimatic record by the proxies of δ¹⁸O and δ¹³C of chemical carbonate (authicarbonate) from core RM in the past 140 ka. The results showed that the values of δ¹⁸O in various carbonates are generally identical, and the values of δ¹³C in it are inconsistent, while there exist better relativity. The studies also demonstrated that there was a negative correlation between δ¹⁸O and δ¹³C of authicarbonate in core RM in the past 140 ka, showing that the changes of δ¹⁸O values were mainly relative to the water temperature. According to above, the climatic evolutionary sequence were rebuilt in the past 140 ka in the region.     

Application of transition metal isotope tracers in global change research

High-precision isotope composition determinations using multicollector, magnetic-sector inductively coupled plasma mass spectrometry (MC-ICPMS) have recently revealed that some transition metal isotopes such as those of Mo, Fe, Cu, Zn etc. can be used as biogeochemical tracers in global change research.The Mo isotope system may be useful in paleoredox investigations indicating that δ^97 ^95Mo in seawater may co-vary with changes in the relative proportions of anoxic and oxic sedimentation in the ocean, and that this variation may be recorded in δ^97 ^95Mo of anoxic sediments. The Mo continental flux into the oceans and the global Mo isotope budget can be estimated from δ^97 ^95M0 values. The Fe isotope composition in seawater is an important issue because Fe plays a controlling role in biological productivity in the oceans and its abundance in seawater may have substantial effect on climate changes. Iron isotope fractionations could result from bio- and abio-processes and have about 0.1% variation ( δ^56 ^54Fe), so Fe isotopes considered alone cannot be used to distinguish the products of abiotic and biotic Fe processing in geological records. Cu and Zn isotopes are also used as biogeochemical tracers, but the researches are relatively less. This review mainly focuses on the methods for preparation, purification and determination of new isotope tracer samples, and on isotope applications in marine environmental changes.     

Variation of d δ18O/dT in precipitation in the Qinghai-Xizang Plateau

The relations between δ¹⁸O and temperature on the different time scales were analysed, according to the data from Tuotuohe (34°13′N, 96°25′E; 4533 m a. s. l.), Delingha (37°22′N, 97°22′E; 2981 m a. s. l.) and Xining (36°37′N, 101°46′E; 2261 m a. s. l.) in the Qinghai-Xizang Plateau. The results show that the significance of d δ¹⁸O/dT on different time scales are different. The d δ¹⁸O/dT on the synoptic scale reflects the interdependent relation between δ¹⁸O and temperature in the short-term synoptic scale process; the d δ¹⁸O/d T on the seasonal scale reflects the relation between them whithin a year; and the d δ¹⁸O/d T on the climatic scale reflects the relation between them in the long-term climatic change. The calculated d δ¹⁸O/dT on climatic scale is very close to the theoretical values on the condition of advection transport for Tuotuohe Station. However, there are great differences between the calculated and the theoretical values for Delingha and Xining stations.     

Stable isotopes in aquatic food web of an artificial lagoon in the Hangzhou Bay, China

Stable isotope values, δ¹³C and δ¹⁵N, were determined for four primary producers and 19 dominant consumers in a small artificial lagoon located in Hangzhou Bay. Based on these results the major pathways for energy flow and trophic structure of the artificial lagoon ecosystem were characterized. The mean δ¹³C values for the 19 consumers ranged from −22.99‰ to −14.24‰. Apart from so-iny mullet Liza haematocheila, the other 18 consumers had intermediate δ¹³C values between those of epibenthic microalgae and particulate organic matter (POM). The results of a multiple source linear mixing model (IsoSource model) indicated that 50% or more of the organic carbon in the tissues of most consumers was derived from epibenthic microalgae. This indicated that these primary producers were the main food source fueling the lagoon food web. The mean δ¹⁵N values for the 19 consumers varied between 4.93‰ and 12.97‰ and indicated four trophic levels in the lagoon. Four macroinvertebrates and zooplankton represented the primary consumers, whilst the other 14 consumers occupied the secondary and tertiary consumer levels. The 19 consumers were divided into three trophic guilds (detritivores/suspension feeders, omnivores and carnivores).     

A 3600 years paleoclimatic change inferred from organic δ13C and TOC/TN of the Gucheng Lake sediments, southeast China

A 6.2 m thick core of Gucheng Lake sediment provided a 3600 years record of climate change. The contents of the TOC in the core changed from 2.63% to 8.48%, and the δ¹³C values of organic matter were from −21.54% to −27.3%. The TOC/TN ratios indicated that the organic materials in sediments were from lake plankton and land-derived plants. The 2.9–22 m core interval with high TOC/TN ratios, low δ¹³C values and low contents of TOC indicated a cold climate stage. The 6.2–5.5 m and 0.4–0.1 m intervals were characterized by low TOC/TN ratios, high δ¹³C values and high contents of TOC, and reflected temperate climate stages. Project 49372129 supported by NSFC.     

Relation between δ18O in atmospheric precipitation and temperature and precipitation

The paper analyzes the relation between δ¹⁸O and temperature and precipitation in different regions of the world on the basis of the data from the global observational network set by the International Atomic Energy Agency (I-AEA) and the World Meteorological Organization (WMO). The results show that there is the marked positive correlation between δ¹⁸O and temperature in the mid-high latitude continent regions, and the marked negative correlation between δ¹⁸O and precipitation in the mid-low-latitude ocean and coast stations.     

Foraminiferal Changes and Response to the Channel Diversion and Discharge Fluctuation of the Yellow River in the North Yellow Sea During the Past Century

Diversion of the Yellow River is a unique geological event in offshore China, causing changes of the sedimentary environment in eastern China Seas. The last diversion took place in AD 1855, with the estuary diverted from the Yellow Sea into the Bohai Sea. The identification of the river diversion events in the shelf sediments would not only provide the definite ages for the sediments, but also give a clue for better understanding of the sedimentation in that area. In this study, 210 Pb, grain size, geochemical element, and foraminiferal data in core H205 from the north Yellow Sea were systematically investigated. A high-resolution sedimentary record was established, which was coupled with the Yellow River diversion and runoff changes. The results show that the foraminiferal composition and foraminiferal abundance of the sediments from the north Yellow Sea had good response to the Yellow River diversion in 1855. Before the change, shallow water assemblages dominated the foraminifera, and the abundance of each foraminiferal species was very low. After the diversion event, the abundance of most foraminifera increased sharply, with a maximum increase of 16 times, and the assemblage was still dominated by shallow water species. Furthermore, the changes in foraminiferal abundance in the core sediments corresponded well with the discharge fluctuation of the Yellow River since 1855. When the Yellow River began entering the Bohai Sea, the Yellow River water, which is rich in nutrients, along with the coastal currents affected the north Yellow Sea, increased the primary productivity in the north Yellow Sea, which is the main reason for the abrupt increase and fluctuation of foraminiferal abundance in this area. At the meantime, the East Asian winter monsoon could also promote the development of nearshore foraminiferal species by enhancing the coastal currents.     

Paleo-fluvial sedimentation on the outer shelf of the East China Sea during the last glacial maximum

Evidence from lithology, foraminiferal assemblages, and high-resolution X-ray fluorescence scanning data of core SFK-1 indicates tidally influenced paleo-fluvial sedimentation during the last glacial maximum (LGM) on the outer shelf of the East China Sea. The paleo-fluvial deposits consist of river channel facies and estuarine incised-valley-filling facies. Different reflections on the seismic profile across core SFK-1 suggest that the river channels shifted and overlapped. River channel deposition formed early in the LGM when sea level fell and the estuary extended to the outer shelf. Channel sediments are yellowish-brown in color and rich in foraminifera and shell fragments owing to the strong tidal influence. Following the LGM, the paleo-river mouth retreated and regressive deposition of estuarine and incised-valley-filling facies with an erosion base occurred. The river channel facies and estuarine incised-valley-filling facies have clearly different sedimentary characteristics and provenances. The depositional environment of the paleoriver system on the wide shelf was reconstructed from the foraminiferal assemblages, CaCO₃ content and Ca/Ti ratio. The main results of this study provide further substantial constraints on the recognition of late Quaternary stratigraphy and land-sea interactions on the ECS shelf.     

Phase evolution of Holocene paleoenvironmental changes in the southern Yellow Sea: Benthic foraminiferal evidence from core C02

Assemblages of benthic foraminifera in a sediment core (C02) near the western margin of the southern Yellow Sea Mud were studied to decipher the phase evolution of Holocene paleoenvironmental changes associated with the Holocene marine transgression. It appears that during the early Holocene (11.2–10.1 kyr BP), the faunal was dominated by low salinity and shallow water species Cribrononion subincertum, Buccella frigida and Ammonia beccarii, reflecting a near coast depositional environment. A rapid increase of the relative abundance of Ammonia compressiuscula between 10.1–9.3 kyr BP indicates that the sea level rose rapidly during that time period. From 9.3–7.7 kyr BP, the benthic foraminiferal assemblage was dominated by high percentage of A. compressiscula, suggesting that the sea level was relatively stable. An obvious transition of benthic foraminifera, from the A. compressiuscula-dominated assemblage to an Ammonia ketienziensis-dominated assemblage, occurred between 7.7–6.2 kyr BP, possibly corresponding to a second sea level rapid rise period in the Yellow Sea during the Holocene. This transition may correspond to the gradually strengthened Yellow Sea warm current (YSWC) and finally is established the modern-type circulation in the Yellow Sea. It may also mark the formation of the Yellow Sea cold bottom water (YSCBW) during that period. Since then, the benthic foraminiferal assemblage based on core C02 was dominated by typical YSCBW species, A. ketienziensis, Astrononion italicum and Hanzawaia nipponica, at 6.2–4 kyr BP. A non-deposition period occurred since ～4 kyr BP, which possibly related to the hydrology changes caused by the East Asia monsoon. The two obvious benthic foraminiferal transitions recorded in core C02 during the early and middle Holocene provide evidence that the Yellow Sea has undergone a two-phase rapid sea level rise during the Holocene marine transgression.     

Sedimentary characteristics of relict deposits on the western South Yellow Sea

Integrated studies of vertical sedimentary sequences, grain sizes, and benthic foraminifera and ostracoda, in combination with AMS 14C dating, and 210Pb and 137Cs analysis were carried out in three vibracores taken from the area of relict deposits on the western South Yellow Sea. The relict sands, which are about 0.4 m thick, overlie on the Early Holocene coastal marsh or tidal flat deposits with an evident erosional interface in between. The middle and upper parts or sometimes the whole of the relict sands have been reworked under the modern dynamic environment. The sedimentation rate varies between 0.20–0.30 cm year-1. The relict sands show a bimodal grain-size distribution pattern in frequency curves, with a sharp peak in the coarse fraction between 3Φ and 4Φ and a secondary peak in the fine fraction of about 7Φ. Of the benthic foraminiferal and ostracod assemblages, the reworked relict sands are characterized by the mixing of the nearshore euryhaline shallow-water species and deeper water species. The erosional interface at the bottom of the relict sands is considered as a regional ravinement surface formed during the transgression in the Early Holocene due to shoreface retreating landwards. The relict sands were accumulated on the ravinement surface during the transgression in the deglaciation period as lag deposits after winnowing and reworking by marine dynamic processes. And the secondary peak of fine fraction in the frequency curve for the relict sands suggests the input of fine-grained sediments during the reworking process. As the conclusion, the relict sands in the study area are interpreted as a type of reworked relict sediments.     

Trophic ecology of small yellow croaker (Larimichthys polyactis Bleeker): stable carbon and nitrogen isotope evidence

The trophic ecology of the small yellow croaker (Larimichthys polyactis) was studied using stable isotope analyses. Samples were collected from July to September 2009 and 34 individuals from eight sites were examined for stable carbon and nitrogen isotopes. Stable carbon isotope ratios (δ13C) ranged from -20.67 to -15.43, while stable nitrogen isotope ratios (δ15N) ranged 9.18-12.23. The relationship between δ13C and δ15N suggested high resource partitioning in the sampling area. Significant differences in stable isotope values among the eight sampling sites may be linked to environmental diversities involving various physical processes (such as ocean current, wind and tide) and different carbon sources. Furthermore, the stable isotope ratios may also explain the ontogenetic variability in diet and feeding, because δ13C and δ15N varied significantly with increasing body size. The findings are consistent with other studies on diet analyses in small yellow croaker. It was also demonstrated that stable isotope analysis could be used to estimate the trophic characters of small yellow croaker in feeding patterns and migrating habits.     

Spatial variation of stable isotopes in different waters during melt season in the Laohugou Glacial Catchment,Shule River basin

To evaluate isotopic tracers at natural abundances by providing basic isotope data of the hydrological investigations and assessing the impacts of different factors on the water cycle, a total of 197 water samples were collected from the Laohugou Glacial catchment in the Shule River basin northwestern China during the 2013 ablation seasons and analyzed their H- and O-isotope composition. The results showed that the isotopic composition of precipitation in the Qilianshan Station in the Laohugou Glacial catchment was remarkable variability. Correspondingly, a higher slope of δ~(18)O-δD diagram, with an average of 8.74, is obtained based on the precipitation samples collected on the Glacier No.12, mainly attributed to the lower temperature on the glacier surface. Because of percolation and elution, the isotopic composition at the bottom of the firn is nearly steady. The δ~(18)O /altitude gradients for precipitation and melt water were -0.37‰/100 m and -0.34‰/100 m, respectively. Exposed to the air and influenced by strong ablation and evaporation, the isotopic values and the δ~(18)O vs δD diagram of the glacial surface ice show no altitudinal effect, indicating that glacier ice has the similar origins with the firn. The variation of isotopic composition in the melt water, varying from -10.7‰ to -16.9‰(δ~(18)O) and from -61.1‰ to -122.1‰(δD) indicates the recharging of snowmelt and glacial ice melt water produced at different altitudes. With a mean value of -13.3‰ for δ~(18)O and -89.7‰ for δD, the isotopic composition of the stream water is much closer to the melt water, indicating that stream water is mainly recharged by the ablation water. Our results of the stable isotopic compositions in natural water in the Laohugou Glacial catchment indicate the fractionations and the smoothing fluctuations of the stable isotopes during evaporation, infiltration and mixture.