中国东北与俄罗斯远东富CO_2矿泉水化学对比

中国东北与俄罗斯远东富CO2矿泉是宝贵的饮用、医用矿水资源。五大连池、长白山天池、俄罗斯远东Primorye地区各泉水水化学特征对比显示,中国东北五大连池与俄罗斯远东Primorye地区出露泉水为低温、微酸、HCO3型、富含Si、Fe、Sr和CO2气体的综合优质饮用矿泉水;长白山天池出露泉水为高温、中性-微碱、HCO3型、富含Si和CO2气体的优质热矿泉水。五大连池和俄罗斯远东富CO2冷矿泉与长白山天池富CO2热矿泉具有相似而不同的形成过程,CO2气体对水化学的形成起了决定性的作用,广泛发育的花岗岩提供了富CO2热泉的物质来源,断层破碎带增加了CO2气体-地下水-花岗岩之间的反应程度,温度仅对可溶性Si有影响。     

Fahlores of the Prasolovka Au-Ag volcanogenic deposit, Kunashir Island, Russian Far East

The chemical study shows that fahlores from the Prasolovka deposit are complex compounds with significant variations in their composition and the proportions of their constituent elements. Based on their major-element composition, they are subdivided into 3 species and 11 inter-and intra-species varieties. The chemical composition of the fahlores in different mineral assemblages from different ore types indicates that As fahlores subsequently replaced by Sb, Te-Sb, and Te fahlores during ore precipitation. The revealed evolution of the ore solutions from the early to late stages testifies that different ores at the Prasolovka deposit were formed under different physicochemical conditions.     

Geochemistry of Thermal Waters of Continental Margin of Far East of Russia

Studied waters belong to warm(T=30-50℃),alkaline(pH=8.9-9.3),low mineralized(TDS235 mg/1)Na-HCO_3 or Na-SO_4-HCO_3 thermal waters with high content of SiO_2(up to 81 mg/l)and F(up to 3.9 mg/1),occur on modern volcano-tectonic rejuvenated areas of Eastern Sikhote-Alin orogenic belt.Low~3He concentration as well as N_2/O_2 and N_2/Ar ratios exclude influence of deep mantle fluid.New rare earth element data constrain our understandmg of water-rock interaction occurring in the water source region.Meteoric origin of waters is proved by stable isotope values varying from-71‰to-136.1‰and from-10.8‰to-18.8‰forδ~2U andδ~(18)O respectively.REE patterns reflect high pH,resultfing from water-rock interaction and oxidative conditions.Calculations of deep aquifer temperature using Na-K and quartz geothermometers show 116.8-131.1°C and 82.2-125.8℃respectively.Presence of deep faults both with abnormal thermal gradient(~45-50 K/km)define unique geochemical shape of thermal waters of Sikhote-Alin,area,where no present volcanic activity is registered.     

俄罗斯远东金属矿床形成条件的古地球动力学分析

根据本区地质构造的新资料,提出了区域板块构造模型。研究了从俯冲到加利福尼亚型转换和由后者又到俯冲的古地球动力学环境更替的意义。这种更替发生在对本区最重要的中—新生代历史时期,对区域成矿带整体乃至一些金属矿床的形成具有重要影响。论证了一些地体性质,尤其是俯冲-增生杂岩对矿床形成的重要意义。     

Geochemistry of mineral water and gases of the Razdolnoe Spa (Primorye,Far East of Russia)

New isotopic and chemical data on the sodium bicarbonate water and associated gases from the Razdolnoe Spa located in the coastal zone of Primorsky Kray of the Russian Far East, together with previous stable isotope data (δ¹⁸O, δD, δ¹³C), allow elucidation of the origin and evolution of the groundwater and gases from the spa. The water is characterized by low temperature (12 °C), TDS – 2.5–6.0 g/L, high contents of B (∼5 mg/L) and F (4.5 mg/L) and low contents of Cl and SO₄. Water isotopic composition indicates its essentially meteoric origin which may comply with an older groundwater that was recharged under different (colder) climatic conditions. Major components of bubbling gases are CH₄ (68 vol%), N₂ (28%) and CO₂ (4%). The obtained values δ¹³C and δD for CO₂ and CH₄ definitely indicate the marine microbial origin of methane. Thus the high methane content in the waters relates to the biochemical processes and presence of a dispersed organic matter in the host rocks. Based on the regional hydrogeology and the geological structure of the Razdolnoe Spa, Mesozoic fractured rocks containing Na–HCO₃ mineral water and gases are reservoir rocks, a chemical composition of water and gases originates in different environmental conditions.     

A geochemical and geophysical approach to derive a conceptual circulation model of CO2-rich mineral waters: A case study of Vilarelho da Raia, northern Portugal

The Vilarelho da Raia-Chaves region, located in northern Portugal adjacent to the Spanish border, is characterized by both hot and cold CO₂-rich mineral waters issuing from springs and drilled wells. The present paper updates the conceptual circulation model of the Vilarelho da Raia cold CO₂-rich mineral waters. Vilarelho da Raia mineral waters, dominated by Na and HCO₃ ions, have formed mainly by interaction with CO₂ of deep-seated mantle origin. The δ ¹⁸O, δ ²H and ³H values indicate that these waters are the result of meteoric waters infiltrating into Larouco Mountain, NW of Vilarelho da Raia, circulating at shallow depths in granitic rocks and moving into Vilarelho da Raia area. The conceptual geochemical and geophysical circulation model indicates that the hot and cold CO₂-rich mineral waters of Chaves (76 °C) and Vilarelho da Raia (17 °C) should be considered manifestations of similar but not the same geohydrological systems. Electronic Publication     

Formation particularities of hypergene ferromanganese nodules: Far East Russia and Vietnam

Ferromanganese nodules (pisolites) form accumulations in basal layers of Pliocene-Quaternary clayey sections of Far East Russia and Vietnam. They are composed of minerals that are in common for both these regions (authigenic vernadite, feroxyhyte, goethite, halloysite, and terrigenous quartz) and minerals that are characteristic of either the northern (authigenic hollandite, lithiophorite, and bernessite) or southern (authigenic alumophorite, lepidocrocite, ferrihydrite, gibbsite, and terrigenous ilmenite) regions. Pisolites are considered to be microbial colonies with Mn and Fe oxides frequently forming biomorphs. The growth of the colonies was accompanied by dying off and mineralization of microorganisms successively from the central toward the peripheral parts of the nodules. The formation of metalliferous pisolites was linked to the oxidizing geochemical barrier developed at the interface between compact sedimentary clays and the underlying porous readily permeable weathered products of basalts.     

On the biostratigraphy of accretionary complexes in the Far East (critical review of several papers)

Being a relatively simple geological discipline, biostratigraphy requires accuracy and sequential logic. The incorrect use of the biostratigraphic method and inaccurate interpretation of biostratigraphic data lead to a distorted understanding of regional tectonics. Frequently occurring errors are analyzed using three recently published works on biostratigraphy of accretionary complexes in the Russian Far East as an example.     

Age and geochemistry of the Early Mesozoic granitoid massifs of the southern Bureya terrane of the Russian Far East

A massif of porhyritic microcline biotite granites located in the southern part of the Bureya (Turan) terrane has an age of 185 ± 1 Ma. The granites are characterized by (K₂O + Na₂O) > 8%, a K₂O predominance over Na₂O, and a moderately differentiated REE distribution pattern ((La/Yb)_n = 14.7–28.5). The obtained age indicates that at least one stage of the Early Mesozoic granitoid magmatism in the Bureya terrane occurred in the Early Jurassic. The formation of early Mesozoic granitoids was presumably related to collision between North Asian and Sino-Korean cratons, and the intervening Amur superterrane, although a subduction origin also cannot be completely ruled out.     

Reconstructions of the Mesozoide structures in the eastern Amur-Okhotsk fold system, Far East

The late Jurassic reconstruction for the Ul’ban synclinorium was proposed based on the lithological and structural similarity of the Upper Permian and Mesozoic complexes of the Yankan-Dzhagdy and Ul’ban lithotectonic zones of the Amur-Okhotsk fold system. It was suggested that the Un’ya-Bom subzone of the Yankan-Dzhagdy LTZ is a fragment of the Ul’ban synclinorium (including its eastern centroclinal closure) that was detached and westward displaced (for 400–600 km) in the first half of the Cretaceous.     

Unfilterable "geoaerosols", their use in the search for thermal, mineral and mineralized waters, and their possible influence on the origin of certain types of mineral waters

 Many articles describing the unusual mobility of solid particles in the subsurface layers of the Earth's crust have been published in the last decades, especially in the geological literature. In an attempt to explain this phenomenon, several hypotheses have been developed. The one closest to the behavior observed in nature is based on quantum mechanics. Based on this phenomenon, a new geological prospecting method called Molecular Form of Elements (MFE) was developed in former Czechoslovakia during the 1970s. It has been widely applied since for various types of prospecting, including the search for thermal and mineral waters. When using the MFE method for prospecting, the relationship between the ascending mineral springs and the four directions of structural faults was discovered. The possibility of whether a process, similar to the one acting during the absorption of elements when using the MFE method, can be a source of dissolved solid particles during the creation of mineral waters is also discussed. Received: 3 March 2000 · Accepted: 11 July 2000     

俄罗斯远东岗仁地体金铜矿床地质、地球化学特征及其LA-ICP-MS 锆石U-Pb 年龄

岗仁地体位于额尔古纳超地体北部边缘,蒙古—鄂霍茨克构造带南部,该区分布着大量的大型、超大型金矿床,这些矿床在成因上与中酸性侵入岩和浅成次火山岩关系密切。岩石地球化学研究表明,花岗闪长岩-闪长岩组合明显富集大离子亲石元素、不相容元素和轻稀土元素,亏损高场强元素和重稀土元素。球粒陨石标准化稀土配分模式为轻稀土元素富集、重稀土元素亏损的右倾型,具有微弱的负Eu异常或基本无Eu异常,无Ce异常,元素地球化学性质反映出花岗闪长岩-闪长岩组岩浆具有壳幔混合的特征,且形成于大陆边缘的火山弧环境。LA-ICP-MS锆石U-Pb测年结果揭示,皮奥涅尔金银矿床含矿闪长玢岩的206Pb/238U年龄加权平均值为113.8±2.0Ma,博尔古利坎铜金钼矿床赋矿二长闪长斑岩的206Pb/238U年龄加权平均值为112.7±2.8Ma,与皮奥涅尔金银矿床和博尔古利坎铜金钼矿床成矿有关的奥列佳花岗闪长岩体的年龄分别为117.2±1.3Ma和117.0±3.6Ma。由此可知,皮奥涅尔金银矿床和博尔古利坎铜金钼矿床形成于燕山早期,与中国黑龙江地区三道湾子金矿、东安金矿等金矿床形成时代一致。     

俄罗斯远东岗仁地体金铜矿床地质、地球化学特征及其LA-ICP-MS锆石U-Pb年龄

岗仁地体位于额尔古纳超地体北部边缘,蒙古—鄂霍茨克构造带南部,该区分布着大量的大型、超大型金矿床,这些矿床在成因上与中酸性侵入岩和浅成次火山岩关系密切。岩石地球化学研究表明,花岗闪长岩-闪长岩组合明显富集大离子亲石元素、不相容元素和轻稀土元素,亏损高场强元素和重稀土元素。球粒陨石标准化稀土配分模式为轻稀土元素富集、重稀土元素亏损的右倾型,具有微弱的负Eu异常或基本无Eu异常,无Ce异常,元素地球化学性质反映出花岗闪长岩-闪长岩组岩浆具有壳幔混合的特征,且形成于大陆边缘的火山弧环境。LA-ICP-MS锆石U-Pb测年结果揭示,皮奥涅尔金银矿床含矿闪长玢岩的206Pb/238U年龄加权平均值为113.8±2.0Ma,博尔古利坎铜金钼矿床赋矿二长闪长斑岩的206Pb/238U年龄加权平均值为112.7±2.8Ma,与皮奥涅尔金银矿床和博尔古利坎铜金钼矿床成矿有关的奥列佳花岗闪长岩体的年龄分别为117.2±1.3Ma和117.0±3.6Ma。由此可知,皮奥涅尔金银矿床和博尔古利坎铜金钼矿床形成于燕山早期,与中国黑龙江地区三道湾子金矿、东安金矿等金矿床形成时代一致。     

Heavy clastic minerals from the Far East island-arc complexes

The results of the study of heavy clastic minerals from the Cretaceous-Paleogene terrigenous complexes of Sikhote-Alin and Kamchatka, as well as from the Cenozoic sediments of the deepwater Vanuatu Trench, are summarized. The data obtained have been interpreted on the basis of their comparison with heavy mineral assemblages of recent sediments deposited in known geodynamic settings. It is shown that the heavy clastic minerals of sedimentary rocks, their relative quantities, and chemical compositions may serve as reliable indicators of different island-arc settings and magmatic processes; these indicators may also be used for identification of such settings in paleobasins of orogenic regions.     

中-东西伯利亚及俄罗斯远东地区构造和成矿作用的研究进展

俄罗斯地质学家在近20年来以岩石圈板块构造理论和地体分析方法,对中-东西伯利亚和俄罗斯远东地区构造和区域成矿作用的研究取得了一系列重要进展。这些进展集中体现在2个多国合作项目取得的成果和2部最新的科学专著中。作者重点介绍了中-东西伯利亚和俄罗斯远东地区区域构造演化、区域构造和区域成矿单元及一些重要金属矿床的基本特征,并对本区地质演化的某些重要问题（转换陆缘、蒙古-鄂霍茨克造山带等）做了讨论,以此向读者提供一个有关俄罗斯东部地区上述领域基本研究现状的梗概。     

Paleogeography of the Bureya Foredeep (in the Far East) in the Jurassic

Using the standard methods of paleogeographic analysis, small-scale paleogeographic sketch maps of the Verkhnyaya Bureya and Gudzhik depressions of the Bureya Foredeep are compiled for the Pliensbachian, Bajocian-Bathonian, Callovian, and Tithonian ages of the Jurassic. Marine sedimentation settings that existed during the Late Triassic and the major part of the Jurassic are characterized.     

东昆仑埃坑德勒斯特二长花岗岩岩石地球化学特征及岩石成因

埃坑德勒斯特铜（钼）矿是近年来在东昆仑地区发现的斑岩型铜（钼）矿,矿区位于东昆南复合拼贴带内,花岗斑岩及外围碎裂的二长花岗岩是主要的赋矿围岩。对二长花岗岩进行了岩石地球化学和Sr-Nd同位素研究,讨论了岩浆来源、岩石成因和构造背景。研究表明,岩石富硅,相对富钠贫钙和镁,属钙碱性过铝质系列岩石。岩石明显富集大离子亲石元素（K、Ba、Rb）和活泼的不相容元素（如Th、U）,相对亏损高场强元素（Nb、Ta、P、Ti）。样品的ISr值为0.707 05~0.707 37,εNd（t）为-2.2~-1.6,Rb/Sr为0.17~0.32,反映岩浆来源具壳幔混合特点。根据Y+Nb-Rb、La/Nb-Ba/Nb等判别图解及与俯冲有关的蛇绿岩带发育特征,表明该岩体形成于安第斯型活动大陆边缘环境。俯冲作用导致俯冲板片的流体降低熔点和直接交代地幔,使地幔部分熔融形成基性岩浆。幔源岩浆底侵作用提供热能,使基性下地壳物质部分熔融形成花岗质岩浆,其中混入了少量幔源岩浆。     

东天山成矿规律与找矿方向的初步研究

根据对东天山1500多处矿产地时空分布规律的初步研究,认为东天山具有矿产资源丰富、矿种多,铁铜镍煤盐等优势矿产比较明显、矿床类型较全、成矿历史悠久、空间分布相对集中且呈“南铁北铜东镍中间金”的特点。鉴于东天山地区基础地质工作程度偏低。科学研究深度不够,根据其地质演化规律和区域对比,认为东天山地区今后的找矿工作既要重视深入研究典型矿床,在查明矿床成因的基础上建立成因模式、找矿模型和综合评价模型,也要不同矿种之间、先后地质时代之间、相邻成矿区带之间相互借鉴,开拓思路,以期取得新进展。建议国家和相关产业部门以铁、铜为导向,集中目标开展找矿会战并带动其他矿种实现找矿新突破。     

New concepts on the composition, structure, and age of the Lower Amur fragment of the Late Jurassic-Early Cretaceous accretionary prism, Russian Far East

On the basis of geological observations and the study of conodont and radiolarian microfauna, a new stratigraphic scheme was proposed for the Mesozoic deposits of the Komsomolsk district of the Amur region. The lower Khorpy Group (T₂-J₃) consists of two units: the Boktor (T₂-J₂) and Kholvasi (J_2–3). The Boktor Sequence (400 m thick) is represented by pelagic cherts with an admixture of cherty-clayey shales and volcanic rocks. The Kholvasi Sequence (500 m thick) is built up of the predominant siltstones and clayey shales with rare intercalations and lenses of clayey cherts and cherty-clayey shales. The upper Komsomolskaya Group (K₁) has a terrigenous composition and includes the Gorin, Pionerskaya, and Pivan formations of 5 km total thickness. It is made up of intercalated sandstones, siltstones, mudstones, and often turbidites (proximal to distal). The rocks contain abundant buchia fauna of Volgian-Valanginian age, as well as carbonized plant detritus and flora of the Early Cretaceous habit. The described complex is characterized by a nappe-fold structure typical of the accretionary prisms in the ocean-continent convergence zones. The predominance of the coherent type of accretionary prisms reflects the simple morphology of the oceanic plate.     

Geochemistry of carbonated mineral waters from the Fadeevskoe deposit of the Primorye region

The geochemical study of bed rocks, underground and surface waters, and associated gases in the Fadeevskoe deposit of carbonated waters (Sikhote Alin, Primorye region) revealed that the chemical composition of these waters is formed in the zone of active water exchange in the limited area of the discharge zone, where hydro carbonate calcic waters with mineralization of up to 1 g/1 are formed in largely potassic-sodic rocks. Calculations of the saturation indices show that the mineral waters are characterized by the early stage of Ca saturation, being undersaturated with carbonates and aluminosilicates. The main factors that influence the water mineralization are the excess carbon dioxide in water and the circulation time. The oxygen and carbon isotope ratios indicate the atmospheric genesis of the aqueous component (δ²H = —117; δ¹⁸O = —15.4%o) and the carbon isotope content in the CO₂ implies the mantle nature of the carbon dioxide (δ¹³C = -9.9%o).