共查询到20条相似文献,搜索用时 46 毫秒
1.
P. Sriramachandran S. P. Bagare N. Rajamanickam K. Balachandrakumar 《Solar physics》2008,252(2):267-281
High-resolution Fourier Transform Spectrometer sunspot umbral spectra of the National Solar Observatory/National Optical Astronomy
Observatory at Kitt Peak were used to detect rotational lines from 19 electronic transition bands of the molecules LaO, ScO
and VO, in the wavenumber range of 11 775 to 20 600 cm−1. The presence of lines from the following transitions is confirmed: A
2
Π
r1/2 – X
2
Σ
+(0, 0; 0, 1), A
2
Π
r3/2 – X
2
Σ
+(1, 0), B
2
Σ
+ – X
2
Σ
+(0, 0; 0, 1; 1, 0) and C
2
Π
r1/2 – A′2Δ
r3/2(0, 0; 1, 1) of LaO; A
2
Π
r3/2 – X
2
Σ
+(0, 0), A
2
Π
r1/2 – X
2
Σ
+(0, 0) and B
2
Σ
+ – X
2
Σ
+(0, 0) of ScO; and C
4
Σ
− – X
4
Σ
−(0, 1; 1, 0; 0, 2) and (2, 0) of VO. However, the presence of A
2
Π
r3/2 – X
2
Σ
+(0, 0) and C
2
Π
r3/2 – A′2Δ
r5/2(0, 0; 1, 1) of LaO and C
4
Σ
− – X
4
Σ
−(0, 0) of VO are found to be doubtful because the lines are very weak, and detections are difficult owing to heavy blending
by strong rotational lines of other molecules. Equivalent widths are measured for well-resolved lines and, thereby, the effective
rotational temperatures are estimated for the systems for which the presence is confirmed. 相似文献
2.
F. Partal Ureña M. Fernández Gómez J.J. López González N. Rajamanickam 《Astrophysics and Space Science》2000,272(4):345-352
The Franck-Condon (FC) factors and r-centroids for the bands systemC
1
Σ
+
→ X
1
Σ
+ of AlD and E
2
Π → X
2
Σ
+ of CaH have been evaluated by means of a reliable numerical integration procedure by using a suitable potential. The dissociation
energy, D
e, for the electronic ground states of AlD and CaH have been estimated by the curve fitting method to the RKRV experimental
potential curve turning out to be 3.01 eV and 2.32 eV, respectively.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
3.
B. Karthikeyan V. Raja N. Rajamanickam S. P. Bagare 《Astrophysics and Space Science》2006,306(4):231-234
For molecular identification in astrophysical sources, an astrophysicist needs some spectroscopic parameters such as dissociation
energy, vibrational or rotational temperature of the source, band or line wavelengths, transition probability parameters,
etc. The Franck-Condon(FC) factors are proportional to the transition probabilities. In this study, the FC factors and r-centroids for the vibronic (vibration-electronic) transitions C
1 Σ + → X
1 Σ + of aluminium hydride (AlH), b
3 Σ ( −) → a
3 Π, C
1 Σ + → A
1 Π & C
′1 Δ → Δ 1 Π of boron hydride (BH) have been evaluated and the results are presented in tables which include band origin/head wavelengths.
The physical & astrophysical significances of our evaluated FC factors & r-centroids have been discussed and the possible presence of AlH in sunspot umbral spectra is also predicted.
PACS: 33 · 70 · Ca 相似文献
4.
R.R. Reddy Y. Nazeer Ahammed B. Sasikala Devi K. Rama Gopal P. Abdul Azeem T.V.R. Rao 《Astrophysics and Space Science》2002,281(4):729-741
The true experimental potential energy curves for the electronic ground states of astrophysically important TaO, TaS, ZrS
and SiO+molecules are constructed by using the Rydberg–Klein–Rees method as modified by Vanderslice et al. The ground state dissociation
energies are determined by curve fitting techniques using the five parameters Hulburt-Hirschfelder (H-H) function. The estimated
dissociation energies are 8.19 ± 0.17, 6.9 ±0.14, 5.89 ± 0.12 and 5.75 ± 0.12 eVfor TaO, TaS, ZrS and SiO+ respectively. These values are in good agreement with the literature values. The r-centriods and Franck–Condon factors (FC
Factors) for the bands of K
2
φ
5/2
- X
2
Δ
3/2
(K-X) system of TaO, A-X
2 Δ (A-X) and B-X
2 Δ (B-X)systems of TaS, B
1 Π - X1 Σ+
(B-X) system of ZrS and B
2Σ+ - X2 Σ+
(B-X) and A
2 Π - X2 Σ+
(A-X)systems of SiO+ molecules have been calculated. The Franck–Condon factors (FC factors) are evaluated by the approximate analytical methods
of Jarmain and Fraser. The absence of the bands of these systems is explained.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
5.
R.R. Reddy Y. Nazeer Ahammed K. Rama Gopal D. Baba Basha 《Astrophysics and Space Science》2003,286(3-4):419-436
The experimental potential energy curves for the different electronic states of molecules like CN, CO and CS observed in comets
are constructed by using the Rydberg-Klein-Rees method as modified by Vanderslice et al. The ground state dissociation energies
are determined by curve fitting technique using the five parameter Hulburt-Hirschfelder (H-H)function. The estimated dissociation
energies are 7.63 ± 0.187, 10.95 ±0.224 and 7.27 ± 0.152 eV for CN, CO and CS respectively. These values are in good agreement
with the literature values. Estimated dissociation energies of CN, CO and CS are used in the relation given by Gaydon and
ionization potentials are evaluated for CO and CS molecules. The estimated ionization potentials are 13.92and 12.15 eV for
CO and CS molecules respectively. The r-centroids and Franck-Condon factors (FC Factors) for the band system of a 3Πr – X1Σ+ (a – X) and A1Π – X 1Σ+ (A -X) of CN, A 2Πi – X2Σ+ (A – X) and B2Σ+-X2Σ+ (B – X) of CO and a 3Πr – X1Σ+ (a – X) of CS molecules have been calculated employing an approximate analytical methods of Jarmain and Fraser and Nicholls
and Jarmain. The absence of the bands in these systems are explained.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
6.
The Franck-Condon factors and r-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable
numerical integration procedure for the bands of B
2∑+ − X
2∑+, F
2∑+ − X
2∑+ systems of SrF and C
1∑+ − X
1∑+, G
1Π − X
1∑+ systems of ScF molecules of astrophysical interest, using a suitable potential. 相似文献
7.
The potential energy curves for theX
2 Σ+ andB
2 Σ+ states of CO+ have been constructed by the Rydberg-Klein-Rees (RKR) method as modified by van der Sliceet al. The dissociation energy is estimated to be 7.70±0.19 eV by the method of curve fitting using the five parameter Hulburt-Hirschfelder’s
function. The estimated value is in good agreement with the value (7.839 eV) given by Misraet al. Carefull observation of the results reveals that accurateD
0 value for CO+ is 8.33 eV 相似文献
8.
P. Sriramachandran R. Shanmugavel S. P. Bagare N. Rajamanickam 《Astrophysics and Space Science》2009,323(1):41-49
A high resolution spectrum of a sunspot umbra is used for identification of rotational lines due to (0, 0) band of the A
2Π–X
2Σ+ system and (0, 0), (1, 1), and (2, 2) bands of the B
2Σ+–X
2Σ+ system of the molecule SrF. The published sunspot umbral spectrum obtained with Fourier Transform Spectrometer and solar
telescope of National Solar Observatory/National Optical Astronomy Observatory at Kitt Peak was used for the study. The new
identification of more than 200 SrF lines in the umbral spectrum confirms that this molecule accounts for the majority of
lines in the spectral range 15050 to 15360 cm−1 and 17240 to 17300 cm−1. Equivalent widths have been measured for well-resolved lines of these bands and the effective rotational temperatures have
been estimated for which the presence is confirmed. 相似文献
9.
The Franck-Condon factors and r-centroids, which are very closelyrelated to relative vibrational transition probabilities, have beenevaluated by the more reliable numerical integration procedure forthe bands of c
1 - a
1 and f
1 - a
1 systems of CN
+ and C
2 +
u- X
2 +
g and D
2 g- A
2 u systems of N
+
2 molecular ions of astrophysical interest,using a suitable potential. 相似文献
10.
Ther-centroids and Franck-Condon factors for the bands of theA
2 –X
2+ of CP,C
3 –X
3 of SiC, andB
2+ –X
2+ of CO+ molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained. 相似文献
11.
The zirconium oxide (ZrO) is well known for its astrophysical importance. The radiative transition parameters that include
Franck-Condon (FC) factor, r-centroid, electronic transition moments, Einstein coefficient, band oscillator strengths, radiative
life time and effective vibrational temperature have been estimated for e
1Π–X
1Σ+ and 1Σ+–X
1Σ+ band systems of 90ZrO molecule for the experimentally known vibrational levels using RKR potential energy curves. A reliable numerical integration
method has been used to solve the radial Schr?dinger equation for the vibrational wave functions of upper and lower electronic
states based on the latest available spectroscopic data and known wavelengths. The estimated radiative transition parameters
are tabulated. The effective vibrational temperatures of these band systems of 90ZrO molecule are found to be below 4200 K. Hence, the radiative transition parameters help us to ascertain the presence of
90ZrO molecule in the interstellar medium, S stars and sunspots. 相似文献
12.
Fabry-Pérot interferograms of comet Hale-Bopp were obtained on several nights in March and April 1997. For this purpose we
utilized the 2-channel focal reducer of the Max-Planck-Institute for Aeronomy at the 2-m telescope of the Pik Terskol Observatory.
Solid Fabry-Pérot etalons of resolving power 30000 were used in both channels of the focal reducer. The main aim of this study
is to measure the velocities and abundances of OH+ and H2O+, both ions closely related to the same parent molecule, H2O. In the blue channel interferograms we identified several individual OH+ rotational lines of the A3Πi - X3Σ− (0-0) transition and measured their Doppler shifts. The target emissions in the red channel were the H2O+ lines of the A2A1 − X2B1 (10-0) band. We found that the line of sight velocities, obtained from the Doppler shifted wavelengths of emissions in the
comet are higher in sunward direction than in the plasma tail and do not exceed 20 km s–1. The corresponding values, deprojected in antisolar direction, are consistent with predictions by magnetohydrodynamical models
of the solar-wind-comet interaction, when one accounts for the extremely high gas production rate of comet Hale-Bopp.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
13.
Antonie Dinculescu 《Astrophysics and Space Science》2004,293(4):423-432
If one attributes to each component i of a gravitational system a dimensionless parameter ψ
i
equal to the ratio of its relative mass (with respect to the mass of the system) to its relative position (with respect to
a generally defined radius) and sums up the ψ
i
values of all components outside the central core, one obtains a mass distribution index Σψ of the order of unity irrespective
of the size or the type of the system. In the case of spiral galaxies (and probable other galactic systems) this property
applies not only to the whole galaxy, but also to the matter inside any radius larger than the core radius. The mass distribution
index in these systems has a maximum Σψ* at a certain radius r
*, which strongly correlates with the surface brightness at r
* in galaxies with similar mass to light ratio. The gravitational acceleration of all galaxies at r
* divided by (Σψ*)2 is constant and approximately equal to MOND acceleration parameter. Also, at this radius all galaxies have a surface temperature
of the order of the temperature of the cosmic microwave background radiation.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
14.
P. D. Singh 《Astrophysics and Space Science》1984,102(2):287-293
The24MgH+ (A
1+ –X
1+) molecular lines have been identified in the photospheric spectrum. The rotational excitation temperature determined from the analysis of molecular line intensities of24MgH+ is found to be of the order of 4850 K which corresponds to the photospheric temperature of the Sun. The CNDO/2 dipole moments of24MgH+ for internuclear distance range: (1.3–2.1) Å in theX
1+ state can be approximated byM(R)=4.92+1.33R. Estimations for the spontaneous emission Einstein coefficients (A
v v
) and the absorption oscillator strengths (f
v v
) for the (1, 0), (2, 0), and (2, 1) transitions in theX
1+ state of the24MgH+ ion are also made.Work partially supported by the CNPq, Brasilia under contract number 30.4076/77. 相似文献
15.
The Franck-Condon factors andr-centroids, which are very closely related to vibrational transition probabilities, have been evaluated by the more reliable
numerical integration procedure for the bands of A
2 Δ - X2 πr system of astrophysical molecule GeH, using a suitable potential. The dissociation energy for the electronic ground state
of astrophysical molecule GeH has been estimated precisely as D
0
0 = 2.69 ± 0.05 eV by fitting the empirical potential function to the experimental potential energy curve using correlation
coefficient.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
16.
R.R. Reddy Y. Nazeer Ahammed K. Rama Gopal P. Abdul Azeem S. Anjaneyulu 《Astrophysics and Space Science》1998,262(2):223-240
The potential energy curves for the electronic ground states of astrophysically important YO, CrO, BN, ScO, SiO and AlO molecules are constructed techniques using the five-parameter Hulburt-Hirschfelder function. The estimated dissociation energies are 7.235±0.15, 4.337 ± 0.09, 3.917 ± 0.09, 6.899 ± 0.14, 8.181 ± 0.17 and 5.202 ± 0.11 eV for YO, CrO, BN, ScO, SiO and AlO, respectively. The estimated D0 values are in reasonably good agreement with literature values. The r-Centroids and Franck-Condon factors for the bands of B2 + – X2 + of YO, B5 –X5 > of CrO, A3 – X3 of BN, B2 + –X2 + of ScO, E1 + – X1 + of SiO and D2 + – X2 + and B2 + –X2 + of AlO molecules have been determined. The Franck-Condon factors are evaluated by the approximate analytical method of Jarmain and Fraser. The absence of the bands in these systems is explained. 相似文献
17.
A high-resolution spectrum clearly shows the presence of A
6Σ+–X
6Σ+(0,0;0,1;1,0;2,0;2,1) and (2,2) bands system of CrH molecular lines in the spectral range 10,000 cm−1 to 14,050 cm−1. At least 3928 lines of the six bands, accounting for 57% of the lines registered in the laboratory can be identified with
certainty in the sunspot spectrum. Most of the lines are found blended with TiO, CaH, MgH and other atomic species. These
molecular lines are typically much more temperature sensitive than atomic lines, which make them ideal, complementary tool
for studying cool stellar atmospheres as well as the internal structure of sunspots. Equivalent width for an adequate number
of well identified molecular lines of these bands using the Gaussian-profile approximation method versus rotational quantum
number J has been used to determine the effective rotational temperature of the CrH molecule. The range of effective rotational temperature
value obtained from these bands is 1766 K to 2442 K. This range agrees well with the effective rotational temperatures derived
for other molecules in sunspot umbrae. 相似文献
18.
A new class of charged super-dense star models is obtained by using an electric intensity, which involves a parameter, K. The metric describing the model shares its metric potential g 44 with that of Durgapal’s fourth solution (J. Phys. A, Math. Gen. 15:2637, 1982). The pressure-free surface is kept at the density ρ b =2×1014 g/cm3 and joins smoothly with the Reissner-Nordstrom solution. The charge analogues are well-behaved for a wide range, 0≤K≤59, with the optimum value of X=0.264 i.e. the pressure, density, pressure–density ratio and velocity of sound are monotonically decreasing and the electric intensity is monotonically increasing in nature for the given range of the parameter K. The maximum mass and the corresponding radius occupied by the neutral solution are 4.22M Θ and 20 km, respectively for X=0.264. For the charged solution, the maximum mass and radius are defined by the expressions M≈(0.0059K+4.22)M Θ and r b ≈−0.021464K+20 km respectively. 相似文献
19.
Jacques Laskar 《Celestial Mechanics and Dynamical Astronomy》2005,91(3-4):351-356
Recently, Breiter et al. [Celest. Mech. Dyn. Astron., 2004, 88, 153–161] reported the computation of Hansen coefficients X
k
γ ,m
for non-integer values of γ. In fact, the Hansen coefficients are closely related to the Laplace b
s
(m), and generalized Laplace coefficients b
s,r
(m) [Laskar and Robutel, 1995, Celest. Mech. Dyn. Astron., 62, 193–217] that do not require s,r to be integers. In particular, the coefficients X
0
γ ,m
have very simple expressions in terms of the usual Laplace coefficients b
γ +2
(m), and all their properties derive easily from the known properties of the Laplace coefficients. 相似文献
20.
The reactivity of C2(X1Σ+g) with simple saturated (CH4, C2H6 and C3H8) and unsaturated (C2H2 and C2H4) hydrocarbons has been studied in the gas phase over the temperature range 24-300 K using the CRESU (Cinétique de Réaction en Ecoulement Supersonique Uniforme or Reaction Kinetics in a Uniform Supersonic Flow) technique. All reactions have been found to be very rapid in this temperature range and the rate coefficients are typically ?10−10 cm3 molecule−1 s−1 with the exception of methane for which the rate coefficient is one order of magnitude lower: ∼10−11 cm3 molecule−1 s−1. These results have been analyzed in terms of potential destruction sources of C2(X1Σ+g) in the atmospheres of Titan and the Giant Planets. It appears that the rate coefficient of the reaction 1C2 + CH4 should be updated with our new data and that reactions with C2H2, C2H4 and C2H6 should also be included in the existing photochemical models. 相似文献