淮河下游地区地表水与地下水同位素特征分析

为探明淮河下游地区地表水与地下水稳定同位素的组成特征,于2020年11月对该区域进行代表性采样,共采集地表水样13个,地下水样82个.结合全球大气降水同位素监测网(GNIP)公布的南京降水同位素数据,根据最小二乘法得出当地大气降水线(LMWL)方程为:δD=8.49δ18O+17.71,其斜率和截距高于全球大气降水线(...     

Study of stable isotopes for highly deformed aquifers in the Hsinchu-Miaoli area, Taiwan

This study was based on the analysis of isotopic compositions of hydrogen and oxygen in samples from precipitation, groundwater and stream water. In addition, parts of groundwater samples were dated by carbon-14 and tritium. These data are integrated to provide other views of the hydrologic cycle in the Hsinchu-Miaoli groundwater district. The groundwater district is principally composed of Pleistocene and Holocene aquifers. The Pleistocene aquifers are highly deformed by folding and faults into small sub-districts with areas of only tens of square kilometers. These aquifers are exclusively recharged by local precipitation. The Holocene aquifers cover narrow creek valleys, only tens of meters in thickness. The local meteoric water line (LMWL), constructed from rainfall samples in the Hsinchu Science Park, is described by the equation δD=8.02δ¹⁸O+10.16, which agrees with the global meteoric water line. In addition, the precipitation isotopic compositions can be categorized into two distinct end members: typhoon type and monsoon type. The groundwater isotopic compositions are perfectly located on an LMWL and can be considered a mixture of precipitations. Based on the mass balance of isotopic compositions of oxygen and hydrogen, infiltration is more active in the rainy season with depleted isotopic compositions. The amount of infiltration during May–September is roughly estimated to comprise at least 55% of the whole year’s recharge. The isotopic compositions of stream water are expressed by a regression equation: δD=7.61δ¹⁸O+9.62, which is similar to the LMWL. Although precipitation isotopic compositions are depleted during summer time, the isotopic compositions contrarily show an enriched trend in the upstream area. This is explained by the opposite altitude effect on isotopic compositions for typhoon-related precipitations.     

猪毛菜在不同降水条件下的水分来源差异研究

通过测定大柴旦与都兰地区猪毛菜木质部水分及其不同潜在水源的稳定性氢氧同位素值,利用多源线性混合模型分析不同水分来源对猪毛菜的贡献率.研究结果表明:大柴旦地区大气降水线为y=7.565x+4.796(R²=0.908),都兰地区大气降水线为y=6.005x-7.856(R²=0.7391),说明两个地区都存在较强的蒸发作用.但是,都兰地区较大柴旦风速大,温度高,雨水蒸发速度快,造成雨水δ¹⁸O偏高,形成比大柴旦地区斜率更小的当地大气降水线.大柴旦和都兰地区的猪毛菜,在两个样地的用水策略上存在显著差异.在降水较少的大柴旦地区,猪毛菜以土壤水为主要水源.在降水较多的都兰地区,则以降水为主要水源.就其对土壤水的使用情况来看,大柴旦的猪毛菜多利用深层土壤水,而都兰地区的猪毛菜却对表层土壤水利用比例较大.两地猪毛菜在生长季的不同时期都存在对利用水源的转换现象.为适应不同地区降水量的变化,猪毛菜根据不同水源调节利用比例.降水格局的改变将导致猪毛菜的水分利用策略发生适应性的变化.     

中国西南季风区不同水体稳定同位素特征分析——以重庆市北碚区为例

通过对重庆市北碚区大气降水和马鞍溪上游龙滩子水库水的氢氧同位素进行的一个水文年（2014年）的样品采集监测,研究了降水与水库的水的氢氧同位素之间的变化特征和规律。结果表明:(1)北碚区大气降水线方程为δD=8.82δ18O+18.97,r=0.99,n=101,P<0.01,δD、δ18O相关性极为显著,该区大气降水线斜率和截距大于全球大气降水线和中国大气降水线,表明研究区主要受西南季风和东南季风双重影响所致;(2)大气降水中δD、δ18O具有明显的季节变化,夏半年偏负,冬半年偏正;(3)大气降水中的δD、δ18O与降水量及温度呈现负相关关系,降水量效应显著,并且该效应远远掩盖了温度效应;(4)水库中水的δD、δ18O具有极好的相关性,其δD、δ18O样点落于全球大气降水线和区域大气降水线附近,并且水库中水d的变化趋势与降水d基本一致,表明前者主要补给来源是降水,而水库中水的δD、δ18O和d的变化幅度远远小于降水,表明前者不仅受降水补给,还受土壤水和地下水的补给。      

哈尼梯田麻栗寨河流域雨季大气降水氢氧同位素特征及影响因素

以红河哈尼梯田文化景观遗产核心区麻栗寨河流域的雨季大气降水为研究对象,对2014年雨季典型月7月的氢氧同位素组成进行了分析,拟合出大气瞬时降水线方程,并与邻近地区及全国、全球降水线方程进行对比,分析温度、湿度、降水量等气象参数和海拔对氢氧稳定同位素的影响,并初步判断该区的水汽来源。结果表明：（1）研究区雨季大气降水δ¹⁸O值变化范围大,与邻近的昆明、贵阳、成都地区相比,贫化明显;（2）大气降水线方程为δD=7.59δ¹⁸O+3.31,其斜率和截距较小,说明研究区雨季降水量大且蒸发强烈、降水的水汽来源非单一化,除受印度洋、孟加拉湾的变热性热带海洋气团的影响,还受研究区地表水体的二次蒸发影响;（3）研究区降水稳定同位素特征显示不但存在明显的降水量效应,也存在温度效应和海拔效应,但各因素是综合作用的,主导因素不明显。     

Isotopic effect of runoff in the Yarlung Zangbo River

This paper mainly analyzed the isotopic effect of precipitation in the Yarlung Zangbo River.On the whole,the isotopic compositions of most water samples fall on the upper right of the global meteoric water line.According to δD and δ18O data of the samples,the precipitation equation is figured out as δD=8 δ18O+10,showing that they are derived from precipitation but have experienced intensive evaporation.With obvious region-continental effect(a continuous depletion in heavy isotopes in water bodies occurs with increasing distance from the coast),the water presents a reducing trend of δD and δ18O westwards and southwards.Altitudinal effect is evident here,occur-ring in both trunk stream and main branches of the Yarlung Zangbo River.The distribution of water isotopic compo-sitions is concerned with the movement of precipitation clouds from the Bay of Bengal and the Nujiang River and is affected by the topographic and climatic conditions of the Tibetan Plateau.     

黑河上游降水同位素特征及其水汽来源分析

为了加深对黑河上游水循环过程的理解, 以研究区5个站点2015年8月至2016年8月的降水同位素实测数据和气象数据为基础, 除对降水同位素特征进行分析外, 主要利用TrajStat软件中的后向轨迹计算模块与潜在源贡献因子分析（PSCF）方法, 对研究区降水的水汽来源进行了分析, 并结合水汽通量等方法进行了补充分析。结果表明： 降水同位素呈夏高冬低趋势, 大气水线斜率（8.02）和截距（11.02）均高于全球大气水线的斜率（8.00）和截距（10.00）, 存在温度效应（δ¹⁸O=0.43x-10.82, r=0.54, P<0.0001）, 不存在降水量效应（δ¹⁸O=-0.05x-7.81, r=0.03, P<0.0001）; 研究区降水受多种水汽影响, 西风水汽影响最大。夏季除受西风水汽影响外, 还受东南季风水汽影响显著且水汽来源复杂; 研究区夏季的潜在蒸发源地集中在一些相对湿度和蒸发量较大的地区, 如祁连山区、 河西地区、 柴达木盆地北部、 青藏高原东南部及酒泉地区西南部等; 当降水量小、 温度高时, 持续性降水的大气水线方程的斜率和截距较小, 暴雨稳定同位素值较贫化, 受东南季风水汽影响最大, 其次是北方和西风水汽, 多种水汽辐合是暴雨事件发生的必要条件。     

热分层效应控制的水库水体氢氧同位素特征

为掌握水库热分层与氢氧同位素空间分布的关系,研究了广西兴安县五里峡水库夏季氢氧同位素空间分布特征及影响因素。研究表明:①五里峡水库夏季出现明显的热分层,库表层至-5 m为表水层,-5 m至-20 m为温跃层,-20 m以下为底温层;②五里峡水库δ18O、δD值沿大气降水线分布,但均落在桂林市大气降水线右下方,其线性方程为δD=4.66δ18O-10.85（R2=0.76）,其斜率与全球大气降雨线（GMWL）和桂林市降雨线（CLMWL）的斜率和截距差异明显,表明五里峡水库主要由降水补给,但在补给五里峡水库前已经过了强烈的蒸发作用和水岩作用;③ δ18O、δD随水深的增加逐渐偏负,具有表水层 > 入库水体 > 温跃层 > 底温层 > 出库水体（>表示偏正）的垂向分布特征。分析认为入库水体氢氧同位素的季节变化和蒸发作用随深度增加而降低是五里峡水库夏季分层期间水体氢氧同位素垂向变化的主要影响因素。     

Oxygen and hydrogen isotopes for the characteristics of groundwater recharge: a case study from the Chih-Pen Creek basin,Taiwan

Assessing the seasonal variation of groundwater recharge is important for effective management of groundwater resources. Stable isotopes of oxygen and hydrogen were used to estimate the sources of groundwater and seasonal contributions of precipitation to groundwater recharge in Chih-Pen Creek basin of eastern Taiwan. Based on the isotopes of precipitation (n = 177), two different local meteoric water regression lines (LMWL) can be obtained for the different seasons: δD = 8.06¹⁸O + 10.08 for wet season precipitation (May through October) and δD = 8.65δ¹⁸O + 17.09 for dry season precipitation (November through April). The slope and intercept of regression line for wet season precipitation are virtually identical to the global meteoric water line (GMWL) of Craig (1961). In contrast to during dry season precipitation due to evaporation effect the intercept of 17.09 is much higher than of the GMWL of 10. The results show the stable isotopes compositions of precipitation decrease with increasing rainfall amount and air temperature, due to the amount effect of precipitation is pronounced. The amount effect is clearly but do not show the temperature effect from January to December 2007. Using a mass-balance equation, a comparison of deuterium excess or d values of precipitation and groundwater indicates the groundwater consist of 76% wet season precipitation and 24% dry season precipitation, representing a distinct seasonal variation of groundwater recharge in study area. About 79% of the groundwater is recharged from the river water of the mountain watershed and 21% is from the rain that falls on the basin.     

北京西山鹫峰地区氢氧稳定同位素特征分析

以北京西山鹫峰低山区为研究对象,通过对降水、土壤水、泉水氢氧同位素的变化特征分析,研究低山区的降水-土壤水-泉水的转化关系。研究结果表明:该地区的雨季降水线与北京地区的地区降水线有明显区别,斜率和截距偏小;随降雨的进行氢氧同位素特征有时程变化和降雨量效应,而降雨的时程变化也对土壤水的同位素特征产生了影响;土壤水分同位素分布特征相对集中,蒸发线方程的斜率和截距相对于当地大气降水线和雨季降水线都偏小,栓皮栎混交林土壤水对于小雨量次降雨事件反应不敏感,而侧柏林的土壤水分运动较栓皮栎混交林快,说明林分类型和土壤特性对不同水体之间的转化有影响;泉水的同位素特征比较稳定,主要分布在地区降水线的右下方与雨季降水线的交点附近;不同水体中降雨的δD、δ18O变化范围较大,土壤水次之,泉水变化最小;而沿着大气降水-土壤水-地下水(泉水)这一水循环路径,水体中的δD、δ18O值总体上呈下降趋势。     

下辽河平原地下水生态水位与可持续开发调控研究

下辽河平原是辽宁省老工业基地的核心地区,水资源问题已经成为制约该区经济发展和生态环境改善的重要因素。地下水资源在整个供水系统中一直占有65%左右的比例,但由于地下水开采所导致的环境水文地质问题也很严重,因此开展研究区内的地下水生态水位及其调控的研究具有重要的意义。首先在研究区内降水入渗与蒸发规律的基础上,结合野外试验资料,采用情景分析的方法,设置了两种情景下地下水生态水位标准,并在第二种情景里又分为考虑地下水调蓄功能与不考虑地下水调蓄功能两种方案;然后通过对地下水实际埋深与生态水位埋深的比较,结合相应的水文地质参数,计算出各种方案下满足地下水生态水位要求的地下水调控量;最后论述了研究区内地下水资源可持续开发利用的对策措施。研究成果对于区内地下水资源的科学开采与有效保护具有一定的参考意义。     

Characteristics of the main inorganic nitrogen accumulation in surface water and groundwater of wetland succession zones

Based on the observation of a complete hydrological year from June 2014 to May 2015, the temporal and spatial variations of the main inorganic nitrogen (MIN, referring to NO3--N, NO2--N, NH4+-N) in surface water and groundwater of the Li River and the Yuan River wetland succession zones are analyzed. The Li River and the Yuan River are located in agricultural and non-agricultural areas, and this study focus on the influence of surface water level and groundwater depth and precipitation on nitrogen pollution. The results show that NO3--N in surface water accounts for 70%-90% of MIN, but it does not exceed the limit of national drinking water surface water standard. Groundwater is seriously polluted by NH4+-N. Based on the groundwater quality standard of NH4+-N, the groundwater quality in the Li River exceeds Class III water standard throughout the year, and the exceeding months’ proportion of Yuan River reaches 58.3%. Compared with the Yuan River, MIN in groundwater of the Li River shows significant temporal and spatial variations owing to the influence of agricultural fertilization. The correlation between the concentrations of MIN and surface water level is poor, while the fitting effect of quadratic correlation between NH4+-N concentration and groundwater depth is the best (R2=0.9384), NO3--N is the next (R2=0.5128), NO2--N is the worst (R2=0.2798). The equation of meteoric water line is δD =7.83δ18O+12.21, indicating that both surface water and groundwater come from atmospheric precipitation. Surface infiltration is the main cause of groundwater NH4+-N pollution. Rainfall infiltration in non-fertilization seasons reduces groundwater nitrogen pollution, while rainfall leaching farming and fertilization aggravate groundwater nitrogen pollution.     

Characteristics of the main inorganic nitrogen accumulation in surface water and groundwater of wetland succession zones

Based on the observation of a complete hydrological year from June 2014 to May 2015, the temporal and spatial variations of the main inorganic nitrogen(MIN, referring to NO_3~--N, NO_2~--N, NH_4~+-N) in surface water and groundwater of the Li River and the Yuan River wetland succession zones are analyzed. The Li River and the Yuan River are located in agricultural and non-agricultural areas, and this study focus on the influence of surface water level and groundwater depth and precipitation on nitrogen pollution. The results show that NO_3~-N in surface water accounts for 70%-90% of MIN, but it does not exceed the limit of national drinking water surface water standard. Groundwater is seriously polluted by H_4~+-N. Based on the groundwater quality standard of H_4~+-N, the groundwater quality in the Li River exceeds Class III water standard throughout the year, and the exceeding months' proportion of Yuan River reaches 58.3%. Compared with the Yuan River, MIN in groundwater of the Li River shows significant temporal and spatial variations owing to the influence of agricultural fertilization. The correlation between the concentrations of MIN and surface water level is poor, while the fitting effect of quadratic correlation between H_4~+-N concentration and groundwater depth is the best(R~2=0.9384), NO_3~-N is the next(R~2=0.5128), NO_2~--N is the worst(R~2=0.2798). The equation of meteoric water line is δD =7.83δ~(18) O+12.21, indicating that both surface water and groundwater come from atmospheric precipitation. Surface infiltration is the main cause of groundwater H_4~+-N pollution. Rainfall infiltration in non-fertilization seasons reduces groundwater nitrogen pollution, while rainfall leaching farming and fertilization aggravate groundwater nitrogen pollution.     

氢氧同位素在地下水流系统的重分布：从高程效应到深度效应

大气降水的氢氧同位素含量具有高程效应,降水入渗后参与地下水循环,其高程效应如何受地下水流系统的影响转化为地下水氢氧同位素的深度效应？现有研究对于这个问题缺少定量认识。文章构建单向倾斜盆地和双峰波状盆地的稳态地下水循环理论模型,采用MODFLOW模拟剖面二维地下水流场、采用MT3DMS模拟重同位素分子的对流-弥散过程,得到地下水D和¹⁸O含量的空间分布,探讨了氢氧同位素高程效应在地下水流系统转化为深度效应的机理。结果表明：在单斜盆地,补给区大气降水D和¹⁸O含量的高程效应转化为排泄区地下水δD和δ¹⁸O值随埋深增大而指数型衰减的深度效应;在双峰波状盆地,当含水层渗透性相对入渗强度较大时(K₀/w=1 000),仅发育一个区域地下水流系统,在区域地下水的排泄区δD和δ¹⁸O随埋深增大呈现S形曲线分布;当含水层渗透性相对入渗强度较小时(K0/w=250),双峰波状盆地发育多个局部地下水流系统,区域地下水的排泄区δD和δ¹⁸O随埋深增大呈现S形曲线,而局部地下水排...     

Diffusion Kinetics of Carbonate Hydroxyapatite （CHAP） for Adsorbing F^- Dissolved in Water

A systematic research was performed about diffusion kinetics of adsorbing F^- dissolved in water for carbonate hydroxyapatite （CHAP） from the natural hydroxyapatite which was modified by adulterating with CO3^2-. The result shows that the speed of F^- adsorption is controlled by membrane diffusion when F^- concentration is relatively low, which is expressed by the kinetic equation of diffusion Q=0.0005（Ci-C）（t-ti）＋0.3967, or by vacancy diffusion when F^- concentration is relatively high, which is expressed by the kinetic equation of diffusion In[C（o, t）]=8.4718-0.5048Int. Based on the feature of CHAP for adsorbing F^- dissolved in water and its special channel of the structure of CO3^3- modified hydroxyapatite, models of vacancy diffusion and membrane diffusion were established.     

矿坑排水与岩溶地面塌陷的关系

浙江省某岩溶矿区南部洼地先后发生6处地面塌陷,引发了当地居民的恐慌。矿区排水是唯一地下水开采活动,为分析塌陷区与矿区之间的水力联系,遂在研究区全面布置地下水监测系统。通过对比分析观测水位、矿坑排水量及当地降雨量数据,探讨地面塌陷与矿区排水之间的关系及其潜在成因。研究表明,研究区岩溶地下水动态变化整体保持一致,受降雨、矿坑排水等综合因素影响。北部矿区和南部洼地存在岩溶连通管道,两者在雨季水力联系微弱、旱季水力联系密切。经长期径流潜蚀作用,〖JP2〗导致区内地面塌陷区灰岩顶板岩溶发育处上覆土层出现土洞,当矿区排水量急剧增大时,南部洼地岩溶水位大幅度下降,使得土洞中出现负压、上覆土层所受浮托力降低、孔隙水与岩溶水补排关系改变,在多种效应共同作用下,土洞最终形成地面塌陷。      

成都地区大气降水稳定同位素组成反应的气候特征

分析了1986-1998年成都地区大气降水的稳定同位素组成。夏季降水的δD和δ^18O值比冬季降水轻,反映了季风气候的降水特点。成都地区的大气降水线方程是：δD=1．42＋7．530δ^18O,与全球和中国降水线方程相比,表明了成都地区的蒸发程度稍大于降雨,说明成都地区大气降水的不平衡蒸发程度弱,反映了海洋性气候特征。成都地区大气降水δ^18O与降雨量、温度和水汽压之间都是负相关关系。但是降雨量对大气降水δ^18O的影响最大。     

Testing the relationship between Holocene peatland palaeoclimate reconstructions and instrumental data at two European sites

Peatland surface wetness records provide long Holocene palaeoclimate reconstructions at 10¹–10² year resolution. They reflect changes in water balance but the relative strength of precipitation and temperature signals are not known. In common with other non-annually resolved records, there has been no testing of the reconstructions against instrumental climate data. In this paper high-resolution records of palaeohydrological change reconstructed from testate amoebae analysis are used to examine critically the relationships between reconstructed water table change, instrumental water table and climate data. A 200-year record of reconstructed water table from northern England shows that the strongest control on reconstructed mean annual water table change is summer precipitation, with summer temperature becoming more important over longer time periods. A 50-year record from Estonia shows that both measured and reconstructed water table records are strongly correlated with summer precipitation. Summer temperature is also correlated with reconstructed water table. We conclude that peatland surface wetness records should be interpreted as primarily reflecting summer precipitation variability, with summer temperature increasingly important in more continental settings.     

长江流域降水稳定同位素的云下二次蒸发效应

对长江流域443个GNIP的降水样品同位素原始资料,分降雪和降雨进行δ2H和δ18O线性回归,得到降雪样品的相关方程为δ2H=7.965δ18O+17.114,有最大的斜率和截距;而降雨样品根据降水量大小从<10mm至>300mm分为4组后,得到的相关方程随着降水量的减小,斜率和截距均减小,斜率从7.701减小为5.705,截距从7.812×10-3减小为-5.479×10-3。δ2H~δ18O相关方程的斜率及截距与气温、水汽压之间的关系表明,在降水从云层底部降落到地面的过程中,仅较小降雨事件有明显的二次蒸发现象,并伴随着同位素的分馏。长江流域较小降雨事件占有比例很小,仅为所有降水事件的6.32%,所以二次蒸发效应仅引起地区大气降水方程斜率和截距的微弱减小。研究表明,单个降水原始资料的同位素分析,能产生长期加权平均降水同位素分析得不到的宝贵信息。     

近30年来降水量变化和人类活动对北京潮白河冲洪积扇地下水动态的影响

对北京潮白河冲洪积扇分布区30年来降水量、地表径流量、地下水水位和地下水储存量进行了时间序列分析。结果表明: 过去30年中,区域地下水动态发生了明显变化,特点是1998年以来,地下水位和地下水储存量迅速下降与减少。1998年以来,年降水量为以往多年平均值的76％左右。在储存量变化的影响因素中,降水量减少导致的补给量减少约占24％,人类活动,如工农业地下水开采、应急水源地地下水开采和地表水体入渗减少等因素约占76％。由于未来气候变化的不确定性,在南水北调的水进京后仍可能出现连续枯水年,因此,以丰水年降水进行水源涵养存在较大风险。对于已经处于严重超采状况的潮白河冲洪积扇来说,为了满足未来供水的需要,应急水源地从现在起应减少开采量或停采以逐步恢复地下水储存量。