Mantle and crustal processes in the magmatism of the Campania region: inferences from mineralogy, geochemistry, and Sr–Nd–O isotopes of young hybrid volcanics of the Ischia island (South Italy)

Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (<2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of ≤1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical δ¹⁸O mantle values, and ⁸⁷Sr/⁸⁶Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more ¹⁸O than ⁸⁷Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.     

Crystal fractionation,magma step ascent,and syn-eruptive mingling: the Averno 2 eruption (Phlegraean Fields,Italy)

The 3.7 ka year-old Averno 2 eruption is one of the rare eruptions to have occurred in the northwest sector of the Phlegraean Fields caldera (PFc) over the past 5 ka. We focus here on the fallout deposits of the pyroclastic succession emplaced during this eruption. We present major and trace element data on the bulk pumices, along with major and volatile element data on clinopyroxene-hosted melt inclusions, in order to assess the conditions of storage, ascent, and eruption of the feeding trachytic magma. Crystal fractionation accounts for the evolution from trachyte to alkali-trachyte magmas; these were intimately mingled (at the micrometer scale) during the climactic phase of the eruption. The Averno 2 alkali trachyte represents one of the most evolved magmas erupted within the Phlegraean Fields area and belongs to the series of differentiated trachytic magmas erupted at different locations 5 ka ago. Melt inclusions record significant variations in H₂O (from 0.4 to 5 wt%), S (from 0.01 to 0.06 wt%), Cl (from 0.75 up to 1 wt%), and F (from 0.20 to >0.50 wt%) during both magma crystallization and degassing. Unlike the eruptions occurring in the central part of the PFc, deep-derived input(s) of gas and/or magma are not required to explain the composition of melt inclusions and the mineralogy of Averno 2 pumices. Compositional data on bulk pumices, glassy matrices, and melt inclusions suggest that the Averno 2 eruption mainly resulted from successive extrusions of independent magma batches probably emplaced at depths of 2–4 km along regional fractures bordering the Neapolitan Yellow Tuff caldera.     

Geochronological and isotopic records of crustal storage and assimilation in the Wolverine Creek–Conant Creek system,Heise eruptive centre,Snake River Plain

Understanding the processes of differentiation of the Yellowstone–Snake River Plain (YSRP) rhyolites is typically impeded by the apparent lack of erupted intermediate compositions as well as the complex nature of their shallow interaction with the surrounding crust responsible for their typically low O isotopic ratios. A pair of normal-δ¹⁸O rhyolitic eruptions from the Heise eruptive centre in eastern Idaho, the Wolverine Creek Tuff and the Conant Creek Tuff, represent unique magmatic products of the Yellowstone hotspot preserving abundant vestiges of the intermediate differentiation steps leading to rhyolite generation. We address both shallow and deep processes of magma generation and storage in the two units by combining high-precision ID–TIMS U–Pb zircon geochronology, trace element, O and Hf isotopic studies of zircon, and Sr isotopic analyses of individual high-Mg# pyroxenes inherited from lower- to mid-crustal differentiation stages. The zircon geochronology confirms the derivation of both tuffs from the same rhyolitic magma reservoir erupted at 5.5941 ± 0.0097 Ma, preceded by at least 92 ± 14 ky of continuous or intermittent zircon saturation approximating the length of pre-eruptive magma accumulation in the upper crust. Some low-Mg# pyroxenes enclosing zircons predate the eruption by at least 45 ± 27 ky, illustrating the co-crystallisation of major and accessory phases in the near-liquidus rhyolitic melts of the YSRP over a significant period of time. Coeval zircon crystals are isotopically heterogeneous (two populations at εHf ~?5 and ?13), requiring the assembly of isotopically distinct melt pockets directly prior to, or during, the eruption. The primitive Mg# 60–90 pyroxenes are out of isotopic equilibrium with the host rhyolitic melt (⁸⁷Sr/⁸⁶Sr_i = 0.70889), covering a range of ⁸⁷Sr/⁸⁶Sr_i = 0.70705–0.70883 corresponding to ratios typical of the most radiogenic YSRP basalts to the least radiogenic YSRP rhyolites. Together with the low εHf in zircon, the Sr isotopic ratios illustrate limited assimilation dominated by radiogenic Archean crustal source materials incorporated into variably evolved YSRP melts as they progress towards rhyolitic compositions by assimilation–fractional crystallisation.     

The behavior of chlorine and sulfur during differentiation of the Mt. Somma-Vesuvius magmatic system

Summary Reheated silicate melt inclusions in volcanic rock samples from Mt. Somma-Vesuvius, Italy, have been analyzed for 29 constituents including H₂O, S, Cl, F, B, and P₂O₅. This composite volcano consists of the older Mt. Somma caldera, formed between 14 and 3.55 ka before present, and the younger Vesuvius cone. The melt inclusion compositions provide important constraints on pre-eruptive magma geochemistry, identify relationships that relate to eruption behavior and magma evolution, and provide extensive evidence for magmatic fluid exsolution well before eruption. The melt inclusion data have been categorized by groups that reflect magma compositions, age, and style of eruptions. The data show distinct differences in composition for eruptive products older than 14.0 ka (pre-caldera rocks) versus eruptive products younger than 3.55 ka. Moreover, pre-caldera eruptions were associated with magmas relatively enriched in SiO₂, whereas eruptions younger than 3.55 ka (i.e., the syn- and post-caldera magmas which generated the Somma caldera and the Vesuvius cone) were derived from magmas comparatively enriched in S, Cl, CaO, MgO, P₂O₅, F, and many lithophile trace elements. Melt inclusion data indicate that eruptive behavior at Vesuvius correlates with pre-eruptive volatile enrichments. Most magmas associated with explosive plinian and subplinian events younger than 3.55 ka contained more H₂O, contained significantly more S, and exhibited higher (S/Cl) ratios than syn- and post-caldera magmas which erupted during relatively passive interplinian volcanic phenomena. Received January 10, 2000 Revised version accepted July 17, 2000     

Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

A cascade of magmatic events during the assembly and eruption of a super-sized magma body

We use comprehensive geochemical and petrological records from whole-rock samples, crystals, matrix glasses and melt inclusions to derive an integrated picture of the generation, accumulation and evacuation of 530 km³ of crystal-poor rhyolite in the 25.4 ka Oruanui supereruption (New Zealand). New data from plagioclase, orthopyroxene, amphibole, quartz, Fe–Ti oxides, matrix glasses, and plagioclase- and quartz-hosted melt inclusions, in samples spanning different phases of the eruption, are integrated with existing data to build a history of the magma system prior to and during eruption. A thermally and compositionally zoned, parental crystal-rich (mush) body was developed during two periods of intensive crystallisation, 70 and 10–15 kyr before the eruption. The mush top was quartz-bearing and as shallow as ~3.5 km deep, and the roots quartz-free and extending to >10 km depth. Less than 600 year prior to the eruption, extraction of large volumes of ~840 °C low-silica rhyolite melt with some crystal cargo (between 1 and 10%), began from this mush to form a melt-dominant (eruptible) body that eventually extended from 3.5 to 6 km depth. Crystals from all levels of the mush were entrained into the eruptible magma, as seen in mineral zonation and amphibole model pressures. Rapid translation of crystals from the mush to the eruptible magma is reflected in textural and compositional diversity in crystal cores and melt inclusion compositions, versus uniformity in the outermost rims. Prior to eruption the assembled eruptible magma body was not thermally or compositionally zoned and at temperatures of ~790 °C, reflecting rapid cooling from the ~840 °C low-silica rhyolite feedstock magma. A subordinate but significant volume (3–5 km³) of contrasting tholeiitic and calc-alkaline mafic material was co-erupted with the dominant rhyolite. These mafic clasts host crystals with compositions which demonstrate that there was some limited pre-eruptive physical interaction of mafic magmas with the mush and melt-dominant body. However, the mafic magmas do not appear to have triggered the eruption or controlled magmatic temperatures in the erupted rhyolite. Integration of textural and compositional data from all available crystal types, across all dominant and subordinate magmatic components, allow the history of the Oruanui magma body to be reconstructed over a wide range of temporal scales using multiple techniques. This history spans the tens of millennia required to grow the parental magma system (U–Th disequilibrium dating in zircon), through the centuries and decades required to assemble the eruptible magma body (textural and diffusion modelling in orthopyroxene), to the months, days, hours and minutes over which individual phases of the eruption occurred, identified through field observations tied to diffusion modelling in magnetite, olivine, quartz and feldspar. Tectonic processes, rather than any inherent characteristics of the magmatic system, were a principal factor acting to drive the rapid accumulation of magma and control its release episodically during the eruption. This work highlights the richness of information that can be gained by integrating multiple lines of petrologic evidence into a holistic timeline of field-verifiable processes.     

Small volume andesite magmas and melt–mush interactions at Ruapehu, New Zealand: evidence from melt inclusions

Historical eruptions from Mt. Ruapehu (New Zealand) have been small (<0.001 km³ of juvenile magma) and have often occurred without significant warning. Developing better modelling tools requires an improved understanding of the magma storage and transport system beneath the volcano. Towards that end, we have analysed the volatile content and major element chemistry of groundmass glass and phenocryst-hosted melt inclusions in erupted samples from 1945 to 1996. We find that during this time period, magma has been stored at depths of ~2–9 km, consistent with inferences from geophysical data. Our data also show that Ruapehu magmas are relatively H₂O-poor (<2 wt%) and CO₂-rich (≤1,000 ppm) compared to typical arc andesites. Surprisingly, we find that melt inclusions are often more evolved than their transporting melt (as inferred from groundmass glass compositions). Furthermore, even eruptions that are separated by less than 2 years exhibit distinct major element chemistry, which suggests that each eruption involved magma with a unique ascent history. From these data, we infer that individual melt batches rise through, and interact with, crystal mush zones formed by antecedent magmas. From this perspective, we envision the magmatic system at Ruapehu as frequently recharged by small magma inputs that, in turn, cool and crystallise to varying degrees. Melts that are able to erupt through this network of crystal mush entrain (to a greater or lesser extent) exotic crystals. In the extreme case (such as the 1996 eruption), the resulting scoria contain melt inclusion-bearing crystals that are exotic to the transporting magma. Finally, we suggest that complex interactions between recharge and antecedent magmas are probably common, but that the small volumes and short time scales of recharge at Ruapehu provide a unique window into these processes.     

Mechanisms driving polymagmatic activity at a monogenetic volcano, Udo, Jeju Island, South Korea

High-resolution, stratigraphically ordered samples of the Udo tuff cone and lava shield offshore of Jeju Island, South Korea, show complex geochemical variation in the basaltic magmas that fed the eruption sequence. The eruption began explosively, producing phreatomagmatic deposits with relatively evolved alkali magma. The magma became more primitive over the course of the eruption, but the last magma to be explosively erupted had shifted back to a relatively evolved composition. A separate sub-alkali magma batch was subsequently effusively erupted to form a lava shield. Absence of weathering and only minor reworking between the tuff and overlying lava implies that there was no significant time break between the eruptions of the two magma batches. Modelling of the alkali magma suggests that it was generated from a parent melt in garnet peridotite at c. 3 to 3.5 GPa and underwent mainly clinopyroxene + olivine ± spinel fractionation at c. 1.5 to 2 GPa. The sub-alkali magma was, by contrast, generated from a chemically different peridotite with residual garnet at c. 2.5 GPa and evolved through olivine fractionation at a shallower level compared to its alkali contemporary. The continuous chemostratigraphic trend in the tuff cone, from relatively evolved to primitive and back to evolved, is interpreted to have resulted from a magma batch having risen through a single dyke and erupted the batch’s head, core and margins, respectively. The alkali magma acted as a path-opener for the sub-alkali magma. The occurrence of the two distinct batches suggests that different magmatic systems in the Jeju Island Volcanic Field have interacted throughout its history. The polymagmatic nature of this monogenetic eruption has important implications for hazard forecasting and for our understanding of basaltic field volcanism.     

Magma mixing and the generation of isotopically juvenile silicic magma at Yellowstone caldera inferred from coupling 238U–230Th ages with trace elements and Hf and O isotopes in zircon and Pb isotopes in sanidine

The nature of compositional heterogeneity within large silicic magma bodies has important implications for how silicic reservoirs are assembled and evolve through time. We examine compositional heterogeneity in the youngest (~170 to 70 ka) post-caldera volcanism at Yellowstone caldera, the Central Plateau Member (CPM) rhyolites, as a case study. We compare ²³⁸U–²³⁰Th age, trace-element, and Hf isotopic data from zircons, and major-element, Ba, and Pb isotopic data from sanidines hosted in two CPM rhyolites (Hayden Valley and Solfatara Plateau flows) and one extracaldera rhyolite (Gibbon River flow), all of which erupted near the caldera margin ca. 100 ka. The Hayden Valley flow hosts two zircon populations and one sanidine population that are consistent with residence in the CPM reservoir. The Gibbon River flow hosts one zircon population that is compositionally distinct from Hayden Valley flow zircons. The Solfatara Plateau flow contains multiple sanidine populations and all three zircon populations found in the Hayden Valley and Gibbon River flows, demonstrating that the Solfatara Plateau flow formed by mixing extracaldera magma with the margin of the CPM reservoir. This process highlights the dynamic nature of magmatic interactions at the margins of large silicic reservoirs. More generally, Hf isotopic data from the CPM zircons provide the first direct evidence for isotopically juvenile magmas contributing mass to the youngest post-caldera magmatic system and demonstrate that the sources contributing magma to the CPM reservoir were heterogeneous in ¹⁷⁶Hf/¹⁷⁷Hf at ca. 100 ka. Thus, the limited compositional variability of CPM glasses reflects homogenization occurring within the CPM reservoir, not a homogeneous source.     

Acigöl rhyolite field,central Anatolia (part II): geochemical and isotopic (Sr–Nd–Pb, δ<Superscript>18</Superscript>O) constraints on volcanism involving two high-silica rhyolite suites

The Acigöl rhyolite field erupted the most recent high-silica rhyolites within the Cappadocian Volcanic Province of central Anatolia, Turkey. It comprises two sequences of domes and pyroclastic rocks with eruption ages of ~150–200 ka (eastern group) and ~20–25 ka (western group). Compositionally, the eastern rhyolite group lavas are less evolved (SiO₂ = 74–76 wt%), whereas the western group has higher silica abundance (SiO₂ = ~77 wt%) with extremely depleted feldspar-compatible trace elements. Within each group, compositional variability is small and ¹⁴³Nd/¹⁴⁴Nd (0.51257–0.51265) and Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb = 18.87–18.88, ²⁰⁷Pb/²⁰⁴Pb = 15.65–15.67 and ²⁰⁸Pb/²⁰⁴Pb = 38.94–38.98) are homogeneous. The western group rhyolites have δ¹⁸O(zircon) overlapping mantle values (5.7 ± 0.2‰), whereas eastern group rhyolites are enriched in δ¹⁸O by ~0.5‰, consistent with a tendency to lower εNd values. By contrast, western group rhyolites have markedly more radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7065–0.7091) compared to those of the eastern group (0.7059–0.7065). The presence of angular granitic xenoliths and a correlation between hydration (based on loss on ignition data) and ⁸⁷Sr/⁸⁶Sr in the western lavas, however, indicates that Sr was added during the eruption or post-eruption alteration. Isotope constraints preclude the possibility that the rhyolite magmas formed by partial melting of any known regional crystalline basement rocks. Basalts and andesites erupted in the periphery of the Acigöl field are characterised by ⁸⁷Sr/⁸⁶Sr ratios between 0.7040 and 0.7053, ¹⁴³Nd/¹⁴⁴Nd = 0.51259–0.51300, ²⁰⁶Pb/²⁰⁴Pb = 18.85–18.87, ²⁰⁷Pb/²⁰⁴Pb = 15.646–15.655, ²⁰⁸Pb/²⁰⁴Pb = 38.90–38.97. The isotopic and trace element data favour an origin of the rhyolites by mixing of basaltic/andesitic magmas with minor amounts of crustal melts and followed by extensive fractional crystallization.     

The role of magma mixing/mingling and cumulate melting in the Neapolitan Yellow Tuff caldera-forming eruption (Campi Flegrei,Southern Italy)

Understanding the mechanisms responsible for the generation of chemical gradients in high-volume ignimbrites is key to retrieve information on the processes that control the maturation and eruption of large silicic magmatic reservoirs. Over the last 60 ky, two large ignimbrites showing remarkable zoning were emplaced during caldera-forming eruptions at Campi Flegrei (i.e., Campanian Ignimbrite, CI, ~?39 ka and Neapolitan Yellow Tuff, NYT, ~?15 ka). While the CI displays linear compositional, thermal and crystallinity gradients, the NYT is a more complex ignimbrite characterized by crystal-poor magmas ranging in composition from trachy-andesites to phonolites. By combining major and trace element compositions of matrix glasses and mineral phases from juvenile clasts located at different stratigraphic heights along the NYT pyroclastic sequence, we interpret such compositional gradients as the result of mixing/mingling between three different magmas: (1) a resident evolved magma showing geochemical characteristics of a melt extracted from a cumulate mush dominated by clinopyroxene, plagioclase and oxides with minor sanidine and biotite; (2) a hotter and more mafic magma from recharge providing high-An plagioclase and high-Mg clinopyroxene crystals and (3) a compositionally intermediate magma derived from remelting of low temperature mineral phases (i.e., sanidine and biotite) within the cumulate crystal mush. We suggest that the presence of a refractory crystal mush, as documented by the occurrence of abundant crystal clots containing clinopyroxene, plagioclase and oxides, is the main reason for the lack of erupted crystal-rich material in the NYT. A comparison between the NYT and the CI, characterized by both crystal-poor extracted melts and crystal-rich magmas representing remobilized portions of a “mature” (i.e., sanidine dominated) cumulate residue, allows evaluation of the capability of crystal mushes of becoming eruptible upon recharge.     

Evolution of silicic magmas in the Kos-Nisyros volcanic center,Greece: a petrological cycle associated with caldera collapse

Multiple eruptions of silicic magma (dacite and rhyolites) occurred over the last ~3 My in the Kos-Nisyros volcanic center (eastern Aegean sea). During this period, magmas have changed from hornblende-biotite-rich units with low eruption temperatures (≤750–800°C; Kefalos and Kos dacites and rhyolites) to hotter, pyroxene-bearing units (>800–850°C; Nisyros rhyodacites) and are transitioning back to cooler magmas (Yali rhyolites). New whole-rock compositions, mineral chemistry, and zircon Hf isotopes show that these three types of silicic magmas followed the same differentiation trend: they all evolved by crystal fractionation and minor crustal assimilation (AFC) from parents with intermediate compositions characterized by high Sr/Y and low Nb content, following a wet, high oxygen fugacity liquid line of descent typical of subduction zones. As the transition between the Kos-Kefalos and Nisyros-type magmas occurred immediately and abruptly after the major caldera collapse in the area (the 161 ka Kos Plateau Tuff; KPT), we suggest that the efficient emptying of the magma chamber during the KPT drew out most of the eruptible, volatile-charged magma and partly solidified the unerupted mush zone in the upper crust due to rapid unloading, decompression, and coincident crystallization. Subsequently, the system reestablished a shallow silicic production zone from more mafic parents, recharged from the mid to lower crust. The first silicic eruptions evolving from these parents after the caldera collapse (Nisyros units) were hotter (up to >100°C) than the caldera-forming event and erupted from reservoirs characterized by different mineral proportions (more plagioclase and less amphibole). We interpret such a change as a reflection of slightly drier conditions in the magmatic column after the caldera collapse due to the decompression event. With time, the upper crustal intermediate mush progressively transitioned into the cold-wet state that prevailed during the Kefalos-Kos stage. The recent eruptions of the high-SiO₂ rhyolite on Yali Island, which are low temperature and hydrous phases (sanidine, quartz, biotite), suggest that another large, potentially explosive magma chamber is presently building under the Kos-Nisyros volcanic center.     

Petrology and geochemistry of the 2014–2015 Holuhraun eruption,central Iceland: compositional and mineralogical characteristics,temporal variability and magma storage

The 2014–2015 Holuhraun fissure eruption provided a rare opportunity to study in detail the magmatic processes and magma plumbing system dynamics during a 6-month-long, moderate- to large-volume basaltic fissure eruption. In this contribution, we present a comprehensive dataset, including major and trace elements of whole-rock and glassy tephra samples, mineral chemistry, and radiogenic and oxygen isotope analyses from an extensive set of samples (n?=?62) that were collected systematically in several field campaigns throughout the entire eruptive period. We also present the first detailed chemical and isotopic characterization of magmatic sulfides from Iceland. In conjunction with a unique set of geophysical data, our approach provides a detailed temporal and spatial resolution of magmatic processes before and during this eruption. The 2014–2015 Holuhraun magma is compositionally indistinguishable from recent basalts erupted from the Bárðarbunga volcanic system, consistent with seismic observations for magma ascent close to the Bárðarbunga central volcano, followed by dyke propagation to the Holuhraun eruption site. Whole-rock elemental and isotopic compositions are remarkably constant throughout the eruption. Moreover, the inferred depth of the magma reservoir tapped during the eruption is consistently 8?±?5 km, in agreement with geodetic observations and melt inclusion entrapment pressures, but inconsistent with vertically extensive multi-tiered magma storage prior to eruption. The near constancy in the chemical and isotopic composition of the lava is consistent with the efficient homogenization of mantle-derived compositional variability. In contrast, occurrence of different mineral populations, including sulfide globules, which display significant compositional variability, requires a more complex earlier magmatic history. This may include sampling of heterogeneous mantle melts that mixed, crystallized and finally homogenized at mid- to lower-crustal conditions.     

A detailed Th,Sr and O isotope study of Hekla: differentiation processes in an Icelandic Volcano

²³⁸U–²³⁰Th disequilibria and Sr and O isotope ratios have been measured in a suite of samples from most of the known prehistoric and historic eruptions of Hekla volcano, Iceland. They cover the compositional range from basaltic andesite to rhyolite. Recent basalts erupted in the vicinity of the volcano and a few Pleistocene basalts have also been studied. Geochemical data indicate that the best tracers of magmatic processes in Hekla are the (²³⁰Th/²³²Th) and Th/U ratios. Whereas most geochemical parameters, including Sr, Nd and O isotopes, could be compatible with crystal fractionation, (²³⁰Th/²³²Th) and Th/U ratios differ in the basalts and basaltic andesites (1.05 and 3.2, respectively) and in the silicic rocks, dacites and rhyolites (0.98 and 3.4–3.7, respectively). This observation precludes fractional crystallization as the main differentiation process in Hekla. On the basis of these results, the following model is proposed: basaltic magmas rise in the Icelandic crust and cause partial melting of metabasic rocks, leading to the formation of a dacitic melt. The basaltic magma itself evolves by crystal fractionation and produces a basaltic andesite magma. The latter can mix with the dacitic liquid to form andesites. At higher levels in the magma chamber, the dacitic melt sometimes undergoes further differentiation by crystal fractionation and produces subordinate volumes of rhyolites. Together all these processes lead to a zoned magma chamber. However, complete zoning is achieved only when the repose time between eruptions is long enough to allow the production of significant volumes of dacitic magma by crustal melting. This situation corresponds to the large plinian eruptions. Between these eruptions, the so-called intra-cyclic activity is characterized by the eruption of andesites and basaltic andesites, with little crustal melting. The magmatic system beneath Hekla most probably was established during the Holocene. The shape and the size of the magma chamber may be inferred from the relationships between the composition of the lavas and the location of the eruption sites. In a cross-section perpendicular to Hekla's ridge, a bell-shaped reservoir 5 km wide and 7 km deep appears the most likely; its top could be at depth of 8 km according to geophysical data.     

Western Kamchatka-Koryak continental-margin volcanogenic belt: Age,composition, and sources

The isotope-geochemical study of the Eocene-Oligocene magmatic rocks from the Western Kamchatka-Koryak volcanogenic belt revealed a lateral heterogeneity of mantle magma sources in its segments: Western Kamchatka, Central Koryak, and Northern Koryak ones. In the Western Kamchatka segment, magmatic melts were generated from isotopically heterogeneous (depleted and/or insignificantly enriched) mantle sources significantly contaminated by quartz-feldspathic sialic sediments; higher ⁸⁷Sr/⁸⁶Sr (0.70429–0.70564) and lower ¹⁴³Nd/¹⁴⁴Nd(ɛ_Nd(T) = 0.06–2.9) ratios in the volcanic rocks from the Central Koryak segment presumably reflect the contribution of enriched mantle source; the high positive ɛ_Nd(T) and low ⁸⁷Sr/⁸⁶Sr ratios in the magmatic rocks from the Northern Koryak segment area indicate their derivation from isotopically depleted mantle source without significant contamination by sialic or mantle material enriched in radiogenic Sr and Nd. Significantly different contamination histories of the Eocene-Oligocene mantle magmas in Kamchatka and Koryakia are related to their different thermal regimes: the higher heat flow beneath Kamchatka led to the crustal melting and contamination of mantle suprasubduction magmas by crustal melts. The cessation of suprasubduction volcanism in the Western Kamchatka segment of the continentalmargin belt was possibly related to the accretion of the Achaivayam-Valagin terrane 40 Ma ago, whereas suprasubduction activity in the Koryak segment stopped due to the closure of the Ukelayat basin in the Oligocene time.     

Post-orogenic shoshonitic magmas of the Yzerfontein pluton,South Africa: the ‘smoking gun’ of mantle melting and crustal growth during Cape granite genesis?

The post-orogenic Yzerfontein pluton, in the Saldania Belt of South Africa was constructed through numerous injections of shoshonitic magmas. Most magma compositions are adequately modelled as products of fractionation, but the monzogranites and syenogranites may have a separate origin. A separate high-Mg mafic series has a less radiogenic mantle source. Fine-grained magmatic enclaves in the intermediate shoshonitic rocks are autoliths. The pluton was emplaced between 533 ± 3 and 537 ± 3 Ma (LA-SF-ICP-MS U–Pb zircon), essentially synchronously with many granitic magmas of the Cape Granite Suite (CGS). Yzerfontein may represent a high-level expression of the mantle heat source that initiated partial melting of the local crust and produced the CGS granitic magmas, late in the Saldanian Orogeny. However, magma mixing is not evident at emplacement level and there are no magmatic kinships with the I-type granitic rocks of the CGS. The mantle wedge is inferred to have been enriched during subduction along the active continental margin. In the late- to post-orogenic phase, the enriched mantle partially melted to produce heterogeneous magma batches, exemplified by those that formed the Yzerfontein pluton, which was further hybridised through minor assimilation of crustal materials. Like Yzerfontein, the small volumes of mafic rocks associated with many batholiths, worldwide, are probably also low-volume, high-level expressions of crustal growth through the emplacement of major amounts of mafic magma into the deep crust.     

The Campanian Ignimbrite (southern Italy) geochemical zoning: insight on the generation of a super-eruption from catastrophic differentiation and fast withdrawal

More than ca 100 km³ of nearly homogeneous crystal-poor phonolite and ca 100 km³ of slightly zoned trachyte were erupted 39 ka during the Campanian Ignimbrite super eruption, the most powerful in the Neapolitan area. Partition coefficient calculations, equilibrium mineral assemblages, glass compositions and texture were used to reconstruct compositional, thermal and pressure gradients in the pre-eruptive reservoir as well as timing and mechanisms of evolution towards magma chamber overpressure and eruption. Our petrologic data indicate that a wide sill-like trachytic magma chamber was active under the Campanian Plain at 2.5 kbar before CI eruption. Thermal exchange between high liquidus (1199°C) trachytic sill and cool country rocks caused intense undercooling, driving a catastrophic and fast (10² years) in situ fractional crystallization and crustal assimilation that produced a water oversaturated phonolitic cap and an overpressure in the chamber that triggered the super eruption. This process culminated in an abrupt reservoir opening and in a fast single-step high decompression. Sanidine phenocrysts crystal size distributions reveal high differentiation rate, thus suggesting that such a sill-like magmatic system is capable of evolving in a very short time and erupting suddenly with only short-term warning.     

Evacuation of multiple magma bodies and the onset of caldera collapse in a supereruption,captured in glass and mineral compositions

Complexities in the nature of large-scale silicic eruptions and their magmatic systems can be discerned through micro-analytical geochemical studies. We present high-resolution, stratigraphically constrained compositional data on glassy matrix material and feldspar crystals from the initial fall deposits and earliest ignimbrite (base of member A) of the 2.08 Ma, ~?2500 km³ Huckleberry Ridge Tuff (HRT), Yellowstone. We use these data to document the nature of the magmatic system and compositional changes related to the transition from fall to widespread ignimbrite deposition, inferred to mark the onset of caldera collapse. Although major element glass compositions are relatively uniform, trace elements span a large range (e.g. Ba 10–900 ppm, Sr/Rb?=?0.005–0.09), with highly evolved glasses dominating in the fall deposits. Several trace elements (e.g. Ba and light rare earth elements) in the glass samples serve to define statistically significant compositional clustering in the fall deposits and basal ignimbrite. These clusters are inferred to reflect melt compositions controlled by fractional crystallisation processes and are interpreted to represent multiple, discrete melt-dominant domains that were tapped by multiple vents. The onset of widespread ignimbrite deposition is marked by an increase in the number of erupted melt compositional clusters from four in the fall deposits to eight, representing nine melt-dominant domains. There is an absence of geographical variation of glass compositions within the basal ignimbrite, with samples from proximal to distal localities north, west and south of the HRT caldera exhibiting similar variability. Pairing of glass analyses with sanidine major and minor element compositional data suggests that the nine melt compositional domains converged at depth into two compositionally distinct upper-crustal magmatic lineages that were both active during these early stages of the eruption. Our data collectively indicate the evacuation of an exceptionally complex and heterogeneous magma system. The onset of widespread ignimbrite deposition, inferred to relate to caldera collapse, occurred after ~ 50 km³ of magma had been discharged. Although external controls were important as an eruption trigger, depressurisation of the system led to caldera collapse with the eruption of numerous discrete melt-dominant domains.     

Petrogenesis of Quebrada de la Mina and Altar North porphyries (Cordillera of San Juan,Argentina): Crustal assimilation and metallogenic implications

We investigate the geology of Altar North (Cu–Au) and Quebrada de la Mina (Au) porphyry deposits located in San Juan Province (Argentina), close to the large Altar porphyry copper deposit (995 Mt, 0.35% Cu, 0.083 g/t Au), to present constraints on the magmatic processes that occurred in the parental magma chambers of these magmatic-hydrothermal systems. Altar North deposit comprises a plagioclase-amphibole-phyric dacite intrusion (Altar North barren porphyry) and a plagioclase-amphibole-biotite-phyric dacite stock (Altar North mineralized porphyry, 11.98 ± 0.19 Ma). In Quebrada de la Mina, a plagioclase-amphibole-biotite-quartz-phyric dacite stock (QDM porphyry, 11.91 ± 0.33 Ma) crops out. High Sr/Y ratios (92–142) and amphibole compositions of Altar North barren and QDM porphyries reflect high magmatic oxidation states (fO₂ = NNO +1.1 to +1.6) and high fH₂O conditions in their magmas. Zones and rims enriched in anorthite (An_37–48), SrO (0.22–0.33 wt.%) and FeO (0.21–0.37 wt.%) in plagioclase phenocrysts are evidences of magmatic recharge processes in the magma chambers. Altar North and Quebrada de la Mina intrusions have relatively homogeneous isotopic compositions (⁸⁷Sr/⁸⁶Sr_(t) = 0.70450–0.70466, ε_Nd(t) = +0.2 to +1.2) consistent with mixed mantle and crust contributions in their magmas. Higher Pb isotopes ratios (²⁰⁷Pb/²⁰⁴Pb = 15.6276–15.6294) of these intrusions compared to other porphyries of the district, reflect an increase in the assimilation of high radiogenic Pb components in the magmas. Ages of zircon xenocrysts (297, 210, 204, 69 Ma) revealed that the magmas have experienced assimilation of Miocene, Cretaceous, Triassic and Carboniferous crustal rocks.Fluids that precipitated sulfides in the Altar deposit may have remobilized Pb from the host rocks, as indicated by the ore minerals being more radiogenic (²⁰⁷Pb/²⁰⁴Pb = 15.6243–15.6269) than their host intrusions. Au/Cu ratio in Altar porphyries (average Au/Cu ratio of 0.14 × 10^?4 by weight in Altar Central) is higher than in the giant Miocene porphyry deposits located to the south: Los Pelambres, Río Blanco and Los Bronces (Chile) and Pachón (Argentina). We suggest that the increase in Au content in the porphyries of this region could be linked to the assimilation of high radiogenic Pb components in the magmas within these long-lived maturation systems.     

Sixty thousand years of magmatic volatile history before the caldera-forming eruption of Mount Mazama, Crater Lake, Oregon

The well-documented eruptive history of Mount Mazama, Oregon, provides an excellent opportunity to use pre-eruptive volatile concentrations to study the growth of an explosive silicic magmatic system. Melt inclusions (MI) hosted in pyroxene and plagioclase crystals from eight dacitic–rhyodacitic eruptive deposits (71–7.7?ka) were analyzed to determine variations in volatile-element concentrations and changes in magma storage conditions leading up to and including the climactic eruption of Crater Lake caldera. Temperatures (Fe–Ti oxides) increased through the series of dacites, then decreased, and increased again through the rhyodacites (918–968 to ~950 to 845–895?°C). Oxygen fugacity began at nickel–nickel-oxide buffer (NNO) +0.8 (71?ka), dropped slightly to NNO +0.3, and then climbed to its highest value with the climactic eruption (7.7?ka) at NNO +1.1 log units. In parallel with oxidation state, maximum MI sulfur concentrations were high early in the eruptive sequence (~500?ppm), decreased (to ~200?ppm), and then increased again with the climactic eruption (~500?ppm). Maximum MI sulfur correlates with the Sr content (as a proxy for LREE, Ba, Rb, P₂O₅) of recharge magmas, represented by basaltic andesitic to andesitic enclaves and similar-aged lavas. These results suggest that oxidized Sr-rich recharge magmas dominated early and late in the development of the pre-climactic dacite–rhyodacite system. Dissolved H₂O concentrations in MI do not, however, correlate with these changes in dominant recharge magma, instead recording vapor solubility relations in the developing shallow magma storage and conduit region. Dissolved H₂O concentrations form two populations through time: the first at 3–4.6 wt% (with a few extreme values up to 6.1 wt%) and the second at ≤2.4 wt%. CO₂ concentrations measured in a subset of these inclusions reach up to 240?ppm in early-erupted deposits (71?ka) and are below detection in climactic deposits (7.7?ka). Combined H₂O and CO₂ concentrations and solubility models indicate a dominant storage region at 4–7?km (up to 12?km), with drier inclusions that diffusively re-equilibrated and/or were trapped at shallower depths. Boron and Cl (except in the climactic deposit) largely remained in the melt, suggesting vapor–melt partition coefficients and gas fractions were low. Modeled Li, F, and S vapor–melt partition coefficients are higher than those of B and Cl. The decrease in maximum MI CO₂ concentration following the earliest dacitic eruptions is interpreted to result from a broadening of the shallow storage region to greater than the diameter of subjacent feeders, so that greater proportions of reservoir magma were to the side of CO₂-bearing vapor bubbles ascending vertically from the locus of recharge magma injection, thereby escaping recarbonation by streaming vapor bubbles. The Mazama melt inclusions provide a picture of a growing magma storage region, where chemical variations in melt and magma occur due to changes in the nature and supply rate of magma recharge, the timing of degassing, and the possible degree of equilibration with gases from below.