Geological Characteristics and Ore-forming Time of the Dexing Porphyry Copper Ore Mine in Jiangxi Province

The Dexing porphyry copper ore mine is located in the Qin-Hang metallogenic belt between the Yangtze block and the Cathaysia block. It is a giant porphyry copper mine in China, including 3 ore districts: Tongchang, Fujiawu and Zhushahong. Our analyses of Re in molybdenite indicate that the ore-forming material of the copper ore deposits in Dexing should be mainly mantle-derived. Our study fills in a gap in the study of formation time of the Dexing copper mine, and further proves that the copper ore deposits in the three ore districts should be formed simultaneously, about 170 Ma, belonging to the early Yanshan period, and that the formation time of the copper ore deposits should be consistent with the formation time of granodiorite porphyry in which the copper ore deposits are hosted. Promising areas for seeking porphyry copper ore deposits is predicated to be the west or southwest of Dexing.     

鄂东南地区鸡笼山矽卡岩金矿床的辉钼矿Re-Os同位素年龄及其构造意义

鄂东南地区是我国长江中下游Cu-Au-Fe-Mo成矿带中最重要的组成部分之一,其中鸡笼山金矿是是区内典型的大型矽卡岩金矿床。本文利用Re-Os同位素定年方法对鸡笼山金矿床进行了成矿时代测定,获得了辉钼矿的Re-Os同位素模式年龄范围为147.7±2.4~151.6±4.0Ma,等时线年龄为148.6±1.5Ma,与矿区内花岗闪长斑岩SHRIMP锆石U-Pb年龄151.6±0.7Ma相吻合,也与鄂东南地区其他矿田的成矿时代基本一致。鸡笼山矽卡岩金矿床可能形成于岩石圈伸展构造背景。硫同位素值为-2.5‰~5.5‰,均值为2.84‰,具有明显的塔式效应,反映了成矿物质具有岩浆来源的特征;辉钼矿中Re含量为174.3×10-6~871.4×10-6,平均为476.2×10-6,表明成矿物质来源属于壳幔混源型。     

首编大别造山带侵入岩地质图(1∶50万)及其说明

湖北蕲春烈马咀钼矿位于大别山南坡,已探明的大型钼矿鲜有报道,对该矿区的深入研究甚少,缺少对成岩成矿时代、成因和构造背景的准确厘定。对烈马咀钼矿及与成矿有关的花岗岩进行了岩相学、岩石地球化学研究和Re−Os同位素测年。结果表明：与成矿有关的岩石为斑状二长花岗岩或二长花岗斑岩,矿区成矿规模小,矿石为浸染状或细脉浸染状展布;辉钼矿等时线年龄为119±8 Ma,年龄加权平均值为118.9±0.98 Ma,指示烈马咀钼矿为早白垩世热液产物;岩石地球化学数据表明其为高硅、高钾钙碱性系列A型花岗岩;稀土元素的总含量高,轻稀土元素含量相对富集,重稀土元素含量相对亏损。烈马咀钼矿区与成矿有关的岩石形成于大别造山带伸展环境,与燕山晚期岩石圈减薄有关。

     

新疆香山铜镍硫化物矿床Re-Os同位素测定

通过对香山铜镍硫化物矿石中的镍黄铁矿进行Re-Os同位素测年,获得等时线年龄数据为(298±7．1)Ma。该数据表明产于东天山黄山—镜儿泉一带的这些铜镍硫化物矿床形成于晚石炭世—早二叠世,与该区广泛发育的造山型金矿、矽卡岩型银铜矿床和火山岩型铁铜矿床为同一时期的产物。其等时线~187Os/~188Os初始比值为0．682±0．32,γ_OS平均为444,表明在成矿过程及岩浆侵位期间有地壳物质加入成矿系统中。     

内蒙古架子山钼(银)矿床辉钼矿Re- Os同位素年龄及其地质意义

本文通过对内蒙古架子山斑岩型钼(银)矿床7件辉钼矿样品的Re-Os同位素测定与分析,获得了辉钼矿的模式年龄介于143.1±2.1～147.2±2.4 Ma之间,加权平均年龄为145.8±1.4 Ma(MSWD=1.5),对应的等时线年龄为147.4±1.4 Ma (MSWD=1.5),表明架子山钼(银)矿床形成于晚侏罗世,属中国东部燕山期大规模钼成矿期成矿。架子山钼(银)矿床Re含量在37.62×10^-6～401.34×10^-6之间,平均值为121.28×10^-6,表明架子山钼(银)矿床的成矿物质具有壳幔混源特征。     

山东孔辛头铜钼矿成矿时代及物质来源：来自黄铜矿、辉钼矿Re Os同位素证据

孔辛头铜钼矿床产于胶东地区伟德山超单元院格庄二长花岗岩与荆山群大理岩接触带形成的夕卡岩中,主矿体呈透镜状、囊状、脉状产出,受岩体内部裂隙构造控制。分别采用电感耦合等离子体质谱、热表面电离质谱Re-Os同位素测试技术对其中的辉钼矿、黄铜矿、磁铁矿进行了研究。结果显示,辉钼矿Re-Os等时线年龄为117±1 Ma,黄铜矿Re-Os等时线年龄为118.4±3.2 Ma,与区域上尚家庄钼矿床、冷家钼矿床成矿时代一致,几个矿床成因均与伟德山超单元有关,表明了胶东地区存在燕山晚期的钼矿化事件。而磁铁矿Re-Os封闭性较差,无法得到年龄。黄铜矿初始~(187)Os/~(188)Os值为0.32±0.17,表明了孔辛头铜钼矿床金属成矿物质为壳幔混合来源,形成于早白垩世太平洋板块向亚欧大陆俯冲而成的弧后拉张背景之下。     

LA-ICP-MS Zircon U-Pb Dating of Intermediate-Acidic Intrusive Rocks and Molybdenite Re-Os Dating from the Bangpu Mo (Cu) Deposit, Tibet and its Geological Implication

The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1?Ma (mean square of weighted deviates (MSWD) =9.5, n=8) and 60.60±0.31?Ma (MSWD=3.8, n=16), which belong to the late Cretaceous–early Paleocene in age. That means, they are products of an early tectonic-magmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19?Ma (MSWD=2.0, n=26) and 15.16±0.09?Ma (MSWD=3.9, n=5) separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2?Ma (MSWD=1.18, n=7) were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic–early Jurassic. Molybdenum (copper) ore-bodies produced in the monzogranite porphyry and copper (molybdenum) ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97–15.84?Ma, while isochron ages are 14.09±0.49?Ma (MSWD=26). The isochron ages of seven molybdenite from molybdenum (copper) ore with monzogranite porphyry type are 14.11±0.31?Ma (MSWD=5.2). There is great error in the isochron ages of four molybdenite from copper (molybdenum) ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2?Ma (MSWD=41), which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09?Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.     

Palaeoproterozoic Chibaisong mafic intrusion and mineralization (Northeast China), the oldest Cu–Ni sulphide deposit in China: evidence from Re–Os dating of pyrrhotite

The Chibaisong magmatic Cu–Ni sulphide deposit is located in Tonghua City, Jilin Province, in the eastern part of the northern margin of the North China Craton. The geological characteristics of the deposit have been investigated, and pyrrhotite Re–Os isotope dating has been utilized to constrain the age. Five pyrrhotite samples separated from the Chibaisong Cu–Ni sulphide deposit yielded a Re–Os isotopic isochron age of 2237 ± 62 Ma (mean squared weighted deviation = 1.13, n = 5), indicating that the only Palaeoproterozoic magmatic Cu–Ni sulphide deposit in China is the Chibaisong Cu–Ni sulphide deposit. The geodynamic setting during ore formation was related to the Liaoning–Jilin Palaeoproterozoic rift split. The Re–Os isotope analyses showed an initial ¹⁸⁷Os/¹⁸⁸Os ratio of 0.778 ± 0.033, and (¹⁸⁷Os/¹⁸⁸Os)_i and γOs(t) values ranged from 0.7531 to 0.8013 (average 0.7734) and from 574 to 617 (average 592), respectively, indicating that abundant crustal material (5–10%) was mixed with the Cu–Ni sulphide ore system during magma ascent and ore formation.     

熊耳群富碲（化物）型金矿床硫同位素组成及成矿作用探讨

熊耳群火山岩中产出各种类型的金矿床,富碲（化物）型（俗称构造蚀变岩型）是其主要类型,该类型金矿出现大量碲化物或富碲、硒。硫化物δ34S以较大负值为特征,δ34S=-19.24‰-+6.68‰。本文通过综合研究及与国内外有关矿床对比,提出该碲化物型金矿床δ34S负值的主要原因,是地表水渗透参与导致成矿热液物理化条件改变,氧逸度（fo2）升高、pH值降低,从而引起硫同位素强烈分馏形成的,δ34SΣS≈0‰显示成矿物质来源于熊耳群富钾火山岩系。该类型金矿床成矿作用为上升的岩浆地热流与下渗的地表水共同作用形成的浅成低温热液系统成矿,其成因类型属浅成低湿热液富碲（化物）型金矿床。     

内蒙古兴和县曹四夭特大型钼矿床辉钼矿铼 锇同位素年龄及…

内蒙古兴和县曹四夭矿床是迄今为止在我国北方找到的最大规模钼矿床,钼的资源量超过200万吨.考虑到大规模地质勘查工作仍在进行中,金属资源量和储量仍有较大提升空间.为了进一步查明曹四夭矿床的形成时间,对主要钼矿体4件辉钼矿样品进行了Re-Os同位素分析,所获同位素年龄值分别为131.9±2.3Ma、131.2±2.3Ma、129.7±2.0Ma和128.6±2.4Ma,平均值为130.4±2.4Ma,与花岗斑岩体锆石U-Pb年龄(134 ～ 131Ma)相近.根据岩(矿)体同位素年龄数据,并且结合辉钼矿呈浸染状和团块状分布于花岗斑岩株中,并且与部分硫化物呈共生结构关系的地质事实,可以推测曹四夭矿区含矿花岗斑岩株及有关钼矿床的形成时间均为早白垩世,属燕山期构造-岩浆活动的产物.曹四天钼矿床形成时代的厘定对于提高该矿床的理论研究水平和指导隐伏金属矿床的找矿勘查工作均具有重要意义.     

Geochronology of the Xiaodonggou Porphyry Mo Deposit in Northern Margin of North China Craton

The Xiaodonggou porphyry Mo deposit is located in the Mesozoic calc-alkaline Xiaodonggou granitoid within a Palaeozoic fold zone of northern China. The mineralization mainly occurred in an area of 0.54 km² at the south-eastern part of the Xiaodonggou granitoid. The mineralization includes disseminated molybdenite, pyrite, chalcopyrite, magnetite and pyrrhotite and stockwork quartz-sulfide veins. A molybdenite-rich inner core is surrounded by a concentric zone of the sulfide mineral assemblage of pyrite, galena and sphalerite. Intense potassic alteration is overprinted by sericitization and silicification in the mineralized zone. SHRIMP U-Pb data of zircon indicate that the granitoid crystallized at 142 ± 2 Ma (2σ). Re–Os age dating for six molybdenite samples from underground galleries of the deposit constrains the age of porphyry-style Mo mineralization to be 138.1 ± 2.8 Ma (2σ). These data suggest that porphyry-style mineralization was associated with the Xiaodonggou granitoid intrusion and support an Early Cretaceous porphyry-type metallogenic epoch along the northern margin of North China Craton.     

Zircon U–Pb and molybdenite Re–Os geochronology,Hf isotope analyses,and whole-rock geochemistry of the Donggebi Mo deposit,eastern Tianshan,Northwest China,and their geological significance

The geodynamic setting of Mesozoic magmatic rocks and associated mineralization in eastern Tianshan, Northwest China, are attracting increasing attention. The newly discovered giant Donggebi molybdenum deposit (0.508 Mt at 0.115% Mo) is located in the central part of eastern Tianshan, Xinjiang. The molybdenum mineralization was genetically associated with the Donggebi stock, comprised of porphyritic granite and granite porphyry. Secondary ion mass spectrometry (SIMS) zircon U–Pb dating constrains that the porphyritic granite and granite porphyry emplacement occurred at 233.8 ± 2.5 Ma and 231.7 ± 2.6 Ma, respectively. The Re–Os model ages of six molybdenite samples range from 235.2 to 237.0 Ma, with a weighted mean age of 236.1 ± 1.4 Ma, which is roughly consistent within errors with the zircon U–Pb ages, suggesting a Middle Triassic magmatic–mineralization event at Donggebi. Geochemically, the Donggebi granitoids are characterized by high SiO₂ and K₂O contents, with low MgO contents, belonging to high-K calc-alkaline granites. These rocks show pronounced enrichment in K, Rb, U, and Pb, and depletion in Sr, Ba, P, and Ti, with negative Eu anomalies (Eu/Eu* = 0.20–0.38). In situ Hf isotopic analyses of zircon from the porphyritic granite and granite porphyry yielded ε_Hf(t) values ranging from +6.6 to +10.5, and from +5.5 to +10.1, respectively. The geochemical and isotopic data imply that the primary magmas of the Donggebi granitoids could have originated by partial melting of a juvenile lower crust that involved some mantle components. Combined with the regional geological history, geochemistry of the Donggebi granitoids, and new isotopic age data, we thus propose that the Donggebi molybdenum deposit was formed in the Middle Triassic, and occurred in an intracontinental extension setting in eastern Tianshan.     

西藏中冈底斯成矿带查个勒铅锌矿床含矿斑岩年代学及其地质意义

查个勒铅锌矿床是西藏中冈底斯成矿带中段新发现的一个大型斑岩-矽卡岩型矿床,但其成岩成矿时代一直缺乏年代学约束。本文对该矿床含矿斑岩进行了LA-ICP-MS锆石U-Pb定年、辉钼矿Re-Os定年、主量和微量元素分析及Sr-Nd-Hf同位素组成研究,获得中冈底斯成矿带中段铜钼铅锌银矿化时代。含矿斑岩LA-ICP-MS锆石U-Pb年龄为64.6~62.9 Ma,代表岩浆的结晶年龄;辉钼矿Re-Os等时线年龄为(62.3±1.4)Ma,代表查个勒主成矿年龄,与其构造岩浆事件一致;结合区域林子宗群大规模火山活动(65~45 Ma)以及以亚贵拉铅锌矿床(68.6~ 65.0 Ma)为代表的成矿作用,表明在印度与欧亚大陆主碰撞过程中均可产生不同规模的成矿作用。查个勒含矿斑岩具富硅、富钾,贫钛、贫磷特征,铝饱和指数(A/CNK)为1.12 ~ 1.60,富集大离子亲石元素Rb、Th、U,亏损高场强元素Nb、Zr等,与冈底斯成熟大陆地壳物质相比具相对高的ε_Nd(t)值(-6.64 ~ -5.79)和相对低的(⁸⁷Sr/⁸⁶Sr)_i值(0.711 813~0.717 307),并具不均一的锆石ε_Hf(t)值(-7.02~-1.27)以及古老的锆石Hf同位素地壳模式年龄(T^C_DM=1 093~1 419 Ma),属于过铝质S型花岗岩类。本文认为中冈底斯成矿带中段古新世岩浆活动和成矿作用,很可能与雅鲁藏布江洋盆闭合之后的印-亚大陆碰撞诱发幔源岩浆底侵导致的冈底斯地体古老地壳物质部分熔融有关,岩浆在上升过程中有不同程度的分离结晶。     

安徽滁州琅琊山铜矿辉钼矿铼-锇同位素定年及其地质意义

首次运用铼-锇同位素方法对滁州琅琊山铜矿床中的辉钼矿进行定年。5件辉钼矿样品的模式年龄为(128.9±1.8)Ma～(130.3±1.9)Ma,187Re-187Os等时线年龄为(128.6±2.2)Ma,其加权平均方差(MSWD)为0.45,为滁州琅琊山铜矿床提供了准确的形成时限。分析结果表明,滁州琅琊山铜矿床是早白垩纪(燕山晚期)区域构造-岩浆活动的产物。琅琊山铜矿床辉钼矿中铼含量较高,推断成矿物质主要是壳幔混源,且主要是幔源。     

河南南沟钼矿矿床地球化学研究兼论东秦岭钼矿床成岩成矿动力学

本文对东秦岭南沟钼矿床开展成矿年代学与地球化学综合研究。岩石地球化学研究表明:南沟钼矿床侵入岩为高钾钙碱性系列,高硅(71.79%～78.09%)、低钛(0.112%～0.268%)、富铝(11.69%～14.89%)、富碱(Na2O含量为2.21%～4.26%,K2O含量是4.01%～7.57%,K2O/Na2O在1.07～3.42之间)、Mg#低(16.44～42.50)、贫钙(0.2%～1.54%)。南沟矿区侵入岩稀土总量较低,轻重稀土分异明显,有弱的铕负异常,δCe有强的负异常,样品的Ce负异常可能是具有Ce负异常的沉积物俯冲重熔所致,反应了形成花岗岩的源区物质可能为俯冲的海相沉积物源的特征,且具有还原特征。稀土配分模式图解与上地壳配分模式十分相似,也指示了花岗岩的物源区有大量的上地壳物质参与。南沟钼矿区侵入岩的微量元素分析表明,具有较高浓度的大离子亲石元素(LILE、Rb、K等),具有相对低含量的高场强元素(HFSE:Zr、Hf等),过渡金属含量变化较大,明显富集Cu,Sc,Co。本区侵入岩贫Ba、Sr,富Rb、K。壳型花岗岩类Ba、Sr含量低,Rb含量高,而幔源型或壳幔同熔型花岗岩的Ba、Sr含量高,且贫Rb,指示本区含钼侵入岩多具有壳源物源的性质。岩石地球化学判别图解指示这些含钼岩体主要为同碰撞花岗岩和后碰撞花岗岩。利用锆石LA-ICP-MS法测定了东秦岭南沟钼矿区两个相对独立的白石尖和马脖壕两个矿段含矿侵入岩体的U-Pb年龄,同时采用辉钼矿Re-Os同位素方法直接测定上面两个矿段的成矿年龄。高精度的锆石LA-ICP-MS研究表明:白石尖矿段花岗岩中锆石206Pb/238U加权平均年龄为451.7±5.7Ma(MSWD=1.6),马脖壕矿段花岗岩锆石206Pb/238U加权平均年龄为109.8±4.1Ma(MSWD=1.17)。由此可见南沟钼矿区至少有两期岩浆活动:1)早古生代晚奥陶世(约451Ma)第一次岩浆活动;2)中生代早白垩世(约109Ma)第二次岩浆活动。辉钼矿的Re-Os同位素模式年龄研究表明:白石尖矿段辉钼矿Re-Os等时线年龄为103±17Ma(MSWD=0.84),马脖壕矿段辉钼矿Re-Os等时线年龄107.08±0.61Ma(MSWD=0.96)。综合上面两种同位素年龄数值结合地质情况表明:南沟钼矿区白石尖矿段和马脖壕矿段为同期形成,都为燕山期,对应于华北板块与扬子板块的碰撞造山后的东西向岩石圈大规模减薄作用。本文在准确厘定成岩成矿年龄的基础上,结合区内花岗岩和钼矿床的地质地球化学研究,探讨了东秦岭钼矿成岩成矿物质来源、地球动力学背景,建立了钼矿成矿模型,提出了区内钼矿找矿的方向。     

冀东地区太阳沟钼矿床成因探讨：来自年代学、地球化学及S、Pb同位素的证据

太阳沟钼矿床位于冀东地区,矿区内出露的岩性主要为花岗斑岩和黑云母二长花岗岩,矿体主要赋存于花岗斑岩及其围岩接触带内,多呈透镜状、脉状产出。本文通过锆石U- Pb定年、全岩地球化学分析、辉钼矿Re- Os同位素测年及金属矿物S、Pb同位素分析,对太阳沟钼矿床的成岩、成矿时代准确厘定,并对矿床成因及成矿过程进行探讨。锆石U- Pb定年结果显示,花岗斑岩与黑云母二长花岗岩样品的206Pb/238U加权平均年龄分别为154. 8±1. 5Ma、156. 5±1. 2Ma。辉钼矿的Re- Os同位素测年获得155. 79±0. 93Ma的模式年龄加权平均值,与锆石U- Pb年龄在误差范围内一致,表明其为晚侏罗世构造- 岩浆活动产物。全岩地球化学特征表现为高硅、富碱,属准铝质、高钾钙碱性系列;相对富集轻稀土元素和Rb、Sr等大离子亲石元素,亏损重稀土元素和Nb、Ta等高场强元素,属高分异I型花岗岩。黄铁矿S、Pb同位素分析结果表明,S同位素组成分布比较集中,δ34S黄铁矿值均为正值（介于1. 3‰~1. 8‰之间,平均值为1. 53‰）;Pb同位素组成较为均一（206Pb/204Pb值范围为16. 76~17. 44,207Pb/204Pb值范围为15. 28~15. 43,208Pb/204Pb值范围为36. 64~37. 46）,均显示成矿物质主要来自受地幔混染的下地壳物质熔融。综合岩石学、年代学、地球化学及S、Pb同位素特征,本文认为：太阳沟钼矿床属于斑岩型钼矿床,是晚侏罗世古太平洋板块俯冲产生的壳幔相互作用引发下地壳物质部分重熔,富集大量的金属元素（Mo）,最终上升侵位、沉淀成矿。     

Re－Os同位素体系及其在岩浆Cu－Ni－PGE矿床研究中的应用

Ｒｅ－Ｏｓ同位素由于其较高的半衰期特点，近年来国外广泛用于前寒武纪含Ｃｕ－Ｎｉ－ＰＧＥ镁铁—超镁铁岩成岩年龄测定，并结合其他地球化学数据，对壳幔岩浆源及作用进行解释研究。特别是由于Ｏｓ是６个ＰＧＥ的其中之一，而多用于岩浆Ｃｕ－Ｎｉ－ＰＧＥ矿床贵金属来源的判别。中国岩浆Ｃｕ－Ｎｉ－ＰＧＥ矿床以金川矿床为代表，已有的研究表明，可能存在岩浆混合成矿作用，开展Ｒｅ－Ｏｓ同位素体系的研究将会提供进一步判断的证据     

Re—Os同位素体系及其在岩浆Cu—Ni—PGE矿床研究中的应用

Ｒｅ－Ｏｓ同位素由于其较高的半衰期特点,近年来国外广泛就于前寒武纪含Ｃｕ－Ｎｉ－ＰＧＥ镁铁－超镁铁岩成岩年,结合其他地球化学数据,对壳幔岩浆源及作用进行解释研究。特别是由于Ｏｓ 是６个ＰＧＥ的其中之一,而多用于岩浆Ｃｕ－Ｎｉ－ＰＧＥ矿床贵金属来源的判别。     

湘东南将军寨钨矿花岗岩地球化学特征及铼-锇同位素定年

将军寨钨矿是湘东南白云仙矿田中一个典型的石英脉型黑钨矿床。岩石学和岩石地球化学研究表明,将军寨钨矿花岗岩体为一复式岩体,是同源岩浆演化的产物,具有壳源花岗岩的特征。文章研究了白云仙矿田将军寨钨矿花岗岩的地球化学特征,并进行石英脉型黑钨矿石中辉钼矿的铼-锇同位素定年,以精确厘定将军寨钨矿的形成时间,揭示湘东南地区钨、锡等有色金属成矿的时限及其地球动力学背景。铼-锇同位素定年结果表明,辉钼矿中铼的含量偏低,表明将军寨钨矿的成矿物质来源可能是以上地壳为主。4件辉钼矿样品的铼-锇同位素模式年龄为(151.3±2.5)Ma～(163.6±2.3)Ma,其等时线年龄为(169.6±2.7)Ma,这表明将军寨钨矿形成于燕山早期,为华南中生代大规模成矿作用的产物。     

河北金厂峪金矿床辉钼矿与金矿化关系研究及意义

辉钼矿Re-Os测年方法现已广泛应用于各类金属硫化物矿床成矿年代学研究领域, 已成为石英脉型金矿床实现直接、准确定年的重要手段。然而, 正确理解辉钼矿与金成矿作用之间的确切关系, 选取具有代表性的辉钼矿样品是测年的前提。本文聚焦冀东地区规模最大的金矿床——金厂峪金矿床, 对其石英-钠长石-多金属硫化物脉中的黄铁矿和辉钼矿两者的产出状态及原位微量元素特征进行了详尽的对比, 研究探讨了金厂峪金矿床中辉钼矿与金矿化之间的关系。研究发现石英-钠长石-多金属硫化物脉含金丰富, 可见金和不可见金均大量赋存, 黄铁矿和辉钼矿均为重要的载金硫化物。镜下矿相学及原位微量元素证据表明, 早期形成的含金黄铁矿经历了再活化过程, 为稍晚形成的富金辉钼矿提供了大量的Au源, 两者可能为同一大的金成矿事件下不同成矿流体脉冲事件的产物。辉钼矿形成于金厂峪金矿的主成矿阶段, 与Au的二次浓集紧密相关, 并可作为高品位金矿体的标志性矿物之一。本文认为在准确厘定辉钼矿与金矿化关系的基础上, 辉钼矿Re-Os方法是一种可靠的石英脉型金矿直接定年手段。