沉积物和悬浮颗粒物在岩溶水系统污染物衰减与运移中的作用

本文讨论了沉积物和悬浮颗粒物/胶体在岩溶水系统污染物衰减与运移中的作用,介绍了关于瑞士某岩溶水系统内颗粒物与微生物污染间关系的实验结果。该实验场包括一个接纳农田排水的落水洞及与其相连的两个泉,其中一个泉是供水水源地。利用便携式粒子计实时监测泉水中颗粒分布的变化情况,同时对浊度、总有机碳和其它参数进行连续监测;并对水中E型大肠菌群进行了分析。在暴雨过后,观测到了浊度的两种不同表现:即泉排泄量增加时,浊度最初表现为脉状水动力条件下岩溶系统内沉积物的二次运移;几天后观测到的浊度则表明水已从落水洞到了泉口,常常具有高的总有机碳、硝酸盐及E型大肠菌群。颗粒分布分析结果差异更大:早期的浊度是不同粒径颗粒物的混合,而后期的浊度更多是由较细颗粒构成,因为大颗粒物已沉积在落水洞到泉口之间的岩溶系统内。E型大肠菌群与0.9～1.5 μm颗粒物之间具有很好的相关性。因而较细颗粒的相对增加可应用于微生物污染 “早期预报系统”。除了水污染,颗粒分还可以帮助我们研究岩溶环境的其它问题,如土壤侵蚀。      

Chloride contamination in construction aggregates due to periodic saline water intrusion: a case study in the Kaluganga River Estuary, Sri Lanka

The Kaluganga River Estuary is one of the main sources of construction sand in Sri Lanka. Salt water intrusion along this estuary due to extensive sand mining has increased over the years. Thus, the focus of the current research is to understand the relationship between river sand mining, salt water intrusion, and the resultant effects on construction sand. Two surveys were conducted along the Kaluganga Estuary along an 11 km stretch from the river mouth at predetermined intervals to measure depth water quality profiles, and to collect sediment samples. These surveys were carried out during maximum spring tide; first in a dry period and then in a wet period, to understand hydrographic effects on the quality of river sands. Sand samples were analysed for absolute chloride content and grain size distribution. Results showed significant salt water intrusion during the dry period, averaging 2,307 μS cm^?1 in surface waters throughout the surveyed 11 km stretch along with 3,818 μS cm^?1 (average) in bottom waters up to 5.6 km upstream from the river mouth causing above normal chloride content in the bottom sandy sediments. The high chloride content in bottom sands was recorded up to 5.5 km from the river mouth making them unsuitable for construction purposes. However, during wet period, salt water intrusion levels in the bottom waters were insignificant (average 61 μS cm^?1) and the chloride content in bottom sediments was very low. This study highlighted the requirement for regulations on river estuary sandmining for construction purposes.     

Effect of sodium chloride on the metabolic activity of halophilic bacteria isolated from the Lake Gardno estuary

The effect of different concentrations of sodium chloride on the metabolic activity of halophilic bacteria derived from the Lake Gardno estuary was studied using respirometric methods. The influence of salt was examined in two ways: the bacteria were preincubated in various concentrations of sodium chloride, and the cells used for respirometric measurements were supplied with substrates dissolved in water amended with various concentrations of the salt. Generally, an increase in the concentration of sodium chloride in the medium used for preincubation resulted in an increase in metabolic activity. Conversely, a decrease was noted when solutions of increasing salt content were employed to dissolve the substrate. The decrease in oxygen uptake noted when increased amounts of salt were added is proposed to be the result of the short period allowed for adaptation of cells to the higher salt concentrations.     

Geochemistry and quality of the groundwater from the karstic and coastal aquifer of Geropotamos River Basin at north-central Crete, Greece

In Geropotamos River Basin, located on the north-central part of Crete, Greece, two main factors were believed to be affecting the geochemistry of the groundwater with high salt contents: seawater intrusion and/or Miocene evaporates. To identify the origin of the high salinity in groundwater, a hydrogeochemical and isotopic study was performed. Water samples from 22 wells and 2 springs were analyzed for physico-chemical parameters, major ions analysis, as well as stable isotopes (??¹⁸O, ??D). From the present survey, in which detailed hydrogeochemical investigation was conducted, the uncertainty of the contamination sources was decreased in the northern part of Geropotamos Basin. The results complement the scenario in which seawater and the widespread human activities are the principal sources of groundwater contamination. Moreover, the results of the stable isotopes analyses (??¹⁸O and ??D) support the same hypothesis and make seawater intrusion the most probable cause for the highest salinity waters. It is indicated that saline intrusion is likely to occur along fractures in a fault zone through otherwise low-permeability phyllite?Cquartzite bedrock, which demonstrates the critical role of fracture pathways in salination problems of coastal aquifers.     

Hydrogeologic effects on the quality of water in the Oued Issen watershed, western Upper Atlas Mountains, Morocco

The study of spatial and temporal variations of some hydrochemical properties in the Oued Issen watershed, Morocco, has revealed their close relation to the area's lithologic and geologic characteristics and to variations in hydroclimatological cycles. High concentrations of sodium chloride are measured during flood periods, when the outcrops of the basin are leached by streams draining the rather dense hydrographic network. These variations depend also on the relative abundance of tributaries on both sides of the Oued, their respective contributions being hydrochemically very different: (1) northern-side tributaries, which mainly leach evaporitic terranes dating from the Late Triassic and Late Liassic periods and which are rich in gypsum and halite, increase the mineralization of the Oued Issen waters flowing toward the Abdelmoumen Dam; (2) the low salinity of water observed in the upstream portion of the watershed is due to dilution by waters from the southern-side tributaries, which are derived from snowmelt and the leaching of the high Paleozoic massif; (3) in the middle part of the basin, the increase in mineralization of the Oued Issen becomes substantial between the Abdelmoumen Dam and the Dkhila Dam, the next dam downstream, due to the absence of dilution by waters from the southern-side tributaries, which are sparse in this part of the basin. In addition, during flood periods, the outflow from the first dam is stopped. Thus, the main contribution of NaCl to the Oued is from the very salty Tirkou spring, which is situated downstream from the first dam. The geological characteristics of the basin have induced the development of high-salinity zones, which are particularly evident in the southwestern part of the basin in the vicinity of the confluence of the Oued Boulebaz with the Oued Issen. The discharge of very salty springs is controlled by faults that offset the formations that underlie the hydrographic network and degrade the quality of the Oued Issen. This water later recharges the unconfined aquifer along the Oued where it flows on the Oued Souss Plain. Received, July 1998/Revised, July 1999, September 1999/Accepted, November 1999     

Assessing the extent and sources of nitrate contamination in the aquifer system of southern Baldwin County,Alabama

A regional-scale groundwater study was conducted over a 2-year period to assess the extent of nitrate contamination and source identification for southern Baldwin County, AL. Groundwater wells were sampled and analyzed for nitrate and a host of other geochemical parameters which revealed that extensive areas within aquifer zone A2 exhibited nitrate concentrations exceeding regulatory limits. Spatial iso-concentration maps of nitrate were constructed using ArcGIS software to determine the extent and severity of contamination for the aquifers underlying southern Baldwin County with the primary interest focused on the heavily utilized aquifer zone A2. Nitrate levels in the central and northeastern portion of the study area were most extensive with maximum concentrations of 63 mg/L likely resulting from agricultural inputs. Several other small regions throughout the study area exhibited elevated levels of nitrate and chloride as high as 112 and 51.1 mg/L, respectively, and sources likely vary (i.e., residential septic systems, animal waste to agriculture). With the exception of a few groundwater samples, there was no obvious correlative relationship between chloride and nitrate concentration for data collected during the 2-year period. Collectively, a general inverse relationship between nitrate concentrations and well depth was observed for the aquifer system under investigation. The study provides an initial current data set of areas impacted or most vulnerable to nitrate contamination and initial assessment of likely sources of nitrate in the region.     

Residence time distribution in the Kirkgoz karst springs (Antalya-Turkey) as a tool for contamination vulnerability assessment

Lumped parameter modeling of environmental tracer (tritium, CFCs and tritiogenic helium-3) transport in the Kirkgoz karst springs (Antalya-Turkey) appears to be a useful tool for assessing the vulnerability to contamination. Based on tritium observations between 1963 and 2000, the springs revealed a mean residence time (MRT) of 120 years. This suggests an active transport volume of 71 billion cubic meters for the aquifer, a value that is coherent with the estimated void volume of karst aquifer based on the mass of associated travertine deposits. The CFC-11 and CFC-12 MRTs are in agreement with tritium-based MRT, after correcting for excess air effect. Excess crustal and mantle helium flux hindered the use of tritiogenic helium-3 as a potential tracer. The residence time distribution (RTD) indicates a groundwater transport system that is fed by recharges extending back to past several hundred years. This wide RTD suggests that any recent contamination that may have entered the system could progress slowly within the entire aquifer but would be unnoticed in the early period because of the dilution effect of uncontaminated past recharge waters. Once the contamination is recognized, it may last for many centuries ahead even if the contamination practice is stopped. Thus, control of contaminant release to aquifer and monitoring of contaminant level in Kirkgoz springs is an immediate task for the associated public health authorities.     

The impact of salt diapirs on the quality of carbonate karst waters,Bastak, Iran

The Gavbast karstic aquifer located in southern Iran is in direct contact with an exposed salt diapir. To assess the influence of the diapir on the quality of groundwater in the karstic aquifer, electrical conductivity, total dissolved solids, flow rate, temperature and major ion concentrations were measured at 57 sampling sites, including springs, surface waters and wells. A conceptual model of groundwater flow is proposed for the Gavbast karstic aquifer based on the geological setting, water budget, local base of erosion, and hydrochemistry of the sampling sites. The model suggests two subbasins in the Gavbast Anticline draining into two distinct discharging alluvial sections. Unexpectedly, groundwater discharging from the carbonate Gavbast aquifer is saline or brackish and water is of chloride type. The study indicates that the source of salinity of the Gavbast aquifers is infiltration of surface diapir-derived brine into the aquifer. The contribution of the diapir brine in the Gavbast karst aquifer is calculated about 4 L/s, using chloride mass balance. Construction of salt basins to evaporate brine discharging from the diapir springs is proposed to reduce the salinity of karst water. A row of strategically placed wells in the Gavbast karst aquifer would potentially exploit large volumes of fresh groundwater before it is contaminated by the salt. Such low-cost remediation should allow the agricultural exploitation of 40 km² of currently barren land.     

Contamination of the cement raw material in a quarry site by seawater intrusion,Darica-Turkey

The open pit mining nearby shoreline is planned to be extended into below sea level in order to use additional reserves of the cement raw material (marl). The raw material is currently contaminated by seawater intrusion below a depth of 20 m up to the distance of 90 m from shoreline. Seawater intrusion related contamination of the material used for the cement production was investigated by means of diffusion process for the future two below sea level mining scenarios covering 43 years of period. According to the results, chloride concentrations higher than the tolerable limit of a cement raw material would be present in the material about 10–25 cm inward from each discontinuity surface, controlling groundwater flow, located between 170 and 300 m landward from the shoreline at below sea level mining depths of 0–30 m. The estimations suggest that total amounts of dilution required for the contaminated raw material to reduce its concentration level to the tolerance limit with uncontaminated raw material are about 113- to 124-fold for scenario I (13 years of below sea level mining after 30 years of above sea level mining) and about 126- to 138-fold for scenario II (43 years of simultaneous above and below sea level minings).     

Water quality deterioration at a karst spring (Gallusquelle,Germany) due to combined sewer overflow: evidence of bacterial and micro-pollutant contamination

The concurrent use of karst aquifers as drinking water resources and receptors of combined sewer overflow lacking appropriate pre-treatment may cause conflicts between drinking water supply and storm water management. A storm water tank (SWT) for combined wastewater is identified as the source of sporadic contamination of a karst spring (Gallusquelle, “Schwäbische Alb”, SW Germany) used for public water supply. Spring water quality was examined by routine and event sampling and by evaluating physicochemical and microbiological parameters. The total number of microbial colonies growing at 20°C and the number of Escherichia coli colonies rose to values up to four orders of magnitude higher than background, 2–5 days after overflow of the SWT. High concentrations of chloride, sodium, and total organic carbon (TOC) and high values of turbidity coincide with this increase. However, high bacterial contamination is also observed while turbidity and TOC are low. Several wastewater-related organic micro-pollutants such as chlorinated and non-chlorinated organophosphates were detected in the SWT and, depending on their K_ow values and their biodegradability, in lower concentrations at the spring.     

Sources of nitrate contamination and age of water in large karstic springs of Florida

In response to concerns about the steady increase in nitrate concentrations over the past several decades in many of Floridas first magnitude spring waters (discharge 2.8 m³/s), multiple isotopic and other chemical tracers were analyzed in water samples from 12 large springs to assess sources and timescales of nitrate contamination. Nitrate-N concentrations in spring waters ranged from 0.50 to 4.2 mg/L, and ¹⁵N values of nitrate in spring waters ranged from 2.6 to 7.9 per mil. Most ¹⁵N values were below 6 per mil indicating that inorganic fertilizers were the dominant source of nitrogen in these waters. Apparent ages of groundwater discharging from springs ranged from 5 to about 35 years, based on multi-tracer analyses (CFC-12, CFC-113, SF₆, ³H/³He) and a piston flow assumption; however, apparent tracer ages generally were not concordant. The most reliable spring-water ages appear to be based on tritium and ³He data, because concentrations of CFCs and SF₆ in several spring waters were much higher than would be expected from equilibration with modern atmospheric concentrations. Data for all tracers were most consistent with output curves for exponential and binary mixing models that represent mixtures of water in the Upper Floridan aquifer recharged since the early 1960s. Given that groundwater transit times are on the order of decades and are related to the prolonged input of nitrogen from multiple sources to the aquifer, nitrate could persist in groundwater that flows toward springs for several decades due to slow transport of solutes through the aquifer matrix.     

Interactions Between Soils and Laboratory Simulated Electrolyte Solution

To study the impact of salt water intrusion on two types of soils from west coast region of India were investigated in the laboratory. The key characteristics evaluated included Atterberg limits, compaction characteristics, hydraulic conductivity and chemical characteristics of selected soils. The sea at this coast receives effluent from different points and hence the characteristics change with time and locality. Therefore, to maintain uniform composition, 0.5 N sodium chloride solution (NaCl) was prepared in the laboratory and batch tests were used to determine the immediate effect on soils. Soil specimens were prepared by mixing the soils with 0.5 N NaCl in the increments of 0, 5, 10 and 20% by weight to vary the degree of contamination. Experimental results of soils mixed with 0.5 N NaCl showed that the maximum dry density increases and the optimum moisture content (OMC) decreases with increasing sodium chloride concentration. The study also revealed that the hydraulic conductivity of the soils tested increases with increase in sodium chloride concentration. The Atterberg limits of contaminated specimens show a remarkable change when compared with uncontaminated specimens.     

Temporal variations in the depth-specific hydrochemistry and sewage-related microbiology of an urban sandstone aquifer,Nottingham, United Kingdom

The temporal and spatial characteristics of groundwater recharge in urban environments remain poorly understood. Depth-specific monitoring of groundwater quality in the Triassic Sandstone underlying the city of Nottingham, UK, indicates that contamination results primarily from sewage and atmospheric sources. The temporal and depth-specific characteristics of microbial and inorganic (e.g. nitrate, chloride, sulphate) contamination over the investigation period differ significantly and reflect the contrasting transport characteristics of surface-loaded solutes and particulate microbial species (bacteria and viruses) in the Triassic Sandstone. Differences result from a variety of factors, which include microbial die-off, dilution, and the contaminant-source characteristics. Observations in this study show that low levels of microbial contamination should be expected at depth in fissured sandstone due to aquifer heterogeneities such as fissuring and the occurrence of mudstone bands, though the magnitude of this contamination will vary over time. Furthermore, urban groundwater-protection measures based on solute-transport estimates may not be applicable to microbial contamination. Electronic Publication     

含NaCl和Na2SO4双组分盐渍土的水盐相变温度研究

盐渍土相变温度是判断土体中水分冻结与融化、盐分结晶与溶解的重要参数.不同盐分含量相变温度的差异,给盐渍土在降温过程中的水盐迁移过程及变形规律的模拟带来极大的不确定性.通过降温试验,研究了降温过程中氯盐和硫酸盐综合作用盐渍土中水盐相变温度的变化情况.结果表明:全盐量相同时,盐结晶温度随NaCl和Na2SO4比例的不同而不...     

Mechanism of Salt Contamination of Karstic Springs Related to the Messinian Deep Stage. The Speleological Model of Port Miou (France)

Submarine karstic springs are frequent on the Mediterranean shore but most of them are brackish which prohibits their use. The numerous attempts to catch these springs ended in failure. Recent studies on the development of karst systems and the paleogeography of the Mediterranean sea explain these failures. Studies on the shores of south-eastern France have enabled us to propose an operating model that explains the mechanism of salt contamination.

The Port Miou system (Cassis, France) is a two kilometers long submarine gallery developped in the limestone series of Calanques (Marseille, France). The average discharge is between 2 to 5 m3/s but the water is brackish. In the 70's a dam was built to prevent sea intrusion in the cave but the water remained brackish upstream of the dam. The use of helium, and then rebreathers by cave divers, made it possible to explore a vertical pit down to -179 m below the sea level at the end of the cave. At that depth, the water is still brackish.

Important quantity of titanium was observed at the surface of the cave sediment upstream of the dam and at the end of the cave. The titanium comes from the residual product of a factory of alumina that is discharged in the Cassidaigne submarine canyon, at a depth of 300 m b.s.l., a few kilometers south to the spring. This residual product locally called «red mud» is very rich in titanium. This supports the model of a sea water aspiration in a deep gallery connected to the canyon. The Cassidaigne canyon that cuts a limestone plateau with dolines and caves is probably a pocket valley. Its presence is related to the several stages of lowering of the Mediterranean sea at the Messinian Deep Stage that allowed the existence of cave networks up to several hundreds of meters below the present sea level. The sea water is now sucked into the system.

A similar example exists in Kefalonia island (Greece) where a sea intrusion is observed in coastal sinkholes. This model explains why the different attempts to diminish the salinity of these brackish springs, by construction of dams close to the outlets, have failed.     

MINERAL WATERS OF BOHEMIA

Mineral waters of Bohemia are characterized by a considerable variety of chemical gaseous composition. They may be subdivided chemically into: calcium bicarbonate, sodium bicarbonate, magnesium sulfate, sodium sulfate, and ferruginous sulfate. Carbonated-water springs are chiefly developed along the periphery of the Bohemian massif. The conditions of formation of such springs in Karlovy Vary, Frantiskovy Lázně and Mariánské Lazne and Luga?evice are highly distinctive. Hydrogen-sulfide waters are widespread along the eastern margin of the region, forming part of an extensive zone of oil-bearing waters stretching from Austria into Czechoslovakia and Poland. The principal chemical types of hydrogen sulfide waters are the sodium bicarbonate and calcium bicarbonate varieties. Waters of Bohemia are distinguished according to the degree of radioactivity, low-, mean-, and high-radioactive. The greatest number of radioactive springs has been found on Rudná Hora, the Sudeten, the Slavkov Forests, Central Bohemia and Bohemian Moravian Hills.

Bohemia's mineral waters are widely used for medicinal purposes. — Auth. English Summary     

Influence of topsoil of pyroclastic origin on microbial contamination of groundwater in fractured carbonate aquifers

The aim of the research was to analyse the influence of a topsoil of pyroclastic origin on microbial contamination of groundwater in a carbonate aquifer and verify the reliability of thermotolerant coliforms and fecal enterococci as bacterial indicators. The research was carried out through hydrogeological and microbiological monitoring at an experimental field site in Italy during two hydrologic years and through column tests in a laboratory. The taxonomic classification of fecal indicators detected in spring water samples was performed using API20 galleries. Fecal enterococci were also identified by means of 16S rRNA gene sequencing. The topsoil of pyroclastic origin significantly retains both thermotolerant coliforms and fecal enterococci. Results of column tests carried out in soil blocks collected randomly within the test site suggest that Escherichia coli was more retained than Enterococcus faecalis, even though this difference is statistically significant in only two out of six soil samples. Thus, a non-uniform difference in retention is expected at field scale. This suggestion is in agreement with the results of the microbiological monitoring. In fact, fecal enterococci were a more reliable indicator than thermotolerant coliforms for detecting contamination at both seasonal springs of the aquifer system, while no significant differences were observed at the perennial spring.     

Hydrogeological and geochemical characterisation of the Rock of Orvieto

The town of Orvieto, located on the Rock of the same name, is an example of “vulnerable town”; problems of slope instability connected with the lithological and morphological characteristics of the Rock have been thoroughly examined and discussed during previous research studies. Hydrogeochemical data about groundwater recharging the springs present in the area were never taken into account. Pollution of the springs is well known but still occurs for unclear reasons. The aim of this work is therefore to present the results of a hydrogeological and geochemical investigation of all the springs along the slopes of Orvieto hill and at the foot of the tuffaceous Rock, to characterize the groundwater flow paths and to suggest a possible source of contamination. The research study was carried out during three hydrogeochemical surveys in the years 1998–1999, 2003–2004, and 2007–2008.     

Amorphous silica solubilities—II. Effect of aqueous salt solutions at 25°C

The solubility of amorphous silica was measured at 25°C in ten separate sets of aqueous salt solutions—potassium chloride, potassium nitrate, sodium chloride, lithium chloride, lithium nitrate, magnesium chloride, calcium chloride, magnesium sulfate, sodium bicarbonate and sodium sulfate. The concentrations of the salts were varied from zero to saturation with both salt and amorphous silica. With increasing concentration of salt, the solubility of amorphous silica always decreased as expected from an average value of 0.00218 m in water. Nevertheless, the extent of decrease differed greatly from a 6% decrease in a solution saturated with NaHCO₃ to a 95.7% decrease in a solution saturated with CaCl₂. A striking correlation was observed: In the 1-1 and 2-1 electrolyte salt solutions at a given molality the effect on the solubility of silica depended upon the cation in the order Mg²⁺, Ca²⁺ > Li⁺ > Na⁺ > K ⁺.     

氯盐和冻融耦合下水泥土的强度和破坏特征

为了研究氯盐侵蚀和冻融循环耦合下水泥土无侧限抗压强度和破坏特征, 进行了不同浓度氯化钠溶液下的水泥土冻融循环试验, 得到了冻融前后的冻融腐蚀因子、 体积变化率和变形模量, 分析了微观结构特征。结果表明： 在氯盐侵蚀和冻融循环耦合下, 水泥土的无侧限抗压强度、 冻融腐蚀因子均随着冻融循环次数的增加而呈现下降趋势; 氯盐浓度越高, 水泥土的无侧限抗压强度、 冻融腐蚀因子下降的幅度越大。随着冻融循环次数的增加, 在同种浓度溶液中, 水泥土的体积变化率增大, 变形模量减小; 氯盐浓度增大, 水泥土体积膨胀变大, 内部结构松散, 抵抗变形的能力减弱。相同冻融循环次数下, 氯盐溶液产生的损伤要大于清水中的损伤, 随着氯盐溶液浓度的增加, 水泥土内部微观结构损伤越严重。