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1.
This paper presents evaluation of cation distributions from diffraction data collected at high T, P, and is an extension of the spinel structure modelling procedure by Lavina et al. (2002). Optimised cation-to-oxygen distances are modified for thermal expansion and compressibility at T and P of interest following Hazen and Prewitt (1977) and Hazen and Yang (1999). The procedure is applied to literature data concerning hercynite, spinel s.s., Zn aluminate, Zn ferrite, magnetite and the (Fe3O4)1–
x
(MgAl2O4)
x
join. Calculated cation distribution is strongly affected by standard deviations in cell parameters and oxygen coordinates. The underestimated values often reported in the literature for powder profile refinements may strongly affect the cation distribution; however, if standard deviations are increased to physically realistic values, consistent results are obtained. For P up to 10 GPa, reasonable evaluations of cation distribution are obtained for spinel s.s., Zn aluminate and magnetite, whereas for Zn ferrite they are limited to 1.8 GPa. For P beyond 10 GPa, compressibility cannot be assumed to be linear; the relationship between cell parameter and pressure is well-defined, but the inaccuracy of oxygen coordinate prevents simple modelling of bond distances with pressure. 相似文献
2.
Vibrational density of states of the NaAlSi2O6 jadeite and NaAlSiO4 calcium ferrite (CF)-type, and SiO2 stishovite is calculated as a function of pressure up to 50 GPa using density functional perturbation theory. The calculated
frequencies are used to determine the thermal contribution to the Helmholtz free energy within the quasi-harmonic approximation
and to derive the equation of state and several thermodynamic properties of interest. A dissociation of jadeite into a mixture
of a CF-type phase and stishovite is predicted to occur at 23.4 GPa and 1,800 K with a positive Clapeyron slope of 2.8 MPa/K.
Elastic anisotropy for jadeite, the CF-type phase, and stishovite also computed clearly shows that stishovite and the CF-type
phase are the most anisotropic and isotropic in these three phases, respectively. 相似文献
3.
4.
L. N. Berdnikov O. V. Vozyakova A. Yu. Kniazev V. V. Kravtsov A. K. Dambis S. V. Zhuiko 《Astronomy Reports》2012,56(4):290-304
We have obtained 26 372 CCD frames in the B, V, and I
c
filters for 81 RR Lyrae stars in 2008–2010, using the 76-cm telescope of the South African Astronomical Observatory and the
40-cm telescope of the Cerro Armazones Observatory, North Catholic University (Chile) using an SBIG ST-10XME CCD camera. For
12 of these RR Lyrae stars, we also obtained 337 brightness measurements in the B and V bands in 2000–2001 using the 60-cm telescope of the High Altitude Mt. Maidanak Observatory (Republic of Uzbekistan). We present
tables of observations, light curves, and improved light-curve elements for all these RR Lyrae stars. The Blazhko effect was
detected for SU Hor. 相似文献
5.
The compressibility at room temperature and the thermal expansion at room pressure of two disordered crystals (space group
C2/c) obtained by annealing a natural omphacite sample (space group P2/n) of composition close to Jd56Di44 and Jd55Di45, respectively, have been studied by single-crystal X-ray diffraction. Using a Birch–Murnaghan equation of state truncated
at the third order [BM3-EoS], we have obtained the following coefficients: V
0 = 421.04(7) Å3, K
T0 = 119(2) GPa, K′ = 5.7(6). A parameterized form of the BM3 EoS was used to determine the axial moduli of a, b and c. The anisotropy scheme is β
c
≤ β
a
≤ β
b
, with an anisotropy ratio 1.05:1.00:1.07. A fitting of the lattice variation as a function of temperature, allowing for linear
dependency of the thermal expansion coefficient on the temperature, yielded αV(1bar,303K) = 2.64(2) × 10−5 K−1 and an axial thermal expansion anisotropy of α
b
≫ α
a
> α
c
. Comparison of our results with available data on compressibility and thermal expansion shows that while a reasonable ideal
behaviour can be proposed for the compressibility of clinopyroxenes in the jadeite–diopside binary join [K
T0 as a function of Jd molar %: K
T0 = 106(1) GPa + 0.28(2) × Jd(mol%)], the available data have not sufficient quality to extract the behaviour of thermal expansion for the same binary join in
terms of composition. 相似文献
6.
SRABANTI BALLAV PRABIR K PATRA YOUSUKE SAWA HIDEKAZU MATSUEDA AHORO ADACHI SHIGERU ONOGI MASAYUKI TAKIGAWA UTPAL K DE 《Journal of Earth System Science》2016,125(1):47-64
Simulation of carbon dioxide (CO2) at hourly/weekly intervals and fine vertical resolution at the continental or coastal sites is challenging because of coarse horizontal resolution of global transport models. Here the regional Weather Research and Forecasting (WRF) model coupled with atmospheric chemistry is adopted for simulating atmospheric CO2 (hereinafter WRF-CO2) in nonreactive chemical tracer mode. Model results at horizontal resolution of 27 × 27 km and 31 vertical levels are compared with hourly CO2 measurements from Tsukuba, Japan (36.05°N, 140.13 oE) at tower heights of 25 and 200 m for the entire year 2002. Using the wind rose analysis, we find that the fossil fuel emission signal from the megacity Tokyo dominates the diurnal, synoptic and seasonal variations observed at Tsukuba. Contribution of terrestrial biosphere fluxes is of secondary importance for CO2 concentration variability. The phase of synoptic scale variability in CO2 at both heights are remarkably well simulated the observed data (correlation coefficient >0.70) for the entire year. The simulations of monthly mean diurnal cycles are in better agreement with the measurements at lower height compared to that at the upper height. The modelled vertical CO2 gradients are generally greater than the observed vertical gradient. Sensitivity studies show that the simulation of observed vertical gradient can be improved by increasing the number of vertical levels from 31 in the model WRF to 37 (4 below 200 m) and using the Mellor–Yamada–Janjic planetary boundary scheme. These results have large implications for improving transport model simulation of CO2 over the continental sites. 相似文献
7.
While multiple species of macroalgae and seagrass can benefit from elevated CO2 concentrations, competition between such organisms may influence their ultimate responses. This study reports on experiments performed with a Northwest Atlantic species of the macroalgae, Ulva, and the seagrass, Zostera marina, grown under ambient and elevated levels of pCO2, and subjected to competition with each other. When grown individually, elevated pCO2 significantly increased growth rates and productivity of Ulva and Zostera, respectively, beyond control treatments (by threefold and 27%, respectively). For both primary producers, significant declines in tissue δ13C signatures suggested that increased growth and productivity were associated with a shift from use of HCO3? toward CO2 use. When grown under higher pCO2, Zostera experienced significant increases in leaf and rhizome carbon content as well as significant increases in leaf carbon-to-nitrogen ratios, while sediments within which high CO2 Zostera were grown had a significantly higher organic carbon content. When grown in the presence of Ulva; however, above- and below-ground productivity and tissue nitrogen content of Zostera were significantly lower, revealing an antagonistic interaction between elevated CO2 and the presence of Ulva. The presence of Zostera had no significant effect on the growth of Ulva. Collectively, this study demonstrates that while Ulva and Zostera can each individually benefit from elevated pCO2 levels, the ability of Ulva to grow more rapidly and inhibit seagrass productivity under elevated pCO2, coupled with accumulation of organic C in sediments, may offset the potential benefits for Zostera within high CO2 environments. 相似文献
8.
R. Chaudhary Y. W. Tong A. K. Dikshit 《International Journal of Environmental Science and Technology》2018,15(10):2183-2192
Axenic culture of microalgae Chlorella vulgaris ATCC® 13482 and Scenedesmus obliquus FACHB 417 was used for phycoremediation of primary municipal wastewater. The main aim of this study was to measure the effects of normal air and CO2-augmented air on the removal efficacy of nutrients (ammonia N and phosphate P) from municipal wastewater by the two microalgae. Batch experiments were carried out in cylindrical glass bottles of 1 L working volume at 25 °C and cool fluorescent light of 6500 lux maintaining 14/10 h of light/dark cycle with normal air supplied at 0.2 L min?1 per liter of the liquid for both algal strains for the experimental period. In the next set of experiments, the treatment process was enhanced by using 1, 2 and 5% CO2/air (vol./vol.) supply into microalgal cultures. The enrichment of inlet air with CO2 was found to be beneficial. The maximum removal of 76.3 and 76% COD, 94.2 and 92.6% ammonia, and 94.8 and 93.1% phosphate after a period of 10 days was reported for C. vulgaris and S. obliquus, respectively, with 5% CO2/air supply. Comparing the two microalgae, maximum removal rates of ammonia and phosphate by C. vulgaris were 4.12 and 1.75 mg L?1 day?1, respectively, at 5% CO2/air supply. From kinetic study data, it was found that the specific rates of phosphate utilization (q phsophate) by C. vulgaris and S. obliquus at 5% CO2/air supply were 1.98 and 2.11 day?1, respectively. Scale-up estimation of a reactor removing phosphate (the criteria pollutant) from 50 MLD wastewater influent was also done. 相似文献
9.
10.
The thermoelastic behaviour of anthophyllite has been determined for a natural crystal with crystal-chemical formula ANa0.01
B(Mg1.30Mn0.57Ca0.09Na0.04) C(Mg4.95Fe0.02Al0.03) T(Si8.00)O22
W(OH)2 using single-crystal X-ray diffraction to 973 K. The best model for fitting the thermal expansion data is that of Berman
(J Petrol 29:445–522, 1988) in which the coefficient of volume thermal expansion varies linearly with T as α
V,T
= a
1 + 2a
2 (T − T
0): α298 = a
1 = 3.40(6) × 10−5 K−1, a
2 = 5.1(1.0) × 10−9 K−2. The corresponding axial thermal expansion coefficients for this linear model are: α
a
,298 = 1.21(2) × 10−5 K−1, a
2,a
= 5.2(4) × 10−9 K−2; α
b
,298 = 9.2(1) × 10−6 K−1, a
2,b
= 7(2) × 10−10 K−2. α
c
,298 = 1.26(3) × 10−5 K−1, a
2,c
= 1.3(6) × 10−9 K−2. The thermoelastic behaviour of anthophyllite differs from that of most monoclinic (C2/m) amphiboles: (a) the ε
1 − ε
2 plane of the unit-strain ellipsoid, which is normal to b in anthophyllite but usually at a high angle to c in monoclinic amphiboles; (b) the strain components are ε
1 ≫ ε
2 > ε
3 in anthophyllite, but ε
1 ~ ε
2 ≫ ε
3 in monoclinic amphiboles. The strain behaviour of anthophyllite is similar to that of synthetic C2/m
ANa B(LiMg) CMg5
TSi8 O22
W(OH)2, suggesting that high contents of small cations at the B-site may be primarily responsible for the much higher thermal expansion
⊥(100). Refined values for site-scattering at M4 decrease from 31.64 epfu at 298 K to 30.81 epfu at 973 K, which couples with similar increases of those of M1 and M2 sites. These changes in site scattering are interpreted in terms of Mn ↔ Mg exchange involving M1,2 ↔ M4, which was first detected at 673 K. 相似文献
11.
Deendayal Rathod K. Muthukkumaran T. G. Sitharam 《Geotechnical and Geological Engineering》2018,36(3):1509-1524
Pile foundations are often subject to lateral loading due to various forces on a variety of structures like high rise buildings, transmission towers, power stations, offshore structures and highway and railway structures. The present investigation is to study the effect of slopes on p-y curves (where p is the static soil reaction and y is the pile deflection) due to static lateral loading in soft clay (Consistency index Ic = 0.42). A series of laboratory model tests were carried out on the instrumented model pile on sloping ground (slopes of 1V:1H, 1V:1.5H, 1V:2H, 1V:3H and 1V:5H) and with varying embedment length to diameter ratio (L/D) of 20, 25 and 30. From the experimental results, the bending moment curves along the pile shaft are double differentiated to obtain the soil resistance (p) and double integrated to obtain the deflection (y) using curve fitting method. New p-y curves for piles located on crest of soft clay with different sloping ground surface under static lateral loading are developed. Moreover, the effect of sloping angles on proposed p-y curves was studied. 相似文献
12.
Chang Wang Ling Wang Ying Wang Yong Liang Jie Zhang 《Environmental Earth Sciences》2012,65(6):1643-1649
To offer an insight into the toxicity of nanomaterials (NM) on the growth of bacteria, Escherichia coli (E. coli), Bacillus subtilis (B. subtilis) and Agrobacterium tumefaciens (A. tumefaciens) were exposed to nano-Au, nano-Ag, nano-Fe and fullerene (C60) in this study. As an effective bactericide, nano-Ag induced high toxicity on these three bacteria; C60 could inhibit their growth; however, B. subtilis and E. coli could recover as exposure time extended. Nano-Au and nano-Fe had hardly any effect on three bacteria. A. tumefaciens showed the lowest resistance and slowest growth rate during exposure. Images obtained by scanning electron microscope (SEM)
revealed that nano-Ag could cause damage to the cell structure of three bacteria at 1 μg/mL. Slight damage on E. coli was found when exposed to C60, whereas no obvious physical damage was found after exposure to nano-Au or nano-Fe. It is assumed that surface activities
of NM might be responsible for the different toxic effects on these bacteria. 相似文献
13.
In the present paper, the parameters affecting the uncertainties on the estimation of M max have been investigated by exploring different methodologies being used in the analysis of seismicity catalogue and estimation of seismicity parameters. A critical issue to be addressed before any scientific analysis is to assess the quality, consistency, and homogeneity of the data. The empirical relationships between different magnitude scales have been used for conversions for homogenization of seismicity catalogues to be used for further seismic hazard assessment studies. An endeavour has been made to quantify the uncertainties due to magnitude conversions and the seismic hazard parameters are then estimated using different methods to consider the epistemic uncertainty in the process. The study area chosen is around Delhi. The b value and the magnitude of completeness for the four seismogenic sources considered around Delhi varied more than 40% using the three catalogues compiled based on different magnitude conversion relationships. The effect of the uncertainties has been then shown on the estimation of M max and the probabilities of occurrence of different magnitudes. It has been emphasized to consider the uncertainties and their quantification to carry out seismic hazard assessment and in turn the seismic microzonation. 相似文献
14.
Luisa M. Saavedra Diego Parra Valeska San Martin Nelson A. Lagos Cristian A. Vargas 《Estuaries and Coasts》2018,41(4):1118-1129
Coastal ecosystems are exposed to changes in physical-chemical properties, such as those occurring in upwelling and freshwater-influenced areas. In these areas, inorganic carbon can influence seawater properties that may affect organisms and populations inhabiting benthic habitats such as the intertidal mussel Perumytilus purpuratus. Feeding and metabolic responses were measured in adult mussels from two geographic regions (central and southern Chile) and two local habitats (river-influenced and non-river-influenced) and three pCO2 levels (380, 750, and 1200 μatm pCO2 in seawater). The feeding rates of mussels tend to increase at high pCO2 levels in seawater; however this response was variable across regions and local habitats. In contrast, there was no difference in the respiratory rate of mussels between geographic areas, but there was a significant reduction of oxygen consumption at intermediate and high levels of pCO2. The results indicate that river-influenced organisms compensate for reductions in metabolic cost at elevated pCO2 levels by having their energy demands met, in contrast with non-river-influenced organisms. The lack of regional-scale variability in the physiological performance of mussels may indicate physiological homogeneity across populations and thus potential for local adaptation. However, the local-scale influences of river- and non-river-influenced habitats may counterbalance this regional response promoting intra-population variability and phenotypic plasticity in P. purpuratus. The plasticity may be an important mechanism that allows mussels to confront the challenges of projected ocean acidification scenarios. 相似文献
15.
Summary The complexation of aluminium(III) and silicon(IV) was studied in a simplified seawater medium (0.6 M Na(Cl)) at 25 °C. The
measurements were performed as potentiometric titrations using a hydrogen electrode with OH
− ions being generated coulometrically. The total concentrations of Si(IV) and Al(III) respectively [Si
tot
] and [Al
t
ot], and −log[H
+] were varied within the limits 0.3 < [Si
tot
] < 2.5 mM, 0.5 < [Al
tot
] < 2.6 mM, and 2 ≤ -log[H
+] ≤ 4.2. Within these ranges of concentration, evidence is given for the formation of an AlSiO(OH)
3
2+
complex with a formation constant log β1,1-1 = −2.75 ± 0.1 defined by the reaction
Al
3++Si (OH)4 ↔ AlOSi(OH)
3
2+
+H
+
An extrapolation of this value to I=0 gives log β1,1-1 = −2.30. The calculated value of log K (Al
3++SiO(OH)
3
−
↔ AlOSi(OH)
3
2+
) = 6.72 (I=0.6 M) can be compared with corresponding constants for the formation of AlF
2+ and AlOH
2+ , which are equal to 6.16 and 8.20. Obviously, the stability of these Al(III) complexes decreases within the series OH
−>SiO(OH)
3
−
> F
− 相似文献
16.
Alejandro?D.?Canepuccia Maria?S.?Fanjul Eugenia?Fanjul Florencia?Botto Oscar?O.?Iribarne Consejo Nacional de Investigaciones Científicas y Técnicas Departamento de Biología Universidad Nacional de Mar del Plata Mar del Plata Argentina 《Estuaries and Coasts》2008,31(5):920-930
The role of positive and indirect interactions is often crucial in communities with intense abiotic stress such as salt marshes.
The burrowing crab, Neohelice (=Chasmagnathus) granulata, is the dominant benthic macroinvertebrate of southwest Atlantic marshes (southern Brazil to Northern Argentinean Patagonia),
having strong direct and indirect effects on marsh soil and, in consequence, on marsh vegetation and primary consumers. In
this work, we investigate if this crab indirectly modifies habitat use by the granivorous rodents, Akodon azarae and Oligoryzomys flavescens, by increasing nutrient availability and thus enhancing seed production by the marsh plant Spartina densiflora. The study was conducted at the Mar Chiquita Coastal Lagoon, Argentina (37°32′ S). Rodent frequencies in S. densiflora were positively correlated with crab densities throughout the low and middle marsh. Additionally, the highest quality of
S. densiflora and inflorescence density was recorded at the highest crab densities. Experimental manipulation of crab densities shows that
N. granulata indirectly enhances the performance of S. densiflora (e.g., decreased fiber content and C/N ratios) and increases density of seeds. Moreover, N. granulata also facilitates S. densiflora seed availability to rodents by concentrating them in sediment mound at their burrows entrances. Experimental rodent exclusions
showed that rodent species used S. densiflora seeds, a variable positively related to crab burrow density. Thus, our results show that N. granulata drives the granivorous rodent distribution and the intensity of seeds–rodent interaction trough facilitative and indirect
interactions in marsh community. 相似文献
17.
The M w 7.8 2015 Gorkha earthquake and its aftershocks significantly impacted the lives and economy of Nepal. The consequences of landslides included fatalities, property losses, blockades of river flow, and damage to infrastructural systems. Co-seismic landslides triggered by this earthquake were significantly widespread and pose a major geodisaster. There were tens of thousands of landslides triggered by the earthquake, majority of which were distributed in between the epicenter of the main shock and the M w 7.3 aftershock. Although 14,670 landslides triggered by this earthquake were identified, only approximately 23% of them were of moderate to large scale with areas greater than 100 m2. Of the moderate- to large-scale landslides identified, just over 90% were triggered by the main shock and smaller aftershocks prior to the major (M w 7.3) aftershock, while nearly 10% were triggered by the ground shaking induced by the major aftershock. Moreover, the number of landslides triggered by the 2015 Gorkha earthquake, specifically by the main shock, was slightly more than the expected number of landslides for the recorded maximum peak ground acceleration (PGA) in comparison to the co-seismic landslides triggered by 26 earthquakes. Over 90% of those moderate- to large-scale landslides were concentrated within the estimated fault rupture surface. Majority of these moderate- to large-scale landslides were disrupted failures with over 96% of which were classified as earth falls. However, the majority of small-scale landslides were rock or boulder falls. The most number of moderate- to large-scale landslides were triggered in the slate, shale, siltstone, phyllite, and schist of the Lesser Himalayan formation followed by an equally significant number in both schist, gneiss, etc. of the Higher Himalayan formation and the phyllite, metasandstone, schist, etc. of the Lesser Himalayan formation. The sizes (i.e., areas) of the landslides were lognormally distributed, with a mode area of 322.0 m2. Slope inclinations of the moderate- to large-scale landslides followed a normal distribution with a mean slope inclination of 32.6° and standard deviation of 13.5°. There exists a strong correlation between the number of landslides and the peak ground acceleration within the study area, specific for different geological formations. 相似文献
18.
C. A. Timotheo C. M. LauerJr. 《International Journal of Environmental Science and Technology》2018,15(3):659-664
Vegetable tannins are complex polyphenols, which occur widely in nature. Traditionally, natural tannins have been used for tanning leather. In Brazil, the main tannin-based products are obtained from Acacia mearnsii, which is a leguminous tree native to Southeastern of Australia, and the first seeds were brought to Brazil in 1928. The main cultivation of acacia was established in Rio Grande do Sul state due to the possibility of raw material for charcoal, adhesives to fuel and for tanning leather. The leather tanning processes based on plant tannins are thought to be less harmful than chromium-based tanning, and it has been used as a sustainable alternative. However, there is scarce information about the environmental impact of the leather tanning processes, with most studies reporting inhibitory effects against microorganisms at high doses and stimulatory and positive health effects at low concentrations. The aim of this study was to evaluate the toxicity of tannin preparations extracted from A. mearnsii in Saccharomyces cerevisiae. Vegetable tannin toxicity in yeast was tested using two tannin treatments in different concentrations. In general, the results showed toxicity of vegetable in yeast, BY4741 and gsh1Δ strains. 相似文献
19.
M. Seifipour M. Emadi-Baygi B. Saffar Sh. Abolmaali 《International Journal of Environmental Science and Technology》2017,14(3):481-486
Cadmium and other heavy metals lead to environmental danger, and these heavy metals are a great threat to human and other animal’s health. Investigation of the relationship between survival of E. coli and metallothionein smtA gene expression against cadmium ion is the goal of this research. Survival of recombinant bacteria containing smtA gene was analyzed against various concentrations of cadmium chloride salt using optical density (OD). At the resistive range, recombinant bacteria were subjected to different treatments. At the logarithmic phase of bacterial growth, sampling, RNA extraction and cDNA synthesis were performed and smtA gene expression was then analyzed by real-time PCR using designed primers for smtA gene and Amp resistance (as the calibrator gene). Relative gene expression was calculated using the ??Ct method. The resistive range against cadmium chloride was 0.5–0.7 mM (minimum inhibitory concentration (MIC = 0.5 mM)). Survival and gene expression analysis showed that in induced bacteria, smtA expression was increased significantly that in turn conferred resistance to cadmium chloride prominently. There was a direct relationship between increased smtA gene expression and survival of the recombinant bacteria. Therefore, our result may help to confront to cadmium metal environmental pollution using overexpression of smtA gene expression in recombinant bacteria. 相似文献
20.
Some thermal infrared anomalies on the earth’s surface are omens of stronger earthquakes, and have a close relationship with
the stress fields. Satellite-based remote sensing is an important means of monitoring and researching this phenomenon. The
M
S 7.3 Yutian earthquake in Xinjiang on March 20, 2008 and the M
S 8.0 Wenchuan earthquake in Sichuan on May 12, 2008 both happened in the Qinghai–Tibet Plateau, China, with epicenters more
than 2,000 km apart. The two events, however, were a production of an identical stress field in different developing phases.
Prior to the M
S 7.3 Yutian earthquake, a large-scale abnormal temperature rise not only covered the epicenter of the forthcoming Yutian earthquake,
but also arrived at the epicenter of the farther Wenchuan earthquake. The revolving elliptic stress thermal field reflecting
earthquake gestation moved from the west to the east of the Wenchuan epicenter at the time of the Yutian event occurrence.
The rotation of the calefactive ellipses and belts prior to the two strong events agreed with the stress field, the focal
mechanism, and modality and mechanism property of the ruptures in the crustal surface induced by the events. It should be
a reflection of the partial mantle uprush and rotation. 相似文献