Salinization in coastal aquifers of arid zones: an example from Santo Domingo,Baja California Sur,Mexico

Groundwater quality in the Santo Domingo Irrigation District area in Baja California Sur, Mexico, indicates the presence of various salinization processes, (1) the geological matter of marine origin comprising the aquifer material suffers diagenetic effects due to its interaction with groundwater of low salinity, (2) the effects of intensive agriculture practices produce effluents that infiltrate to the saturated zone, and (3) the extraction of groundwater causes modifications in the natural flow system induces lateral flow of seawater from the coast line. However, groundwater management has been carried out with the belief that the latter is the main source of salinization. This has resulted in a policy of installing wells increasingly far from the coast, which is not solving the problem. Irrigation-return and seawater that remains in the geological units have been identified as major sources of salinization. Controls should be imposed when installing wells in contact with clayey units that form the base of the aquifer. Extracted groundwater consists of a mixture of (1) groundwater of relatively low salinity that circulates in the aquifer and (2) an extreme member with salinity different to seawater contained mainly in formations that have low permeability, which limits the aquifer underneath. The geochemistry of carbonates and cation-exchange reactions (both direct and reverse) control the concentration of Ca, Mg, Na, and HCO₃, as well as pH values. The concentrations of dissolved trace elements (F, Li, Ba, Sr) suggest that the extreme saline member is different from the average seawater composition. A distinction between the salinization caused by farming practices and that blamed on seawater is defined by the use of NO₃.     

Occurrence of landslides during the approach of tropical cyclone Juliette (2001) to Baja California Sur,Mexico

The approach of tropical cyclone (TC) Juliette, in 2001, to the Baja California Peninsula triggered at least 419 landslides. Most of the landslides were shallow slips and debris slides of limited areal extent, which were converted rapidly into debris flows to be exported quickly out of the mountain areas towards the lowlands. Main factors affecting landslide occurrence were total storm rainfall and intensity, aspect, geology and vegetation association. Two processes can be distinguished as initiating slope failure. Accumulation of rainfall from exposed bedrock slopes, generating excess overland flow, was the main process linked to failures in concave topography. A combination of wind and excess overland flow in the more convex or planar upper slopes was a secondary process related to heterogeneity of vegetation associations in the oak-dry tropical forests ecotone, as uprooted trees dislodged large regolith and bedrock blocks, priming hillslopes for further runoff concentration. An estimative threshold curve for triggering landslides in this region is sketched. From the analysis of historical information, storms like Juliette approach the southern peninsula on average once every 100 years. Denudation estimates are in the higher end of the spectrum for a tectonically passive margin. These estimates should be considered when taking decisions regarding management of water resources in this area through damming of streams. The results emphasize the need for a more detailed representation of the spatial distribution of the rainfall and winds for this mountainous region affected by TCs.     

Biological influences on modern sulfates: Textures and composition of gypsum deposits from Guerrero Negro,Baja California Sur,Mexico

Gypsum (CaSO₄·2H₂O) deposits from a range of sedimentary environments at Guerrero Negro, Baja California Sur, Mexico were investigated for microscale texture and composition in order to differentiate features formed under substantial microbial influence from those for which microbial effects were relatively minor or absent. Gypsum deposits were classified according to their sedimentary environment, textures, crystal habit, brine composition and other geochemical factors. The environments studied included subaqueous sediments in anchialine pools and in solar salterns, as well as subsurface sediments of mudflats and saltpans. Gypsum that developed in the apparent absence of biofilms included crystals precipitated in the water column and subsedimentary discs that precipitated from phreatic brines. Subsedimentary gypsum developed in sabkha environments exhibited a sinuous microtexture and poikilitically enclosed detrital particles. Water column precipitates had euhedral prismatic habits and extensive penetrative twinning. Gypsum deposits influenced by biofilms included bottom nucleated crusts and gypsolites developing in anchialine pools and saltern ponds. Gypsum precipitating within benthic biofilms, and in biofilms within subaerial sediment surfaces provided compelling evidence of biological influences on crystal textures and habits. This evidence included irregular, high relief surface textures, accessory minerals (S°, Ca-carbonate, Sr/Ca-sulfate and Mg-hydroxide) and distinctive crystal habits such as equant forms and crystals having distorted prism faces.     

Arsenic content and groundwater geochemistry of the San Antonio-El Triunfo, Carrizal and Los Planes aquifers in southernmost Baja California, Mexico

 The San Antonio-El Triunfo mining district, located at a mountainous region 45 km south-east of La Paz, Baja California, has been worked since the late 1700s. Mine waste material produced during 200 years of mineral extraction area poses a risk of local groundwater pollution and eventually, regional pollution to the Carrizal (west basin) and the Los Planes (east basin) aquifers. There are different types of deposits in the mining area. These are dominated by epithermal veins, in which arsenopyrite is an important component. Carrillo and Drever (1998a) concluded that, even though the amount of mine waste is relatively small in comparison to the large scale area, significant As in groundwater derived from the mine waste piles is found locally in the groundwater. This paper shows the results of geochemical analyses of groundwater samples from the San Antonio-El Triunfo area and the Carrizal and Los Planes aquifers during several years of monitoring (1993–1997). The highest values of total dissolved solids (TDS) and As are in the mineralized area where the mining operations occurred (∼1500 ppm TDS and 0.41 ppm As). The lowest concentrations of TDS and As are, in general, away from the mineralized area (∼500 ppm TDS and 0.01 ppm As). Sulfate and bicarbonate (alkalinity) are, in general, high near the mineralized area and low away from it. The arsenic concentrations vary seasonally, especially after the heavy summer thunderstorms. Geochemical modeling (MINTEQA2 and NETPATH) and analysis of the regional geochemical evolution of the groundwater from the mining area towards the aquifer of Los Planes shows that the most likely hydrochemical processes include: dilution, precipitation of calcite, and adsorption of As onto surfaces of iron oxyhydroxides (ferrihydrite). These processes act as natural controls to the extent and amount of As pollution in the Carrizal and Los Planes aquifers. Received: 4 May 1999 · Accepted: 22 February 2000     

Late Pliocene to Early Quaternary extensional detachment in the La Paz–El Cabo area (Baja California Sur, Mexico): implications on the opening of the Gulf of California and the mechanics of oblique rifting

We demonstrate that Pliocene to Early Quaternary sedimentary formations in Baja California Sur (Mexico) were deposited syn-tectonically over a major detachment associated with the exhumation of Mesozoic crust. The detachment dips to the ENE and is associated with E–W stretching. This large extensional structure strikes almost parallel to the general trend of the Gulf of California and extension is oblique to the East-Pacific seafloor-spreading direction. Crustal-scale stretching in this area was still active after the beginning of seafloor spreading c.  3.6 Ma ago. The detachment is capped by Late Pleistocene–Holocene alluvial sediments the deposition of which seems to be partly syn-tectonic and controlled by minor stretching subparallel to the present-day North American–Pacific kinematic vector. We discuss the implications of our observations on strain partitioning during opening of the California Gulf as well as on the structure of the Gulf of California margin.     

A geochemical and 3D-geometry geophysical survey to assess artificial groundwater recharge potential in the Pacific coast of Baja California,Mexico

A geophysical and geochemical study was carried out in the Maneadero aquifer, Baja California, Mexico, with the aim of identifying potential recharge locations for reclaimed water (RW). This coastal aquifer shows a significant decline in water quality, both as a result of salinization and the pollution by nitrates. Total dissolved solids (TDS) in an extreme case increased from 4 g l^?1 in 2000 to 27 g l^?1 in 2011. Nitrate as N–NO₃, reaches 46 mg l^?1. Based on their geochemistry and location, four water-quality zones are identified: (a) fresh water with TDS ≈ 1 g l^?1 in the upper creeks, (b) mixture between seawater and freshwater in the coast-proximal sections, (c) water significantly enriched in nitrate below and adjacent to the town of Maneadero, and (d) brackish water with no signs of current interaction with freshwater. The 3D geophysics identifies the influence of modern recharge areas and also buried flow-paths down to at least 30 m depth. The locations best suitable for aquifer recharge are those with equal or higher TDS concentrations (>2.5 g l^?1) than RW, which are located at the brackish water zone and/or at the coastal limits of the mixing zones.     

Detrital zircon ages in Palaeozoic and Mesozoic basement assemblages of the Peninsular Ranges batholith,Baja California,Mexico: constraints for depositional ages and provenance

The origin and continuity of Phanerozoic lithostratigraphic terranes in southern and Baja California remain an unsolved issue in Cordilleran tectonics. We present data from eight detrital zircon samples collected across the southern extent of the Peninsular Ranges that help constrain the provenance of detritus and the depositional ages of these basement units. Detrital zircon signatures from units in the eastern Peninsular Ranges correlate with Palaeozoic passive margin assemblages in the southwestern North American Cordillera. Units in the central belt, which consists of Triassic–Jurassic metasedimentary turbidite assemblages that probably deformed in an accretionary prism setting, and Cretaceous metasedimentary and metavolcanic units that represent the remnants of a continental margin arc, were derived from both proximal and more distal sources. The westernmost units, which are locally structurally interleaved with the Triassic through Cretaceous units of the central belt, are Cretaceous deposits that represent a series of collapsed basin complexes located within and flanking the Cretaceous Alisitos volcanic island arc. Cretaceous intra-arc units show little influx of cratonal material until approximately 110 Ma, whereas coeval sediments on the northern and eastern flanks of the Alisitos arc contain abundant cratonal detritus. Intra-arc strata younger than approximately 110 Ma contain large amounts of Proterozoic and older detrital zircons. These data suggest that basins associated with the Alisitos arc were either too distant or somehow shielded from North American detritus before 110 Ma. In the case of the former, increased influx of continental detritus after 110 Ma would support a tectonic model in which the arc was separated from North America by an ocean basin and, as the arc approached the continent, associated depositional centres were close enough to receive input from continental sources.     

A participatory approach to integrated aquifer management: The case of Guanajuato State,Mexico

Guanajuato State, located in central Mexico, with less than 2% of the countrys area, has almost 17,000 deep water wells, from which nearly 4,000 cubic hectometers (hm³) per year are being extracted, more than 1,000 hm³ over the estimated renewable yield. Since, in Mexico, water is administered under federal jurisdiction by the National Water Commission (CNA, for its Spanish acronym), the state government faces the challenge of ensuring its populations economic development without formal means of intervention. Being thus limited to apply mandatory policies and measures, the state water program has focused on the implementation of a two-sided strategy. First, basic hydrogeological studies and mathematical groundwater hydrodynamic models were developed upon a comprehensive survey of existing wells and a general revision of the states geological framework. Second, a structure for water users participation in water management actions was promoted (from the dissemination of information to the implementation of pilot efficient water use projects) with financial, technical and political support from the state. Simultaneously, a coordinated effort towards the completion of the water users registry was performed with the federal authority along with other supporting measures such as training and monitoring programs. In this paper, a general overview of the projects achievements and challenges is presented.To make direct contact with the water-user associations mentioned in this paper, please write to Eng. Aurelio Navarrete of the State Water Council at: cehgto@prodigy.net.mx.     

A geostatistically based approach to the identification of aquifer transmissivities in Yolo Basin, California

A geostatistically based approach is developed for the identification of aquifer transmissivities in Yolo Basin, California. The approach combines weighted least-squares with universal kriging and cokriging techniques in an overall scheme that (1)considers a prioriknown information on aquifer transmissivity and specific capacities of wells, (2)considers uncertainties in water level and transmissivity data, and (3)estimates the reliability of the generated transmissivity values. Minimization of a global least-squares function that incorporates calibration and plausibility criteria leads to a transmissivity map that shows a good agreement with pumping-test results.     

多源地质数据综合三维建模及地质学分析——以青海木里三露天勘探区为例

常规的二维地质图件难以直观地表达煤炭资源的三维空间展布。基于青海木里三露天勘探区的钻孔数据、二维平面地形地质图、煤层底板等高线和地质勘探剖面图,对该地区地形、煤层底板和断层的三维空间形态及温度场进行了重构。三维重建结果清晰明确地展示了三露天勘探区煤层的形态特征、各个沉积旋回的聚煤范围和强度、构造轮廓特征以及地下地温特征等。结果表明,基于多源地质数据的三维可视化技术可直观形象地反映煤层等地质体的形态和属性特征,可有效地分析复杂断层在地质历史中产生的先后顺序及古构造应力场特征。使用三维建模技术重构地质体对沉积构造及地质体属性特征分析是一种行之有效的手段。     

The double solid reactant method: II. An application to the shallow groundwaters of the Porto Plain,Vulcano Island (Italy)

This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.

Miocene andesitic lavas of Sierra de Angangueo: a petrological,geochemical, and geochronological approach to arc magmatism in Central Mexico

ABSTRACT

The early and middle Miocene andesitic lavas of the Sierra de Angangueo (MALSA) represent one of the most prominent landforms of intermediate magmatism in Central Mexico. In this paper, we present new petrological, geochemical, thermobarometric, and geochronological data in order to discuss the conditions of MALSA’s emplacement in the lithosphere.

MALSA comprises a voluminous eroded early Miocene andesitic structure, emplaced on a Mesozoic basement. MALSA shows a wide variety of textures, from glassy and aphanitic to porphyritic, mainly composed of plagioclase (An_10-55), clinopyroxene (Wo_60-65; En_35-40), amphibole (Mg-hornblende/edenite), and rarely olivine (Fo_75–86) or orthopyroxene (En_72-80). Major and trace elements plots follow a typical calc-alkaline trend with relatively increasing fractionation.

The ⁸⁷Sr/⁸⁶Sr isotopic signatures range between 0.703343 and 0.704459 and εNd values from +1.37 to +4.84; apparently without a significant contribution of an old, thick, or highly radiogenic continental crust. Lead isotope values ²⁰⁶Pb/²⁰⁴Pb vary between 18.68 and 18.83, ²⁰⁷Pb/²⁰⁴Pb from 15.57 to 15.65, and ²⁰⁸Pb/²⁰⁴Pb from 38.39 to 38.67, suggesting contamination of magmas by juvenile crust. Thermodynamic calculations indicate equilibrium conditions at ≤900°C and ~2 kbar and an average log ?O₂ ≈ ?10.

Ar–Ar and K–Ar dating carried out on whole rock, matrix, amphibole, and plagioclase phenocrysts yielded ages between 13.0 ± 0.5 and 23.9 ± 0.3 Ma. These dates indicate a series of pulses with maximum magmatic activity between 24 and 18 Ma.

The geochemical and petrologic data suggest partial melting processes in the lower or middle crust associated with possible magma mixing during its ascent; such a mechanism could explain a hybrid mantle-lower crust origin of this large volume of andesites. The MALSA, as well as the early to middle Miocene magmatism from Western Mexico, could represent two coeval and independent magmatic arcs prior to the present Trans-Mexican Volcanic Belt (TMVB) in Central Mexico.     

A proposed geotechnical-based method for evaluation of liquefaction potential analysis subjected to earthquake provocations (case study: Korzan earth dam, Hamedan province, Iran)

During the earthquakes, a number of earth dams have had severe damages or suffered major displacements as a result of liquefaction, thus modeling by computer codes can provide a reliable tool to predict the response of the dam foundation against earthquakes. These modeling can be used in the design of new dams or safety assessments of existing ones. In this paper, on the basis of the field and laboratory tests and by combination of several software packages a seismic geotechnical-based analysis procedure is proposed and verified by comparison with computer model tests and field and laboratory experiences. Verification or validation of the analyses relies to the ability of the applied computer codes. By using the Silakhor earthquake (2006, M _s 6.1) as a basis in order to check the efficiency of the proposed framework, the procedure is applied to the Korzan earth dam of Iran which is located in Hamedan Province to analyze and estimate the liquefaction and safety factor. Design and development of a computer code by the authors which was named as the ??Abbas Converter?? with graphical user interface which operates as logic connecter function that can compute and model the soil profiles is the critical point of this study. The results confirmed and proved the ability of the generated computer code on the evaluation of soil behavior during earthquake excitations. Also, this code was able to facilitate this study better than previous ones have, taking over the encountered problem.     

A predictive modeling approach to assessing the groundwater pollution susceptibility of the Paluxy Aquifer, Central Texas, using a Geographic Information System

The Paluxy aquifer in north-central Texas is composed primarily of Lower Cretaceous clastics. This aquifer provides water for both domestic and agricultural purposes in the region. The study area for this investigation incorporates the outcrop and recharge areas, as well as the confined and unconfined portions of the aquifer. The purpose of this investigation is to develop a predictive modeling approach for evaluating the susceptibility of groundwater in the Paluxy aquifer to contamination, and then compare this susceptibility evaluation to water-chemistry data collected from wells completed within the aquifer. Using such an approach allows one to investigate the potential for groundwater contamination on a regional, rather than site-specific scale. Based on data from variables such as land use/land cover, soil permeability, depth to water, aquifer hydraulic conductivity and topography, subjective numerical weightings have been assigned according to each variables' relative importance in groundwater pollution susceptibility. The weights for each variable comprise a Geographic Information System (GIS) map layer. These map layers are combined to formulate the final pollution susceptibility map. Using this method of investigation, the pollution susceptibility map classifies 32% of the study area as having low pollution susceptibility, 41% as having moderate pollution susceptibility, 25% as having high pollution susceptibility, and 2% as having very high pollution susceptibility. When comparing these modeling results with water-chemistry data from wells within the Paluxy aquifer, the four wells with the highest concentration of nitrate contamination are all found within regions of very high pollution potential. This confirms the accuracy and usefulness of the predictive modeling approach for assessing aquifer pollution susceptibility. Received: 1 June 1999 · Accepted: 30 August 1999     

A multi‐method approach to dating the burial and skeleton of Kiacatoo Man,New South Wales,Australia

Kiacatoo Man, a large, rugged Aboriginal adult buried in the Lachlan riverine plains of southeastern Australia, was discovered in 2011. Laser‐ablation uranium series analysis on bone yielded a minimum age for the burial of 27.4 ± 0.4 ka (2σ). Single‐grain, optically stimulated luminescence ages on quartz sediment in which the grave had been dug gave a weighted mean age of 26.4 ± 1.5 ka (1σ). Luminescence samples from the grave infill and from sediment beneath the grave exhibit overdispersed dose distributions consistent with bioturbation or other disturbance, which has obscured the burial signal. The overlap between the minimum (U‐series) and maximum (luminescence) ages places the burial between 27.0 and 29.4 ka (2σ). Luminescence ages obtained from the channel belt of between 28 ± 2 and 25 ± 3 ka indicate that fluvial sedimentation was occurring before the Last Glacial Maximum, which is consistent with the broader geomorphic setting. Together, these results are internally and regionally consistent, and indicate that Kiacatoo Man was one of the more ancient individuals so far identified in Australia. His remains are important to our understanding of patterns of biological variation and other processes that have shaped people in the Murray‐Darling Basin through time. Copyright © 2019 John Wiley & Sons, Ltd.     

Water-rock-tailings interactions and sources of sulfur and metals in the subtropical mining region of Taxco,Guerrero (southern Mexico): A multi-isotopic approach

Multi-isotope (H, O, S, Sr, Pb) systems coupled with conventional (major and trace element) hydrogeochemical analysis were applied to determine the origin of water, to model water-rock-tailings interactions and for source apportionment of sulfur and associated toxic metals in the mining region of Taxco, Guerrero in southern Mexico. Oxygen and H isotopes indicate that meteoric water in the zone is rainwater undergoing varying degrees of isotopic fractionation by atmospheric evaporation whereas Sr isotopes trace the interaction of pristine water from volcanics of the regional recharge zone and subsequently flowing through sandstone and shale to spring points. Leachates form from two distinctive sources (spring water and surface water) having differential interactions with bedrocks prior to entering the tailings. Compared to pristine water, leachates are enriched in sulfate, metals (e.g. Fe, Mn, Pb and Zn) and metalloids (e.g. As). The sulfur isotopic composition of ore-sulfides, leachates, secondary precipitates, regional surface water and hypogenic sulfates is described in terms of a two-component mixing model with shale of Mexcala and limestone of Morelos formations representing the light and heavy end-members, respectively, whereas Sr isotopic composition is bracketed combining three lithogenic (Mexcala/Morelos, Tilzapotla and Taxco Schist) sources. Finally, leachates have a mixture of lead from ore-sulfides and Taxco Schist Formation (Family I) or from ore-sulfides alone (Family II). The application of multiple environmental isotopic techniques is an outstanding tool for elucidating complex interactions of water with bedrocks and tailings and for determining the source of sulfur and toxic metal from mining and other metal polluted environments.     

多种建模方法耦合建立冲积扇三维构型模型:以克拉玛依油田六中东区下克拉玛依组为例

以克拉玛依油田六中东区下克拉玛依组为例,通过对8口小井距的密闭取心井及周围24口井的构型特征分析,建立了研究区目的层段的三维构型模型。分析得到冲积扇不同亚相实用的构型建模方法：冲积扇扇根为泛连通体,各级构型展布范围不大,主要为片流砂砾体,三维构型建模适合用基于目标的模拟方法;扇中主要构型单元为漫流细粒、辫流水道和漫流砂体,辫流水道与漫流砂体有明显的接触分带关系,适合用截断高斯模拟方法;扇缘主要构型单元为漫流细粒,少量分布径流水道和漫流砂体,适合用序贯指示及基于目标的模拟方法。最终建立的三维构型模型能较好地体现了各级构型单元在平面上和垂向上的展布范围和接触关系。为后期剩余油分布的预测、井网调整及剩余油挖潜提供了准确的依据。     

Evaluation of the solute geothermometry of thermal springs and drilled wells of La Primavera (Cerritos Colorados) geothermal field,Mexico: A geochemometrics approach

A detailed study on the solute geothermometry of thermal water (18 springs and 8 drilled wells) of La Primavera geothermal field (LPGF) in Mexico has been carried out by employing a geochemical database compiled from the literature and by applying all the available solute geothermometers. The performance of these geothermometers in predicting the reservoir temperatures has been evaluated by applying a geochemometrics (geochemical and statistical) method. The springs of the LPGF are of bicarbonate type and the majority have attained partial-equilibrium chemical conditions and the remaining have shown non-equilibrium conditions. In the case of geothermal wells, water is dominantly of chloride-type and, among the studied eight geothermal wells, four have shown full-equilibrium chemical conditions and another four have indicated partial-equilibrium conditions. All springs of HCO₃^−​ type water have provided unreliable reservoir temperatures, whereas the only one available spring of SO₄²⁻ type water has provided the reservoir temperature nearer to the average BHT of the wells. Contrary to the general expected behavior, spring water of non-equilibrium and geothermal well water of partial-equilibrium chemical conditions have indicated more reliable reservoir temperatures than those of partially-equilibrated and fully-equilibrated water, respectively. Among the chemical concentration data, Li and SiO₂ of two springs, SO₄²⁻ and Mg of four springs, and HCO₃ and Na concentrations of two geothermal wells were identified as outliers and this has been reflected in very low reservoir temperatures predicted by the geothermometers associated with them (Li–Mg, Na–Li, Na–K–Mg, SiO₂ etc.). Identification of the outlier data points may be useful in differentiating the chemical characteristics, lithology and the physico-chemical and geological processes at the sample locations of the study area.In general, the solute geothermometry of the spring waters of LPGF indicated a dominantly (94%) of underestimated deep reservoir temperatures, whereas in the case of the geothermal wells, many temperatures (54%) are underestimated, some are (43%) overestimated and a very small number (3%) are similar to an average bottom-hole temperatures (BHT) of the wells. 28 out of the total applied 29 geothermometers for spring waters have predicted the deep reservoir temperatures that are characterized by statistically significant large differences compared to the average BHTs of the geothermal wells. In the case of waters of the geothermal wells, 23 out of the total applied 28 geothermometers have predicted the reservoir temperatures similar (statistically no significant differences) to the BHTs of the corresponding geothermal wells.     

Clay mineralogy of archaeological soil: an approach to paleoclimatic and environmental reconstruction of the archaeological sites of the Paharpur area,Badalgacchi upazila,Naogaon district,Bangladesh

A geo-archaeological examination was carried out in and around the Paharpur area, Badalgacchi upazila of Naogaon District in the north-western part of Bangladesh. Clay mineralogy and global paleo-temperature curves were used to determine the paleoclimatic and depositional environmental conditions of the Holocene archaeological soils (Barind clay residuum) of the Paharpur archaeological spot. Clay mineralogical data show that the dominant clay mineral is illite with subordinate amounts of kaolinite and chlorite. The high illite and low kaolinite content implies a marine or estuarine deposit. The clay mineral ratio log diagram, constructed by plotting the 7–10°Å integrated intensity ratios versus depth, supports this assumption. The presence of illite, together with quartz and feldspar, suggests high detrital input under generally cool to temperate and dry climates. Chlorite is another common by-product of weathering reactions with low hydrolysis, which is typical for cool to temperate and dry climates. The results suggest the existence of a marine–estuarine influence under a generally cool to temperate and dry climates around Paharpur and the surrounding region throughout the Pala dynasty around mid-century 700 a.d. to early 1100 a.d. Furthermore, this observation is consistent with the global paleo-temperature curves.