柴达木盆地大浪滩梁ZK02孔早—中更新世石盐纯液相流体包裹体均一温度及其对钾盐成矿的约束

运用低温冷冻成核方法,对柴达木盆地大浪滩地区梁ZK02孔早—中更新世石盐样品的纯液相流体包裹体进行均一温度测试,获得158个均一温度数据。所测石盐样品的镜下形貌显示有石盐“人”字晶特征,其内部流体包裹体呈负立方体晶形,且测试均一温度数据与包裹体粒度相关性不明显,指示了测试石盐及包裹体原生性良好,其最大均一温度可代表古代夏季气温。最大均一温度测试结果表明:(1)早更新世最大均一温度主要分布于25~30 ℃温度区间,高泥质、粉砂岩性特征指示早期气候较为温和,淡水补充相对丰富;晚期盐类矿物含量升高,反映干旱程度升高;个别时间段夏季温度高于40 ℃,呈高温干旱特征。(2)中更新世温度位于30~35 ℃温度区间,出现了更新世以来最高温度50.6 ℃,包裹体最大均一温度与高含量盐类矿物共同指示了高温干旱环境特征。与早更新世相比,中更新世环境温度总体呈升高趋势,蒸发盐含量升高,干旱程度增加,温度波动加剧,显示出中更新世更加不稳定的气候特点,与世界范围内中更新世总体气候特征一致,且盐类分布显示这种气候不稳定性在大浪滩地区自早更新世晚期就开始显现了。结合石盐包裹体古温度研究成果,对阿尔金山前砂砾岩孔隙含钾卤水矿成矿模式进行补充:早更新世较为温和湿润的环境下,风化盐分和N22古盐发生溶滤,汇聚形成含盐卤水,赋存于阿尔金山前冲洪积扇砂砾岩孔隙中,历经中更新世的高温蒸发,最终形成KCl砂砾岩孔隙储层卤水矿床。     

Evaporation Stage of Paleo-saline Lake in the Sichuan Basin, China: Insight from Fluid inclusions in Halite

Sichuan Basin is one of the most important marine–salt forming basins in China. The Simian and Triassic have a large number of evaporites. The Triassic strata have found a large amount of polyhalite and potassium-rich brine. However, no soluble potassium salt deposit were found. In this study, the halite in well Changping 3 which is located at the eastern part of the Sichuan basin was studied using the characteristics, hydrogen and oxygen isotopes of the fluid inclusion in halite to reconstruct the paleoenvironment. The salt rocks in well Changping 3 can be divided into two types: grey salt rock and orange salt rock. The result shows that the isotopic composition of the halite fluid inclusion is distinct from the global precipitation line reflecting that the salt formation process is under strong evaporation conditions and the climate is extremely dry. At the same time, compared with the hydrogen and oxygen isotopes of brine in the Sichuan Basin and the hydrous isotope composition of the inclusions in the salt inclusions of other areas in China, it is shown that the evaporation depth of the ancient seawater in the Sichuan Basin was high and reached the precipitation of potassium and magnesium stage.     

甘肃省礼县中川地区李坝式金矿床载金矿物地球化学特征及矿床成因意义

中川地区载金矿物硫同位素、氢氧同位素和碳氧同位素特征说明成矿作用与沉积建造有较大的亲缘性。载金矿物流体包裹体中大量的 Cl- 、SO4 2 - 和 Ca2 、Na 高含量及其特征比值显示出大气降水带入了大量的建造中的物质成分。热液期黄铁矿微量元素标型特征体现地下热卤水溶滤成因特征 ,同时也显示了岩浆活动对成矿作用影响的痕迹     

Fluid Inclusion Study of Skarns in the Maruyama Deposit, the Kamioka Mine, Central Japan

Abstract: Fluid inclusions in skarn minerals in the Maruyama deposit, the Kamioka mine, central Japan were studied. Homogenization temperatures (Th) of fluid inclusions in 48 skarn minerals (hedenbergite, andradite, epidote and quartz) were measured, and gas composition of fluid inclusions in 12 skarn minerals was measured with a quadrupole mass spectrometer. The maximum Th value of primary inclusions in hedenbergite is 380C with peaks around 360C. Primary inclusions in hedenbergite near contact between skarn and limestone have slightly lower Th values and their distribution has a tendency of long trail skirt toward low temperature, which indicates ceasing of skarnization coincides with temperature decrease. Fluid inclusions in andradite and quartz in the hedenbergite skarn have lower Th values, in this order, than those in hedenbergite. CH4–detected fluid inclusions are localized around the Maruyama fault. Gas composition of the fluid inclusions indicates that fluid trapped in the hedenbergite has CO2 content less than 1 mole % and is not in equilibrium with graphite.     

The conservation of an aqueous fluid in inclusions in minerals and their interstices at high pressures and temperatures during the decomposition of antigorite

An experimental study of serpentine decomposition at high pressure (4.5 GPa) was carried out to elucidate if water can be preserved in the system in the form other than structural admixtures in minerals. This problem is of interest because it is water that plays a leading role in the melting in a subducted slab and a mantle wedge. To estimate the possible content of an aqueous fluid in deep-seated rocks, a BARS pressless split-sphere apparatus was used in complex with thermobarogeochemistry and gas chromatography. It has been established that the serpentine decomposition is accompanied by the release of water, which concentrates in inclusions in the produced minerals (olivine and orthopyroxene) and their interstices. Chromatographic analysis with a stepwise heating of samples showed that most of the released water is localized in the interstices, and the rest is conserved in fluid inclusions in the minerals. The produced solid phases conserve 0.13 to 2.43 wt.% fluids as inclusions, with water amounting to 0.1–2.06 wt.%. The content of inclusions determined by microscopic examination falls in this region. Since the mobility of the fluid conserved as inclusions in the olivine and orthopyroxene is significantly lower than that in the interstices, this fluid might be better preserved in olivine-containing rocks subsided to depth.     

Metamorphic and post-metamorphic fluid flow in the low-grade rocks of the Harlech Dome, north Wales

A combination of fluid inclusion, stable isotope and geochemical techniques has been used to study the nature of fluids present and their behaviour during Caledonian low-grade metamorphism of the Harlech Dome, north Wales. Fluid inclusion studies show that in most of the metasedimentary sequence the peak metamorphic fluid was an aqueous Na–K–Cl brine but in the graphitic Clogau Formation and in parts of the overlying Maentwrog Formation immiscible H₂O-rich and CH₄-rich fluids coexisted. Late-stage inclusions are of calcium-rich brine and a dilute aqueous fluid. The chemical composition of chlorite in metamorphic veins and rocks varies between different formations and quartz-oxygen isotopic compositions show considerable variation between different units. Both of these features are taken to indicate that there was little or no pervasive movement of fluid between different units at the peak of metamorphism. After the metamorphic peak there was focused flow of fluid upward through the sequence along fractures, in response to end-Caledonian uplift and unloading. Where the migrating fluid crossed the graphitic shales, interaction between the fluid and the shales gave rise to the formation of the auriferous veins of the Dolgellau Gold Belt. Subsequent to this mineralizing event there was widespread development of ¹⁸O-enriched calcites and micas. In the case of vein minerals it is possible that these crystallized directly from late-stage fluids at lower temperature than the quartz in the same veins. Alternatively, the original vein minerals may have re-equilibrated with later ¹⁸O-enriched or cooler fluid. In the case of muscovites in the rock matrix it is proposed that the isotopically heavy compositions are the result of re-equilibration of initially light grains with an introduced fluid, requiring considerable influx of fluid. This event may relate to either of two late-stage fluids observed as inclusions.     

江西吉泰盆地卤水型锂钾矿物源区岩石地球化学特征及成因分析

中国探明锂钾资源主要分布于青藏、罗布泊盐湖和川西等地,资源开发成本高、难度大,难以满足产业发展需求。目前,在江西吉泰盆地勘探发现卤水中氯化锂浓度超过600 mg/L,氯化钾含量接近1%,锂钾含量均超过或接近工业品位,综合利用价值高。本文在前人研究的基础上,通过对吉泰盆地中生代火成岩开展矿物学、岩石学、地球化学、流体包裹体研究以及高压釜水-岩反应模拟实验,重点研究了时间、温度、流体成分等对火成岩水-岩反应的影响,探究其对富钾锂卤水物质来源和成因机制的指示意义。研究结果表明,吉泰盆地卤水具有高锂低镁的特征,表明吉泰盆地卤水在成因上受到火山活动的影响;研究区岩浆发生不同程度的分异,火成岩蚀变作用强烈,表明地下热液对研究区火成岩的交代作用强烈,火成岩通过水-岩反应为富锂钾卤水矿提供了物质来源;温度是流体对元素的淋滤能力的主要控制因素,高盐度流体是各成矿元素主要的迁移载体;地表成因的卤水中Mg/Li值主要受原岩成分控制;水-岩反应是卤水形成的重要过程,而地表蒸发浓缩是卤水成矿最主要机理。     

四川盆地三叠纪古盐湖已达钾石盐析出阶段——来自石盐流体包裹体化学组成的约束

石盐的流体包裹体成分可提供古流体组成的物理化学信息,用以探查卤水组成变化及环境演化规律等。四川盆地位于上扬子地台,其中的早-中三叠纪沉积建造是中国海相找钾的有利层位之一。获取石盐沉积时期的卤水成分信息,是深刻认识四川盆地古海水蒸发浓缩程度的重要途径。文章利用激光剥蚀电感耦合等离子体质谱法,对采自川东地区长平3井嘉陵江组的石盐流体包裹体开展了化学组成分析,结果显示古卤水化学类型为Mg_SO4型;流体包裹体中的ρ(K~+)与现代海水浓缩到钾石盐析出阶段的ρ(K~+)基本一致,可能揭示了盆地三叠纪时期古卤水已达到钾石盐析出阶段,对四川盆地沉积环境演化及钾盐成矿规律研究等具有重要的理论意义。     

鄂尔多斯盆地上古生界致密砂岩气田储集层特征与成因*

鄂尔多斯盆地上古生界致密砂岩储集层普遍以低孔低渗为主要特征,但在低孔低渗的背景上发育相对优质储集层。应用偏光显微镜、恒速压汞等技术手段,从碎屑岩的粒度、碎屑组分、孔隙结构等分析入手,对比神木气田、榆林气田和苏里格气田3个大气田的储集层特点,并对致密砂岩中相对优质储集层的成因进行了分析。研究认为：高石英类矿物含量、适量的可溶性组分(包括长石、火山岩岩屑及凝灰质等）及残余少量粒间孔形成的酸性流体的渗流通道是形成相对优质储集层的必要条件;而较高含量的千枚岩屑、泥板岩等软组分,在上覆地层压力作用下被压实变形、充填孔隙,造成残余粒间孔全部丧失和酸性流体渗流通道的缺乏,因而形成低孔低渗的致密砂岩储集层。     

青海察尔汗盐湖现代沉积中的变质变形规律

应用基础资料从温度、压力、物性及物源诸方面阐明了盐湖成岩作用,从湖水演化及析盐过程讨论了矿物沉积序列。以卤水、盐类矿物、原生矿物、细菌活动以及岩石分带为特征阐明了盐湖沉积中的变质和变形现象。以结构面的力学性质及变形规律、应力矿物及矿物变质规律表征了应力条件下盐湖沉积中不同物质组分的变质变形状态及演变规律。从盐湖沉积物的“生长型组构”阐明其受力变化以及与新构造运动相连系的变质变形机制。     

CO2-Brine immiscibility at high temperatures,evidence from calcareous metasedimentary rocks

Study of fluid inclusions in quartz segregations and in the rock matrix of a calcareous psammite and a carbonate schist suggests that brines containing 23–24 weight percent salt (NaCl equivalent) are immiscible with CO₂ at the metamorphic conditions of approximately 600° and 6.5 Kb. The presence of a high temperature solvus between saline brine and CO₂ is supported by other fluid inclusion studies as well as experimental measurements from the literature. As saline brines are common in metamorphic and hydrothermal systems, CO₂-brine immiscibility should play an important role in petrogenesis. The fluid inclusions preserved in the quartz segregations probably represent the fluids generated by prograde metamorphic reactions, whereas the compositions of the fluids trapped in the rock matrix quartz suggest they have reequilibrated with the matrix minerals during incipient retrograde reactions. The isochores from the densest inclusions observed in this study pass close to the inferred peak metamorphic conditions; other isochores suggest an episode of deformation and recrystallization at 275° C and 1.4 Kb. Using the density information preserved in all the inclusions, a convex-downward uplift path on a P-T diagram is inferred for these rocks.     

湘西花垣地区铅锌矿床流体包裹体显微测温与特征元素测定

花垣铅锌矿床的成矿流体演化特点和铅锌矿物沉淀机制存有分歧,为了总结矿床成因并建立成矿模式,指导该地区铅锌矿的下一步找矿勘探工作.对闪锌矿、主成矿期方解石和萤石中的流体包裹体进行岩相学观察、显微测温、拉曼光谱分析以及同步辐射X射线荧光微探针分析,结果显示花垣地区铅锌矿床成矿流体温度主要为150~220℃,总盐度一般为13%~23% NaCl_eqv,多> 15% NaCl_eqv,密度多 > 1 g/cm3,成矿流体为NaCl-CaCl₂-MgCl₂-H₂O卤水体系.成矿流体均一温度具有由北而南降低的趋势.流体液相组分中主要为Ca2+、Mg2+、Na+、Cl-,具有盆地热卤水体系特点.流体包裹体气相中发育CO₂、CH₄,方解石、萤石中流体包裹体均有成矿元素Pb、Zn的存在.花垣矿集区成矿流体属于低温度、中-高盐度、中-高密度,成分以钠和钙氯化物为主的含矿热水溶液,流体运移方向为由北向南,流体来源于封层水、大气降水和少量变质水.铅锌矿物的沉淀与热化学硫酸盐还原作用有关.闪锌矿、方铅矿等矿石矿物与方解石、萤石等脉石矿物应属同一富含Pb、Zn、Mn、Fe、As、Cr等成矿元素的成矿流体在同一成矿期次相同条件下沉淀的产物.      

The role of chloride-carbonate melts in the formation of sideritic carbonatites of the KARASUg FE-F-REE deposit (Tyva Republic,Russia)

The authors have studied melt-fluid and fluid inclusions in quartz and fluorite of sideritic and ankerite-calcitic carbonatites of the Karasug ore field, as well as melt inclusions in apatite from granosyenites. The content of salt and fluid components in brine-melt inclusions was evaluated on the basis of the thermodynamic data, the calculations of volumes and densities of the solid phases, a solution of about 50% concentration, and the gas phase of the inclusions, as well as the results of the LA-ICP-MS analysis. The content of salt phases, the solution, and the gas phase amounted to 85–70, 10–25, and about 5% of the inclusion substance, respectively. The total percentage of salt and fluid components (H₂O and CO₂) amounted to 90–80 and 10–20 wt %, respectively. The fraction of a carbonate constituent in the inclusions was as high as 45–50% and over in ankerite-calcite carbonatites and about 15 wt % in sideritic carbonatites. The 117.2 ± 1.3 Ma age of these carbonatites by ⁴⁰Ar/³⁹Ar, along with other datings for this area, shows that their formation was associated with a manifestation of the Cretaceous alkaline-mafic magmatism (117–120 Ma). The presented model of the formation of carbonatites is in agreement with the sequence of the development of magmatic processes and mineralization in this area. The model is also confirmed by the results of the studies of melt and fluid inclusions in minerals.     

流体的热力学前缘研究

总结了当前国内外关于流体的热力学前缘研究领域如下：（１）流体体系的ｐ－Ｖ－Ｔ－ｘ相关系研究，主要对象是Ｈ２Ｏ－ＣＯ２－盐类多组分体系高温高压下相图的实验和理论研究。（２）矿物在流体中的溶解度及溶解后在流体中溶解类型的形式和热力学性质——平衡常数（或Ｇｉｂｂｓ自由能）及各种偏摩尔性质的研究。（３）流体热力学模型化研究，已研制出大量的计算机软件，包括多种矿物、溶解类型的热力学数据库和模拟热液平衡、矿物溶解性质、反应路径和水—岩相互作用的实用程序。（４）超临界流体的相关系和化学反应等有许多特殊的性质，对认识地球内部的演化将有重要意义。（５）新技术新方法的发展，使分析单个矿物包裹体成分变成了现实。     

中国深部岩心钻探钻井液技术应用现状及研究方向的探讨

出于深部找矿与科学钻探的需要,岩心钻探由浅孔向深孔迈进,钻遇易坍塌地层、硬岩地层、高温高压地层、盐膏层等复杂地层的几率增加,从而对深部取心钻进钻井液技术提出了更高的要求。在总结各类深部复杂地层取心钻进钻井液使用现状的基础上,分析并归纳了强抑制防塌钻井液、强润滑减阻钻井液、高温钻井液、饱和盐水钻井液、高密度钻井液的研配要点及难点,提出了针对性钻井液体系的性能调控思路以及研究重点,为深部岩心钻探钻井液体系选用提供借鉴依据及参考。     

云南白秧坪银多金属矿集区成矿流体特征及成矿机制

云南白秧坪银多金属矿集区是滇西兰坪盆地内新发现的矿集区,属东特提斯—喜马拉雅成矿域的一部分。通过流体包裹体的类型、均一温度和盐度的研究分析,结合流体包裹体的化学成分和C、H、O同位素资料及成矿地质条件的综合分析,提出流体包裹体主要具有盆地沉积卤水及大气降水的特征,但成矿流体具有壳幔混合来源的特征。这些特征与该区特定的地质背景和演化历史密切相关。兰坪盆地是在澜沧江和金沙江两条深大断裂之间发展起来的一个拉分盆地,这两条深断裂连同盆地中央的中轴断裂,不仅控制了盆地的发生和发展过程,而且也控制了盆地内成矿流体的来源及银、铜等多金属矿床的成矿作用。因此认为成矿作用是流体混合作用、有机质和膏盐地层的还原作用等综合作用的结果。     

松辽盆地钱家店砂岩型铀矿床油气运移与铀成矿的关系:来自流体包裹体的证据

为探究油气运移与铀成矿的关系,笔者以松辽盆地钱家店砂岩型铀矿床为研究对象,系统开展了含矿砂岩薄片鉴定、电子探针研究以及流体包裹体岩相学和显微测温研究.结果表明:①研究区强矿化段砂岩硅质胶结物含量较多,为隐晶质玉髓胶结物;成岩演化序列为,泥晶方解石、自生黏土膜,石英加大边、石英加大边外围黏土膜、颗粒间压实的隐晶质玉髓胶结...     

Geowissenschaftliche Probleme bei der Endlagerung radioaktiver Substanzen in Salzdiapiren Norddeutschlands

In the Federal Republic of Germany disposal of low-level radioactive waste is practiced in rock salt of the salt dome Asse since years. Projects also exist for the disposal of high-level waste from nuclear reactors in salt domes. The feasibility of the “evaporite concept? has to be founded on some basic principles of the origin and metamorphism of marine salt deposits. The German Zechstein salt deposits (Permian) were formed about 230 million years ago. Since that time the salt formations have had a chequered history: 1. Solution metamorphism and thermal metamorphism have altered the primary chemical and mineralogical composition of salt rocks in the presence of unsaturated solutions and/or temperatures up to 100? C and more. 2. Mechanical deformation and dynamic metamorphism processes have preserved the chemical and mineralogical composition of the evaporites. Solution metamorphism: The minerals halite, sylvite, and carnallite are very sensitive to subsequent penetrating unsaturated solutions. Very important in this context is the origin of specific equilibrium solutions and mineral associations. Primary salt rocks (e. g. carnallite rock) have been altered to secondary mineral associations (e. g. Hartsalze and sylvite rocks of the potash seams Thüringen, Hessen, Stassfurt). Most of the solutions which infiltrated the salt deposits from outside are later squeezed out into the adjacent rocks. Geochemical and physicochemical processes of the solution metamorphism are not limited to the geologic past. They are also efficient at the present time as a result of deformation processes in partially extracted salt deposits, for example. Solution metamorphism processes are also possible in the future during the period of about one million years which is necessary for the disposal of high-level radioactive waste in salt domes. A concept which is based upon observed properties of salt formations and with secure scientific foundation must guarantee no radioactive contamination of salt solutions in the case of long time contacts between radionuclides and brines. An excellent method for the immobilisation of radioactive waste seems to be production of a synthetic igneous rock system SYNROC (Ringwood, 1978). In such a rock the radionuclides are fixed in the lattices of minerals. Additional safety barriers which prevent the entry of radionuclides from the geologic barrier into the biosphere are the metallic alloy Ni₃Fe, for waste containers and layers of basalt and corundum. Borosilicate glasses are not suitable for the safe immobilisation of radionuclides because the glasses readly devitrify in contact with solutions and steam at elevated pressures and temperatures. Thermal metamorphism: The heat-generation of high-level waste produces zones of different temperatures in the evaporites of the salt domes. The salt hydrates kainite and carnallite react at relative low temperatures (> 072? C and > 80? C) and form solid phases with less hydrated compounds and equilibrium solutions. For example, effects of thermal metamorphism are to be expected in the case of influencing higher temperatures upon carnallite rocks which were squeezed into parts of rock salt during the geologic past. Increasing temperatures generated by radionuclides must be limited in carnallite rocks to 30 %–50 % of the recent rock temperatures in salt domes. A difference of 10? C should be guaranteed between the temperature zones around the high-level waste and the beginning of carnallite dehydratation at 80? C–85? C under normal pressure. Dynamic metamorphism: Dynamic metamorphism is concerned mainly with isochemical and isophase recrystallizations. The original thickness and composition of evaporites can be altered by the property of plasticity and by creep deformations of salt minerals and rocks. Solutions (e. g. pore solution) and increasing temperatures lead to the effects of dynamic metamorphism. A concept which is based upon observed properties of salt formations and with secure scientific foundation must guarantee temperatures ≦ 100? C in the vicinity around the high-level waste containers. Only for temperatures up to 100? C are relevant geologic data about the plastic deformation of rock salt available in the German salt deposits. The effects of salt rock deformation with increasing temperatures > 100? C could be examined only by laboratory experiments. It seems to be a considerable uncertainty and a risk to develop experimental deformation models for salt rocks valid for a time of 10²–10³ years. The present program in the Federal Republic of Germany for a geologic disposal of radionuclides in evaporites is sometimes characterized as the best concept of the world (e. g. v.Weizsäcker, 1978). For such a general statement no geoscientific foundation is available today. Alternative geologic disposal programs seem to be more acceptable in view of their geoscientific and technical base (e. g.Ringwood, 1978).     

Impact of solid second phases on deformation mechanisms of naturally deformed salt rocks (Kuh-e-Namak,Dashti, Iran) and rheological stratification of the Hormuz Salt Formation

Viscosity contrasts displayed in flow structures of a mountain namakier (Kuh-e-Namak - Dashti), between ‘weak’ second phase bearing rock salt and ‘strong’ pure rock salt types are studied for deformation mechanisms using detailed quantitative microstructural study. While the solid inclusions rich (“dirty”) rock salts contain disaggregated siltstone and dolomite interlayers, “clean” salts reveal microscopic hematite and remnants of abundant fluid inclusions in non-recrystallized cores of porphyroclasts. Although the flow in both, the recrystallized “dirty” and “clean” salt types is accommodated by combined mechanisms of pressure-solution creep (PS), grain boundary sliding (GBS), transgranular microcracking and dislocation creep accommodated grain boundary migration (GBM), their viscosity contrasts observed in the field outcrops are explained by: 1) enhanced ductility of “dirty” salts due to increased diffusion rates along the solid inclusion-halite contacts than along halite–halite contacts, and 2) slow rates of intergranular diffusion due to dissolved iron and inhibited dislocation creep due to hematite inclusions for “clean” salt types Rheological contrasts inferred by microstructural analysis between both salt rock classes apply in general for the “dirty” salt forming Lower Hormuz and the “clean” salt forming the Upper Hormuz of the Hormuz Formation and imply strain rate gradients or decoupling along horizons of mobilized salt types of different composition and microstructure.     

俯冲带深部流体:来自超高压变质锆石晶内结构和包裹物的证据

利用阴极发光和激光拉曼研究了大别山俯冲带超高压基性和长英质变质岩中的锆石。超高压变质增生锆石环带或新生锆石颗粒从不同角度反映了俯冲带地幔深度流体作用信息。其一,在超高压变质锆石生长域中存在微米级流体包裹体。由于其十分细小,组成往往难以测定。但是在变基性岩中检测到富CO2的负晶形包裹体。其二,在超高压锆石生长域中较普遍地发现富含挥发份的多硅白云母和磷灰石包裹体,其与典型的超高压变质矿物———柯石英稳定共生。副矿物研究表明,即使是在新鲜的弱退变质的榴辉岩中,富含挥发份的矿物相———磷灰石仍是含量较高的矿物,说明在俯冲带的深部(>100km),流体仍可以稳定地保存在高挥发份的矿物晶体格架中。其三,超高压变质增生锆石环带的边界呈蚕食状或港湾状,指示流体参与了锆石的变质生长过程,即通过流体与锆石之间的相互作用导致原有锆石的溶解和新生锆石的沉淀结晶。考虑到如此高的锆溶解度,认为在地幔俯冲深度,流体的成分复杂,并不是简单的富水体系,其化学组成与深熔融体相似,且赋存状态应为含水融体相。