Comparison of PFS and TES observations of temperature and water vapor in the martian atmosphere

The interval from L_s = 330° in Mars Year (MY) 26 until L_s = 84° in MY 27 has been used to compare and validate measurements from the Mars Global Surveyor Thermal Emission Spectrometer (TES) and the Mars Express Planetary Fourier Spectrometer (PFS). We studied differences between atmospheric temperatures observed by the two instruments. The best agreement between atmospheric temperatures was found at 50 Pa between 40°S and 40°N latitude, where differences were within ±5 K. For other atmospheric levels, differences as large as ∼25 K were observed between the two instruments at some locations. The largest temperature differences occurred mainly over the Hellas Planitia, Argyre Planitia, Tharsis and Valles Marineris regions.On this basis we report on the variability of the martian atmosphere during the 5.5 martian years of Mars climatology obtained by combining the two data sets from TES and PFS. Atmospheric temperatures at 50 Pa responded to the global-scale dust storms of MY 25 and in MY 28 raising temperatures from ∼220 K to ∼250 K during the daytime. An atmospheric temperature of ∼140 K at 50 Pa was observed poleward of 70°N during northern winter and poleward of 60°S during southern winter each year in both the PFS and TES results. Water vapor observed by the two spectrometers showed consistent seasonal and latitudinal variations.     

Methane adsorption on a martian soil analog: An abiogenic explanation for methane variability in the martian atmosphere

Recent observations suggest methane in the martian atmosphere is variable on short spatial and temporal scales. However, to explain the variability by loss reactions requires production rates much larger than expected. Here, we report results of laboratory studies of methane adsorption onto JSC-Mars-1, a martian soil simulant, and suggest that this process could explain the observations. Uptake coefficient (γ) values were measured as a function of temperature using a high-vacuum Knudsen cell able to simulate martian temperature and pressure conditions. Values of γ were measured from 115 to 135 K, and the data were extrapolated to higher temperatures with more relevance to Mars. Adsorptive uptake was found to increase at lower temperatures and larger methane partial pressures. Although only sub-monolayer methane surface coverage is likely to exist under martian conditions, a very large mineral surface area is available for adsorption as atmospheric methane can diffuse meters into the regolith. As a result, significant methane may be temporarily lost to the regolith on a seasonal time scale. As this weak adsorption is fully reversible, methane will be re-released into the atmosphere when surface and subsurface temperatures rise and so no net loss of methane occurs. Heterogeneous interaction of methane with martian soil grains is the only process proposed thus far which contains both rapid methane loss and rapid methane production mechanisms and is thus fully consistent with the reported variability of methane on Mars.     

Interannual variability in TES atmospheric observations of Mars during 1999-2003

We use infrared spectra returned by the Mars Global Surveyor Thermal Emission Spectrometer (TES) to retrieve atmospheric and surface temperature, dust and water ice aerosol optical depth, and water vapor column abundance. The data presented here span more than two martian years (Mars Year 24, L_s=104°, 1 March 1999 to Mars Year 26, L_s=180°, 4 May 2003). We present an overview of the seasonal (L_s), latitudinal, and longitudinal dependence of atmospheric quantities during this period, as well as an initial assessment of the interannual variability in the current martian climate. We find that the perihelion season (L_s=180°-360°) is relatively warm, dusty, free of water ice clouds, and shows a relatively high degree of interannual variability in dust optical depth and atmospheric temperature. On the other hand, the aphelion season (L_s=0°-180°) is relatively cool, cloudy, free of dust, and shows a low degree of interannual variability. Water vapor abundance shows a moderate amount of interannual variability at all seasons, but the most in the perihelion season. Much of the small amount of interannual variability that is observed in the aphelion season appears to be caused by perihelion-season planet-encircling dust storms. These dust storms increase albedo through deposition of bright dust on the surface causing cooler daytime surface and atmospheric temperatures well after dust optical depth returns to prestorm values.     

Investigation of the water sorption properties of Mars-relevant micro- and mesoporous minerals

Encouraged by recent results of the Mars Odyssey spacecraft mission and the OMEGA team (Mars Express) concerning water in equatorial latitudes between ±45° on Mars and the possible existence of hydrated minerals, we have investigated the water sorption properties of natural zeolites and clay minerals close to martian atmospheric surface conditions as well as the properties of Mg-sulfates and gypsum. To quantify the stability of hydrous minerals on the martian surface and their interaction with the martian atmosphere, the water adsorption and desorption properties of nontronite, montmorillonite, chabazite and clinoptilolite have been investigated using adsorption isotherms at low equilibrium water vapor pressures and temperatures, modeling of the adsorption equilibrium data, thermogravimetry (TG), differential scanning calorimetry (DSC), and proton magic angle spinning nuclear magnetic resonance measurements (¹H MAS NMR). Mg-sulfate hydrates were also analyzed using TG/DSC methods to compare with clay mineral and zeolites. Our data show that these microporous minerals can remain hydrated under present martian atmospheric conditions and hold up to 2.5-25 wt% of water in their void volumes at a partial water vapor pressure of 0.001 mbar in a temperature range of 333-193 K. Results of the ¹H MAS NMR measurements suggest that parts of the adsorbed water are liquid-like water and that the mobility of the adsorbed water might be of importance for adsorption-water-triggered chemistry and hypothetical exobiological activity on Mars.     

The H2O and CO2 adsorption properties of phyllosilicate-poor palagonitic dust and smectites under martian environmental conditions

The recent detection of up to ∼10 wt% water-equivalent H heterogeneously distributed in the upper meter of the equatorial regions of the martian surface and the presence of the 3-μm hydrations feature across the entire planet raises the question whether martian surficial dust can account for this water-equivalent H. We have investigated the H₂O and CO₂ adsorption properties of palagonitic dust (<5 μm size fraction of phyllosilicate-poor palagonitic tephra HWMK919) as a martian dust analog and two smectites under simulated martian equatorial surface conditions. Our results show that the palagonitic dust, which contains hydrated and hydroxylated volcanic glass of basaltic composition, accommodates significantly more H₂O under comparable humidity and temperature conditions than do the smectites nontronite and montmorillonite.     

Evaporation effects on the formation of martian gullies

In order to investigate the formation of martian gullies and the stability of fluids on Mars, we examined about 120 gully images. Twelve HiRISE images contained a sufficient number of Transverse Aeolian Ridges (TARs) associated with the gullies to make the following measurements: overall gully length, length of the alcove, channel and apron, and we also measured the frequency of nearby TARs. Six of the 12 images examined showed a statistically significant negative correlation between overall gully length (alcove, channel and apron length) and TAR frequency. Previous experimental work from our group has shown that at temperatures below ∼200 K, evaporation rate increases by about an order of magnitude as wind speed increases from 0 to ∼15 m/s. Thus the negative correlations we observe between gully length and dune frequency can be explained by formation at temperatures below ∼200 K where wind speed/evaporation is a factor governing gully length. In these cases evaporation of the fluid carving the gully was a constraint on their dimensions. Cases where there is no correlation between gully length and TAR frequency, can be explained by formation at temperatures >200 K. The temperatures are consistent with Global Circulation Model and Thermal Emission Spectrometer (TES) data for these latitudes. The temperatures suggested by these trends are consistent with the fluid responsible for gully formation being a strong brine, such as Fe₂(SO₄)₃ which has a eutectic temperature of ∼200 K. We also find that formation timescales for gullies are 10⁵-10⁶ years.     

A cold and wet Mars

Water on Mars has been explained by invoking controversial and mutually exclusive solutions based on warming the atmosphere with greenhouse gases (the “warm and wet” Mars) or on local thermal energy sources acting in a global freezing climate (the “cold and dry” Mars). Both have critical limitations and none has been definitively accepted as a compelling explanation for the presence of liquid water on Mars. Here is considered the hypothesis that cold, saline and acidic liquid solutions have been stable on the sub-zero surface of Mars for relatively extended periods of time, completing a hydrogeological cycle in a water-enriched but cold planet. Computer simulations have been developed to analyze the evaporation processes of a hypothetical martian fluid with a composition resulting from the acid weathering of basalt. This model is based on orbiter- and lander-observed surface mineralogy of Mars, and is consistent with the sequence and time of deposition of the different mineralogical units. The hydrological cycle would have been active only in periods of dense atmosphere, as having a minimum atmospheric pressure is essential for water to flow, and relatively high temperatures (over ∼245 K) are required to trigger evaporation and snowfall; minor episodes of limited liquid water on the surface could have occurred at lower temperatures (over ∼225 K). During times with a thin atmosphere and even lesser temperatures (under ∼225 K), only transient liquid water can potentially exist on most of the martian surface. Assuming that surface temperatures have always been maintained below 273 K, Mars can be considered a “cold and wet” planet for a substantial part of its geological history.     

Water ice cloud formation on Mars is more difficult than presumed: Laboratory studies of ice nucleation on surrogate materials

The role of water ice clouds in the martian water cycle and climate depends on cloud properties such as particle size and number distribution. These properties, in turn, depend on heterogeneous nucleation parameters which are poorly understood. Here we report laboratory experiments performed under martian temperature and water partial pressure conditions (158–185 K, 9 × 10⁻⁷–1 × 10⁻⁴ Torr H₂O) to determine the critical saturation ratio for ice onset, S_crit, as a function of temperature and dust composition. Using infrared spectroscopy to monitor ice nucleation and growth, we find a significant barrier to ice formation, with a pronounced temperature dependence. Even on clay minerals which show uptake of non-crystalline water before ice nucleation, we find a saturation ratio of 2.5 or more (RH_ice > 250%) is needed to begin ice growth at temperatures near 160 K. These results could lead to changes of four orders of magnitude in the nucleation rate relative to the presumptions used currently in Mars microphysical models, which commonly set the contact parameter, m, to a single value of 0.95. Our results range from m = 0.84 to m = 0.98. For ice nucleation on Arizona Test Dust, the temperature dependence is described by m = 0.0046 * T_nucl + 0.1085, while m = 0.0055 * T_nucl + 0.0003 on a smectite-rich clay sample. Our findings suggest that cloud formation will be more difficult than previously thought, potentially leading to areas of increased near-surface humidity but generally drier conditions in the atmosphere of Mars, overall.     

MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region (T_surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO₂ cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO₂ at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.     

A 1 Gyr climate model for Mars: new orbital statistics and the importance of seasonally resolved polar processes

New results from a 1 Gyr integration of the martian orbit are presented along with a seasonally resolved energy balance climate model employed to illuminate the gross characteristics of the long-term atmospheric pressure evolution. We present a new analysis of the statistical variation of the martian obliquity and precession prior to and subsequent to the formation of the Tharsis uplift, and explore the long term effects on the martian climate. We find that seasonal polar cycles have a critical influence on the ability for the regolith to release CO₂ at high obliquities, and find that the atmospheric CO₂ actually decreases at high obliquities due to the cooling effect of polar deposits at latitudes where seasonal caps form. At low obliquity, the formation of massive, permanent polar caps depends critically on the values of the frost albedo, A_frost, and frost emissivity, ?_frost. Using our model with values of A_frost=0.67 and ?_frost=0.55, matched to the NASA Ames General Circulation Model (GCM) results (Haberle et al., 1993, J. Geophys. Res. 98, 3093-3123, and Haberle et al., 2003, Icarus 161, 66-89), we find that permanent caps only form at low obliquities (<13°), suggesting that any permanent deposits on the surface of Mars today may be residuals left over from a period of very low obliquity, or are the result of mechanisms not represented by this model. Thus, contrary to expectations, the martian atmospheric pressure is remarkable static over time, and decreases both at high and low obliquity. Also, from our one billion year orbital model, we present new results on the fraction of time Mars is expected to experience periods of low obliquity and high obliquity.     

Analysis of Thermal Emission Spectrometer data using spectral EOF and tri-spectral methods

We introduce two new techniques in analyzing martian spectrally resolved radiance data obtained by the Thermal Emission Spectrometer (TES): spectral empirical orthogonal function (EOF) analysis and the tri-spectral algorithm. Spectral EOF analysis allows us to obtain the variability of spectra and associated temporal and spatial patterns. The case study with TES 20° S-20° N data shows that the first principal component (PC1) dominates the total variance and is associated with surface or near-surface brightness temperature variations. The PC2 is associated with atmospheric variability, and a negative correlation between dust and ice absorptions can be clearly seen over many regions. The annual cycle is a major component of the PC1 temporal patterns. The fingerprint of the dust storm can be clearly seen in the PC2 temporal patterns in most areas except the highlands. Spectral EOF can be used for validation of the variability of martian GCMs. The tri-spectral algorithm is based on the differences between three bands (dust, ice and a weak CO₂ absorption band) to distinguish spectra sampled in different situations: water ice cloud, dust, and surface anisothermality. We use a line-by-line radiative transfer model coupled with multiple scattering to investigate the sensitivity of this algorithm to dust and ice optical depth as well as surface emissivity. The comparisons between results of this algorithm and the TES team's retrieved dust and ice opacity are consistent over all studied periods except during the peak of the dust storm. Our algorithm is complementary to the more sophisticated TES retrieval and can be used to screen large amounts of data to get an overview.     

The atmospheric circulation and dust activity in different orbital epochs on Mars

A general circulation model is used to evaluate changes to the circulation and dust transport in the martian atmosphere for a range of past orbital conditions. A dust transport scheme, including parameterized dust lifting, is incorporated within the model to enable passive or radiatively active dust transport. The focus is on changes which relate to surface features, as these may potentially be verified by observations. Obliquity variations have the largest impact, as they affect the latitudinal distribution of solar heating. At low obliquities permanent CO₂ ice caps form at both poles, lowering mean surface pressures. At higher obliquities, solar insolation peaks at higher summer latitudes near solstice, producing a stronger, broader meridional circulation and a larger seasonal CO₂ ice cap in winter. Near-surface winds associated with the main meridional circulation intensify and extend polewards, with changes in cap edge position also affecting the flow. Hence the model predicts significant changes in surface wind directions as well as magnitudes. Dust lifting by wind stress increases with obliquity as the meridional circulation and associated near-surface winds strengthen. If active dust transport is used, then lifting rates increase further in response to the larger atmospheric dust opacities (hence circulation) produced. Dust lifting by dust devils increases more gradually with obliquity, having a weaker link to the meridional circulation. The primary effect of varying eccentricity is to change the impact of varying the areocentric longitude of perihelion, l, which determines when the solar forcing is strongest. The atmospheric circulation is stronger when l aligns with solstice rather than equinox, and there is also a bias from the martian topography, resulting in the strongest circulations when perihelion is at northern winter solstice. Net dust accumulation depends on both lifting and deposition. Dust which has been well mixed within the atmosphere is deposited preferentially over high topography. For wind stress lifting, the combination produces peak net removal within western boundary currents and southern midlatitude bands, and net accumulation concentrated in Arabia and Tharsis. In active dust transport experiments, dust is also scoured from northern midlatitudes during winter, further confining peak accumulation to equatorial regions. As obliquity increases, polar accumulation rates increase for wind stress lifting and are largest for high eccentricities when perihelion occurs during northern winter. For dust devil lifting, polar accumulation rates increase (though less rapidly) with obliquity above o=25°, but increase with decreasing obliquity below this, thus polar dust accumulation at low obliquities may be increasingly due to dust lifted by dust devils. For all cases discussed, the pole receiving most dust shifts from north to south as obliquity is increased.     

Evidence for Mg-rich carbonates on Mars from a 3.9 μm absorption feature

The origin and nature of the early atmosphere of Mars is still debated. The discovery of sulfate deposits on the surface, coupled with the evidence that there are not large abundances of carbonates detectable on Mars in the optically accessible part of the regolith, leaves open different paleoclimatic evolutionary pathways. Even if carbonates are responsible for the feature observed by TES and Mini-TES at 6.76 μm, alternative hypotheses suggest that it could be due to the presence of Hydrated Iron Sulfates (HIS). Carbonates can be discerned from HIS by investigating the spectral region in which a strong overtone carbonate band is present. The Planetary Fourier Spectrometer on board the Mars Express spacecraft has acquired several thousand martian spectra in the range 1.2-45 μm since January 2004, most of which show a weak absorption feature between 3.8 and 4 μm. A similar feature was observed previously from the Earth, but its origin could not be straightforwardly ascribed to surface materials, and specifically to carbonates. Here we show the surficial nature of this band that can be ascribed to carbonate mixed with the martian soil materials. The materials that best reproduce the detected feature are Mg-rich carbonates (huntite [CaMg₃(CO₃)₄] and/or magnesite [MgCO₃]). The presence of carbonates is demonstrated in both bright and dark martian regions. An evaluation of the likeliest abundance gives an upper limit of ∼10 wt%. The widespread distribution of carbonates supports scenarios that suggest carbonate formation occurred not by precipitation in a water-rich environment but by weathering processes.     

Further observations of regional dust storms and baroclinic eddies in the northern hemisphere of Mars

We have investigated the near-surface meteorology in the northern hemisphere of Mars through detailed analysis of data obtained with Mars Global Surveyor in January-August 2005. The season in the northern hemisphere ranged from midsummer through winter solstice of Mars Year (MY) 27. We examined composite, wide-angle images from the Mars Orbiter Camera and compiled a catalog of the dust storms that occurred in this interval. As in previous martian years, activity in the northern hemisphere was dominated by regional “flushing” dust storms that sweep southward through the major topographic basins, most frequently in Acidalia Planitia. We also used atmospheric profiles retrieved from radio occultation experiments to characterize eddy activity near the surface at high northern latitudes. There are strong correlations between the two sets of observations, which allowed us to identify three factors that influence the timing and location of the regional dust storms: (1) transitions among baroclinic wave modes, which strongly modulate the intensity of meridional winds near the surface, (2) storms zones, which impose strong zonal variations on the amplitude of some baroclinic eddies, and (3) stationary waves, which further modulate the wind field near the surface. The flushing dust storms ceased abruptly in midautumn, possibly in response to source depletion, CO₂ condensation, a shift in the period of the baroclinic eddies, and changes in the tidal wind field near the surface. Our results extend the meteorological record of the northern hemisphere, substantiate the findings of previous investigations, and further illuminate the climatic impact of baroclinic eddies.     

The influence of van der Waals forces on the state of water in the shallow subsurface of Mars

Microscopic liquid layers of water can evolve via adsorption on grain and mineral surfaces at and in the soil of the surface of Mars. The upper parts of these layers will start to freeze at temperatures clearly below the freezing point of bulk water (freezing point depression). A sandwich structure with layers of ice (top), liquid water (in between) and mineral surface (bottom) can evolve. The properties of the interfacial water (of adsorption water and premelted ice) on grain surfaces are described by a sandwich-model of a layer of liquid-like adsorption water between the adsorbing mineral surface layer and an upper ice layer. It is shown that the thickness or number of mono-layers of the interfacial water (of adsorption water and premelted ice) depends on temperature and atmospheric relative humidity. The derived equations for the sandwich model fit well to a known phenomenological relation between thickness of the liquid layer and relative humidity, and can be a tool to estimate or to determine for appropriate materials Hamaker's constant for van der Waals interactions on grains and in porous media. The curvature of grain surfaces is shown to have no remarkable effects for particles in the μm-range and larger. The application of these equations to thermo-physical conditions on Mars shows that the thickness of frost-layers, which can evolve over several hours on cooling surface parts of Mars, is typically of the order or a few tenths of one millimeter or less. This is in agreement with observations. Furthermore, an equation is derived, which relates the freezing point depression for van der Waals force governed interfacial water to the value of the Hamaker constant, to the latent heat of solidification, to the mass density of water ice, and to the thickness of the liquid-like layer. Again, this equation fits well to a known phenomenological relation between freezing point depression and thickness of the liquid-like layer. The derived equation shows that the lower limiting temperature of the liquid phase can reach about 180 K under martian conditions having an atmospheric water content of around 10 pr μm. An “Equilibrium Moisture Content” (EMC)/“Equilibrium Relative Humidity” (ERH) relation for the water content of martian soil has been derived, which relates, for equilibrium conditions, soil water content and atmospheric relative humidity. This relation indicates that the content of liquid interfacial water in the upper surface of Mars can reach up to 10% by weight and more in course of saturation during night hours, and it can be of about 2% by weight during the dry daytime hours.     

The presence and stability of ground ice in the southern hemisphere of Mars

We calculate new estimates of ground-ice stability and the depth distribution of the ice table (the depth boundary between ice-free soil above and ice-cemented soil below) and compare these theoretical estimates of the distribution of ground ice with the observed distribution of leakage neutrons measured by the Neutron Spectrometer instrument of the Mars Odyssey spacecraft's Gamma Ray Spectrometer instrument suite. Our calculated ground-ice distribution contains improvements over previous work in that we include the effects of the high thermal conductivity of ice-cemented soil at and below the ice table, we include the surface elevation dependence of the near-surface atmospheric humidity, and we utilize new high resolution maps of thermal inertia, albedo, and elevation from Mars Global Surveyor observations. Results indicate that ground ice should be about 5 times shallower than in previous predictions. While results are dependent on the atmospheric humidity, depths are generally between a few millimeters and a few meters with typical values of a few centimeters. Results are also geographically similar to previous predictions with differences due to the higher resolution of thermal inertia and the inclusion of elevation effects on humidity. Comparison with the measured epithermal-neutron count rates in the southern hemisphere indicate that the geographic distribution of the count rate is best correlated with ground ice in equilibrium with 10 to 20 pr μm (precipitable micrometers) column abundance of atmospheric water, assuming a uniform distribution with CO₂; however, given the uncertainties, 5 to 30 pr μm also may be viable. This water abundance represents a longer-term average over 100 to 1000 yr. There is a high degree of correlation between the depth of the ice table and the epithermal count rate that agrees remarkably well with predicted count rates as a function of ice-table depth. These results indicate that ground ice in the upper meter of the martian soil is in diffusive equilibrium with the atmosphere. Since ground ice in this depth zone is expected to undergo saturation/desiccation cycles with orbital variations, this ice should be younger than about 500 kyr and was emplaced under similar cold and dry climate conditions of today. Remaining differences between the predicted depths of the ice table and those inferred from the neutron data are likely to be due to subpixel heterogeneity in the martian surface including the presence of rocks, slopes, and patches of soil with varying thermophysical properties.     

Martian water vapor: Mars Express PFS/LW observations

We present the seasonal and geographical variations of the martian water vapor monitored from the Planetary Fourier Spectrometer Long Wavelength Channel aboard the Mars Express spacecraft. Our dataset covers one martian year (end of Mars Year 26, Mars Year 27), but the seasonal coverage is far from complete. The seasonal and latitudinal behavior of the water vapor is globally consistent with previous datasets, Viking Orbiter Mars Atmospheric Water Detectors (MAWD) and Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES), and with simultaneous results obtained from other Mars Express instruments, OMEGA and SPICAM. However, our absolute water columns are lower and higher by a factor of 1.5 than the values obtained by TES and SPICAM, respectively. In particular, we retrieve a Northern midsummer maximum of 60 pr-μm, lower than the 100-pr-μm observed by TES. The geographical distribution of water exhibits two local maxima at low latitudes, located over Tharsis and Arabia. Global Climate Model (GCM) simulations suggest that these local enhancements are controlled by atmospheric dynamics. During Northern spring, we observe a bulge of water vapor over the seasonal polar cap edge, consistent with the northward transport of water from the retreating seasonal cap to the permanent polar cap. In terms of vertical distribution, we find that the water volume mixing ratio over the large volcanos remains constant with the surface altitude within a factor of two. However, on the whole dataset we find that the water column, normalized to a fixed pressure, is anti-correlated with the surface pressure, indicating a vertical distribution intermediate between control by atmospheric saturation and confinement to a surface layer. This anti-correlation is not reproduced by GCM simulations of the water cycle, which do not include exchange between atmospheric and subsurface water. This situation suggests a possible role for regolith-atmosphere exchange in the martian water cycle.     

Influences of atmospheric variations on Mars's record of small craters

Planetary atmospheres influence cratering rates at small diameters (∼2-250 m) by filtering impactor populations via ablation, aerobraking and breakup of entering objects. The atmosphere of Mars undergoes rapid and drastic obliquity-driven variations in density, corresponding to pressure variations between zero and several tens of millibars. Here a simulation is used to assess the fate of a large population of impactors interacting with the present and predicted past and future martian atmospheres. We find that even Mars's present atmosphere significantly reduces crater production rates at small diameters (<30 m) and past denser atmospheres would have affected cratering even more strongly, and to considerably larger diameters. These effects are increased if the inner Solar System's small impactor population contains significant numbers of icy, cometary bodies. Evidence of recent atmospheric density variations may be detectable in the martian small cratering record with future planned imaging capabilities. Because of martian atmospheric effects and variations, surface ages derived from counts of craters of less than about 250 m on Mars may be underestimated.     

Spectral reflectance properties of minerals exposed to simulated Mars surface conditions

A number of mineral species were exposed to martian surface conditions of atmospheric pressure and composition, temperature, and UV light regime, and their evolution was monitored using reflectance spectroscopy. The stabilities for different groups varied widely. Phyllosilicate spectra all showed measurable losses of interlayer H₂O, with some structural groups showing more rapid H₂O loss than others. Loss of OH from the phyllosilicates is not always accompanied by a change in metal-OH overtone absorption bands. OH-bearing sulfates, such as jarosite and alunite, show no measurable change in spectral properties, suggesting that they should be spectrally detectable on Mars on the basis of diagnostic absorption bands in the 0.4-2.5 μm region. Fe³⁺- and H₂O-bearing sulfates all showed changes in the appearance and/or reduction in depths of hydroxo-bridged Fe³⁺ absorption bands, particularly at 0.43 μm. The spectral changes were often accompanied by visible color changes, suggesting that subsurface sulfates exposed to the martian surface environment may undergo measurable changes in reflectance spectra and color over short periods of time (days to weeks). Organic-bearing geological materials showed no measurable change in CH related absorption bands, while carbonates and hydroxides also showed no systematic changes in spectral properties. The addition of ultraviolet irradiation did not seem to affect mineral stability or rate of spectral change, with one exception (hexahydrite). In some cases, spectral changes could be related to the formation of specific new phases. The data also suggest that hydrated minerals detected on Mars to date retain their diagnostic spectral properties that allow their unique identification.     

Stability of ice on Mars and the water vapor diurnal cycle: Experimental study of the sublimation of ice through a fine-grained basaltic regolith

In order to advance our understanding of the long-term stability of subsurface ice, the diurnal martian water cycle, and implications for liquid water, we determined diffusion coefficients and adsorption kinetics for the water vapor produced by the sublimation of ice buried beneath various layers of fine-grained (<63, 63-125, and 125-250 μm) basaltic powder under simulated martian conditions. Sublimation rates at shallower depths, <10 mm, were determined to be affected by mass transfer through the atmosphere in addition to the basalt layer. For greater depths, the measured diffusion coefficients for water vapor moving through basalt grains were 1.56±0.53×¹⁰⁻⁴, 2.05±0.82×¹⁰⁻⁴, and for the <63, 63-125, and 125-250 μm basaltic layers, respectively. Through the Brunauer, Emmett and Teller (BET) isotherm, which assumes multiple molecular layers of adsorbed water, we determined the adsorption constants of 52.6±8.3 at 270 K for <63 μm, 39.0±6.4 at 267 K for 63-125 μm, and 54.3±9.3 at 266 K for 125-250 μm, resulting in surface areas of 2.6±0.1×¹⁰⁴, 1.7±0.3×¹⁰⁴, , respectively. These results suggest that while diffusion is too rapid to explain the purported diurnal cycle in water content of the atmosphere, adsorption is efficient and rapid, and does provide an effective mechanism to explain such a cycle. The present diffusion data suggest that very thin, <50 pr μm, shallow, 10 mm, ice deposits would last for >10 h at ∼224 K, just above the freezing point of saturated CaCl₂. Temperatures can remain above ∼224 K over most of the planet, which means that water, even as saturated brine, will sublimate before the freezing point is reached and liquid could be formed. On the other hand, 1 m ice layers below 1 m of fine-grained basaltic regolith at 235 K and 10 Pa of atmospheric water could last 600 to 1300 years. At deeper depths and lower temperatures, ice could last since the last major obliquity change 400,000 years ago.