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1.
Calculated Phase Relations in the System NCKFMASH (Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O) for High-Pressure Metapelites 总被引:5,自引:0,他引:5
Petrogenetic grids in the system NCKFMASH (Na2OCaOK2OFeOMgOAl2O3SiO2H2O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the PT range 730kbar and 450680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H2O in excess. These grids, together with calculated compatibilitydiagrams and PT and TXCa and PXCa pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different PT conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and PTconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in PT and PXCapseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry 相似文献
2.
Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists 总被引:2,自引:0,他引:2
Pressuretemperature grids in the system Na2OCaOK2OFeOMgOAl2O3SiO2H2O and its subsystems have been calculatedin the range 1545 kbar and 550900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressuretemperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H2O-carriersin subducting slabs. Depending on bulk composition and pressuretemperaturepath, amphibole may or may not be a major H2O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H2O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists 相似文献
3.
Using a previously published, internally consistent thermodynamic dataset and updated models of activity–composition relations for solid solutions, petrogenetic grids in the model system KFMASH (K2O–FeO–MgO–Al2O3–SiO2–H2O) and the subsystems KMASH and KFASH have been calculated with the software THERMOCALC 3.1 in the P–T range 5–36 kbar and 400–810 °C, involving garnet, chloritoid, biotite, carpholite, talc, chlorite, staurolite and kyanite/sillimanite with phengite, quartz/coesite and H2O in excess. These grids, together with calculated AFM compatibility diagrams and pseudosections, are shown to be powerful tools for delineating the phase equilibria and P–T conditions of pelitic high-P assemblages for a variety of bulk compositions. The calculated equilibria and mineral compositions are in good agreement with petrological observation. The calculation indicates that the typical whiteschist assemblage kyanite–talc is restricted to the rocks with extremely high XMg values, decreasing XMg in a bulk composition favoring the stability of chloritoid and garnet. Also, the chloritoid–talc paragenesis is stable over 19–20 kbar in a temperature range of ca. 520–620 °C, being more petrologically important than the previously highlighted assemblage talc–phengite. Moreover, contours of the calculated Si isopleths in phengite in P–T and P–X pseudosections for different bulk compositions extend the experimentally derived phengite geobarometers to various KFMASH assemblages. 相似文献
4.
GARCIA-CASCO ANTONIO; HAISSEN FAOUZIYIA; CASTRO ANTONIO; EL-HMIDI HASSAN; TORRES-ROLDAN RAFAEL LUIS; MILLAN GUILLERMO 《Journal of Petrology》2003,44(10):1727-1757
We document experiments on a natural metapelite in the range650775°C, 614 kbar, 10 wt % of added water,and 700850°C, 410 kbar, no added water. Staurolitesystematically formed in the fluid-present melting experimentsabove 675°C, but formed only sporadically in the fluid-absentmelting experiments. The analysis of textures, phase assemblages,and variation of phase composition and FeMg partitioningwith P and T suggests that supersolidus staurolite formed at(near-) equilibrium during fluid-present melting reactions.The experimental results are used to work out the phase relationsin the system K2ONa2OFeOMgOAl2O3SiO2H2Oappropriate for initial melting of metapelites at the upperamphibolite facies. The PT grid developed predicts theexistence of a stable PT field for supersolidus staurolitethat should be encountered by aluminous Fe-rich metapelitesduring fluid-present melting at relatively low temperature andintermediate pressures (675700°C, 610 kbarfor XH2O = 1, in the KNFMASH system), but not during fluid-absentmelting. The implications of these findings for the scarcityof staurolite in migmatites are discussed. KEY WORDS: metapelites; migmatites; partial melting; PT grid; staurolite 相似文献
5.
Solubility of Anhydrite, CaSO4, in NaCl-H2O Solutions at High Pressures and Temperatures: Applications to Fluid-Rock Interaction 总被引:1,自引:0,他引:1
Anhydrite solubility in H2ONaCl solutions was measuredat 614 kbar, 600800°C and NaCl mole fractions(XNaCl) of 00·3 in pistoncylinder apparatus.Solubilities were determined by weight changes of natural anhydritein perforated Pt envelopes confined with fluid in larger Ptcapsules. In initially pure H2O at 10 kbar and 800°C, CaSO4concentration is low (0·03 molal), though much largerthan at the same temperature and 1 kbar. Hematite-buffered experimentsshowed slightly lower solubilities than unbuffered runs. CaSO4solubility increases enormously with NaCl activity: at 800°Cand 10 kbar and XNaCl of 0·3, CaSO4 molality is 200 timeshigher than with pure H2O. Whereas CaSO4 solubility in pureH2O decreases with rising T at low T and P, the high-P resultsshow that anhydrite solubility increases with T at constantP at all XNaCl investigated. The effects of salinity and temperatureare so great at 10 kbar that critical mixing between sulfate-richhydrosaline melts and aqueous salt solutions is probable at900°C at XNaCl 0·3. Recent experimental evidencethat volatile-laden magmas crystallizing in the deep crust mayevolve concentrated salt solutions could, in light of the presentwork, have important implications regarding such diverse processesas Mount Pinatubo-type S-rich volcanism, high-f O2 regionalmetamorphism, and emplacement of porphyry CuMo ore bodies,where anhydritehematite alteration and fluid inclusionsreveal the action of very oxidized saline solutions rich insulfur. KEY WORDS: anhydrite; sulfur; solubility; metamorphic brines; granulites 相似文献
6.
Calculation of Phase Relations Involving Haplogranitic Melts Using an Internally Consistent Thermodynamic Dataset 总被引:5,自引:4,他引:5
A simple thermodynamic model is developed for silicate meltsin the system CaONa2OK2OAl2O3SiO2H2O(CNKASH). The Holland & Powell (Journal of Metamorphic Geology,16, 289302, 1998) internally consistent thermodynamicdataset is extended via the incorporation of the experimentallydetermined melting relationships in unary and binary subsystemsof CNKASH. The predictive capability of the model is evaluatedvia the experimental data in ternary and quaternary subsystems.The resulting dataset, with the software THERMOCALC, is thenused to calculate melting relationships for haplogranitic compositions.Predictions of the PT stabilities of assemblages in water-saturatedand -undersaturated bulk compositions are illustrated. It isnow possible to make useful calculations of the melting behaviourof appropriate composition rocks under crustal conditions. KEY WORDS: thermodynamics; melts; granite; dataset 相似文献
7.
Phase Relations in Peridotitic and Pyroxenitic Rocks in the Model Systems CMASH and NCMASH 总被引:1,自引:1,他引:0
Alpine-type peridotites and associated pyroxenites are foundas lenses in the continental crust in many different orogens.The reconstruction of the pressuretemperature (PT)evolution of these rocks is, however, difficult or even impossible.With geothermobarometry, usually one point on the overall PTpath can be obtained. To use the different mineral assemblagesobserved in ultramafic rocks as PT indicators, quantitativePT phase diagrams are required. This study presents newcalculated phase diagrams for peridotitic and pyroxenitic rocksin the model systems CaOMgOAl2O3SiO2H2O(CMASH) and Na2OCaOMgOAl2O3SiO2H2O(NCMASH), which include the respective solid solutions as continuousexchange vectors. These phase diagrams represent applicablepetrogenetic grids for peridotite and pyroxenite. On the basisof these general petrogenetic grids, phase diagrams for particularperidotite and pyroxenite bulk compositions are constructed.In an example of pyroxenite from the Shackleton Range, Antarctica,the different observed mineral assemblages are reflected bythe phase diagrams. For these rocks, a high-pressure metamorphicstage around 18 kbar and an anticlockwise PT evolution,not recognized previously, can be inferred. KEY WORDS: Antarctic; high-pressure metamorphism; peridotite; phase diagrams; pyroxenite 相似文献
8.
An Experimentally Constrained Petrogenetic Grid in the Silica-Saturated Portion of the System KFMASH at High Temperatures and Pressures 总被引:4,自引:0,他引:4
Experiments in the quartz-saturated part of the system KFMASHunder fO2 conditions of the haematitemagnetite bufferand using bulk compositions with XMg of 0·81, 0·72,0·53 define the stability limits of several mineral assemblageswithin the PT field 912 kbar, 8501100°C.The stability limits of the mineral assemblages orthopyroxene+ spinel + cordierite ± sapphirine, orthopyroxene + garnet+ sapphirine, sapphirine + cordierite + orthopyroxene and garnet+ orthopyroxene + spinel have been delineated on the basis ofPT and TX pseudosections. Sapphirine did not appearin the bulk composition of XMg = 0·53. A partial petrogeneticgrid applicable to high MgAl granulites metamorphosedat high fO2, developed in our earlier work, was extended tohigher pressures. The experimental results were successfullyapplied to several high-grade terranes to estimate PTconditions and retrograde PT trajectories. KEY WORDS: KFMASH equilibria; experimental petrogenetic grid at high fO2 相似文献
9.
The equilibrium temperatures of the reaction muscovite+chlorite+quartz= cordierite+phlogopite+H2O (1) in the pure system K2OMgOAl2O2SiO2H2Owere found to be 495±10°C at 1 kb PH2O; 525±10°Cat 2 kb; 610±15°C at 5 kb; 635±10°C at6 kb. From intersection of this curve with the lower temperaturestability limit of cordierite close to 645°C, 6.5 kb PH2O,a reaction cordieritc+muscovite = phlogopite+aluminum silicate+quartz+H2O(2) is generated which has a negative slope and passes throughthe points 645°C, 6.5 kb PH2O and 700°C, 5 kb PH2O.On the high-pressure side of this reaction curve cordieriteis restricted to K2Opoor bulk compositions. Application of the experimentally determined phase relationsto more complex natural pelitic rocks suggests that reaction(1) represents maximum temperatures for the disappearance ofchlorite from pelitic assemblages containing muscovite and quartz,whereas reaction (2) gives maximum water pressures for the disappearanceof cordierite from these rocks. 相似文献
10.
The Effect of Reaction Overstep on Garnet Microtextures in Metapelitic Rocks of the Ilesha Schist Belt, SW Nigeria 总被引:2,自引:4,他引:2
Garnet-bearing assemblages of K-rich and K-poor metapelitesfrom the Ilesha Schist belt, SW Nigeria, are investigated. K-richsamples contain the assemblages (A) garnetstaurolitemuscovitechloritemagnetite,(B) andalusitegarnetstaurolitemuscovitechloritemagnetiteand (C) sillimaniteandalusitegarnetmuscovitechloritemagnetite.K-poor samples contain the assemblages (D) garnetstaurolitecordieritechloriteand (E) garnetcordieritechlorite ± staurolite.All assemblages contain quartz, plagioclase, biotite and ilmenite.PT pseudosections calculated in the system CaONa2OK2OTiO2MnOFeOMgOAl2O3SiO2 H2O ± O2 suggest peak metamorphismat 590 ± 20°C at 5 ± 0·5 kbar, followedby retrogression to 550°C at 3·0 kbar, in agreementwith field evidence, domain assemblages, mineral compositions,modes and geothermobarometry. The absence of compositional zonationshows that garnet in all investigated rocks nucleated and grewat constant PTX in equilibrium with associatedminerals on the thin-section scale. However, the garnet-in reactiondid not begin until the establishment of a significant temperatureoverstep of 相似文献
11.
Variation in Metamorphic Style along the Northern Margin of the Damara Orogen, Namibia 总被引:2,自引:0,他引:2
The northern margin of the Inland Branch of the Pan-AfricanDamara Orogen in Namibia shows dramatic along-strike variationin metamorphic character during convergence between the Congoand Kalahari Cratons (M3 metamorphic cycle). Low-P contact metamorphismwith anticlockwise PT paths dominates in the westerndomains (Ugab Zone and western Northern Zone), and high-P Barrovianmetamorphism with a clockwise PT path is documented fromthe easternmost domain (eastern Northern Zone). The sequenceof M3 mineral growth in contact aureoles shows early growthof cordierite porphyroblasts that were pseudomorphed to biotitechloritemuscoviteat the same time as an andalusitebiotitemuscovitetransposed foliation was developed in the matrix. The peak-Tmetamorphic assemblages and fabrics were overprinted by crenulationsand retrograde chloritemuscovite. The KFMASH PTpseudosection for metapelites in the Ugab Zone and western NorthernZone contact aureoles indicates tight anticlockwise PTloops through peak metamorphic conditions of 540570°Cand 2·53·2 kbar. These semi-quantitativePT loops are consistent with average PT calculationsusing THERMOCALC, which give a pooled mean of 556 ± 26°Cand 3·2 ± 0·6 kbar, indicating a high averagethermal gradient of 50°C/km. In contrast, the eastern NorthernZone experienced deep burial, high-P/moderate-T Barrovian M3metamorphism with an average thermal gradient of 21°C/kmand peak metamorphic conditions of c. 635°C and 8·7kbar. The calculated PT pseudosection and garnet compositionalisopleths in KFMASH, appropriate for the metapelite sample fromthis region, document a clockwise PT path. Early plagioclasekyanitebiotiteparageneses evolved by plagioclase consumption and the growthof garnet to increasing XFe, XMg and XCa and decreasing XMncompositions, indicating steep burial with heating. The developedkyanitegarnetbiotite peak metamorphic parageneseswere followed by the resorption of garnet and formation of plagioclasemoats, indicating decompression, which was followed by retrogressivecooling and chloritemuscovite growth. The clockwise PTloop is consistent with the foreland vergent foldthrustbelt geometry in this part of the northern margin. Earlier formed(580570 Ma) pervasive matrix foliations (M2) were overprintedby contact metamorphic parageneses (M3) in the aureoles of 530± 3 Ma granites in the Ugab Zone and 553514 Magranites in the western Northern Zone. Available geochronologicaldata suggest that convergence between the Congo and KalahariCratons was essentially coeval in all parts of the northernmargin, with similar ages of 535530 Ma for the main phaseof deformation in the eastern Northern Zone and Northern Platformand 538505 Ma high-grade metamorphism of the CentralZone immediately to the south. Consequently, NNESSW-directedconvergent deformation and associated M3 metamorphism of contrastingstyles are interpreted to be broadly contemporaneous along thelength of the northern margin of the Inland Branch. In the westheat transfer was dominated by conduction and externally drivenby granites, whereas in the east heat transfer was dominatedby advection and internally driven radiogenic heat production.The ultimate cause was along-orogen variation in crustal architecture,including thickness of the passive margin lithosphere and thicknessof the overlying sedimentary succession. KEY WORDS: Pan-African Orogeny; PT paths; pseudosections; low-P metamorphism; contact metamorphism; Barrovian metamorphism 相似文献
12.
Chemical zoning of garnet is often used to deduce PTpaths of rocks by inverse calculation. To validate the derivedPT paths, it is desired to establish a method to predictthe chemical compositions of garnet theoretically. This studyproposes a new forward calculation of the formation of MgFeMngarnet from chlorite, which solves the non-linear simultaneousequations using nested iterative calculations. Growth of garnetconsuming chlorite and quartz was modelled in a MnOFeOMgOAl2O3SiO2H2Osystem, using the most recent thermodynamic data for the minerals.The prograde PT history of the Sambagawa metamorphicbelt, SW Japan, was modelled. To reproduce growth zoning, crystallizedgarnet was removed step by step from the system; perfect diffusionwas assumed for chlorite. The proposed model derived the evolutionof molar amounts and chemical compositions of MgFeMnchlorite and garnet. It successfully reproduced the shape ofthe observed chemical profile of garnet, although the temperaturecondition was higher than general observations. The Mn contentof the garnet core was generally high, and Mg/Fe ratio alwaysstarted rising rapidly after Mn was depleted. Thermodynamicproperties of minerals, initial chlorite composition, PTpath, H2O partial pressure, and Ca content in garnet were variedto test the behaviour of the system. The properties of Mn phasesinfluenced only the chemical composition of the garnet core.The temperature range in which garnet grew depended on the H2Opartial pressure or the Ca content in garnet. KEY WORDS: chemical equilibrium; chemical zoning; garnet; forward modelling; Sambagawa metamorphic belt 相似文献
13.
Polymetamorphism in the NE Shackleton Range, Antarctica: Constraints from Petrology and U-Pb, Sm-Nd, Rb-Sr TIMS and in situ U-Pb LA-PIMMS Dating 总被引:1,自引:0,他引:1
Metapelitic rock samples from the NE Shackleton Range, Antarctica,include garnet with contrasting zonation patterns and two agespectra. Garnet porphyroblasts in K-rich kyanitesillimanitestaurolitegarnetmuscovitebiotite schistsfrom Lord Nunatak show prograde growth zonation, and give SmNdgarnet, UPb monazite and RbSr muscovite ages of518 ± 5, 514 ± 1 and 499 ± 12 Ma, respectively.Geothermobarometry and PT pseudo-section calculationsin the model system CaONa2OK2O TiO2MnOFeOMgOAl2O3SiO2H2Oare consistent with garnet growth during prograde heating from540°C/7 kbar to 650°C/7·5 kbar, and partial resorptionduring a subsequent PT decrease to <650°C at <6kbar. All data indicate that rocks from Lord Nunatak were affectedby a single orogenic cycle. In contrast, garnet porphyroblastsin K-poor kyanitesillimanite staurolitegarnetcordieritebiotite-schistsfrom Meade Nunatak show two growth stages and diffusion-controlledzonation. Two distinct age groups were obtained. Laser ablationplasma ionization multicollector mass spectrometry in situ analysesof monazite, completely enclosed by a first garnet generation,yield ages of c. 1700 Ma, whereas monazite grains in open garnetfractures and in most matrix domains give c. 500 Ma. Both agegroups are also obtained by UPb thermal ionization massspectrometry analyses of matrix monazite and zircon, which fallon a discordia with lower and upper intercepts at 502 ±1 and 1686 ± 2 Ma, respectively. SmNd garnet datingyields an age of 1571 ± 40 Ma and RbSr biotiteanalyses give an age of 504 ± 1 Ma. Integrated geochronologicaland petrological data provide evidence that rocks from MeadeNunatak underwent a polymetamorphic Barrovian-type metamorphism:(1) garnet 1 growth and subsequent diffusive garnet annealingbetween 1700 and 1570 Ma; (2) garnet 2 growth during the RossOrogeny at c. 500 Ma. During the final orogenic event the rocksexperienced peak PT conditions of about 650°C/7·0kbar and a retrograde stage at c. 575°C/4·0 kbar. KEY WORDS: garnet microtexture; PT pseudosection; geochronology; polymetamorphism; Shackleton Range; Antarctica 相似文献
14.
We investigated phase equilibria in the six-component systemNa2OK2OAl2O3SiO2F2O1H2Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranitecryoliteH2Oat 640°C and 4 wt % F, and haplogranitetopazH2Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topazcryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H2O at the quartzcryolitetopazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation 相似文献
15.
DANYUSHEVSKY LEONID V.; EGGINS STEPHEN M.; FALLOON TREVOR J.; CHRISTIE DAVID M. 《Journal of Petrology》2000,41(8):1329-1364
The H2O contents and trace-element abundances are presentedfor two well-studied suites of mid-ocean ridge basalt (MORB)glasses from the Northern East Pacific Rise (EPR, 911°N)and the South East Indian Ridge (SEIR, 127129°E).Exactly the same region of the glass samples has been analysedfor these components using microbeam techniques. Our data allowexamination of the fine details of H2O geochemical behaviourduring MORB genesis. We demonstrate that relative H2O contents[i.e. H2O/(another incompatible element)] vary systematicallywith increasing (La/Sm)N in MORB glasses from both the EPR andSEIR. This indicates that H2O behaves like other incompatible(in peridotite mineralogies) elements during MORB petrogenesis,and is primarily controlled by solidmelt partitioning.However, the relative H2O contents of MORB glasses from theSEIR are higher than in glasses from the EPR at a given (La/Sm)N,demonstrating global variations in the H2O contents of MORB.Despite regional differences in relative H2O contents, the incompatiblebehaviour of H2O is similar in both studied regions. The relativeincompatibility of H2O varies systematically with increasing(La/Sm)N: in depleted MORB, H2O is similar to La whereas inEMORB, H2O is similar to Ce. Similar patterns of varying relativeincompatibility (to REE) are displayed by Zr, Hf, and P. Ourdata are best explained if H2O is stored in the mantle in thesame phase with LREE (clinopyroxene?) at sub-solidus. Regionalvariations in relative H2O contents in EMORB that have moreradiogenic Sr, Nd and Pb isotopes might be explained by differencesin the nature of enriched components recycled via subductionprocesses. However, when EMORB have the same radiogenic isotopecompositions as NMORB within a segment, relative H2O contentsin EMORB probably reflect local processes that lead to enrichmentin incompatible elements. Regional differences in relative H2Ocontents of NMORB may reflect either initial variations in theEarths mantle or inhomogeneities left after formationof the continental crust. KEY WORDS: glass; geochemistry; H2O; MORB; petrology 相似文献
16.
Sediment Melts at Sub-arc Depths: an Experimental Study 总被引:14,自引:0,他引:14
The phase and melting relations in subducted pelites have beeninvestigated experimentally at conditions relevant for slabsat sub-arc depths (T = 600–1050°C, P = 2·5–4·5GPa). The fluid-present experiments produced a dominant paragenesisconsisting of garnet–phengite–clinopyroxene–coesite–kyanitethat coexists with a fluid phase at run conditions. Garnet containsdetectable amounts of Na2O (up to 0·5 wt%), P2O5 (upto 0·56 wt%), and TiO2 (up to 0·9 wt%) in allexperiments. Phengite is stable up to 1000°C at 4·5GPa and is characterized by high TiO2 contents of up to 2 wt%.The solidus has been determined at 700°C, 2·5 GPaand is situated between 700 and 750°C at 3·5 GPa.At 800°C, 4·5 GPa glass was present in the experiments,indicating that at such conditions a hydrous melt is stable.In contrast, at 700°C, 3·5 and 4·5 GPa, asolute-rich, non-quenchable aqueous fluid was present. Thisindicates that the solidus is steeply sloping in P–T space.Fluid-present (vapour undersaturated) partial melting of thepelites occurs according to a generalized reaction phengite+ omphacite + coesite + fluid = melt + garnet. The H2O contentof the produced melt decreases with increasing temperature.The K2O content of the melt is buffered by phengite and increaseswith increasing temperature from 2·5 to 10 wt%, whereasNa2O decreases from 7 to 2·3 wt%. Hence, the melt compositionschange from trondhjemitic to granitic with increasing temperature.The K2O/H2O increases strongly as a function of temperatureand nature of the fluid phase. It is 0·0004–0·002in the aqueous fluid, and then increases gradually from about0·1 at 750–800°C to about 1 at 1000°C inthe hydrous melt. This provides evidence that hydrous meltsare needed for efficient extraction of K and other large ionlithophile elements from subducted sediments. Primitive subduction-relatedmagmas typically have K2O/H2O of 0·1–0·4,indicating that hydrous melts rather than aqueous fluids areresponsible for large ion lithophile element transfer in subductionzones and that top-slab temperatures at sub-arc depths are likelyto be 700–900°C. KEY WORDS: experimental petrology; pelite; subduction; UHP metamorphism; fluid; LILE 相似文献
17.
The phase diagram for lherzoliteCO2H2O providesa framework for interpreting the distribution of phase assemblagesin the upper mantle with various thermal structures, in differenttectonic settings. Experiments show that at depths >80 km,the near-solidus partial melts from lherzoliteCO2H2Oare dolomitic, changing through carbonatesilicate liquidswith rising temperatures to mafic liquids; vapor, if it coexists,is aqueous. Experimental data from simple systems suggest thata critical end-point (K) occurs on the mantle solidus at anundetermined depth. Isobaric (TX) phase diagrams forvolatile-bearing systems with K elucidate the contrasting phaserelationships for lherzoliteCO2H2O at depths belowand above a critical end-point, arbitrarily placed at 250 km.At levels deeper than K, lherzolite can exist with dolomiticmelt, aqueous vapor, or with critical fluids varying continuouslybetween these end-members. Analyses of fluids in microinclusionsof fibrous diamonds reveal this same range of compositions,supporting the occurrence of a critical end-point. Other evidencefrom diamonds indicates that the minimum depth for this end-pointis 125 km; maximum depth is not constrained. Constructed cross-sectionsshowing diagrammatically the phase fields intersected by upwellingmantle indicate how rising trace melts may influence trace elementconcentrations within a mantle plume. KEY WORDS: mantle solidus; critical end-point; dolomitic magma; diamond inclusions; critical fluids 相似文献
18.
We have investigated the stability and composition of potassiumamphibole and its high-pressure breakdown product phase X insynthetic peralkaline and subalkaline KNCMASH (K2ONa2OCaOMgOAl2O3SiO2H2O)and natural KLB-1 peridotite bulk compositions between 10 and23 GPa at 8001800°C. In the KNCMASH system, potassiumamphibole reaches its upper pressure stability limit at 1315GPa at 相似文献
19.
Thermodynamic calculations based on addition of mass balanceequations to the Gibbs Method (Spear, 1986) are used to modelthe cordierite-producing reaction in pelitic gneiss from theMcCullough Range, southern Nevada. Calculations which treatthe model paragenesis as a system open to transfer of H2O areconsistent with textural relations. Results indicate that cordieritegrew by the continuous net-transfer reaction: 0?76 BIO+1?72 SILL+3? 55 QTZ+0?27 PLG+0?005 GRT +0?06Al2R2+1Si1[BIO]1?02 KSP+0?76 H2O +0?30 FeMg1[CRD]+0?15FeMg1[BIO]+0?0005 FeMg1[GRT] +0?005 CaNaAl1Si1[PLG] with decreasing P, decreasing T, and increasing aH2O The steepretrograde dP/dT path for these low-pressure granulites contrastswith isobaric cooling paths typical of higher pressure granulites,and suggests uplift and erosion were active during Proterozoicgranulite-grade metamorphism in this area. 相似文献
20.
The bronzitechromite-anorthite assemblage of the Funit(Cameron & Emerson, 1959) from the Critical Zone of theBushveld Igneous Complex, was examined with the aid of an electrolyticcell designed after Sato (1971). The resultant fO2-T data reveala last equilibration at an fO2 value of 1011·82 ±·40 atm and at a temperature of 1091 ± 35 °C.These fO2-T data when compared with: (1) a one atmosphere quenchingtechnique solidus determinationof 1110 ± 5 °C, (2) the Bushveld plagioclase compositional trends (Cameron,1970), (3) Bushveld petrofabric examinations (Cameron, 1969) (4) phase equilibria in the system CaOMgOFeOCaAl2Si2O8SiO2(Roeder & Osborn, 1966), (5) phase equilibria in the system CaAl2Si2O8NaAlSi3O8SiO2MgOFeO2H2OCO2(Eggler, 1974), all support the idea that the Eastern Bushveld magma was notappreciably differentiating in the middle Critical Zone betweenF and the L Horizons, an accumulation of nearly 220 meters. 相似文献