Metasomatic Stages and Scapolitization Effects on Chemical Composition of Pasveh Pluton,NW Iran

Pasveh gabbros are mafic component of a plutonic complex in the northwest Sanandaj-Sirjan Zone.These cumulative rocks are composed of plagioclase and calcic clinopyroxene(Cpx) ,which yield unusually high CaO(>19 wt.%) in whole-rock chemistry.Petrographical and geochemical data suggest that Pasveh gabbros can be divided into two groups:free scapolite and scapolite-bearing gabbros.The second group has higher Na2O,K2O,and P2O5 relative to free scapolite ones and is enriched in LIL(large ion lithophile) and HFS...     

Origin and timing of the post-Variscan gabbro–granite complex of Porto (Western Corsica)

The post-Variscan complex of Porto consists of metaluminous to slightly peraluminous A-type biotite granites mingled with gabbro-dioritic rocks, and late dykes with basaltic to trachyandesitic composition. U-Pb zircon dating by LA-ICP-MS on two mafic intrusive samples constrains the time of the gabbro–granite crystallisation at 281 ± 3 Ma and 283 ± 2 Ma. Hornblende ⁴⁰Ar-³⁹Ar ages from a late trachyandesite dyke date the dyking event at 280 ± 2 Ma, which is within error the U-Pb zircon ages of the intrusives. Biotite granites show variable major and trace element compositions and similar initial ε_Nd (−0.3 to +0.9). Whole rock chemistry variations and trace element compositions of plagioclase and allanite indicate that the granites are genetically linked, essentially through fractional crystallisation of feldspars and minor allanite. On the basis of whole-rock chemistry e.g. initial ε_Nd +4.9 to +1.7 and trace element clinopyroxene compositions, we have ascertained that the mafic intrusives and basic dykes formed from isotopically depleted mantle source-derived melts with similar trace element signature. These basic melts experienced slightly different evolutionary histories, controlled by fractional crystallisation and crustal contamination, mainly by the acid magma that gave rise to the associated biotite granites, but also by the enclosing older Variscan granitoids. U-Pb zircon data suggest that the Porto complex was affected by hydrothermal fluid circulation at 259 ± 9 Ma.     

Fluid Transfer in High-grade Metamorphic Terrains Intruded by Anorogenic Granites: The Thor Range, Antarctica

A composite intrusive igneous complex in the central mountainrange of Queen Maud Land (Thor Range), Antarctica, displayscharacteristic features of anorogenic granites. A suite of massiveintrusives and various sets of dykes and satellite intrusionsare ferroan, alkalic to alkali–calcic, and weakly peraluminous.An early set of plutons consists of charnockitic alkali-granites;a later group of plutons comprises fayalite Qtz-syenites. Coarsemesoperthite is the dominant mineral in all rocks, quartz isabundant and plagioclase is a minor mineral. Olivine (fayalite)is the characteristic mafic mineral, but subcalcic augite andoccasionally pigeonite or orthopyroxene are present. In mostsamples, amphibole is the dominant mafic mineral and its compositionis close to end-member hastingsite. It contains high concentrationsof F and Cl. Some samples contain igneous fluorite. Thermobarometrysuggests a temperature of 900 ± 25°C and a pressureof 0·4 ± 0·1 GPa for the crystallizationconditions of the pyroxene–olivine assemblages. The solidustemperature of 800–850°C for both suites of plutonicrocks is typical of water-deficient granitic melts. The estimatedlow water activity of 0·3–0·5 at solidusconditions is consistent with the high halogen content of thebulk-rocks and their constituent minerals. In the absence ofan aqueous fluid, the halogens remained in the minerals at thesolidus. Oxygen fugacity stayed below QFM in all igneous rocksabove solidus. This is typical of melts derived from partialmelting of mafic source rocks. The igneous rocks were locallyaffected by at least three distinct episodes of hydration. Asthe melt approached solidus conditions, fayalite and pyroxenewere locally transformed into hastingsite as a result of increasingfugacity of volatile components. Fayalite-free and fayalite-bearingigneous rocks are arranged in banded structures. Subsolidushydration locally modified the igneous rocks and transformedpyroxene- and fayalite-bearing granites into biotite-granitesand hornblende-granites in which all evidence of former high-Thistory was erased. This local hydration of igneous rocks occurredin response to uptake of H₂O that had been given off by gneissicxenoliths as a result of progressing, continuous, dehydrationreactions. The reactions in the gneiss xenoliths were drivenby contact metamorphism. This exchange of H₂O between igneousand metamorphic rocks occurred in a fluid-absent regime at temperaturesof about 750°C. Late reaction veins formed by hydraulicfracturing of the plutonic rocks and indicate the presence ofa low-density fluid phase at amphibolite facies conditions. KEY WORDS: anorogenic granite; fayalite; hastingsite; fluid recycling; Antarctica     

Superposition of replacements in the mafic granulites of the Jijal complex of the Kohistan arc, northern Pakistan: dehydration and rehydration within deep arc crust

A deep-level crustal section of the Cretaceous Kohistan arc is exposed in the northern part of the Jijal complex. The occurrence of mafic to ultramafic granulite-facies rocks exhibits the nature and metamorphic evolution of the lower crust. Mafic granulites are divided into two rock types: two-pyroxene granulite (orthopyroxene+clinopyroxene+plagioclase±quartz [1]); and garnet–clinopyroxene granulite (garnet+clinopyroxene+plagioclase+quartz [2]). Two-pyroxene granulite occurs in the northeastern part of the Jijal complex as a relict host rock of garnet–clinopyroxene granulite, where the orthopyroxene-rich host is transected by elongated patches and bands of garnet–clinopyroxene granulite. Garnet–clinopyroxene granulite, together with two-pyroxene granulite, has been partly replaced by amphibolite (hornblende±garnet+plagioclase+quartz [3]). The garnet-bearing assemblage [2] is expressed by a compression–dehydration reaction: hornblende+orthopyroxene+plagioclase=garnet+clinopyroxene+quartz+H₂O↑. Subsequent amphibolitization to form the assemblage [3] is expressed by two hydration reactions: garnet+clinopyroxene+plagioclase+H₂O=hornblende+quartz and plagioclase+hornblende+H₂O=zoisite+chlorite+quartz. The mafic granulites include pod- and lens-shaped bodies of ultramafic granulites which consist of garnet hornblendite (garnet+hornblende+clinopyroxene [4]) associated with garnet clinopyroxenite, garnetite, and hornblendite. Field relation and comparisons in modal–chemical compositions between the mafic and ultramafic granulites indicate that the ultramafic granulites were originally intrusive rocks which dissected the protoliths of the mafic granulites and then have been metamorphosed simultaneously with the formation of garnet–clinopyroxene granulite. The results combined with isotopic ages reported elsewhere give the following tectonic constraints: (1) crustal thickening through the development of the Kohistan arc and the subsequent Kohistan–Asia collision caused the high-pressure granulite-facies metamorphism in the Jijal complex; (2) local amphibolitization of the mafic granulites occurred after the collision.     

The Serra da Graciosa A-type Granites and Syenites, southern Brazil: Part 2: Petrographic and mineralogical evolution of the alkaline and aluminous associations

The Serra da Graciosa Granites and Syenites comprise five distinct plutons in the Brasiliano/Pan-African Graciosa A-type Province, southern Brazil. Six petrographic series can be identified in these plutons: (1) Alkaline series 1, composed of amphibole-bearing alkali feldspar syenites with varied mafic mineralogy and quartz contents, from alkali feldspar syenites with calcic amphibole, clinopyroxene, olivine and allanite to alkali feldspar quartz syenites with sodic–calcic amphibole and chevkinite–perrierite and to alkali feldspar granites with sodic amphibole; (2) Alkaline series 2, characterized by amphibole-bearing alkali feldspar granites, with limited modal variations but amphibole compositions also varying from calcic to sodic; (3) Alkaline series 3, of limited occurrence, which includes alkali feldspar syenites with olivine and clinopyroxene and no amphibole; (4) Aluminous series 1, of widespread occurrence, with various petrographic facies of biotite granites with amphibole; (5) Aluminous series 2, characterized by alkali feldspar granites with biotite and only minor amphibole; (6) Monzodiorites, typically with biotite, calcic amphibole and augitic clinopyroxene, partially mingled with granitic magmas. The mafic minerals present are, in general, Fe-rich with correspondingly low Mg and Al contents. In Alkaline series 1, amphiboles crystallized in progressively more oxidizing and alkaline conditions, while in Alkaline series 2, the initial conditions were somewhat more oxidizing and shifted to reducing in the final stages. In Aluminous series 1 and Aluminous series 2, amphiboles are calcic and comparatively homogeneous. The amphiboles in the monzodioritic rocks, while also homogeneous, are more Mg-rich and show compositions quite distinct from the calcic varieties in the other associations, and this is also the case for clinopyroxene. Mg# in biotite decreases from the monzodioritic rocks to Aluminous series 1 and further to Aluminous series 2. Contrasting evolution of the various associations suggests that several coeval magmatic series are present in the Serra da Graciosa granites.     

Coeval potassic and sodic calc-alkaline series in the post-collisional Hercynian Tanncherfi intrusive complex, northeastern Morocco: geochemical, isotopic and geochronological evidence

The post-collisional late Hercynian Tanncherfi intrusive complex (TIC) is part of a widespread intrusive episode in the Moroccan Meseta. The complex contains a wide range of rock types, from monzogabbros to monzogranites. Two distinct magmatic series are recognized: (1) a potassic (shoshonitic) series consisting of monzogabbros, quartz monzonites and monzogranites; and (2) a sodic (granodioritic) series represented by quartz monzodiorites and granodiorites. All the Tanncherfi plutonic rocks display similar spider-diagram profiles, with LILE and LREE enrichment and Nb, Ta, Ti depletion, which are typical of subduction-related magmas. Combined major, trace element compositions and Sr, Nd isotopic results indicate that the two series have been derived from a LILE- and LREE-enriched continental lithospheric mantle source, under different partial melting and/or depth conditions. Intrusion of the Tanncherfi rocks was not temporally related to subduction and the enrichment of their source is likely to be linked to preceding subduction events. The two series evolved by fractional crystallization, of clinopyroxene, plagioclase, hornblende, biotite, K-feldspar and accessories (Fe–Ti oxide minerals, titanite, apatite and zircon) for the potassic series while the sodic series combined fractional crystallization with assimilation of felsic magmas with lower Sr isotopic ratio than the more mafic term of the series, the quartz monzodiorite. The intrusion of the potassic magmas (344±6 Ma) marks a major change in the tectonic regime of eastern Meseta. These magmas intruded during post-thickening uplift and extension, both probably favored by convective thinning of the lithosphere. This model provides a reasonable mechanism for the genesis of other Hercynian intrusive complexes in Morocco.     

Intrusive rocks in the ophiolitic mélange of Crete – Witnesses to a Late Cretaceous thermal event of enigmatic geological position

The ophiolitic mélange in the uppermost tectonic unit of the Cretan nappe pile contains crystalline slices which consist of a low-pressure/high-temperature metamorphic sequence and synmetamorphic intrusions, ranging in composition from diorite to granite. The plutonic rocks conform to two different igneous suites, dominated by diorites in eastern, and granites in central Crete, displaying I-type and A-type characters, respectively. Some of the granites from central Crete are classified as transitional I/S-type. They are closely associated with migmatitic paragneisses. Based on major and trace element, REE, Sr- and Nd-isotope geochemistry, the mafic members of both suites are derived from a depleted mantle source. The higher concentrations of P and Ti in the mafic members of the igneous suite in central Crete and the deviant trend of the whole suite may be explained by a different mantle source or a lower degree of partial melting. In both suites, magmatic evolution was governed by fractional crystallization of amphibole/clinopyroxene, plagioclase and minor phases. In addition, mixing or mingling of compositionally different magmas is indicated for the intrusive suite of eastern Crete whereas in central Crete the magma composition was at least partially modified through assimilation of (meta)pelites. The geochemical results suggest that the plutonic rocks formed in a supra-subduction zone setting. However, a formation during continental lithospheric extension cannot be ruled out. Published and new Rb–Sr and K–Ar dates on amphiboles and biotites from intrusive rocks and their metamorphic country rocks show that the peak of the low-P/high-T metamorphism and the intrusion of the two igneous suites testify to the same thermal event of Late Cretaceous age. A similar Late Cretaceous association of metamorphic and plutonic rocks has been described from the uppermost tectonic unit in the Attic–Cycladic Crystalline Complex. Together with the Cretan occurrences, they form a small sector radiating SSW along a distance of 300 km, across the general trend of the tectonic zones in the Hellenic orogen. This N–S alignment is regarded as a primary feature which may delineate the frontier zone between the Hellenides and the Taurides. The real paleogeographic position and geodynamic significance of the Late Cretaceous low-pressure/high-temperature belt, however, remains enigmatic. Received: 1 June 1999 / Accepted: 2 February 2000     

Geochemistry and Sm–Nd geochronology of the metasomatised mafic rocks in the Khetri complex,Rajasthan, NW India: Evidence of an Early Cryogenian metasomatic event in the northern Aravalli orogen

The mafic magmatic rocks associated with 1720–1700 Ma albitised A-type granites in the northern segment of the Aravalli orogen, NW India show evidence of metasomatism. It is, however, not clear whether the metasomatism of mafic rocks is related to the cooling of these associated granites or whether it took place much later after the emplacement of the granites on a regional scale. For this, we have investigated the mafic magmatic rocks, which occur in close association with these granites. In the Biharipur intrusive, the mafic rocks are intensely commingled with the A-type granites, whereas in the vicinity of the Dosi intrusive, the mafic rocks (clinopyroxenite) do not show any evidence of granite mingling. The commingled and metasomatised Biharipur mafics occur in contact with the albitised granites instead of original granite, indicating that the mafics were metasomatised along with the granites. This is supported by the similarity in REE and spider patterns of the intermixed mafic rocks and the albite granites. On the other hand, the Dosi mafic rocks, free from granite commingling, are scapolitised where the original diopside has been partly transformed to chlorine-rich marialites with a meionite component ranging from Me14.0 to Me16.0. The scapolite, occurring as anastomosing veins, within these rocks is also of similar composition, and the undeformed nature of these veins suggests that the scapolitisation postdates regional metamorphism in the region. Mineralogical, geochemical and Nd isotopic characteristics of the mafic rocks indicate that originally, these were clinopyroxenites, which have been altered to a monomineralic actinolite-bearing rock. The immobile incompatible trace element ratios indicate a continental tholeiite affinity for the mafics, which is in consonance with the A-type nature of the associated granites. During this metasomatic event, the mafic magmatic rocks experienced albitisation and scapolitisation, although the dominance of these processes varied on a local scale depending on the fluid composition.A whole-rock-mineral (clinopyroxene and scapolite) Sm–Nd isochron of the scapolitised clinopyroxenite at Dosi yields an age of 831 ± 15 Ma. Synthesis of this age data along with previously published geochronological data indicate an important Early Cryogenian (850–830 Ma) metasomatic event in the northern Aravalli orogen, which is also synchronous with the Erinpura granite event in the southern Aravalli orogen.     

Origin of late Archean granite: geochemical evidence from the Vermilion Granitic Complex of northern Minnesota

The 2,700-Ma Vermilion Granitic Complex of northern Minnesota is a granite-migmatite terrane composed of supracrustal metasedimentary rocks, mafic rocks, tonalitic and granodioritic plutonic rocks, and granite. The metasedimentary rocks are predominantly graywacke, which has been regionally metamorphosed to garnet-sillimanite-muscovite-bearing biotite schist, and has locally undergone anatexis. The mafic rocks form early phases within the complex and are of two types: (1) basaltic amphibolite, and (2) monzodiorite and essexite rich in large ion lithophile elements (LILE). The members of the early plutonic suite form small bodies that intrude the metasedimentary rocks and mafic rocks, producing an early migmatite. The granite is of two distinct varieties: (1) white garnet-muscovite-biotite leucogranite (S-type; Chappell and White 1974) and (2) grayish-pink biotite-magnetite Lac La Croix Granite (I-type). The leucogranite occurs in the early migmatite and in paragneissic portions of the complex, whereas the Lac La Croix Granite is a late-stage intrusive phase that invades the early migmatite and metasediment (producing a late migmatite) and forms a batholith. This study focuses specifically on the origin of granite in the Vermilion Granitic Complex. Chemical mass-balance calculations suggest that the S-type two-mica leucogranite had a metagraywacke source, and that the I-type Lac La Croix Granite formed via partial fusion of calc-alkaline tonalitic material, which may have been similar to rocks of the early plutonic suite. This model is satisfactory for petrogenesis of similar Late Archean post-kinematic granites throughout the Canadian Shield.     

Petrogenesis of Sierra Nevada plutons inferred from the Sr, Nd, and O isotopic signatures of mafic igneous complexes in Yosemite Valley, California

Mafic complexes in the central Sierra Nevada batholith record valuable geochemical information regarding the role mafic magmas play in arc magmatism and the generation of continental crust. In the intrusive suite of Yosemite Valley, major and trace element compositions of the hornblende-bearing gabbroic rocks from the Rockslides mafic complex and of the mafic dikes in the North America Wall are compositionally similar to high-alumina basalt. Of these rocks, two samples have higher Ni and Cr abundances as well as higher ε_Nd values than previously recognized for the intrusive suite. Plagioclase crystals in rocks from the North America Wall and the Rockslides have prominent calcic cores and sharply defined sodic rims, a texture commonly associated with mixing of mafic and felsic magmas. In situ analyses of ⁸⁷Sr/⁸⁶Sr in plagioclase show no significant isotopic difference from the cores to the rims of these grains. We propose that the high ⁸⁷Sr/⁸⁶Sr (~0.7067) and low ε_Nd (~?3.4) of bulk rocks, the homogeneity of ⁸⁷Sr/⁸⁶Sr in plagioclase, and the high δ¹⁸O values of bulk rocks (6.6–7.3 ‰) and zircon (Lackey et al. in J Petrol 49:1397–1426, 2008) demonstrate that continental crust was assimilated into the sublithospheric mantle-derived basaltic precursors of the mafic rocks in Yosemite Valley. Contamination (20–40 %) likely occurred in the lower crust as the magma differentiated to high-alumina basalt prior to plagioclase (and zircon) crystallization. As a consequence, the isotopic signatures recorded by whole rocks, plagioclase, and zircon do not represent the composition of the underlying lithospheric mantle. We conclude that the mafic and associated felsic members of the intrusive suite of Yosemite Valley represent 60–80 % new additions to the crust and include significant quantities of recycled ancient crust.     

The Grayback Pluton: Magmatism in a Jurassic Back-Arc Environment, Klamath Mountains, Oregon

The Jurassic Grayback pluton was emplaced in a back-arc settingbehind a contemporaneous oceanic arc. Th\alphae main stage ofthe pluton consists of an early, reversely zoned tonalite togabbro that was intruded by synplutonic noritic and gabbroicmagmas. Late-stage activity was characterized by intrusion oftonalitic and granitic dikes, many of which contain mafic enclavesand hybrid zones. Most mafic rocks in the pluton are calc-alkaline,with characteristic magnesian clinopyroxene, calcic cores inplagioclase, and elemental abundances similar to H₂O-rich arcbasalts. However, some mafic rocks contain relatively Fe-richclinopyroxene, lack calcic cores in plagioclase, and are compositionallysimilar to evolved high-alumina tholeiite. Compositional variation in the main stage can be modeled inpart by fractional crystallization and crusted assimilationduring which parental calc-alkaline basalt evolved to graniticcompositions. Cumulates related to this process are representedby modally variable melagabbro and pyroxenite. Mixing of basalticand tonalitic magmas accounts for the compositions of most main-stageintermediate rocks, but mixing of basaltic and granitic magmaswas uncommon until late in the pluton's history. Oxygen, Sr and Nd isotopic data indicate that virtually allmain-stage magmas in the pluton contain a crustal component.Isotopic and trace element data further suggest that late-stagetonalitic dikes represent melts derived from older, metavolcanicarc crust Deep crustal contamination of main-stage rocks tookplace below the level of emplacement, probably in a magma-richzone where basalts ponded and mixed with crustal melts. The Grayback pluton illustrates the diversity of Jurassic back-arcmagmatism in the Klamath province and demonstrates that ancientmagmatism with arc-like features need not be situated in anarc setting. KEY WORDS: Grayback Pluton; Klamath Mountains; Oregon; back arc; crustal contamination ^*Corresponding author     

Late Neoarchean thick-skinned thrusting and Paleoproterozoic reworking in the MacQuoid supracrustal belt and Cross Bay plutonic complex,western Churchill Province,Nunavut, Canada

In the western Churchill Province, Canadian Shield, Neoarchean supracrustal and plutonic rocks, intruded by Paleoproterozoic mafic dykes and granitic rocks, comprise the MacQuoid supracrustal belt and the structurally overlying Cross Bay plutonic complex. They form part of the northwestern Hearne subdomain that occupies an intermediate position between the continental Rae domain to the north and west, and the oceanic central Hearne subdomain to the south and east. New geological mapping and supporting geoscience are compatible with the presence of 2550–2500 Ma, southeast-directed, mid-crustal, thick-skinned thrusting that juxtaposed the plutonic complex over the supracrustal belt. The structural contact between the MacQuoid supracrustal belt and the Cross Bay plutonic complex potentially represents a fundamental boundary between isotopically distinct crustal blocks.The ∼2190 Ma MacQuoid mafic dyke swarm cuts across Neoarchean deformation fabrics, but records ∼1.9 Ga, deep-crustal, regional metamorphism that affected both the supracrustal belt and the plutonic complex. Other Paleoproterozoic deformation events that occurred at ∼1850–1810 Ma are of local extent and appear to be relatively minor manifestations of more important events elsewhere, related to the Trans-Hudson orogen.     

海南屯昌早白垩世晚期埃达克质侵入岩的锆石U-Pb年代学、地球化学与岩石成因

海南岛屯昌地区侵入岩由花岗闪长岩、花岗岩及少量辉绿-闪长玢岩（脉）、镁铁质包体组成。本文报道了这些侵入岩的锆石LA-ICPMS U-Pb 定年结果和地球化学组成, 定年结果显示岩石形成于早白垩世晚期（~107 Ma）。地球化学特征显示, 花岗闪长岩和花岗岩具有高的SiO2、Al2O3 含量以及高的Sr 含量和Sr/Y 比值, 低的Y 和Yb 含量, Eu 异常不明显等, 属于埃达克质岩。屯昌埃达克质岩具有比较均一的Sr、Nd 同位素组成（ISr＝0.7082~ 0.7096, εNd（t）＝？6.55~ ？3.85）。镁铁质岩脉和包体则显示了稍低的ISr （0.7064~0.7086）和变化的εNd（t） （？5.10~ ＋0.13）。埃达克质岩的锆石原位Hf 同位素组成为： （176Hf/177Hf）i = 0.28257~0.28277, εHf（t）= ？4.86~ ＋2.09, 相应的两阶段模式年龄TDM2 变化于1.09 Ga 和1.54 Ga 之间。闪长玢岩脉的（176Hf/177Hf）i = 0.28257~0.28264, εHf（t） = ？4.94~ ？2.42, TDM2＝1.38~1.55 Ga, 类似于埃达克质岩。屯昌埃达克质岩很可能由新底侵的玄武质下地壳物质部分熔融所形成, 俯冲的古太平洋板块在早白垩世晚期（约107 Ma）的后撤作用所 导致的软流圈上涌为地壳熔融提供了热源。     

Mafic microgranular enclaves in Late Paleozoic granitoids in the Burgasy quartz syenite massif, western Transbaikalia: Composition and petrogenesis

The paper presents original data on the inner structure, mineralogy, and geochemistry of the Late Paleozoic Burgasy quartz syenite massif in western Transbaikalia and mafic microgranular enclaves (MME) in its rocks. The composition of the mafic microgranular enclaves is close to that of phase-1 monzonitoids of this pluton, but the enclaves are not xenoliths of these rocks but were produced by the crystallization of an individual portion of dispersed hybridized basalt melt. The basaltoid nature of the enclaves follows, first of all, from the relict assemblage of calcic plagioclase (An _73–60) and clinopyroxene and from the magmatic dolerite and microgabbro textures of the rocks. The monzonitoid composition of the enclaves was caused by hybridism, which was responsible for the crystallization of quartz, potassic feldspar, and sodic plagioclase due to the introduction of silica, potassium, and some other components. Hybridism was restricted to a boundary crystallization layer in the deep portion of the magmatic chamber (near its bottom). The scatter of the enclaves throughout the whole volume of the pluton is explained by the density inversion of the hybrid layer and material transfer by convective flows. The mafic enclaves crystallized from basaltic melt of within-plate geochemical type. In spite of intense hybridism, the enclaves preserved typical compositional signatures of mafic magma related to the generation of granites in western Transbaikalia in the Late Paleozoic. The basaltoid nature of the mafic enclaves of the Burgasy Massif testifies that magma was simultaneously generated in the mantle and crust during the development of the Late Paleozoic province in the area.     

P-T-t Evolution of Ultrahigh-Temperature Granulites from the Saxon Granulite Massif, Germany. Part I: Petrology

The granulites of the Saxon Granulite Massif equilibrated athigh pressure and ultrahigh temperature and were exhumed inlarge part under near-isothermal decompression. This raisesthe question of whether P–T–t data on the peak metamorphismmay still be retrieved with confidence. Felsic and mafic granuliteswith geochronologically useful major and accessory phases haveprovided a basis to relate P–T estimates with isotopicages presented in a companion paper. The assemblage garnet +clinopyroxene in mafic granulite records peak temperatures of1010–1060°C, consistent with minimum estimates ofaround 967°C and 22·3 kbar obtained from the assemblagegarnet + kyanite + ternary feldspar + quartz in felsic granulite.Multiple partial overprint of these assemblages reflects a clockwiseP–T evolution. Garnet and kyanite in the felsic granulitewere successively overgrown by plagioclase, spinel + plagioclase,sapphirine + plagioclase, and biotite + plagioclase. Most ofthis overprinting occurred within the stability field of sillimanite.Garnet + clinopyroxene in the mafic granulite were replacedby clinopyroxene + amphibole + plagioclase + magnetite. Thehigh P–T conditions and the absence of thermal relaxationfeatures in these granulites require a short-lived metamorphismwith rapid exhumation. The ages of peak metamorphism (342 Ma)and shallow-level granitoid intrusions (333 Ma) constrain thetime span for the exhumation of the Saxon granulites to     

Petrogenesis of Evolved Basalts and Rhyolites at Austurhorn, Southeastern Iceland: the Role of Fractional Crystallization

The Austurhorn intrusive complex in southeastern Iceland representsthe evolved hypabyssal remains of an eroded Tertiary (6–7Ma) central volcano. The complex consists of a layered gabbrointrusion, a composite granophyric stock, and abundant maficand felsic dikes. Mineralogical and geochemical trends amongcontemporaneous, compositionally diverse liquids from the complexprovide insight into the genesis of evolved basalts and rhyolitesin Iceland that are difficult to infer from studies of onlylavas. Mafic and felsic samples have comparable ranges in incompatibletrace element ratios (Ba/La and P/Ce) and Sr- and Pb-isotopes(O'Nions and Pankhurst, 1973; B. Hanan, pers. comm., 1988),suggesting derivation from a common parental composition. Majorand trace element variations throughout the Austurhorn suiteare consistent with fractional crystallization of the observedphenocrysts. Quartz-normative basalts were derived from parentalbasalt containing 7.8 wt.% MgO by extensive low-pressure crystallizationof olivine, augite, plagioclase, magnetite, and ilmenite. Thefractionating assemblage is consistent with the observed mineralogyof associated gabbro. Moreover, the cumulus mineralogy of thegabbro provides evidence for fractionation processes in a compositionalinterval not represented by dikes and sills (i.e., 54–63wt.% SiO₂).Diversity among the mafic dikes reflects severaladditional factors: (1) crystallization under conditions ofvariable oxygen fugacity; (2) separate mantle melting eventsthat produce different Ce/Yb values; (3) contamination of somemafic dikes at depth, presumably by interaction with felsicmagmas. Major and trace element trends among most felsic samples canbe modeled by fractionation of the observed mineral phases:plagioclase, K-feldspar, clinopyroxene, ilmenite, apatite, allanite,and zircon. Although crustal melting has been proposed for generatingIcelandic rhyolites, most Austurhorn felsic samples are unlikeliquids derived by melting of hydrated basalts. In particular,apatite and zircon have controlled the abundances of Zr, Hf,and the REE in the felsic rocks, but they are unlikely to beresidual phases during partial melting of basalt. One felsicdike, interpreted as a melt of an evolved source, shows petrographicevidence of in situ anatexis and also has anomalous trace elementabundances and unusually high ₂₀₆Pb/₂₀₄Pb.     

Petrogenesis of a Late Jurassic Peraluminous Volcanic Complex and its High-Mg, Potassic, Quenched Enclaves at Xiangshan, Southeast China

A late Mesozoic belt of volcanic–intrusive complexes occursin SE China. Volcanic activity at Xiangshan in the NW of thebelt took place mainly in the Late Jurassic (158–135 Ma).The volcanic rocks from the Xiangshan volcanic complex includerhyolitic crystal tuffs, welded tuffs, rhyolite lavas, porphyriticlavas, and associated subvolcanic rocks. Mineral assemblagesin these magmatic rocks include K-feldspar, plagioclase, quartz,Fe-rich biotite and minor amphibole, orthopyroxene and almandine.Mineral geothermometry indicates a high crystallization temperature(>850°C) for the Xiangshan magmas. The volcanic rocksare generally peraluminous; SiO₂ contents are between 65·4%and 76·8% and the samples have high alkalis, rare earthelements (REE), high field strength elements and Ga contentsand high Ga/Al ratios, but are depleted in Ba, Sr and transitionmetals. Trace element geochemistry and Sr–Nd–O isotopesystematics imply that the Xiangshan magmas were probably derivedfrom partial melting of Middle Proterozoic metamorphic lower-crustalrocks that had been dehydrated during an earlier thermal event.These features suggest an A-type affinity. Quenched mafic enclaves,hosted by the subvolcanic rocks, consist mainly of alkali feldspar,plagioclase, clinopyroxene, phlogopite and amphibole. Geothermometrycalculations indicate that the primary magmas that chilled toform the quenched enclaves had anomalously high temperatures(>1200°C). The quenched enclaves have boninitic affinities;for example, intermediate SiO₂ contents, high MgO and low TiO₂contents, high Mg-numbers and high concentrations of Sc, Ni,Co and V. However, they also have shoshonitic characteristics,e.g. enrichment in alkalis, high K₂O contents with high K₂O/Na₂Oratios, high light REE and large ion lithophile element contents,low initial _Nd values (–4·2) and high initial ⁸⁷Sr/⁸⁶Srratios (0·7081). We suggest a phlogopite-bearing spinelharzburgitic lithospheric mantle source for these high-Mg potassicmagmas. Underplating of such anomalously high-temperature magmascould have induced granulite-facies lower-crustal rocks to partiallymelt and generate the Xiangshan A-type volcanic suite. A back-arcextensional setting, related to subduction of the Palaeo-Pacificplate, is favoured to explain the petrogenesis of the Xiangshanvolcanic complex and quenched enclaves. KEY WORDS: volcanic complex; quenched enclaves; petrology; geochemistry; back-arc extension setting; Xiangshan; SE China     

Commingling and mixing of S-type peraluminous, ultrapotassic and basaltic magmas in the Cayconi volcanic field, Cordillera de Carabaya, SE Peru

The Cayconi district of the Cordillera de Carabaya, SE Peru, exposes a remnant of an upper Oligocene–Lower Miocene (22.2–24.4 Ma) volcanic field, comprising a diverse assemblage of S-type silicic and calc-alkaline basaltic to andesitic flows, members of the Picotani Group of the Central Andean Inner Arc. Basaltic flows containing olivine, plagioclase, clinopyroxene, ilmenite and glass, and glassy rhyolitic agglutinates with phenocrystic quartz, cordierite, plagioclase, sanidine, ilmenite and apatite, respectively exhibit mineralogical and geochemical features characteristic of medium-K mafic and Lachlan S-type silicic lavas. Cordierite-bearing dacitic agglomerates and lavas, however, are characterized by dispersed, melanocratic micro-enclaves and phenocrysts set in a fine-grained quartzo-feldspathic matrix. They contain a bimodal mica population, comprising phlogopite and biotite, as well as complexly zoned, sieve-textured plagioclase grains, sector-zoned cordierite, sanidine, quartz, irregular patches of replaced olivine, clinopyroxene and orthopyroxene and accessory phases including zircon, monazite, ilmenite and chromite. The coexistence of minerals not in mutual equilibrium and the growth/dissolution textures exhibited by plagioclase are features indicative of magmatic commingling and mixing. Trachytic-textured andesite flows interlayered with olivine+plagioclase–glomerophyric, calc-alkaline basalts have a phenocrystic assemblage of resorbed orthopyroxene and plagioclase and exhibit melanocratic groundmass patches of microphenocrystic phlogopite, Ca-rich sanidine, ilmenite and aluminous spinel. The mineralogical and mineral chemical relationships in both the dacites and the trachytic-textured andesites imply subvolcanic mixing between distinct ultrapotassic mafic melts, not represented by exposed rock types, and both the S-type silicic and calc-alkaline mafic magmas. Such mixing relationships are commonly observed in the Oligo-Miocene rocks of the Cordillera de Carabaya, suggesting that the S-type rocks in this area and, by extension, elsewhere derive their unusually high K₂O, Ba, Sr, Cr and Ni concentrations from commingling and mixing with diverse, mantle-derived potassic mafic magmas.     

The Petrology and Geochemistry of Mafic Igneous Rocks in the Anorthosite-Bearing Adirondack Highlands, New York

Igneous rocks of broadly basaltic composition are widely distributedin the anorthosite-bearing Adirondack Highlands of New York.They constitute a mafic series of rocks that occurs on the marginsof the anorthosite series and up to 50 km away from the anorthosite.On an Sr reference diagram, the mafic series has an apparentinitial ⁸⁷Sr/⁸⁶Sr value of 0.7036, which is consistent with1100 Ma subcontinental mantle. The series was probably emplacedin the interval 1150–1100 Ma, during which time anorthositeand granitic magmas were also emplaced. The rocks were metamorphosedshortly thereafter ({small tilde} 1088 Ma) under upper-amphiboliteand granulite facies conditions. Individual bodies of maficrocks range in thickness from small enclaves and layers >>1 m thick to large lensoid masses several tens of meters thick.Despite deformation and metamorphic recrystallization, manyof the rocks retain chiHed margins, cross-cutting relationships,and relict igneous textures. Selected samples of the mafic series have been analyzed fortheir major and trace element compositions. Metamorphism didnot significantly alter the igneous geochemical relationships,and the rocks retain mantle-like values for Zr/Nb, K/Zr, K/Rb,Rb/Sr, and ⁸⁷Sr/⁸⁶Sr. The most primitive rocks of the seriesare silica-undersaturated gabbroic troctolites, and the moreevolved rocks are basaltic in composition. The mafic seriesas a whole has high abundances of A1₂O₃, FeO, the light rareearth elements (LREE), and other incompatible trace elements.Even the most geochemically primitive compositions have highFeO contents. The Fe enrichment and Si depletion that are shownby chemically evolved compositions are consistent with a Fennertrend of fractionation. Low levels of normative di indicatethat high Fe is not a result of the extensive fractionationof cpx. The geochemical trends that are defined by the traceelements, including the REE, suggest the basaltic rocks maybe differentiates of a parental magma of gabbroic troctolitecomposition. The main compositional trend of the mafic seriescan be simulated by 61% crystallization of olivine and plagioclaseof a gabbroic troctolite, followed by 13% crystallization ofolivine, plagioclase, clinopyroxene, and titanomagnetite atthe final stages. The modelled ratio of olivine to plagioclasecrystallization changes from 1–8: 1 to 0–64: 1.These non-cotectic ratios may reflect a delay in the crystallizationof plagioclase relative to olivine, possibly as a result oflow nucleation rates. At later stages of differentiation, plagioclasewas more important in the crystallization of the series. Delayedcrystallization of plagioclase may also have resulted in thehigh A1₂O₃ contents and enhancement of Eu and Sr relative toother trace elements at early stages of differentiation. The mafic series and the silica-saturated anorthosite seriestogether form an anorthosite-norite-troctolite (ANT) suite.More than one mantle composition may have been involved in generatingthe Adirondack mafic magmas. The rocks retain geochemical evidenceof a source that was depleted in basaltic components (cpx) butenriched in Fe, Ti, K, and the LREE. Previously documented evidenceof anticlockwise cooling paths (Bohlen, 1987) and of a regionalgravity high centered beneath the Adirondack region (Simmons,1964) suggests that of the continental crust by basaltic magmasmay have underplating of the continental crust by basaltic magmasmay have been an important feature of the tectonic evolutionofthe region. A model of mantle upwelling beneath thinning continentalcrust explains the geochemically hybrid nature of the maficseries magmas. It is also consistent with a tectonic settingof incipient or failed continental rifting, to which the generationof the anorthosites is commonly attributed.     

Geochemical and thermodynamic modeling of the petrogenesis of A1-type granites and associated intermediate rocks: A case study from the central Fennoscandian Shield

The origin of ferroan A-type granites in anorogenic tectonic settings remains a long-standing petrological puzzle. The proposed models range from extreme fractional crystallization of mantle-derived magmas to partial melting of crustal rocks, or involve combination of both. In this study, we apply whole-rock chemical and Sm-Nd isotopic compositions and thermodynamically constrained modeling (Magma Chamber Simulator, MCS) to decipher the genesis of a suite of A1-type peralkaline to peraluminous granites and associated intermediate rocks (monzodiorite-monzonite, syenite) from the southwestern margin of the Archean Karelia craton, central Finland, Fennoscandian Shield. These plutonic rocks were emplaced at ca. 2.05 Ga during an early stage of the break-up of the Karelia craton along its western margin and show trace element affinities to ocean island basalt-type magmas. The intermediate rocks show positive ε_Nd(2050 Ma) values (+1.3 to +2.6), which are only slightly lower than the estimated contemporaneous depleted mantle value (+3.4), but much higher than average ε_Nd(2050 Ma) of Archean TTGs (–10) in the surrounding bedrock, indicating that these rocks were essentially derived from a mantle source. The ε_Nd(2050 Ma) values of the peralkaline and peraluminous granite samples overlap (–0.9 to +0.6 and –3.2 to +0.9, respectively) and are somewhat lower than those in the intermediate rocks, suggesting that the mafic magmas parental to granite must have assimilated some amount of older Archean continental crust during their fractionation, which is consistent with the continental crust-like trace element signatures of the granite members. The MCS modeling indicates that fractional crystallization of mantle-derived magmas can explain the major element characteristics of the intermediate rocks. The generation of the granites requires further fractional crystallization of these magmas coupled with assimilation of Archean crust. These processes took place in the middle to upper crust (∼2–4 kbar, ∼7–15 km) and involved crystallization of large amounts of clinopyroxene, plagioclase and olivine. Our results highlight the importance of coupled FC-AFC processes in the petrogenesis of A-type magmas and support the general perception that magmas of A-type ferroan granites become more peraluminous by assimilation of crust. They further suggest that variable fractionation paths of the magmas upon the onset of assimilation may explain the broad variety of A-type felsic and intermediate igneous rocks that is often observed emplaced closely in time and space within the same igneous complex.