Noble gases in ten Nullarbor chondrites: Exposure ages,terrestrial ages,and weathering effects

Abstract— We present concentration and isotopic composition of He, Ne, and Ar in ten chondrites from the Nullarbor region in Western Australia as well as the concentrations of ⁸⁴Ke, ¹²⁹Xe, and ¹³²Xe. From the measured cosmogenic ¹⁴C concentrations (Jull et al. 1995), shielding‐corrected production rates of ¹⁴C are deduced using cosmogenic ²²Ne/²¹Ne ratios. For shielding conditions characterized by ²²Ne/²¹Ne >1.10, this correction becomes significant and results in shorter terrestrial ages. The exposure ages of the ten Nullarbor chondrites are in the range of values usually observed in ordinary chondrites. Some of the meteorites have lost radiogenic gases as well as cosmogenic ³He. Most of the analyzed specimens show additional trapped Ar, Kr, and Xe of terrestrial origin. The incorporation of these gases into weathering products is common in chondrites from hot deserts.     

Neon produced by solar cosmic rays in ordinary chondrites

Solar‐cosmic‐ray‐produced Ne (SCR‐Ne), in the form of low cosmogenic ²¹Ne/²²Ne ratios (²¹Ne/²²Ne_cos <0.8), is more likely to be found in rare meteorite classes, like Martian meteorites, than in ordinary chondrites. This may be the result of a sampling bias: SCR‐Ne is better preserved in meteorites with small preatmospheric radii and these specimens are often only studied if they belong to unusual or rare classes. We measured He and Ne isotopic concentrations and nuclear tracks in 25 small unpaired ordinary chondrites from Oman. Most chondrites have been intensively heated during atmospheric entry as evidenced by the disturbed track records, the low ³He/²¹Ne ratios, the low ⁴He concentrations, and the high peak release temperatures. Concentration depth profiles indicate significant degassing; however, the Ne isotopes are mainly undisturbed. Remarkably, six chondrites have low ²¹Ne/²²Ne_cos in the range 0.711–0.805. Using a new physical model for the calculation of SCR production rates, we show that four of the chondrites contain up to ~20% of SCR‐Ne; they are analyzed in terms of preatmospheric sizes, cosmic ray exposure ages, mass ablation losses, and orbits. We conclude that SCR‐Ne is preserved, regardless of the meteorite class, in specimens with small preatmospheric radii. Sampling bias explains the predominance of SCR‐Ne in rare meteorites, although we cannot exclude that SCR‐Ne is more common in Martian meteorites than it is in small ordinary chondrites.     

Cosmic‐ray prdocution rates of helium,neon and argon isotopes in H chondrites based on chlorine‐36/argon‐36 ages

Abstract— We present the concentrations and isotopic compositions of He, Ne, and Ar for nonmagnetic fractions and bulk samples of 17 H chondrites which were recently investigated for their ³⁶Cl‐³⁶Ar cosmic‐ray exposure ages (Graf et al., 2001). All selected meteorites are observed falls with cosmic‐ray exposure ages close to the 7 Ma peak. The rare gas data are consistent with ¹⁰Be and ³⁶C1 production rates in the metal phase. Remarkably, only 1 out of the 17 H chondrites, Bath, shows clear indications for a complex exposure history. Based on rare gas concentrations and ³⁶Cl‐³⁶Ar exposure ages, ²¹Ne production rates as a function of ²²Ne/²¹ Ne and a mean ³⁸Ar production rate are determined. The results confirm model calculations which predict that the relationship between ²¹Ne production rates and ²²Ne/²¹Ne is ambiguous for high shielding. Besides the mean ³⁸Ar production rate we also give production rate ratios P(³⁸Ar from Ca)/P(³⁸Ar from Fe). They vary between 10 and 77, showing no significant correlation with ³⁸Ar concentrations or ²²Ne/²¹Ne. By investigating the metal separates, Graf et al. (2001) found significant ³He deficits for 6 out of the 17 meteorites. For the nonmagnetic fractions and bulk samples investigated here, the data points in a ³He/²¹Ne vs. ²²Ne/²¹Ne diagram plot in the area defined by most of the H chondrites. This means that ³He deficits in the metal phase are much more pronounced than in silicate minerals and we will argue that ³H diffusive losses in meteorites should be the rule rather than the exception. The ²¹Ne exposure ages, calculated on the basis of modeled ²¹Ne production rates, confirm the assumption by Graf et al. (2001) that the H5 chondrites with low ³He/³⁸Ar in the metal formed in a separate event than those with normal ³He/³⁸Ar ratios. The data can best be interpreted by assuming that the prominent 7 Ma exposure age peak of the H chondrites is due to at least two events about 7.0 and 7.6 Ma ago.     

Comparison of cosmic‐ray exposure ages and trapped noble gases in chondrule and matrix samples of ordinary,enstatite, and carbonaceous chondrites

Abstract— We performed a comprehensive study of the He, Ne, and Ar isotopic abundances and of the chemical composition of bulk material and components of the H chondrites Dhajala, Bath, Cullison, Grove Mountains 98004, Nadiabondi, Ogi, and Zag, of the L chondrites Grassland, Northwest Africa 055, Pavlograd, and Ladder Creek, of the E chondrite Indarch, and of the C chondrites Hammadah al Hamra 288, Acfer 059, and Allende. We discuss a procedure and necessary assumptions for the partitioning of measured data into cosmogenic, radiogenic, implanted, and indigenous noble gas components. For stone meteorites, we derive a cosmogenic ratio ²⁰Ne/²²Ne of 0.80 ± 0.03 and a trapped solar ⁴He/³He ratio of 3310 ± 130 using our own and literature data. Chondrules and matrix from nine meteorites were analyzed. Data from Dhajala chondrules suggest that some of these may have experienced precompaction irradiation by cosmic rays. The other chondrules and matrix samples yield consistent cosmic‐ray exposure (CRE) ages within experimental errors. Some CRE ages of some of the investigated meteorites fall into clusters typically observed for the respective meteorite groups. Only Bath's CRE age falls on the 7 Ma double‐peak of H chondrites, while Ogi's fits the 22 Ma peak. The studied chondrules contain trapped ²⁰Ne and ³⁶Ar concentrations in the range of 10^?6–10^?9 cm³ STP/g. In most chondrules, trapped Ar is of type Q (ordinary chondritic Ar), which suggests that this component is indigenous to the chondrule precursor material. The history of the Cullison chondrite is special in several respects: large fractions of both CR‐produced ³He and of radiogenic ⁴He were lost during or after parent body breakup, in the latter case possibly by solar heating at small perihelion distances. Furthermore, one of the matrix samples contains constituents with a regolith history on the parent body before compaction. It also contains trapped Ne with a ²⁰Ne/²²Ne ratio of 15.5 ± 0.5, apparently fractionated solar Ne.     

Solar-proton-produced neon in shergottite meteorites and implications for their origin

Abstract— Measured Ne isotopes in samples of shergottite ALHA77005 show variations in ²¹Ne/²²Ne ratios and ²¹Ne abundances that are consistent with the presence of two cosmogenic components: a component produced by nuclear interactions of galactic cosmic rays (GCR) and a component produced at shallow shielding depths (～0–3 cm) by energetic solar flare protons (SCR). We suggest that the ²¹Ne/²²Ne ratio generally can be used to distinguish between SCR and GCR components in many meteorite types. Analysis of cosmogenic Ne produced in chondrite mineral separates, eucrites, and anorthositic lunar rocks, all having diverse major element compositions, indicate that the GCR ²¹Ne/²²Ne ratio increases modestly with relative Mg content. Data for hundreds of chondrite analyses suggest that SCR Ne is present in no more than a very small fraction of chondrites. Examination of literature data for other shergottites, however, indicate that all of these meteorites contain SCR Ne but that it is apparently absent in other SNC meteorites. The ubiquitous presence of SCR Ne in shergottites, in contrast to most other types of meteorites, suggests that the martian origin of shergottites gave them different orbital parameters compared to other meteorites. This in turn may have contributed to slower entry velocities and lesser surface ablation in the atmosphere or even to higher SCR production rates.     

Ordinary Chondrites: 1. Short Life of Small Meteorites

The data on the concentration of cosmogenic neon isotopes and the density of cosmic-ray tracks in about 600 ordinary chondrites were analyzed. For ordinary chondrites of all chemical classes, the dispersion of the ratios between cosmogenic isotopes of neon, (²²Ne/²¹Ne) _c , and a fraction of meteorites with high rates of cosmic-ray-track formation were demonstrated to decrease with increasing cosmic-ray-exposure age. Most likely, these effects are related to the fact that chondrites of small exposure ages are more frequent among meteorites with low degrees of shielding (small sizes), probably because smaller meteorites are placed into Earth-crossing orbits faster than larger ones. This, in turn, is attributed to more effective insertion of small asteroid-belt bodies into resonances, most likely due to the diurnal Yarkovsky effect.     

The Cu isotopic composition of iron meteorites

Abstract– High‐precision Cu isotopic compositions have been measured for the metal phase of 29 iron meteorites from various groups and for four terrestrial standards. The data are reported as the δ⁶⁵Cu permil deviation of the ⁶⁵Cu/⁶³Cu ratio relative to the NIST SRM 976 standard. Terrestrial mantle rocks have a very narrow range of variations and scatter around zero. In contrast, iron meteorites show δ⁶⁵Cu approximately 2.3‰ variations. Different groups of iron meteorites have distinct δ⁶⁵Cu values. Nonmagmatic IAB‐IIICD iron meteorites have similar δ⁶⁵Cu (0.03 ± 0.08 and 0.12 ± 0.10, respectively), close to terrestrial values (approximately 0). The other group of nonmagmatic irons, IIE, is isotopically distinct (?0.69 ± 0.15). IVB is the iron meteorite group with the strongest elemental depletion in Cu and samples in this group are enriched in the lighter isotope (δ⁶⁵Cu down to ?2.26‰). Evaporation should have produced an enrichment in ⁶⁵Cu over ⁶³Cu (δ⁶⁵Cu >0) and can therefore be ruled out as a mechanism for volatile loss in IVB meteorites. In silicate‐bearing iron meteorites, Δ¹⁷O correlates with δ⁶⁵Cu. This correlation between nonmass‐dependent and mass‐dependent parameters suggests that the Cu isotopic composition of iron meteorites has not been modified by planetary differentiation to a large extent. Therefore, Cu isotopic ratios can be used to confirm genetic links. Cu isotopes thus confirm genetic relationships between groups of iron meteorites (e.g., IAB and IIICD; IIIE and IIIAB); and between iron meteorites and chondrites (e.g., IIE and H chondrites). Several genetic connections between iron meteorites groups are confirmed by Cu isotopes, (e.g., IAB and IIICD; IIIE and IIIAB); and between iron meteorites and chondrites (e.g., IIE and H chondrites).     

Meteorites from Mongolia

Abstract— The mineralogy and composition of six Mongolian meteorites were studied in some detail. Previously, only limited information existed about these rocks, and some were still unclassified. The six meteorites include three ordinary chondrites and three irons. The ordinary chondrite Adzhi-Bogdo (stone) is a regolith breccia (LL3–6) containing various types of clasts (some of foreign origin) embedded within a fine-grained clastic matrix. Tugalin Bulen (H6) and Noyan Bogdo (L6) meteorites are typical, well-metamorphosed ordinary chondrites. Adzhi-Bogdo (iron) has to be regarded as an IA iron meteorite like Campo del Cielo or Canyon Diablo; although the sample studied had been heated to about 900 °C–950 °C some time in the past, thus eradicating all original structural elements. Manlai is structurally closely related to the IIC iron meteorites; but based on its chemistry, which does not fit into this group, it is suggested that Manlai is an anomalous iron meteorite. The third iron, Sargiin Gobi, is certainly a normal member of the IA iron meteorites. The concentrations and isotopic compositions of He, Ne, and Ar were measured for all meteorites and their gas retention ages and exposure ages are discussed.     

Weathering in Antarctic H and CR chondrites: Quantitative analysis through Mössbauer spectroscopy

Abstract— Mössbauer spectroscopy is a very useful tool for identifying ferric iron weathering products in meteorites because of the capability to quantify the relative amounts of ferric iron in them. Mössbauer measurements were made of 33 Antarctic H chondrites (predominately H5) and two paired Antarctic CR chondrites. The primary goals of this study are to determine if Mössbauer spectroscopy can be used to determine which phases are weathering in Antarctic meteorites and if the relative amounts of ferric iron correlate with terrestrial age. Determining which minerals are weathering in ordinary chondrites appears very difficult due to variations in composition for different ordinary chondrites of the same meteorite class and possible problems in preparing homogeneous samples. The analysis of the two paired CR chondrites appears to indicate that metallic iron is predominately weathering to produce ferric iron for this class of meteorite. No correlation is seen between the relative amounts of ferric iron and terrestrial age for ordinary chondrites. One Antarctic H5 chondrite (ALHA77294) with a short ¹⁴C age of 135 ± 200 years from the dating of interior carbonate weathering products does have a relatively low amount of ferric iron, which is consistent with this meteorite being exposed on the surface for a relatively short time.     

Noble gases in metal and schreibersite of the Acuña (IIIAB) iron meteorite

Abstract— We measured abundances and isotopic compositions of noble gases in metal and schreibersite of the Acuña (IIIAB) iron meteorite. The concentrations of noble gases in Acuña metal are very low compared to those reported so far for other iron meteorites. The isotopic ratios of He, Ne and Ar indicate that they are mostly of cosmogenic origin. Cosmogenic components are even present in Kr and Xe, which could not have been produced from Fe, Ni and P and are probably due to the spallation of trace elements of higher masses. The high ⁴He/²¹Ne ratio of 420 in Acuña metal indicates that the samples were at a deep position within a very large meteoroid. The exposure ages of Acuña were estimated to be 50–200 Ma from ³He, ²¹Ne and ³⁸Ar abundances and by utilizing the diagrams of production rates vs. the ⁴He/²¹Ne ratio based on the Signer-Nier model. The low exposure age of Acuña may indicate a history different from that of other IIIAB irons whose exposure ages cluster at ～670 Ma. Otherwise, Acuña may be one of the samples with the low production rate, which can not be estimated from the diagrams of the Signer-Nier model.     

Light noble gases and cosmogenic radionuclides in Estherville,Budulan, and other mesosiderites: Implications for exposure histories and production rates

Abstract— We report measurements of ²⁶AI, ¹⁰Be, ⁴¹Ca, and ³⁶Cl in the silicate and metal phases of 11 mesosiderites, including several specimens each of Budulan and Estherville, of the brecciated meteorite Bencubbin, and of the iron meteorite Udei Station. Average production rate ratios (atom/atom) for metal phase samples from Estherville and Budulan are ²⁶Al/¹⁰Be = 0.77 ± 0.02; ³⁶Cl/¹⁰Be = 5.3 ± 0.2. For a larger set of meteorites that includes iron meteorites and other mesosiderites, we find ²⁶Al/¹⁰Be = 0.72 ± 0.01 and ³⁶Cl/¹⁰Be = 4.5 ± 0.2. The average ⁴¹Ca/³⁶Cl production rate ratio is 1.10 ± 0.04 for metal separates from Estherville and four small iron falls. The ⁴¹Ca activities in dpm/(kg Ca) of various silicate separates from Budulan and Estherville span nearly a factor of 4, from <400 to >1600, indicating preatmospheric radii of >30 cm. After allowance for composition, the activities of ²⁶Al and ¹⁰Be (dpm/kg silicate) are similar to values measured in most ordinary chondrites and appear to depend only weakly on bulk Fe content. Unless shielding effects are larger than suggested by the ³⁶Cl and ⁴¹Ca activities of the metal phases, matrix effects are unimportant for ¹⁰Be and minor for ²⁶Al. Noble gas concentrations and isotopic abundances are reported for samples of Barea, Emery, Mincy, Morristown, and Marjalahti. New estimates of ³⁶Cl/³⁶Ar exposure ages for the metal phases agree well with published values. Neon‐21 production rates for mesosiderite silicates calculated from these ages and from measured ²¹Ne contents are consistently higher than predicted for L chondrites despite the fact that the mesosiderite silicates have lower Mg contents than L chondrites. We suggest that the elevation of the ²¹Ne production rate in mesosiderite silicates reflects a “matrix effect,” that is, the influence of the higher Fe content of mesosiderites, which acts to enhance the flux of low‐energy secondary particles and hence the ²¹Ne production from Mg. As ¹⁰Be production is relatively insensitive to this matrix effect, ¹⁰Be/²¹Ne ages give erroneously low production rates and high exposure ages. By coincidence, standard ²²Ne/²¹Ne based “shielding” corrections give fairly reliable ²¹Ne production rates in the mesosiderite silicates.     

Exposure history and terrestrial ages of ordinary chondrites from the Dar al Gani region,Libya

Abstract— We measured the concentrations of noble gases in 32 ordinary chondrites from the Dar al Gani (DaG) region, Libya, as well as concentrations of the cosmogenic radionuclides ¹⁴C, ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca in 18 of these samples. Although the trapped noble gases in five DaG samples show ratios typical of solar or planetary gases, in all other DaG samples, they are dominated by atmospheric contamination, which increases with the degree of weathering. Cosmic ray exposure (CRE) ages of DaG chondrites range from ?1 Myr to 53 Myr. The CRE age distribution of 10 DaG L chondrites shows a cluster around 40 Myr due to four members of a large L6 chondrite shower. The CRE age distribution of 19 DaG H chondrites shows only three ages coinciding with the main H chondrite peak at ?7 Myr, while seven ages are <5 Myr. Two of these H chondrites with short CRE ages (DaG 904 and 908) show evidence of a complex exposure history. Five of the H chondrites show evidence of high shielding conditions, including low ²²Ne/²¹Ne ratios and large contributions of neutron‐capture ³⁶Cl and ⁴¹Ca. These samples represent fragments of two or more large pre‐atmospheric objects, which supports the hypothesis that the high H/L chondrite ratio at DaG is due to one or more large unrecognized showers. The ¹⁴C concentrations correspond to terrestrial ages <35 kyr, similar to terrestrial ages of chondrites from other regions in the Sahara but younger than two DaG achondrites. Despite the loss of cosmogenic ³⁶Cl and ⁴¹Ca during oxidation of metal and troilite, concentrations of ³⁶Cl and ⁴¹Ca in the silicates are also consistent with ¹⁴C ages <35 kyr. The only exception is DaG 343 (H4), which has a ⁴¹Ca terrestrial age of 150 ± 40 kyr. This old age shows that not only iron meteorites and achondrites but also chondrites can survive the hot desert environment for more than 50 kyr. A possible explanation is that older meteorites were covered by soils during wetter periods and were recently exhumed by removal of these soils due to deflation during more arid periods, such as the current one, which started ?3000 years ago. Finally, based on the ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne systematics in 16 DaG meteorites, we derived more reliable estimates of the ¹⁰Be/²¹Ne production rate ratio, which seems more sensitive to shielding than was predicted by the semi‐empirical model of Graf et al. (1990) but less sensitive than was predicted by the purely physical model of Leya et al. (2000).     

Rumuruti chondrites: Noble gases,exposure ages,pairing, and parent body history

Abstract— In this paper, we present concentration and isotopic composition of the light noble gases He, Ne, and Ar as well as of ⁸⁴Kr, ¹³²Xe, and ¹²⁹Xe in bulk samples of 33 Rumuruti (R) chondrites. Together with previously published data of six R chondrites, exposure ages are calculated and compared with those of ordinary chondrites. A number of pairings, especially between those from Northwest Africa (NWA), are suggested, so that only 23 individual falls are represented by the 39 R chondrites discussed here. Eleven of these meteorites, or almost 50%, contain solar gases and are thus regolithic breccias. This percentage is higher than that of ordinary chondrites, howardites, or aubrites. This may imply that the parent body of R chondrites has a relatively thick regolith. Concentrations of heavy noble gases, especially of Kr, are affected by the terrestrial atmospheric component, which resides in weathering products. Compared to ordinary chondrites, ¹²⁹Xe/¹³²Xe ratios of R chondrites are high.     

Complex exposure histories for meteorites with “short” exposure ages

Abstract— We report measurements of ²⁶Al and ¹⁰Be activities in nine ordinary chondrites and of the light noble gas concentrations and ³⁶Cl and ⁴¹Ca activities in subsets of those meteorites. All but Murray have low ²¹Ne concentrations (<1.0 × 10^?8cm³STP/g) and have previously been used to estimate ²¹Ne production rates. Ladder Creek, Murchison, Sena, and Timochin have inventories of cosmogenic radionuclides that are compatible with a single stage of irradiation and give ²¹Ne production rates that are consistent with the standard L-chondrite value of 0.33 × 10^?8cm³STP/g/Ma. In contrast, Cullison, Guenie, Shaw, and Tsarev experienced complex irradiation histories. They and several other meteorites with low nominal exposure ages also have lower ³He/²¹Ne ratios than expected based on their ²²Ne/²¹Ne ratios. A general association between low ²¹Ne contents and ³He losses suggests that meteorites with short lifetimes often occupy orbits with small perihelia. However, meteorites with low ²¹Ne contents, one-stage exposure histories, and losses of cosmogenic ³He are rare. Possible explanations for the scarcity are (1) statistical, (2) that it is harder for more deeply buried protometeoroids to lose gas in a liberating collision, and (3) that it is harder to insert more deeply buried protometeoroids directly into orbits with small perihelia.     

Simulation of the interaction of galactic cosmic ray protons with meteoroids: On the production of 3H and light noble gas isotopes in isotropically irradiated thick gabbro and iron targets

Abstract— Thick spherical targets, one made of gabbro (R = 25 cm) and one made of iron (R = 10 cm), were irradiated isotropically with 1.6 GeV protons at Laboratoire National Saturne (LNS)/Saclay to simulate the interactions of galactic cosmic ray protons with meteoroids in space. At various depths, both artificial meteoroids contained a large number of high‐purity, single‐element target foils and chemical compounds of up to 28 target elements. In these individual target foils, the elemental production rates of radionuclides and noble gas isotopes were measured. Here, we report the results for the light noble gas isotopes ^3,4He, ^20,21,22Ne, and ^36,38,39Ar for the most cosmochemically relevant target elements as well as for some meteoritic material from Jilin, Farmington, and Cape York. From ³He analyses done several years apart, ³H diffusive losses during sample storage have been obtained, and direct as well as cumulative ³He production rates for O, Mg, Al, Si, Fe, Ni, and the meteoritic material are given. Losses by diffusion of tritium from metallic Mg and Fe are found to occur on time scales of months, while metallic Al, Si, and stone meteorites are much more retentive. The production rate ratios P(³H)/P(³He)_d obtained in the simulation experiments are 0.73, 1.28, and 1.16 for O, Al, and Si, respectively. These rates are based on our best knowledge about the ³H and ³He production rates and should, therefore, replace data published earlier (Leya et al. 2000a). The earlier calculations for ⁴He, ^20,21,22Ne, and ^36,38,39Ar remain valid. The new modeled correlation ³He_cum/²¹Ne versus ²²Ne/²¹Ne for chondrites exposed to cosmic rays with an energy spectrum characterized by a modulation parameter of φ = 650 MeV is in fair agreement with the empirical relationship (“Berne plot”). However, for small meteorites and little shielding in larger ones, there are systematic differences that most likely are due to an underestimation of the spallogenic ²²Ne/²¹Ne ratio by ?2%.     

An improved extraction system to measure carbon‐14 terrestrial ages of meteorites and pairing of the Antarctic Yamato‐75097 group chondrites

Abstract— We examined an improved system for extraction of carbon from meteorites, using a vacuum‐tight RF melting method. Meteorite samples mixed with an iron combustion accelerator, including a specific amount of carbon (0.052%), were combusted in a RF furnace (LECO HF‐10). ¹⁴CO₂ extracted from the meteorite was diluted with a known amount of nearly ¹⁴C‐free CO₂, evolved from the iron accelerator on combustion. The ¹⁴C activities of the recently fallen Holbrook (L6) and Mt. Tazerzait (L5) meteorites were measured by this method. The mean value was 56.5 ± 3.0 dpm/kg, which is similar to the values reported for recently fallen L6 chondrites. Furthermore, terrestrial ages were measured for four Antarctic meteorites: 1.8 ± 0.5 kyr for Yamato (Y‐) 75097 (L6), 1.8 ± 0.5 kyr for Y‐75108 (L6), and 0.1 ± 0.1 kyr for Y‐74192 (H5). For Y‐74190 (L6), an apparent age of 0.8 ± 0.5 kyr was calculated. After consideration of the shielding effect by using ²²Ne/²¹Ne values, we obtained about 1.8 kyr for the terrestrial age of this chondrite. The five samples Y‐74190, Y‐75097, and Y‐75108, together with Y‐75102 (L6) and Y‐75271 (L6), have been reported to be paired and fragments of an L‐chondrite shower (Honda 1981; Takaoka 1987). The result of this work and literature data for the latter two samples confirmed that they are paired. More discussion and experimental work are needed for other recently fallen meteorites, both for L and H chondrites, and a correction for the shielding effect should be done to determine a more reliable terrestrial age.     

Isotope fractionation and concentration measurements of Zn in meteorites determined by the double spike,IDMS‐TIMS techniques

Abstract– The isotope fractionation of Zn in meteorites has been measured for the first time using thermal ionization mass spectrometry and a double spiking technique. The magnitude of δZn ranged from ?0.29 to +0.38‰ amu^?1 for five stone meteorites whereas the iron meteorite Canyon Diablo displays δZn of 1.11 ± 0.11‰ amu^?1. The results for chondrites in this work can be divided into positive and negative δZn, supporting a previous proposal that chondrites are a mixture of materials from two different temperature sources. The Zn isotope fractionation present in meteorites may represent a primordial heterogeneity formed in the early solar system. An anomalous isotopic composition of Zn obtained for the Redfields iron meteorite suggests large‐scale inherited isotope heterogeneity of the protosolar nebula, or the presence of a parent body that has formed within its own isotopically anomalous reservoir. These anomalies are in the same direction but smaller than nuclear field shift effects observed in chemical exchange reactions. The isotope dilution mass spectrometry (IDMS) technique was used to measure Zn concentration, yielding a range from 20.1 μg g^?1 to 302 μg g^?1 in five stone meteorites and from 0.019 to 26 μg g^?1 in seven iron meteorites. The IDMS‐measured abundance of Zn in Orgueil is 302 ± 14 μg g^?1 and should be considered for future compilations of the abundance of Zn in the solar system.     

The Burnwell,Kentucky, low iron oxide chondrite fall: Description,classification and origin

Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ¹⁷O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.     

Ordinary Chondrites: 2. Diffusion Losses of Rare Gases

Data on the isotopic abundances and ratios of light rare gases (He and Ne) in 600 ordinary chondrites are analyzed. The ratio of cosmogenic isotopes (³He/²¹Ne) _c in 20% of the ordinary chondrites has been found to lie well below the correlation line that represents the dependence of (³He/²¹Ne) _c on (²²Ne/²¹Ne) _c . This effect shows up most clearly in ⁴He _r -chondrites, particularly in meteorites with diffusion losses of radiogenic ²¹Ne _c , and is most likely attributable to the predominant (compared to ³He _c ) diffusion losses of cosmogenic ³He_cthrough the solar heating of meteorites in orbits with small perihelion distances. This effect is enhanced by periodic variations in orbital parameters (including the perihelion distance) of meteorites throughout their exposure histories. Thermoluminescence data for ordinary chondrites confirm this scenario. The (³He/²¹Ne) _c ratio for 15% of the chondrites was significantly overestimated, which may stem from the fact that such meteorites were heavily shielded in preatmospheric bodies.     

Cosmic‐ray exposure history of two Frontier Mountain H‐chondrite showers from spallation and neutron‐capture products

Abstract— We measured the concentrations of ¹⁰Be, ²⁶Al, ³⁶Cl, ⁴¹Ca and ¹⁴C in the metal and/or stone fractions of 27 Antarctic chondrites from Frontier Mountain (FRO), including two large H‐chondrite showers. To estimate the pre‐atmospheric size of the two showers, we determined the contribution of neutron‐capture produced ³⁶Cl (half‐life = 3.01 times 10⁵ years) and ⁴¹Ca (1.04 times 10⁵ years) in the stone fraction. The measured activities of neutron‐capture ³⁶Cl and ⁴¹Ca, as well as spallation produced ¹⁰Be and ²⁶Al, were compared with Monte Carlo‐based model calculations. The largest shower, FRO 90174, includes eight fragments with an average terrestrial age of (100 ± 30) × 10³ years; the neutron‐capture saturation activities extend to 27 dpm/kg stone for ³⁶Cl and 19 dpm/kg stone for ⁴¹Ca. The concentrations of spallation produced ¹⁰Be, ²⁶Al and ³⁶Cl constrain the radius (R) to 80–100 cm, while the neutron‐capture ⁴¹Ca activities indicate that the samples originated from the outer 25 cm. With a pre‐atmospheric radius of 80–100 cm, FRO 90174 is among the largest of the Antarctic stony meteorites. The large pre‐atmospheric size supports our hypothesis that at least 50 of the ～150 classified H5/H6‐chondrites from the Frontier Mountain stranding area belong to this single fall; this hypothesis does not entirely account for the high H/L ratio at Frontier Mountain. The smaller shower, FRO 90001, includes four fragments with an average terrestrial age of (40 ± 10) × 10³ years; they contain small contributions of neutron‐capture ³⁶Cl, but no excess of ⁴¹Ca. FRO 90001 experienced a complex exposure history with high shielding conditions in the first stage (150 < R < 300 cm) and much lower shielding in the second stage (R < 30 cm), the latter starting ～1.0 million years (Ma) ago. Based on the measured ¹⁰Be/²¹Ne and ²⁶Al/²¹Ne ratios, the cosmic‐ray exposure ages of the two showers are 7.2 ± 0.5 Ma for FRO 90174 and 8 ± 1 Ma for FRO 90001. These ages coincide with the well‐established H‐chondrite peak and corroborate the observation that the exposure age distribution of FRO H‐chondrites is similar to that of non‐Antarctic falls. In addition, we found that corrections for neutron‐capture ³⁶Ar (from decay of ³⁶Cl) result in concordant ²¹Ne and ³⁸Ar exposure ages.