峨眉山玄武岩铂族元素地球化学类型探讨

铂族元素是探讨幔源岩浆形成、演化的重要示踪元素.我们通过对峨眉山大火成岩省包括宾川、丽江、攀枝花、米易、六盘水、峨眉山等地的玄武岩及苦橄岩中铂族元素含量的系统分析,对铂族元素组成特征变化进行了成因区分,探讨了铂族元素在地幔部分熔融过程中的地球化学行为.结合峨眉山大火成岩省典型镁铁-超镁铁岩成矿岩体铂族元素组成,分析了不同矿化类型成矿岩体与峨眉山玄武岩不同铂族元素地球化学类型的成因联系.     

苏北东海晋宁期蛇绿岩与苏胶造山带演化

苏北东海－赣榆地区出露的东海杂岩是苏胶杂岩的重要组成部分，它代表苏胶造山带的古老中带早期演化历史的重要地区。本文通过恢复和研究东海镁铁－超镁铁岩中的蛇绿岩、追苏胶造山带早期演化历史，为寻找金红石蓝晶石、金刚石、榴石宝石等与镁铁－超镁铁岩有成因联系的矿产资源提供背景资料。     

峨眉山大火成岩省部分镁铁-超镁铁岩体的橄榄石成分特征及成因意义

橄榄石是镁铁-超镁铁岩中最重要的造岩矿物,我们通过对峨眉山大火成岩省中包括云南弥渡县金宝山、元谋县朱布、热水塘、四川会理县力马河、杨合五等成矿岩体橄榄石成分的分析,结合有关苦橄岩中橄榄石的研究成果,探讨了不同矿化类型的成矿岩体在橄榄石组成特征上的异同及其成因意义.     

青海省北祁连山中段超镁铁岩带金矿化特征及成因探讨

北祁连早古生代蛇绿岩是我国规模较大的蛇绿岩带之一,超镁铁岩体极为发育。在该区基性、超基性岩体中相继发现含金超镁铁岩体20余处,矿点两处。金矿(化)体主要赋存于超镁铁蚀变岩石中。金属矿物主要为自然金、毒砂、黄铁矿、黝铜矿等。根据砂金、岩金分布特征及矿物组合,超镁铁岩中金元素丰度、载金矿物硫同位素特征、石英气液包裹体测温及成分测定结果,以及区域成矿条件等特征分析,提出金矿物质主要来自超镁铁岩,金矿成因属中温变质热液型。     

新街镁铁—超镁铁侵入体的铂族元素地球化学特征

采用镍硫试金预处理中子活化分析方法,系统测定了新街层状侵入体镁铁－超镁铁岩和与其有成因联系的玄武岩及正长岩的铂族元素含量,探讨了岩浆作用过程中铂族元素的地球化学行为。结果表明,新街岩体的铂元素分异特征与布什维尔德等铁质超镁铁岩相似,而明显不同于科马提岩和阿尔卑斯型橄榄岩,二叠系峨眉山玄武岩的铂族元素分异特征与新街岩体相似,再次证实二者为同源岩浆分异产物。     

一个与前寒武纪火山碎屑沉积岩及超镁铁岩有成因联系的锡矿床

经详细研究九毛锡矿各类地质体的含锡量,确定了锡在火山-沉积变质岩及变超镁铁岩中的初始富集。根据不同变质程度岩石含锡量变化趋势、微量元素含量的继承性关系、成因矿物等方面的研究,确定锡矿床与超镁铁岩及火山-沉积岩间有成因联系。本文强调了锡的多重性及锡在超镁铁岩中的初始富集,指出变质作用是古陆区锡成矿的重要地质营力。     

黄山东镁铁-超镁铁侵入杂岩中橄榄石深部结晶作用的发现

近年来,在新疆哈密黄山地区发现了一系列与铜镍硫化物矿床有关的镁铁超-镁铁侵入杂岩,构成了黄山铜镍成矿带。黄山东镁铁-超镁铁侵入杂岩为该成矿带重点岩体之一,其主要造岩矿物橄榄石深部结晶作用的发现对于丰富岩浆的成因理论、确切地解释杂岩体成岩成矿过程中岩浆的分异演化和成矿带内其它杂岩橄榄石深部结晶作用的确定均有重要意义。     

桂北元宝山地区超镁铁岩的年代、源区及其地质意义

桂北元宝山地区超镁铁岩的SHRIMP锆石U-Pb年龄为(841±22)Ma(2σ),与桂北三防-何家湾地区出露的镁铁-超镁铁侵入岩年龄(约825 Ma)接近,表明桂北地区出露的镁铁-超镁铁侵入岩具有基本一致的结晶年龄.超镁铁岩的岩石学和主量元素特征表明超镁铁岩是堆晶岩,其微量元素质量分数较低(＜NMORB),蛛网图上除了Nb、Ta、Zr、Hf亏损外,一般表现为平坦的分配曲线.超镁铁岩εNd(t)的变化范围为-1.0～6.5,表明超镁铁岩的母岩浆遭受了一定程度的地壳混染.元宝山地区超镁铁岩低的w(Th)/w(Nb)比值与原始地幔非常类似,而与大陆弧玄武岩浆的比值明显不同,推测元宝山地区超镁铁岩应形成于板内环境,而不是活动大陆边缘,其形成很可能与导致新元古代Rodinia超大陆裂解的发生于约825 Ma的华南地幔柱有关.     

喜马拉雅造山带中段深成相和超浅成相超镁铁岩的发现及意义

青藏高原众多的蛇绿岩带中出露大量的超镁铁岩 ,这与特提斯的形成和演化密切相关 .然而在长达2 0 0 0km的喜马拉雅造山带内部没有超镁铁岩的报道 ,也没有找到新生代的火山岩 .最近我们通过 1∶2 5万定结幅、陈塘区幅 (国内部分 )区域地质调查 ,首次在喜马拉雅造山带中段定结 -定日一带发现晚新生代不同类型的超镁铁岩 ,主要是深成相的尖晶石橄榄方辉岩、尖晶石橄榄二辉岩和超浅成相的苦橄玄武岩、玻基辉橄岩 ,常与高压基性麻粒岩伴生 .它们是喜马拉雅和青藏高原软流圈及岩石圈的结构和热状态、壳幔相互作用的一个窗口 .深成相和超浅成相的超…     

论造山带中超镁铁岩的成对分布

文中把俯冲-碰撞型造山带中出露的超镁铁岩分为蛇绿岩型和火山弧型两类,后者又细分为义敦型、阿拉斯加型及橄榄岩-闪长岩型等三个亚类。在同一造山带内,如果蛇绿岩与火山弧型超镁铁岩在空间上相伴分布,侵位的时间相近,则可共同组成一对超镁铁岩带。蛇绿岩代表封闭的洋盆残迹,而火山弧型岩体则来自过渡壳之下、消减带之上的地幔楔。文中还概述了造山带中成对超镁铁岩的分布、产出条件及其在造山带研究中的意义。     

高压-超高压变质带中超基性岩的成因类型及其流体活动

超基性岩的地质过程提供了地幔岩在造山带形成过程中所作的贡献,并记录了地质构造以及壳-幔之间相互作用的信息。根据现有的研究,可将俯冲带橄榄岩大致分为陆下地幔橄榄岩、基性-超基性堆晶杂岩和大洋地幔橄榄岩。文中简要评述了不同类型造山带橄榄岩的岩石学和地球化学特征。不同类型的橄榄岩所经历的地质历史不同,而留有不同的岩石学和地球化学特征。大多数造山带橄榄岩经历了高压-超高压变质作用,并受到蛇纹岩化等多期次流体和融体的交代作用,因而俯冲造山带的辉石岩和橄榄岩无论在岩石学的组成、结构和地球化学等特征方面通常表现得复杂多变。     

辉石岩：高压结晶还是再循环洋壳？

        辉石岩有三种不同的成因：（1）堆晶成因（Ⅰ类辉石岩） ;（2）再循环洋壳变质成因（Ⅱ类辉石岩） ;（3）交代成 因。 I 类辉石岩由橄榄岩部分熔融产生的熔体在岩浆通道内上升过程中,在1.5~2.5 GPa 压力范围内结晶形成。常具有堆晶 结构或火成结构,在 CaO/MgO-SiO2/MgO 图解中无明显的线性关系,无Eu 异常,其 Sr-Nd-O 同位素组成与幔源岩浆相似。 II 类辉石岩多数为再循环洋壳的变质产物,常具变晶结构,在CaO/MgO-SiO2/MgO 图解中形成明显的线性关系,具Eu 正异常, 其εNd 值与MORB 相似,而Sr 同位素比值变化范围大;其O 同位素组成与原岩有关,如原岩是洋壳下部,δ18O < 地幔值; 如原岩是洋壳上部,则δ18O > 地幔值。交代成因辉石岩是熔体- 橄榄岩相互反应的结果,常被方辉橄榄岩或纯橄岩包围, 矿物种类相对其他两类辉石岩单一,在CaO/MgO-SiO2/MgO 图解中较分散,其εNd 值较II 类辉石岩低,而Sr 同位素比值变 化较小,δ18O 值低于、高于、近似于地幔值都存在。再循环洋壳在俯冲到地幔深部和随超基性岩体上升的过程中由流体萃 取作用和部分熔融作用形成化学成分丰富的流体和熔体,这些熔/ 流体或交代围岩橄榄岩将其转化为辉石岩,或直接高压 结晶形成辉石岩,或者由洋壳变质形成的榴辉岩经退变质形成Ⅱ类辉石岩。上述过程导致了在同一超基性岩体中各类成分、 成因不同辉石岩共存的现象。     

Peculiar Mg–Ca–Si metasomatism along a shear zone within the mantle wedge: inference from fine-grained xenoliths from Avacha volcano,Kamchatka

We found extremely high-Mg# (=Mg/(Mg + total Fe) atomic ratio) ultramafic rocks in Avacha peridotite suite. All the high-Mg# rocks have higher modal amounts of clinopyroxene than ordinary Avacha peridotite xenoliths, and their lithology is characteristically heterogeneous, varying from clinopyroxenite through olivine websterite to pyroxene-bearing dunite. The Mg# of minerals is up to 0.99, 0.98 and 0.97 in clinopyroxene, orthopyroxene and olivine, respectively, decreasing progressively toward contact with dunitic part, if any. The petrographical feature of pyroxenes in the high-Mg# pyroxenite indicates their metasomatic origin, and high LREE/HREE ratio of the metasomatic clinopyroxene implies that the pyroxenites are the products of reaction between dunitic peridotites and high-Ca, silicate-rich fluids. The lithological variation of the Avacha high-Mg# pyroxenites from clinopyroxenite to olivine websterite resulted from various degrees of fluid-rock reaction coupled with fractional crystallization of the high-Ca fluids, which started by precipitation of high-Mg# clinopyroxene. Such fluids were possibly generated originally at a highly reduced serpentinized peridotite layer above the subducting slab. The fluids can reach the uppermost mantle along a shear zone as a conduit composed of fine-grained peridotite that developed after continent-ward asthenospheric retreats from the mantle wedge beneath the volcanic front. The fluids are incorporated in mantle partial melts when the magmatism is activated by expansion of asthenosphere to mantle wedge beneath the volcanic front.     

大别山北麓尖晶石橄榄岩中石榴辉石岩包体的成因矿物学信息

大别山北坡霍山饶拔寨等地的超基性岩中含有石榴辉石岩的包体。石榴辉石岩为草绿色致密块状 ,呈分米级的块体出现于蛇纹石化强烈的橄榄岩中。运用成因矿物学的方法 ,研究对比了石榴辉石岩的主要矿物组成石榴子石 ( Prp2 5— 3 5 )和钠质普通辉石 ( Jd1 0— 2 5 )等。岩石结构显示退变质作用有两期 :榴辉岩相退变形成的麻粒岩相矿物组合明显地被角闪岩相所切割。石榴辉石岩的寄主岩是尖晶石橄榄岩类 ,包括尖晶石方辉橄榄岩和尖晶石二辉橄榄岩。由于强烈的蛇纹石化 ,残余的橄榄石 ( Fo92— 93 )仅占 5%～ 4 0 % ,斜方辉石富镁 ( En87— 93)并有解理弯曲等韧性变形现象。采用 Ellisand Green的石榴子石单斜辉石 Fe-Mg交换平衡温度计 ,可计算出石榴辉石岩的 Fe-Mg分配系数 ( KD)为 4 .0 6～ 5.2 8。变质温度 t=84 1～ 94 3℃ ,估算压力 p=1 .5GPa,可以推测该橄榄岩体是从深度约 60 km的地幔 ,固态侵位于下地壳 ,而后与之一起隆升到地表。显然 ,此种石榴辉石岩应属 Coleman所划分的 A型榴辉岩 ,它与地幔岩浆作用有密切关系。石榴辉石岩和橄榄岩的岩石化学特征和稀土配分形式 ,说明它们的化学性质相当于地幔部分熔融所形成的玄武岩熔体及其残留体。在侧重探讨石榴辉石岩及其有关岩石中主要造岩矿物的成因矿物?     

Devonian rodingite from the northern margin of the North China Craton: mantle wedge metasomatism during ocean–continent convergence

The northern margin of the North China Craton (NCC) was an active convergent margin during Palaeozoic and preserves important imprints of magmatic and metasomatic processes associated with oceanic plate subduction. Here, we investigate the mafic–ultramafic rocks in the Xiahabaqin–Sandaogou complexes from the northern NCC including pyroxenite, hornblendites, hornblende gabbro, and their rodingitized counterparts within a serpentinite domain. We present petrological, zircon U–Pb geochronological, and geochemical data to constrain the nature and timing of the magmatic and metasomatic processes in the subduction zone mantle wedge. The rock suites investigated in this study are characterized by low contents of SiO₂, Na₂O, and K₂O, with high CaO, FeO, Fe₂O₃, and MgO. The rodingitized rocks show markedly high CaO and lower MgO compared to their ultramafic protolith, suggesting extensive post-magmatic infiltration of Ca-rich, Si-poor fluids derived by serpentinization of mantle peridotite. The enrichment of large ion lithophile and light rare earth elements such as Ba, Sr, K, La, and Ce with relative depletion of high field strength elements like Nb, Ta, Zr, and Hf in the ultramafic rocks collectively suggest metasomatism of a fore-arc mantle wedge by fluids released through dehydration of subducted oceanic slab and subduction-derived sediments. Dehydration and decarbonation leading to metasomatic fluid influx and serpentinization of mantle wedge peridotite account for the enriched geochemical signatures for the rodingitized rocks. The zircon grains in these rocks show textures indicating magmatic crystallization followed by fluid-controlled dissolution–precipitation. Magmatic zircons from altered pyroxenite, hornblendite, and rodingitized pyroxenite in Xiahabaqin yield protolith crystallization ages peaks at 396 Ma and 392 Ma and metasomatic grains show ages of 386 Ma, 378 Ma, and 348 Ma. The zircons from hornblendite and basaltic trachyandesite indicate protolith emplacement during 402–388 Ma. Metasomatic zircon grains from rodingitized hornblende gabbro in Sandaogou complex show a wide range of ages as 412 Ma, 398 Ma, 383 Ma, and 380 Ma. The common magmatic zircon ages peaks at 398–388 Ma in most of the rocks suggest a similar time for magma crystallization in the Xiahabaqin and Baiqi during Middle Devonian. Subsequently, repeated pulses fluids and melts resulted in metasomatic reactions in mantle wedge until early Permian. The Lu–Hf analysis of the zircon grains from these rocks display markedly negative εHf(t) values ranging from ?22.4 to ?7.7, suggesting magma derivation from an enriched, hydrated lithospheric mantle through fluid–rock interaction and mantle wedge metasomatism. Rodingitization processes are associated with exhumation of ultramafic mantle wedge rocks within a serpentinized subduction channel close to the subducted slab in response to slab roll back in a long-lasting subduction regime. This study offers insights into magmatic and metasomatic processes of ultramafic rocks in the fore-arc mantle wedge which were exhumed and accreted to an active continental margin during the southward subduction of the Palaeo-Asian oceanic lithosphere beneath the NCC.     

Neoproterozoic ophiolitic peridotites along the Allaqi-Heiani suture, South Eastern Desert, Egypt

The Wadi Allaqi ophiolite along the Egyptian-Sudanese border defines the southernmost ophiolitic assemblage and suture zone in the Eastern Desert. Ophiolite assemblages comprise nappes composed mainly of mafic and ultramafic rocks that were tectonically emplaced and replaced by serpentine and carbonates along shear zones probably due to CO₂-metasomatism. Serpentinites, altered slices of the upper mantle, represent a distinctive lithology of dismembered ophiolites of the western YOSHGAH suture. Microscopically, they are composed of more than 90 % serpentine minerals with minor opaque minerals, carbonate, brucite and talc. The mineral chemistry and whole-rock chemical data reported here indicate that the serpentinized peridotites formed as highly-depleted mantle residues. They show compositions consistent with formation in a suprasubduction zone environment. They are depleted in Al₂O₃ and CaO similar to those in fore-arc peridotites. Also, high Cr# (Cr/ (Cr+Al)) in the relict chrome spinels (average ~0.72) indicates that these are residual after extensive partial melting, similar to spinels in modern fore-arc peridotites. Therefore, the studied serpentinites represent fragments of an oceanic lithosphere that formed in a fore-arc environment, which belongs to an ophiolitic mantle sequence formed in a suprasubduction zone.     

Early Cretaceous Sung Valley ultramafic-alkaline-carbonatite complex, Shillong Plateau, Northeastern India: petrological and genetic significance

Summary The Shillong Plateau of northeastern India hosts four Early Cretaceous (105–107Ma) ultramafic-alkaline-carbonatite complexes (UACC), which have been associated with the Kerguelen plume igneous activity. Petrological and geochemical characteristics of one of these UACC, the Sung Valley, are presented. The Sung Valley UACC was emplaced in to the Proterozoic Shillong Group of rocks and consists of ultramafics (serpentinized peridotite, pyroxenite, and melilitolite), alkaline rocks (ijolite and nepheline syenite), and carbonatites. Serpentinized peridotite, pyroxenite, and ijolitic rocks form the major part of the complex, the others constitute less than 5% of the total volume. Ijolite and melilitolite intrude peridotite and pyroxenite, while nepheline syenite and carbonatite intrude the ultramafic rocks as well as ijolite. Mineralogically, the carbonatites are classified as calcite carbonatite with minor apatite, phlogopite, pyrochlore and ilmenite. The serpentinized peridotites are wehrlitic. Chemical compositions of the silicate rocks do not show a distinct co-genetic relationship amongst them, nor do they show any geochemical relationships with the carbonatites. No noticeable fractionation trend is observed on the chemical variation diagrams of these rocks. It is difficult to establish the genetic evolution of the Sung Valley UACC through fractional crystallization of nephelinitic magma or through immiscible liquids. On the basis of petrological and geochemical data and previously published isotopic results from these rocks, it is suggested that they have been derived from a primary carbonate magma generated by the low-degree melting of a metasomatized mantle peridotite.     

Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central China

Garnet peridotites occur as lenses, blocks or layers within granulite–amphibolite facies gneiss in the Dabie-Sulu ultra-high-pressure (UHP) terrane and contain coesite-bearing eclogite. Two distinct types of garnet peridotite were identified based on mode of occurrence and petrochemical characteristics. Type A mantle-derived peridotites originated from either: (1) the mantle wedge above a subduction zone, (2) the footwall mantle of the subducted slab, or (3) were ancient mantle fragments emplaced at crustal depths prior to UHP metamorphism, whereas type B crustal peridotite and pyroxenite are a portion of mafic–ultramafic complexes that were intruded into the continental crust as magmas prior to subduction. Most type A peridotites were derived from a depleted mantle and exhibit petrochemical characteristics of mantle rocks; however, Sr and Nd isotope compositions of some peridotites have been modified by crustal contamination during subduction and/or exhumation. Type B peridotite and pyroxenite show cumulate structure, and some have experienced crustal metasomatism and contamination documented by high ⁸⁷Sr/⁸⁶Sr ratios (0.707–0.708), low ε_Nd( t ) values (−6 to −9) and low δ¹⁸O values of minerals (+2.92 to +4.52). Garnet peridotites of both types experienced multi-stage recrystallization; some of them record prograde histories. High- P–T  estimates (760–970 °C and 4.0–6.5±0.2 GPa) of peak metamorphism indicate that both mantle-derived and crustal ultramafic rocks were subducted to profound depths >100 km (the deepest may be ≥180–200 km) and experienced UHP metamorphism in a subduction zone with an extremely low geothermal gradient of <5 °C km⁻¹.     

Petrology of ultramafic nodules from São Tomé Island, Cameroon Volcanic Line (oceanic sector)

Ultramafic xenoliths were found in recent alkali basalts from São Tomé Island. These include spinel peridotites (lherzolites, harzburgites and dunites) and pyroxenites (orthopyroxenites and clinopyroxenites). Textures and mineral compositions indicate that pyroxenites originated from crystal/liquid separation processes operating on magmas similar to those giving rise to their present host rocks whereas spinel peridotite xenoliths had an accidental origin; Fo (>89) and Ni (>0.36 wt.%) contents in olivines, Mg# (91–95) of orthopyroxenes and low Ti in clinopyroxene (primary crystals: TiO₂<0.06 wt.%) and in spinel (TiO₂<0.1 wt.%) are within the range reported for abyssal peridotites, indicating São Tomé spinel peridotites represent refractory residues of melting. Nevertheless, the lack of correlation between mineral chemistry and modal composition suggests that spinel peridotite xenoliths are not simple residues and were affected by infiltration of fluid/melts within the mantle. The wide temperature range obtained for spinel peridotites (700 to >1150 °C) is compatible with a long period of pre-entrainment cooling supporting Fitton's [Tectonophysics 94 (1983) 473] hypothesis that proposes oceanic lithosphere uprising in the Cameroon Volcanic Line prior to the initiation of the current thermal regime, related to São Tomé magmatism. The association of upper mantle (peridotite) xenoliths with igneous cumulates (pyroxenites) suggests that the spinel peridotite suite originated in the uppermost mantle above the São Tomé magma storage zone(s), probably in a region of high strain rate, near the boundary between the mantle and the overlying oceanic crust.     

O–H isotope ratios of high pressure ultramafic rocks: implications for fluid sources and mobility in the subducted hydrous mantle

We examine the O-H isotope signatures of Alpine ultramafic rocks and eclogitic metagabbros of the Erro-Tobbio peridotite Unit (western Italian Alps), which record a subduction and exhumation cycle. Localization of subduction-related deformation along serpentinite mylonite shear zones favoured preservation of pre-subduction mantle and low temperature (oceanic) alteration assemblages within undeformed (meta)peridotite that underwent partial static recrystallization to high-pressure metamorphic parageneses. Bulk rock and mineral separate (clinopyroxene and serpentine) oxygen isotope ratios of the serpentinized mantle peridotites (5-8‰) are slightly enriched in ¹⁸O compared with those of the high-pressure metaperidotites and the serpentinite mylonites (4.4-7.6‰). The lowest values occur in high-pressure veins (3.5-5.7‰) and eclogitic metagabbros (3.1-5.3‰). These variations are comparable to variations observed in modern oceanic rocks and in non-subducted ophiolites. Preservation of pre-eclogitic '¹⁸O signatures of the Erro-Tobbio rocks and a lack of oxygen isotope re-equilibration between different shear zones imply local-scale fluid flow at low water/rock ratios and closed system behaviour during high-pressure metamorphism. Different serpentine generations show a bimodal distribution in 'D values: pre-eclogitic lizardite and chrysotile range from -102 to -77‰; high-pressure antigorite in the mylonites and in low strain metaperidotites range from -71 to -57‰ and -83 to -60‰, respectively. Comparable ranges occur in antigorite in the associated high-pressure veins, suggesting that the hydrogen signatures were acquired prior to veining. We propose that the isotopic variations reflect multiple events of fluid uptake in different geodynamic environments. The H- and O-isotope ratios in the eclogitic mylonites suggest that initial hydration occurred over a range of temperatures during local interaction with altered seawater along oceanic shear zones. The ¹⁸O-enriched and H-depleted compositions of chrysotile and lizardite in the mantle peridotites suggest that a second hydration event may have occurred as a result of interaction with metamorphic fluids at the early stages of burial in a forearc setting, where slabs undergo large-scale, low-temperature fluid fluxing. The oceanic mantle is thus a candidate for continuous hydration during its oceanic and early subduction history. The Erro-Tobbio unit thus represents an example of cycling of internally-derived fluids, whereby the different structural and textural domains behaved as relatively closed systems to fluid circulation during high-pressure metamorphism.