High-Ti muscovite as a prograde relict in high pressure granulites with metamorphic Devonian zircon ages (Běstvina granulite body,Bohemian Massif): Consequences for the relamination model of subducted crust

High-pressure kyanite–K-feldspar granulites in the Běstvina granulite body, which belongs to the Variscan orogenic root in the Bohemian Massif, preserve muscovite, rutile and kyanite inclusions in garnet. High-Ti muscovite (Ti = 0.09–0.20 p.f.u., Si = 0.21–3.24 p.f.u.) included in garnet is associated with quartz and is in crystallographic continuity with biotite, interpreted in terms of exsolution from an original less-dioctahedral higher-Ti muscovite. The assemblage garnet–kyanite–antiperthite–perthite–quartz–rutile and the mineral compositions indicate a peak of metamorphism at about 900 °C and 17–21 kbar, based on P–T pseudosection modeling, ternary-feldspar and Zr-in-rutile thermometry. The matrix assemblage garnet–kyanite–plagioclase-K-feldspar–quartz–rutile–ilmenite and garnet rim compositions at contact with feldspars and quartz indicate the end of overall equilibration in the presence of melt at 12–14 kbar and 820–840 °C. Embayments of biotite and plagioclase locally replacing garnet, and connected with modification of garnet composition, may indicate sites of last isolated melt or diffusion of H₂O from that melt down to 10 kbar and 800 °C. Zircon with uniform cathodoluminescence (CL) pattern is present as rims around cores with faint oscillatory zoning, or as entire rounded grains. These zircons gave a cluster of ages at 359 ± 4 Ma, interpreted as the age of metamorphism. Zircon ages from the cores with common faint oscillatory zoning range from 500 to 398 Ma, and are interpreted as magmatic grains variably reset during metamorphism. Two older ages obtained on cores of 620 ± 18 Ma probably represent an inherited zircon component. Molar isopleths of zircon along the P–T path in pseudosections suggest that crystallization of metamorphic zircon occurred during decompression and cooling from 17 to 21 kbar and 900 °C to 12–14 kbar and 820–840 °C. The inferred P–T path and the age of metamorphism are discussed in the framework of a geodynamic model that considers the granulites to be a part of a subducted plate that failed to continue to subduct and was spread below the upper plate.     

Geochronological problems related to polymetamorphism in the Limpopo Complex,South Africa

The integration of new and published geochronologic data with structural, magmatic/anatectic and pressure–temperature (P–T) process information allow the recognition of high-grade polymetamorphic granulites and associated high-grade shear zones in the Central Zone (CZ) of the Limpopo high-grade terrain in South Africa. Together, these two important features reflect a major high-grade D₃/M₃ event at ~ 2.02 Ga that overprinted the > 2.63 Ga high-grade Neoarchaean D₂/M₂ event, characterized by SW-plunging sheath folds. These major D₂/M₂ folds developed before ~ 2.63 Ga based on U–Pb zircon age data for precursors to leucocratic anatectic gneisses that cut the high-grade gneissic fabric. The D₃/M₃ shear event is accurately dated by U–Pb monazite (2017.1 ± 2.8 Ma) and PbSL garnet (2023 ± 11 Ma) age data obtained from syntectonic anatectic material, and from sheared metapelitic gneisses that were completely reworked during the high-grade shear event. The shear event was preceded by isobaric heating (P = ~ 6 kbar and T = ~ 670–780 °C), which resulted in the widespread formation of polymetamorphic granulites. Many efforts to date high-grade gneisses from the CZ using PbSL garnet dating resulted in a large spread of ages (~ 2.0–2.6 Ga) that reflect the polymetamorphic nature of these complexly deformed high-grade rocks.     

Timing and rate of granulite facies metamorphism and cooling from multi-mineral chronology on migmatitic gneisses,Sierras de La Huerta and Valle Fértil,NW Argentina

Migmatitic paragneisses of the Valle Fértil–La Huerta Ranges at the Western margin of the Sierras Pampeanas are composed of garnet–cordierite–plagioclase–biotite–quartz-bearing units that experienced peak metamorphic conditions of ca. 800 °C at 6–7 kbar. Based on petrological studies, pseudosection modeling and petrographic observations, an anticlockwise P–T path with a small pressure increment is proposed. Rare earth element LA-ICP-MS patterns acquired from rutile bearing garnets suggest a single stage of garnet growth at high-T at pressures above the ilmenite–rutile transition. U–Pb dating of zircon rims from the migmatites indicates two distinct metamorphic U–Pb ages of 525 ± 9 Ma and 478 ± 9 Ma. The older age is suggested to record an amphibolite facies event of the Pampean orogeny. The younger metamorphic age is contemporary with igneous zircons from metatonalites and pegmatites that yield 478 ± 4 Ma. We suggest that the prograde high-T metamorphic Famatinian event is associated with the emplacement of large magmatic bodies in which large-scale magmatic activity gave rise to an increased geothermal gradient of about 35 °C/km. Sm–Nd garnet ages of 447 ± 3 Ma indicate a time span of around 30 Ma for which temperatures above the garnet closure temperature prevailed. Using U–Pb, Sm–Nd and Rb–Sr isotope systems, a cooling rate of 3 to 6 °C/Myr is inferred.     

Intrusion age,geochemistry and metamorphic conditions of a quartz-monzosyenite intrusion at the craton–Eastern Ghats Belt contact near Jojuru,India

The boundary between the Archean cratons and the Eastern Ghats Belt in peninsular India represents a rifted Mesoproterozoic continental margin which was overprinted by a Pan-African collisional event associated with the westward thrusting of the Eastern Ghats granulites over the cratonic foreland. The contact zone contains a number of deformed and metamorphosed nepheline syenite complexes of rift-related geochemical affinities. In addition to the nepheline-bearing rocks, metamorphosed quartz-bearing monzosyenitic bodies can also be identified along the suture in the region between the Godavari-Pranhita graben and the Prakasam Igneous Province. One such occurrence at Jojuru near Kondapalle is geochemically comparable to the nepheline syenites and furnishes a weighted mean concordant U–Th–Pb SHRIMP zircon age of 1263 ± 23 Ma (2σ), which provides a lower age bracket for the rift-related magmatic activity. The original igneous mineral assemblage in the monzosyenite was partially replaced by the formation of coronitic garnet during the Pan-African metamorphism of the rocks. P–T estimates of garnet corona formation at the interface between clinopyroxene–orthopyroxene–ilmenite clusters and plagioclase indicate mid to upper amphibolite facies condition (5.5–7.0 kbar and 600–700 °C) during the thrust induced deformation and metamorphism associated with the Pan-African collisional tectonics.     

Metamorphic evolution of the Maud Belt: P–T–t path for high-grade gneisses in Gjelsvikfjella,Dronning Maud Land,East Antarctica

A metamorphic petrological study, in conjunction with recent precise geochronometric data, revealed a complex P–T–t path for high-grade gneisses in a hitherto poorly understood sector of the Mesoproterozoic Maud Belt in East Antarctica. The Maud Belt is an extensive high-grade, polydeformed, metamorphic belt, which records two significant tectono-thermal episodes, once towards the end of the Mesoproterozoic and again towards the late Neoproterozoic/Cambrian. In contrast to previous models, most of the metamorphic mineral assemblages are related to a Pan-African tectono-thermal overprint, with only very few relics of late Mesoproterozoic granulite-facies mineral assemblages (M₁) left in strain-protected domains. Petrological and mineral chemical evidence indicates a clockwise P–T–t path for the Pan-African orogeny. Peak metamorphic (M_2b) conditions recorded by most rocks in the area (T = 709–785 °C and P = 7.0–9.5 kbar) during the Pan-African orogeny were attained subsequent to decompression from probably eclogite-facies metamorphic conditions (M_2a).The new data acquired in this study, together with recent geochronological and geochemical data, permit the development of a geodynamic model for the Maud Belt that involves volcanic arc formation during the late Mesoproterozoic followed by extension at 1100 Ma and subsequent high-grade tectono-thermal reworking once during continent–continent collision at the end of the Mesoproterozoic (M₁; 1090–1030 Ma) and again during the Pan-African orogeny (M_2a, M_2b) between 565 and 530 Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions (M_2c) followed and is ascribed to post-orogenic bimodal magmatism between 500 and 480 Ma.     

Multi-stage metamorphic evolution of retrograde eclogite with a granulite-facies overprint in the Zhaigen area of the North Qinling Belt,China

Retrograde eclogite from the central part of the Qinling Complex, Zhaigen area of the North Qinling Belt, was studied using integrated petrology, mineral chemistry, pseudosection modeling, and geochronology. Microstructures and mineral relationships reveal five metamorphic stages and associated mineral assemblages as follows: (1) pre-peak stage M₁, which is recorded by the inner cores of garnets together with mineral inclusions of clinopyroxene (Cpx₁) + amphibole (Am₁) + plagioclase (Pl₁) ± quartz ± rutile, occurred under conditions of 760–770 °C and 11.4–14.0 kbar; (2) eclogite-facies stage M₂, recorded by garnet cores + relic omphacite (with a high jadeite content up to 31%) + rutile + quartz under conditions of > 16.7 kbar and 679–765 °C; (3) high-pressure granulite-facies stage M₃, characterized by clinopyroxene (Cpx₂) + plagioclase (Pl₂) symplectites under conditions of 14.5–15.6 kbar and 800–850 °C; (4) medium-pressure granulite-facies stage M₄, characterized by the growth of plagioclase + orthopyroxene coronas around garnet under conditions of 8.3–10 kbar and 795–855 °C; and (5) retrogressive amphibolite-facies stage M₅, which is represented by amphibole (Am₃) + plagioclase (Pl₃) kelyphitic rims around garnet at conditions of < 4 kbar and < 620 °C. Based on Laser Raman analysis of mineral inclusions, cathodoluminescence images, in situ trace element concentrations from different domains within zircon grains, and LA-ICP-MS and SHRIMP U–Pb dating, the protolith age of the Zhaigen retrograde eclogite is suggested at 786 ± 10 Ma and the eclogite-facies metamorphic age recorded by metamorphic zircon cores is limited within 501–497 Ma. The retrograde zircon rims display ages of 476–447 Ma and 425 Ma that probably reflect the timing of two stages of retrograde metamorphism, respectively. The mineral assemblages, P–T conditions, and zircon U–Pb data define a clockwise P–T–t path for the retrograde eclogite, suggesting that the Neoproterozoic protolith of the retrograde eclogite might evolved into continental subduction and eclogite-facies metamorphism during 501–497 Ma before undergoing retrograde metamorphism during an initial stage of exhumation to middle–upper crust level at 474–447 Ma and subsequent exhumation to shallow upper crust at ~ 420 Ma.     

Mafic xenoliths in Proterozoic kimberlites from Eastern Dharwar Craton,India: Mineralogy and P–T regime

Mafic xenoliths of garnet pyroxenite and eclogite from the Wajrakarur, Narayanpet and Raichur kimberlite fields in the Archaean Eastern Dharwar Craton (EDC) of southern India have been studied. The composition of clinopyroxene shows transition from omphacite (3–6 wt% Na₂O) in eclogites to Ca pyroxene (<3 wt% Na₂O) in garnet pyroxenites. Some of the xenoliths have additional phases such as kyanite, enstatite, chromian spinel or rutile as discrete grains. Clinopyroxene in a rutile eclogite has an X_Mg value of 0.70, which is unusually low compared to the X_Mg range of 0.91–0.97 for all other samples. Garnet in the rutile eclogite is also highly iron-rich with an end member composition of Prp_26.5Alm_52.5Grs_14.7Adr_5.1TiAdr_0.3Sps_1.0Uv_0.1. Garnets in several xenoliths are Cr-rich with up to 8 mol% knorringite component. Geothermobarometric calculations in Cr-rich xenoliths yield different P–T ranges for eclogites and garnet pyroxenites with average P–T conditions of 36 kbar and 1080 °C, and 27 kbar and 830 °C, respectively. The calculated P–T ranges approximate to a 45 mW m^?2 model geotherm, which is on the higher side of the typical range of xenolith/xenocryst geotherms (35–45 mW m^?2) for several Archaean cratons in the world. This indicates that the EDC was hotter than many other shield regions of the world in the mid-Proterozoic period when kimberlites intruded the craton. Textural and mineral chemical characteristics of the mafic xenoliths favour a magmatic cumulate process for their origin as opposed to subducted and metamorphosed oceanic crust.     

Palaeozoic polymetamorphism in the North Qinling orogenic belt,Central China: Insights from petrology and in situ titanite and zircon U–Pb geochronology

The Qinling orogenic belt experienced multiple phases of orogenesis during the Palaeozoic. Unraveling the timing and P–T conditions of these events is the key to understanding the convergence processes between the South China and the North China Blocks. The Songshugou Complex, located in the southern part of the North Qinling orogenic belt, has registered multistage metamorphism in Palaeozoic, and thus potentially provides insights into the tectonic evolution of the Qinling orogenic belt. In this study, three metabasic rocks (a garnet pyroxenite, a garnet amphibolite and a gneissic amphibolite) from the Songshugou Complex were selected for petrological study and zircon and titanite U–Pb dating. Our results show that the metabasic rocks experienced three metamorphic events during the Palaeozoic. The first metamorphic event (M1) is characterized by high pressure conditions. Two zircon grains in equilibrium with garnet and in absence of plagioclase were recognized from the garnet pyroxenite sample. They yielded Ti-in-zircon temperatures of 660–851 °C at ∼12.0 kbar and a weighted mean age of 498 ± 15 Ma, providing the constraints on the temperature and timing of prograde or peak metamorphism (M1-1). Zircons that are inequilibrium with garnet from the garnet pyroxenite and the garnet amphibolite gave U–Pb ages of 494 ± 9 Ma and 484 ± 4 Ma, and Ti-in-zircon temperatures of 793 ± 33 °C and 738 ± 18 °C, respectively. Thus, these zircons were formed on the retrograde amphibolite-facies conditions at ∼8.0 kbar (M1-2). Titanite inclusions were found in actinolite cores of zoned amphibole from the garnet amphibolite. They yielded a U–Pb age of ∼470 Ma and Zr-in-titanite temperature of 676 ± 23 °C at pressure of ∼7.0 kbar, suggesting that the amphibolite-facies retrogression perhaps persisted to ∼470 Ma.Weakly zoned zircons from the garnet amphibolite and inclusion-free titanites from the garnet pyroxenite gave consistent U–Pb ages of 418 ± 5 Ma and 423 ± 10 Ma, and Ti-in-zircon temperature of 742 ± 26 °C and Zr-in-titanite temperature of 764 ± 18 °C at ∼7.0 kbar, respectively. It is suggested that a heating event (M2) is registered by a subsequent phase of amphibolite-facies metamorphism. The ilmenite-bearing titanite crystals from the garnet pyroxenite yielded a U–Pb age of 352 ± 4 Ma, recording a late thermal event (M3).On the basis of combined petrological and geochronological results, we propose a revised tectonic model for the North Qinling orogeny in Palaeozoic. The high pressure granulites were formed by the northward subduction of the Shangdan oceanic slab and the arc-continent collision at ca. 500 Ma. Their exhumation happened at ca. 494–484 Ma as a result of slab breakoff. Subsequent amphibolite-facies metamorphism dated at ca. 440–420 Ma are coeval with the widespread magmatism in the North Qinling Terrane, which are likely caused by the reinitiation northward-subducted of Shangdan oceanic slab. At ca. 350 Ma, the North Qinling Terrane was likely affected by another thermal overprinting event.     

Ultrahigh-temperature metamorphism and anticlockwise P–T–t path of Paleozoic granulites from north Qinling-Tongbai orogen,Central China

Mafic and semi-pelitic granulites from the Qinling-Tongbai orogen in central China preserve petrological evidence and mineral paragenesis suggesting four distinct stages of metamorphic evolution. The prograde history (M₁) is recorded by the occurrence of cordierite, orthopyroxene and biotite inclusions in garnet porphyroblasts of the peak-metamorphic (M₂) assemblage. Peak-metamorphism was followed by cooling with minor decompression (M₃), which formed symplectites and coronitic textures. The greenschist facies retrograde metamorphic assemblage (M₄) is represented by hydrous minerals replacing minerals of the M₂ and M₃ assemblages. We present LA-ICPMS zircon U-Pb data which show ages of 432 ± 4 Ma for the peak metamorphism and 403 to 426 Ma for the retrograde stage. Microstructural analysis, P–T pseudosections, and mineral isopleths in conjunction with the zircon U-Pb ages define an anticlockwise P–T–t path. The P–T estimates for peak metamorphic conditions of 880–920 °C and 8.0–10 kbar suggest that these rocks witnessed extreme crustal metamorphism under ultrahigh-temperature conditions. The anticlockwise trajectory reported in this study is comparable with similar P–T paths recorded from subduction–collision settings, and correlate the Tongbai granulites to hot orogens developed within a Paleozoic collisional suture. We propose a ridge subduction and slab window setting to explain the formation of the Tongbai orogen, in a convergent plate setting associated with the northward subduction of the Paleo-Tethyan Qinling Ocean.     

Ultrahigh-temperature mafic granulites from Panrimalai,south India: Constraints from phase equilibria and thermobarometry

The Panrimalai area constitutes part of the granulite-facies rocks of the Madurai block in the Southern Granulite Terrain (SGT), India. Garnet-bearing mafic granulites in Panrimalai occur as small enclaves within charnockite. The common stable assemblage during peak metamorphism contains hornblende, garnet, orthopyroxene, clinopyroxene, quartz and plagioclase. The resorption of garnet in various reaction textures and the development of spectacular orthopyroxene–plagioclase and hornblende–plagioclase symplectites characterize the subsequent stages of metamorphism. Application of multi-equilibrium calculation procedures for mineral core compositions of the early assemblage yields near peak conditions at  ≥ 900 °C at 9 kbar. These estimates are the highest yet reported in mafic granulites from the Madurai block. The post-peak P–T path is constructed for the mafic granulites based on observed microstructural relations and thermobarometric results is characterized by a steep clockwise decompressional P–T segment from  ≥ 9 to  < 4.5 kbar. Constraints from model Nd ages provide evidence for Paleoproterozoic magmatism restricted to the Madurai block in the Southern Granulite Terrain. The early part of the crustal evolution of the Panrimalai granulites could be coeval with the Paleoproterozoic event. Subsequent development of symplectitic assemblages via near-isothermal decompression can be ascribed to a distinctly later tectonic event. Available U–Pb and Sm–Nd mineral dates suggest a widespread Pan-African tectonothermal event in the SGT. Given the general recognition of ultrahigh-temperature (UHT) and isothermal decompression (ITD) in Pan-African age metamorphism in the East-African–Antarctic Orogen (EAAO) , the Panrimalai UHT history is considered to be part of this record.     

High-pressure and ultrahigh-temperature metamorphism at Komateri,northern Madurai Block,southern India

We report for the first time the evidence for prograde high-pressure (HP) metamorphism preceding a peak ultrahigh-temperature (UHT) event in the northernmost part of the Madurai Block in southern India. Mg–Al-rich Grt–Ged rocks from Komateri in Karur district contain poikiloblastic garnet with numerous multi-phase inclusions. Although most of the inclusion assemblages are composed of gedrite, quartz, and secondary biotite, rare staurolite + sapphirine and spinel + quartz are also present. The X_Mg (=Mg/[Fe+Mg]) of staurolite (0.45–0.49) is almost consistent with that reported previously from Namakkal district in the Palghat–Cauvery Shear Zone system (X_Mg = 0.51–0.52), north of the Madurai Block. The HP event was followed by peak UHT metamorphism at T = 880–1040 °C and P = 9.8–12.5 kbar as indicated by thermobarometric computations in the Grt–Ged rock and associated mafic granulite. Symplectic intergrowth of spinel (X_Mg = 0.50–0.59, ZnO < 1.7 wt.%) and quartz, a diagnostic indicator of UHT metamorphism, probably formed by decompression at UHT conditions. The rocks subsequently underwent retrograde metamorphism at T = 720–760 °C and P = 4.2–5.1 kbar. The P–T conditions and clockwise exhumation trajectory of the Komateri rocks, comparable to similar features recorded from the Palghat–Cauvery Shear Zone system, suggest that the Madurai Block and the Palghat–Cauvery Shear Zone system underwent similar HP and UHT metamorphic history probably related to the continent–continent collision during the final stage of amalgamation of Gondwana supercontinent.     

The Temaguessine Fe-cordierite orbicular granite (Central Hoggar,Algeria): U–Pb SHRIMP age,petrology, origin and geodynamical consequences for the late Pan-African magmatism of the Tuareg shield

The Temaguessine high-level subcircular pluton is intrusive into the LATEA metacraton (Central Hoggar) Eburnian (2 Ga) basement and in the Pan-African (615 Ma) granitic batholiths along a major NW–SE oriented major shear zone. It is dated here (SHRIMP U–Pb on zircon) at 582 ± 5 Ma. Composed of amphibole–biotite granite and biotite syenogranite, it comprises abundant enclaves: mafic magmatic enclaves, country-rock xenoliths and remarkable Fe-cordierite (#Fe = 0.87) orbicules. The orbicules have a core rich in cordierite (40%) and a leucocratic quartz–feldspar rim. They are interpreted as resulting from the incongruent melting of the meta-wacke xenoliths collapsed into the magma: the breakdown of the biotite + quartz assemblage produced the cordierite and a quartz–feldspar minimum melt that is expelled, forming the leucocratic rim. The orbicule generation occurred at T < 850° and P < 0.3 GPa. The Fe-rich character of the cordierite resulted from the Fe-rich protolith (wacke with 4% Fe₂O₃ for 72% SiO₂). Strongly negative ε_Nd (−9.6 to −11.2), Nd T_DM model ages between 1.64 and 1.92 Ga, inherited zircons between 1.76 and 2.04 Ga and low to moderately high I_Sr (0.704–0.710) indicate a Rb-depleted lower continental crust source for the Temaguessine pluton; regional considerations impose however also the participation of asthenospheric material. The Temaguessine pluton, together with other high-level subcircular pluton, is considered as marking the end of the Pan-African magma generation in the LATEA metacraton, resulting from the linear delamination along mega-shear zones, allowing asthenospheric uprise and melting of the lower continental crust. This implies that the younger Taourirt granitic province (535–520 Ma) should be considered as a Cambrian intraplate anorogenic event and not as a very late Pan-African event.     

Combined U-Pb,Lu-Hf,Sm-Nd and Ar-Ar multichronometric dating on the Bailang eclogite constrains the closure timing of the Paleo-Tethys Ocean in the Lhasa terrane,Tibet

The Lhasa terrane, the main tectonic component of the Himalayan–Tibetan orogen, has received much attention as it records the entire history of the orogeny. The occurrence of Permian to Triassic high-pressure eclogites has a significant bearing on the understanding of the Paleo-Tethys subduction and plate suturing processes in this area. An eclogite from the Bailang, eastern Lhasa terrane, was investigated with a combined metamorphic P–T and U–Pb, Lu–Hf, Sm–Nd and Ar–Ar multichronometric approach. Pseudosection modeling combined with thermobarometric calculations indicate that the Bailang eclogite equilibrated at peak P–T conditions of ~ 2.6 GPa and 465–503 °C, which is much lower than those of Sumdo and Jilang eclogites in this area. Garnet–whole rock–omphacite Lu–Hf and Sm–Nd ages of 238.1 ± 3.6 Ma and 230.0 ± 4.7 Ma were obtained on the same sample, which are largely consistent with the corresponding U–Pb age of 227.4 ± 6.4 Ma for the metamorphic zircons within uncertainty. The peak metamorphic temperature of the sample is lower than the Lu–Hf and Sm–Nd closure temperatures in garnet. This, combined with the core-to-rim decrease in Mn and HREE concentrations, the slightly U-shaped Sm zonation across garnet and the exclusive occurrence of omphacite inclusion in garnet rim, are consistent with the Lu–Hf system skewing to the age of the garnet core and the Sm–Nd system favoring the rim age. The Sm–Nd age was thus interpreted as the age of eclogite-facies metamorphism and the Lu–Hf age likely pre-dated the eclogite-facies metamorphism. ⁴⁰Ar/³⁹Ar dating of hornblende from the eclogite yielded ages about 200 Ma, which is interpreted as a cooling age and is probably indicative of the time of exhumation to the middle crust. The difference of peak eclogite-facies metamorphic conditions and the distinct metamorphic ages for the Bailang eclogite (~ 2.6 GPa and ~ 480 °C; ca. 230 Ma), the Sumdo eclogite (~ 3.4 GPa and ~ 650 °C; ca. 262 Ma) and Jiang eclogite (~ 3.6 GPa and ~ 750 °C; ca. 261 Ma) in the same (ultra)-high-pressure belt indicate that this region likely comprises different slices that had distinct P–T histories and underwent (U)HP metamorphism at different times. The initiation of the opening the Paleo-Tethys Ocean in the Lhasa terrane could trace back to the early Permian. The ultimate closure of the Paleo-Tethys Ocean in the Lhasa terrane was no earlier than ca. 230 Ma.     

Synmetamorphic Cu remobilization during the Pan-African orogeny: Microstructural,petrological and geochronological data on the kyanite-micaschists hosting the Cu(–U) Lumwana deposit in the Western Zambian Copperbelt of the Lufilian belt

The Pan-African Lufilian orogenic belt hosts world-class Cu deposits. In the Congolese Copperbelt (DRC), Cu(–Co) deposits, are mostly hosted within evaporitic and siliciclastic Neoproterozoic metasedimentary rocks (Mines Subgroup) and are interpreted as syn- to late-diagenetic deposits. In this paper, we present new data on Cu(–U) deposit hosted in metamorphic rocks of the internal zone of the Lufilian belt known as the Western Zambian Copperbelt in which a primary Cu mineralization is overprinted by a second syn-metamorphic Cu mineralizing event. This mineralizing event is synchronous with the Pan-African metamorphism affecting both the pre-Katanga basement and the Katanga metasedimentary sequence. Cu(–U) occurrences in the Western Zambian Copperbelt are hosted by kyanite-micaschists metamorphosed in the upper amphibolite facies.Mineral inclusions of graphite, micas and sulfides in kyanite porphyroblasts of the Cu-bearing kyanite-micaschists in the Lumwana Cu deposit point to a sedimentary protolith with relics of an inherited Cu stock. Based on petrologic, microstructural and geochronological evidence, we propose that this initial Cu-stock was remobilized during the Pan-African orogeny. Graphite, micas and sulfides preserved in a first generation of kyanite poikiloblasts (Ky₁) define an inherited S_0/1 foliation developed during the prograde part of the P–T path (D₁ deformation-metamorphic stage) reaching HP–MT metamorphic conditions.Remobilization during the retrograde part of the P–T path is evidenced by chalcopyrite–pyrrhotite and chalcopyrite–bornite delineating a steep-dipping S₂ schistosity and by chalcopyrite and bornite delineating a shallow-dipping S₃ schistosity associated with top to the south kinematic criteria. This retrograde path is coeval with ductile deformation in the kyanite field as evidenced by a second generation of synkinematic kyanite porphyroblasts (Ky₂) transposed in the S₃ schistosity (Ky_2–3), and is marked by progressive cooling from ca. 620 °C down to 580 °C (rutile geothermometry). Syn-S_2–3 metamorphic monazite grains yield U–Th–Pb ages ranging from ca. 540 to 500 Ma.Final retrogression and remobilization of Cu is marked by recrystallization of the sulfides in top to the north C₃ shear bands associated with rutile crystals yielding temperatures from ca. 610 to 540 °C. This final remobilization is younger than ca. 500 Ma (youngest U–Th–Pb age on syn-S₃ recrystallized monazite). These data are consistent with successive Cu remobilization for more than 40 Ma during Pan-African reworking of sediment-hosted deposits either from the basement of the Katanga sedimentary sequence or from the Katanga sequence itself marked by burial (D₁), syn-orogenic exhumation (D₂), and post-orogenic exhumation during gravitational collapse (D₃).     

Coupled Lu–Hf and Sm–Nd geochronology constrains blueschist-facies metamorphism and closure timing of the Qilian Ocean in the North Qilian orogen

The Qilian–Qaidam orogenic belt at the northern edge of the Tibetan Plateau has received increasing attention as it recorded a complete history from continental breakup to opening and closure of ocean basin, and to the ultimate continental collision in the time period from the Neoproterozoic to the Paleozoic. Determining a geochronological framework of the initiation and termination of the fossil Qilian Ocean subduction in the North Qilian orogenic belt plays an essential role in understanding the whole tectonic process. Dating the high-pressure metamorphic rocks in the North Qilian orogenic belt, such as blueschist and eclogite, is the key in this respect. A blueschist from the southern North Qilian orogenic belt was investigated with a combined metamorphic P–T and U–Pb, Lu–Hf, and Sm–Nd multichronometric approaches. Pseudosection modeling indicates that the blueschist was metamorphosed under peak P–T conditions of 1.4–1.6 GPa and 530–550 °C. Zircon U–Pb ages show no constraints on the metamorphism due to the lack of metamorphic growth of zircon. Lu–Hf and Sm–Nd ages of 466.3 ± 2.0 Ma and 462.2 ± 5.6 Ma were obtained for the blueschist, which is generally consistent with the U–Pb zircon ages of 467–489 Ma for adjacent eclogites. Lutetium and Sm zoning profiles in garnet indicate that the Lu–Hf and Sm–Nd ages are biased toward the formation of the garnet inner rim. The ages are thus interpreted to reflect the time of blueschist-facies metamorphism. Previous ⁴⁰Ar/³⁹Ar ages of phengitic muscovite from blueschist/eclogite in this area likely represent a cooling age due to the higher peak metamorphic temperature than the argon retention temperature. The differences of peak metamorphic conditions and metamorphic ages between the eclogites and adjacent blueschists indicate that this region likely comprises different tectonic slices, which had distinct P–T histories and underwent high-pressure metamorphism at different times. The initial opening of the Qilian Ocean could trace back to the early Paleozoic, and the ultimate closure of the Qilian Ocean was no earlier than c. 466 Ma.     

Syn-kinematic emplacement of the Pangong metamorphic and magmatic complex along the Karakorum Fault (N Ladakh)

This paper investigates the age, P–T conditions and kinematics of Karakorum Fault (KF) zone rocks in the NW part of the Himalaya–Karakorum belt. Granulite to greenschist facies assemblages were developed within the KF zone during strike-slip shearing. The granulites were formed at high temperature (800 °C, 5.5 kbar), were subsequently retromorphosed into the amphibolite facies (700–750 °C, 4–5 kbar) and the greenschist facies (350–400 °C, 3–4 kbar). The Tangtse granite emplaced syn-kinematically at the contact between a LT and the HT granulite facies. Intrusion occurred during the juxtaposition of the two units under amphibolite conditions. Microstructures observed within the Tangtse granite exhibit a syn-magmatic dextral S–C fabric. Compiled U–Pb and Ar–Ar data show that in the central KF segment, granulite facies metamorphism occurred at a minimum age of 32 Ma, subsequent amphibolite facies metamorphism at 20–18 Ma. Further shearing under amphibolite facies (650–500 °C) was recorded at 13.6 ± 0.9 Ma, and greenschist-facies mica growth at 11 Ma. These data give further constrains to the age of initiation and depth of the Karakorum Fault. The granulite-facies conditions suggest that the KF, accommodating the lateral extrusion of Tibet, could be at least a crustal or even a Lithosphere-scale shear zone comparable to other peri-Himalayan faults.     

Metamorphic evolution of the Río Santa Rosa Granulites,northern Sierra de Comechingones,Argentina

Highly anhydrous granulites from Río Santa Rosa in the eastern Sierras Pampeanas of Argentina occur as a thick lens surrounded by melt-depleted migmatites. Grt–Crd granulite composed of Qtz+Pl+Grt+Crd+Ilm±Spl±Ath±Phl is the dominant rock, whereas Opx–Grt granulite appears as discontinuous lenses in the center of the granulite body. Grt–Crd granulite includes blocks of metabasite that are relics of refractory lithologic beds interlayered in the supracrustal sequence. A distinct assemblage composed of Qtz, Pl, Grt, Crd, Opx, Spl, Crn, Sil, Bt, Phl, Ath, and Fe–Ti oxides in different combinations was generated in a reaction zone between Grt–Crd granulites and metabasites at peak metamorphism (850–900 °C and 7.6±0.5 kbar). The P–T trajectory of Grt–Crd granulites suggests an early prograde garnet-forming stage followed by nearly isothermal decompression that caused garnet breakdown. Melting and melt draining accompanying garnet growth was active during heating (to 900 °C) at intermediate pressures (∼7.6 kbar). Peak P–T estimates for Opx–Grt granulites are similar to those obtained with Grt–Crd granulites, which indicates that both granulites passed through the highest thermal stage. These results constrain the late evolution of Opx–Grt granulite to a garnet-consuming stage. Furthermore, they imply that garnet formation in Opx–Grt granulite happened at an early prograde P–T trajectory. Garnet growth in Opx–Grt granulite cannot result from heating at high pressure, which would lead to an apparent contradiction in the prograde P–T paths of the two granulites. This discrepancy may be solved by demonstrating that Opx–Grt granulite is the product of synmetamorphic mafic magmatism that was contaminated while cooling. The Río Santa Rosa granulites are inferred to have formed in a thickened crust in which mafic magmatic activity providing a local heat input.     

Mesoproterozoic granulites of the Shillong–Meghalaya Plateau: Evidence of westward continuation of the Prydz Bay Pan-African suture into Northeastern India

Thermo-chronologic considerations in the Australo-Antarctic domains suggest that the Prydz Bay Pan-African suture of East Antarctica continues westward into India. However, the location of the suture within Eastern India has so far been uncertain because of a lack of adequate thermo-chronological information. In this study, electron microprobe (EPMA) monazite dates and mineral paragenesis of granulite facies metapelites are reported from two areas of the Shillong–Meghalaya gneissic complex (SMGC), a crustal block located in the extreme northeast of the Indian shield close to the Australo-Antarctic block in Neoproterozoic-Cambrian paleomagnetic reconstructions of the Rodinia supercontinent. In the Garo-Goalpara Hills region, a well constrained Mesoproterozoic age of 1596 ± 15 Ma (n = 103) is correlated with a counterclockwise pressure–temperature path with near peak conditions of 7–8 kbar and 850 °C. Rare matrix monazite rims record younger ages (1032–1273 Ma). At Sonapahar region, 50 km ESE of Garo-Goalpara Hills, homogenous monazite grains in granulite facies metapelites yield EPMA dates tightly clustered at 500 ± 14 Ma (n = 36) irrespective of their textural setting in a well-annealed mineral matrix. In a few zoned monazite grains, the cores yield older ages of 1078 ± 31 Ma (n = 10) and 1472 ± 38 Ma (n = 13). The 500 Ma date corresponds with the ca. 880–480 Ma Rb–Sr dates of porphyritic granites that predominantly intruded the east-central part of the SMGC. We propose that the progressively eastward dominance of Cambro-Ordovician ages in the SMGC indicates a Pan-African final amalgamation of the Indian plate with the Australo-Antarctic plate and a northward extension of the Prydz Bay suture through the SMGC, with the western boundary of the suture possibly located between the Garo-Goalpara Hills and Sonapahar areas.     

High-P amphibolite-facies metamorphism in the Adrar–Souttouf Metamafic Complex,Oulad Dlim Massif (West African Craton margin,Morocco)

The Oulad Dlim Massif represents the northern segment of the Mauritanide belt that thrusts over the western margin of the Reguibat Shield, north of the West African Craton (WAC). This belt includes various metamorphic units of Archean, Neoproterozoic and Palaeozoic ages that were stacked and thrust eastward during the Variscan orogeny. The core of the Oulad Dlim Massif comprises the Adrar–Souttouf Metamafic Complex that represents a large tectonic unit made of high-grade mafic rocks and vast exposures of amphibolites. A characterisation of the metamorphism in these amphibolites is essential to understand the relationships of the Oulad Dlim Massif with the southern segments of the Mauritanide belt and to provide constraints on the geodynamic evolution of the western margin of the WAC. Here we determine the P–T conditions of metamorphism of two samples of garnet amphibolites collected at the northernmost end of the Adrar–Souttouf Metamafic Complex. The samples show a main mineral assemblage of garnet + low-Ti pargasite + oligoclase + phengite + epidote + quartz + rutile ± paragonite ± K-feldspar. We calculated their P–T conditions using the amphibole–plagioclase NaSi–CaAl exchange thermometer, and the garnet–amphibole–plagioclase–quartz and the amphibole–plagioclase Si–Al partitioning barometers. The thermobarometric results indicate that this mineral assemblage was formed at high-P amphibolite-facies conditions at 650–700 °C and 10–13 kbar. The observed stability of paragonite and phengite reveals fluid-absent conditions or the presence of a fluid phase with reduced H₂O activity during the peak of metamorphism. We found no relicts of eclogite-facies mineral assemblage in the garnet amphibolites. This contrasts with the eclogite-facies metamorphism found due south in the Tarf Magneïna unit. This suggests that the northernmost end of the Adrar–Souttouf Metamafic Complex may have been buried to shallower depths than the units further south, probably during the Variscan orogeny. However, precise absolute radiometric dating of the high-P amphibolite-facies metamorphism is required to confirm these findings.     

Metamorphic peak conditions of eclogites in the Tauern Window,Eastern Alps,Austria: Thermobarometry of the assemblage garnet + omphacite + phengite + kyanite + quartz

Metamorphic peak P–T conditions of five kyanite eclogites from the Tauern Window, Austria, are evaluated on the basis of recent calibrations of the assemblage garnet + omphacite + phengite + kyanite + quartz. Results are about 25 kbar, 630 °C according to the dataset of Holland and Powell [Holland, T.J.B., Powell, R., 1998. An internally consistent thermodynamic data set for phases of petrological interest. Journal of Metamorphic Geology 16, 309–343 (updated 2002)]. Mostly higher P–T values are calculated with the calibrations of Krogh Ravna and Terry [Krogh Ravna, E.J., Terry, M.P., 2004. Geothermobarometry of UHP and HP eclogites and schists—an evaluation of equilibria among garnet–clinopyroxene–kyanite–phengitecoesite/quartz. Journal of Metamorphic Geology 22, 579–592] and Brandelik and Massonne [Brandelik, A., Massonne, H.-J., 2004. PTGIBBS—an EXCEL Visual Basic program for computing and visualizing thermodynamic functions and equilibria of rock forming minerals. Computers and Geosciences 30, 909–923], in part already in the stability field of coesite. However, no indications for this phase are evident from the Tauern samples. The presence of talc is consistent with these P–T values and high H₂O activities. In contrast, the stability limits of paragonite and zoisite are situated at lower pressure and suggest a later formation during the decompression stage. THERMOCALC pseudosections in the NCFMASH system are constructed with the incorporation of fractional crystallization of garnet. Calculated garnet zonations are in better agreement with the observed compositions at peak pressures of about 25 kbar than results at lower pressures. This is also consistent with values from thermobarometry obtained with the same program.