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1.
The late Early Permian (273 – 271 Ma) Wandrawandian Siltstone in the southern Sydney Basin of New South Wales represents a marine highstand that can be correlated over 2000 km. A mainly fine-grained terrigenous clastic succession, the Wandrawandian Siltstone contains evidence for cold, possibly glacial conditions based on the presence of outsized clasts and glendonites, mineral pseudomorphs after ikaite, a mineral that forms in cold (0 – 7°C) marine sediments. A lithostratigraphic and facies analysis of the unit was conducted, based on extensive coastal outcrops and continuous drillcores. Eight facies associations were identified: (i) siltstone; (ii) siltstone with minor interbedded sandstone; (iii) interbedded tabular sandstone and siltstone; (iv) admixed sandstone and siltstone to medium-grained sandstone; (v) discrete, discontinuous sandstone intervals; (vi) chaotic conglomerate and sandstone in large channel forms; (vii) chaotically bedded and pervasively soft-sediment-deformed intervals; and (viii) tuffaceous siltstone and claystone. Using lithology and ichnology, relative water depths were ascribed to each facies association. Based on these associations, the unit was divided into five informal members that reveal a history of significant relative sea-level fluctuations throughout the formation: member I, interbedded/admixed sandstone and siltstone; member II, siltstone; member III, slumped masses of members I and II; member IV, siltstone and erosionally based lensoid sandstone beds and channel bodies; and member V, interbedded/admixed sandstone and siltstone with abundant tuffs. Member I marks an initial marine transgression from shoreface to offshore depths. Member II records the maximum water depth of the shelf. Member III is interpreted to be a slump sheet; plausible mechanisms for its emplacement include seismicity produced by tectonism or glacio-isostatic rebound, changes in pore-water pressures due to sea-level fluctuations, or an increase in sedimentation rates. Members IV and V record minor fluctuations in depositional environments from offshore to shoreface water depths. Member IV includes regionally extensive, large channel bodies, with composite fills that are interpreted as storm-influenced mass-flow deposits. Member V includes a greater abundance of volcanic ash. Glacial controls (isostasy, eustasy) and tectonic affects may have worked in concert to produce the changes in depositional environments observed in the Wandrawandian Siltstone.  相似文献   

2.
Strong negative cerium anomalies are developed in the saprolite zone of two serpentinite lateritic profiles in the Mada region of the Kongo–Nkamouma massif in the Lomié ultramafic complex (South-East Cameroon).The total lanthanide contents increase strongly from the parent rock (1.328 ppm) to the weathered materials (ranging from 74.32 to 742.18 ppm); the highest value is observed in the black nodules from the western weathering profile and the lowest one in the top of the clayey surface soil from the same profile. The lanthanide contents, except cerium, are highest in the saprolite and decrease along the profile. The light REE contents are very high compared to those of the heavy REE (LREE/HREE ranging from 3.21 to 44.37). The lanthanides normalized with respect to the parent rock reveal: (i) strong negative Ce anomalies with [Ce/Ce1] ranging from 0.006 to 0.680 in the saprolite zone; (ii) strong positive Ce anomalies with [Ce/Ce1] ranging from 1.23 to 23.96 from the top of the saprolite to the clayey surface horizon; (iii) positive Eu anomalies with [Eu/Eu1] ranging from 2.09 to 2.41 in all the weathered materials.Mass balance evaluation shows that, except cerium, lanthanides have been highly accumulated in the saprolite zone and moderately concentrated in the upper part of both profiles. Cerium has been highly accumulated in the nodules of the West Mada profile. The presence of negative Ce anomalies is confirmed by its low degree of accumulation whereas the positive ones are related to its high degree of accumulation.  相似文献   

3.
The Mammoth Peak sheeted intrusive complex formed in the interior of a ~7–10 km deep magma chamber, specifically in the Half Dome granodiorite of the Tuolumne batholith, central Sierra Nevada, CA (USA). The sheets consist of fractionated melts with accumulated hornblende, biotite, magnetite, titanite, apatite, and zircon. The accumulation, especially of titanite, had a profound effect on minor and trace elements (Nb, Ta, Ti, REE, U, Th, P, Zr, Hf, etc.), increasing their contents up to five to six times. Our thermal–mechanical modeling using the finite element method shows that cooling-generated tensile stresses resulted in the inward propagation of two perpendicular sets of dilational cracks in the host granodiorite. We interpret the sheeted complex to have formed by a crack-seal mechanism in a high strength, crystal-rich mush, whereby outward younging pulses of fractionated magma were injected into these syn-magmatic cracks at the margin of an active magma chamber. Thermal–mechanical instabilities developed after the assembly of the sheeted complex, which was then overprinted by late ~NW–SE magmatic foliation. This case example provides a cautionary note regarding the interpretation that sheeted zones in large granitoid plutons imply a diking mechanism of growth because the sheeted/dike complexes in plutons (1) may display inverse growth directions from the growth of the overall intrusive sequence; (2) need not record initial chamber construction and instead may reflect late pulsing of magma within an already constructed magma chamber; (3) have an overprinting magmatic fabric indicating the continued presence of melt after construction of sheeted complexes and thus a prolonged thermal history as compared to dikes; and (4) because the scale of the observed sheeted complexes may be small (<1%) in comparison to large homogenous parts of plutons, in which there is no evidence for sheeting or diking. Thus, where extensive dike complexes in plutons are absent, such as in much of the Tuolumne batholith, the application of an incremental diking model to explain chamber construction is at best speculative.  相似文献   

4.
The behaviour of PGE in a rainforest ecosystem were investigated in four lateritic profiles (Nkamouna, Napene, West and East Mada) developed on serpentinites in the Kongo–Nkamouna massif (Lomié region, South-East Cameroon). In serpentinites, the total PGE content attains 22 ppb whilst it ranges between 26 and 200 ppb in the weathering blanket. Amongst the analyzed elements (platinum, iridium, ruthenium, rhodium, palladium), platinum and ruthenium contents are high in the saprolite zone and in the hardened materials of some weathering profiles (40–66 ppb for platinum, 50–71 ppb for ruthenium). Apart from the hardened materials, the total PGE content decreases from the coarse saprolite towards the clayey surface soil. The Fe2O3-PGE diagram indicates a relatively similar behaviour in these iron-rich samples. The Pt–Ir, Pt–Pd, Pt–Ru, Pt–Rh diagrams portray positive correlations between platinum and other PGE. This fact is supported by the positive correlation noticed between IPGE and PPGE. The Pt/Ir, Pt/Pd, Pt/Ru and Pt/Rh values indicate that iridium, palladium, ruthenium and rhodium are more mobile than platinum. These data confirm the mobility of PGE in laterites and the positive correlation reveals that PGE might be accommodated in the interfaces of iron oxides. The mass balance assessment shows that PGE are strongly leached from the Kongo–Nkamouna weathering blanket except in the coarse saprolite of the Nkamouna profile.  相似文献   

5.
Fossil pollen data from China indicate continued forest decline during the mid‐ to late Holocene in most regions north of the Yangtze River. The earliest forest decline can be detected ca. 5000 yr BP in the middle and lower Yellow River regions. North, northeast and northwest from this region, forest decline became progressively later, and almost no decline took place in the northernmost part of northeast China and in the remote areas of west China during the last 5000 yr. Climate changes could hardly account for the temporal and spatial patterns of the forest decline. Instead, anthropogenic disturbance may have been of overwhelming importance. Ancient agriculture and high‐density settlement expanded outward from the middle and lower Yellow River regions in similar patterns to those of forest change. This study also indicates that land‐use and land‐cover changes may have started in the early stage of Chinese civilization in an extensive area of the country. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

6.
How late are K-feldspar megacrysts in granites?   总被引:1,自引:0,他引:1  
R.H. Vernon  S.R. Paterson 《Lithos》2008,104(1-4):327-336
Various petrologists have suggested that K-feldspar megacrysts grow in granites that are extensively crystallized, even at subsolidus conditions. However, experimental evidence indicates that, though K-feldspar nucleates relatively late in the crystallization history, abundant liquid is available for development of large crystals. A great deal of evidence, involving many different factors, favours a magmatic/phenocrystic origin for K-feldspar megacrysts in granites, namely simple twinning, oscillatory zoning, euhedral plagioclase inclusions, and concentric, crystallographically controlled arrangements of inclusions. In addition, abundant evidence has been presented of (1) mechanical accumulation of K-feldspar megacrysts in granites, (2) alignment of megacrysts and megacryst concentrations in magmatic flow foliations, (3) involvement of megacrysts in zones of magma mixing in granite plutons, and (4) occurrence of megacrysts in some volcanic rocks, implying that the megacrysts were suspended in enough liquid to be moved without fracturing or plastic deformation. Detailed trace element and isotopic data also indicate that megacrysts can move between coexisting felsic and more mafic magmas. Irregular overgrowths on megacrysts are consistent with continued magmatic growth after euhedral megacrystic growth ceased, the overgrowths being impeded by simultaneously crystallizing quartz and feldspar grains.  相似文献   

7.
This paper provides a record and analysis of a site in east-midland England, at which organic and soil material are found between two Middle Pleistocene tills. This is the first discovery of its kind in the area, and demonstrates unequivocally that the region was glaciated on two separate occasions, something that has long been inferred and articulated, but not actually demonstrated. The landforms, sediments and soils are studied with respect to their geomorphological, lithological, pedological, palaeobotanical and structural properties. The organic and soil material along with soil structures indicate, sequentially, a periglacial climate, a long period of warm temperate weathering and a cool temperate climate. Evaluation of this evidence in terms of existing published work identifies a number of problems with existing models and suggests that the most likely model for the glacial history of this part of midland England is an early Middle Pleistocene glaciation which is represented only by trace erratics, a Marine Isotope Stage (MIS) 12 age glaciation which moved across the area from the NW and deposited a chalk-free till, and an MIS 8 age glaciation that transported and deposited an upper chalky till from the NE. © 2021 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.  相似文献   

8.
40Ar/39Ar geochronological data on hornblende, biotite and K-feldspar provide constraints on the cooling path experienced by a high-grade metamorphic complex from the Mühlig–Hofmannfjella and Filchnerfjella (6–8°E), central Dronning Maud Land, Antarctica, during the late Neoproterozoic-early Palaeozoic Pan–African orogeny. Hornblende ages yield c. 481 Ma, biotite ages range from c. 466 Ma to c. 435 Ma, whereas K-feldspar ages of the gneisses are c. 437 Ma. The 40Ar/39Ar data suggest initial cooling at a rate of ~10 °C/Myr between 481 and 465 Ma, followed by a lower cooling rate of ~6 °C/Myr during the subsequent c. 30 million years. The K-feldspar 40Ar/39Ar ages place a lower time limit on the duration of the exhumation, by the time of thermal relaxation to a stable continental geotherm. The 40Ar/39Ar data reflecting cooling indicate tectonic exhumation related to orogenic collapse during a later phase of the Pan–African orogeny.  相似文献   

9.
The estuarine and coastal systems play an important role in sedimentary deposition which acts as a sink of particle-associated contaminants (PACs) such as heavy metals and polycyclic aromatic hydrocarbons. These pollutants are supposed to be harmful to biota in aquatic systems by their persistence, bio-accumulation and toxicity. Therefore, it is needed to understand how anthropogenic activities change the concentrations of potential contaminants in the aquatic environment. In addition, chronologies of metal concentrations can be constructed by ^137Cs and ^210Pbex in dated core sediments. In the present work, the concentrations of the heavy metals As, Cd, Cr, Pb, Cu, Zn, Co, Fe, and Mn were measured in sediment cores collected from four stations (W0, W2, W6, W9) around the Guangdong Nuclear Power Station (GNPS) at the Daya Bay (China). Methods: after dissolved by mixed mineral acids, the concentrations of heavy metals were determined by PE AAnalysit-700 atomic absorption spectroscopy. The composition of total organic mater (TOC) and total nitrogen (TN) was also evaluated by elemental analysis instruments (CHN-O-RAPID, Heraeus, Germany). Activities of ^210Pbex and ^137Cs were determined on a Gamma-ray spectrometer (EG & G ORTEC ADCAM-2000, P-type, relative efficiency 35%). Results and discussion: the experimental data showed that the average values of heavy metals are 18.6, 0.035, 32.9, 38.1, 10.6, 74.9, 4.1, 29100 and 543 mg/kg for As, Cd, Cr, Pb, Cu, Zn, Co, Fe and Mn, respectively, which are obviously larger than the background abundances of those heavy metals in sediment cores.  相似文献   

10.
This study focuses on two Mediterranean oligotrophic high mountain lakes located in the Sierra Nevada National Park (southern Spain): Río Seco (RS) and La Caldera (LC). A combination of field measurements and laboratory experiments is used: (i) to quantify in situ settling fluxes; (ii) to study the soluble reactive phosphorus (SRP) release or uptake by settling and resuspended particles; and (iii) to discriminate between the biotic and abiotic contribution for such patterns. In general, all suspensions (lake water untreated and lake water enriched with settling and with resuspended matter) in both study lakes release significantly more SRP to the solution when biological activity was suppressed. Biological uptake from settling and resuspended matter is likely to be limited by the bacterial consumption of P. Despite of these similarities, this study has revealed notable differences in the effect of sediment resuspension on SRP dynamics in both study lakes, when simulating natural conditions (biotic and abiotic processes). While in LC, the enrichment of lake water with settling and with resuspended matter did not cause an increase in SRP concentrations in lake water, SRP concentrations in RS at the end of the experiment were significantly higher (probability P < 0.05) in lake water enriched with resuspended matter (3.2 μg/l) than in natural lake water (lower than the detection limit). Accordingly, it is reasonable to expect that sediment resuspension, which occurs more frequently in RS compared with LC, affects drastically the SRP availability in the water column in RS.  相似文献   

11.
All the geological constraints for an exhaustive reconstruction of the Triassic to Tertiary tectonic history of the southern Dinaric-Hellenic belt can be found in Albania and Greece. This article aims to schematically reconstruct this long tectonic evolution primarily based on a detailed analysis of the tectonic setting, the stratigraphy, the geochemistry, and the age of the ophiolites. In contrast to what was previously reported in the literature, we propose a new subdivision on a regional scale of the ophiolite complexes cropping out in Albania and Greece. This new subdivision includes six types of ophiolite occurrences, each corresponding to different tectonic units derived from a single obducted sheet. These units are represented by: (1) sub-ophiolite mélange, (2) Triassic ocean-floor ophiolites, (3) metamorphic soles, (4) Jurassic fore-arc ophiolites, (5) Jurassic intra-oceanic-arc ophiolites, and (6) Jurassic back-arc basin ophiolites. The overall features of these ophiolites are coherent with the existence of a single, though composite, oceanic basin located east of the Adria/Pelagonian continental margin. This oceanic basin was originated during the Middle Triassic and was subsequently (Early Jurassic) affected by an east-dipping intra-oceanic subduction. This subduction was responsible for the birth of intra-oceanic-arc and back-arc oceanic basins separated by a continental volcanic arc during the Early to Middle Jurassic. From the uppermost Middle Jurassic to the Early Cretaceous, an obduction developed, during which the ophiolites were thrust westwards firstly onto the neighboring oceanic lithosphere and then onto the Adria margin.  相似文献   

12.
High sedimentation rates (up to 12 cm/kyear) of laminated organic carbon-rich biogenic limestones in the Tarfaya Basin provide an unusually high (millennial) resolution record of the late Cenomanian oceanic anoxic event (OAE-2). The global positive carbon-isotope excursion across the Cenomanian–Turonian corresponds to 11 light/dark sedimentary cycles. We interpret these cycles as a response to orbital obliquity variation and estimate the duration of the complete excursion as 440 kyear or one long eccentricity cycle. On this timescale, the main increase in 13C values occurred over a short time interval of less than 20 kyear in the late Cenomanian and reached a first maximum approximately 15 kyear prior to the bulk (mainly coccoliths) 18O-derived sea surface maximum temperature that occurs coeval to the extinction of Rotalipora cushmani. Organic carbon-accumulation rates follow obliquity cycles, reaching a maximum approximately 10 kyear after the last occurrence of R. cushmani, then slowly decreasing during the early Turonian. Thus, the maximum temperature and the maximum organic carbon accumulation in the Tarfaya Basin lagged by at least 15 kyear behind the global carbon-isotope shift and a proposed reduction of atmospheric CO2 content. The climate change across the Cenomanian/Turonian boundary probably occurred independent of CO2 levels and may have been controlled by different greenhouse gases (water vapour and methane) and changes in ocean circulation (i.e., opening of the Equatorial Atlantic gateway)  相似文献   

13.
The final assembly of Gondwana, known as the late Pan-African orogeny, is characterized by Ediacaran–early Cambrian ultrahigh temperature (UHT) metamorphism, which is widely identified within reconstructed East Gondwana. This distinctive feature likely provides a reliable criterion for identifying new Gondwanan terranes that lack paleo-geomagnetic data. Here we present zircon U–Pb geochronology and phase equilibria calculations for a variety of granulite types newly recognized from western Qaidam, China, which provide the first evidence that the Qaidam block, at least western Qaidam, experienced high-grade metamorphism in excess of 900 °C before/at 540–520 Ma. These UHT metamorphic rocks, similar to many well-known Pan-African UHT metamorphic terranes, is inferred to evolve along a clockwise PT path that is usually related to collisional orogens. Comparison between new metamorphic zircon U–Pb ages from western Qaidam and the published age data from the UHT metamorphic terranes within East Gondwana suggests that the UHT metamorphic rocks found in western Qaidam similarly records the final assembly of Gondwana. Although the exact paleo-geographical location of the Qaidam block during the Gondwana period is unknown yet because of lacking paleo-geomagnetic data, new Pan-African UHT metamorphic record found in western Qaidam indicates, for the first time, that the Qaidam block is a Gondwanan terrane that split from this semi-supercontinent after the Pan-African orogeny.  相似文献   

14.
Increased interest in paleoenvironmental studies is a result of climatic changes occurring at present and predicted for the future. Such studies could be done using the stable isotope compositions (δ2H and δ18O) of kaolins, which provide knowledge on the paleoenvironmental conditions prevailing during the time of kaolinisation. In this study, the stable isotopic compositions of clay-size fraction of kaolins occurring in Cretaceous and Tertiary Formations of the Douala Sub-Basin in Cameroon are presented, with the aim of reconstructing the paleoenvironmental conditions of the Sub-Basin. To achieve this, the clay-size fraction (< 2 μm fraction) of 8 kaolinite-rich samples were analysed for their δ2H and δ18O compositions, and results were reported as part per mil (‰) relative to the SMOW standard. The δ18O values of kaolins found in the Cretaceous–Tertiary Formations of the Douala Sub-Basin varied between +18.2 and +21.0‰, whereas the δ2H values varied between –69 and –53‰. Nine of the eleven samples plotted on the right of the supergene–hypogene line. Five of these nine samples plotted very close to the kaolinite line, which represents the composition of kaolinite in equilibrium with meteoric water at 20 °C; suggesting a supergene weathering origin of these kaolins. The determination of the temperature of kaolinisation yielded mean formation temperatures of 22 ± 2 °C and 27 ± 6 °C for Cretaceous and Tertiary kaolins, respectively. Excluding the two samples falling in the hypogene field, averages of kaolinisation temperatures were 20 and 25 °C during the Cretaceous and Tertiary periods, respectively. These temperatures are slightly below the present mean annual temperature in Douala (27 °C), thereby suggesting that the climate was becoming warmer from the Cretaceous to the Present. Therefore, Douala had a cooler and rainy climate during the Cretaceous, and the climate is gradually becoming hotter and more humid, favouring the refinement of existing kaolins and the kaolinisation of kaolin-forming minerals in the Sub-Basin.  相似文献   

15.
Holocene paleoenvironmental changes have been interpreted on the basis of benthic foraminifera and calcareous nannofossils recovered in samples from Napostá Grande Stream, Bahía Blanca estuary, southern Buenos Aires Province. Samples are fine sands and clay sediments from a Holocene outcrop and were studied with quantitative techniques. The benthic foraminiferal assemblage is dominated by Ammonia parkinsoniana, Ammonia tepida, Bolivina pseudoplicata, Bolivina striatula, Bolivina sp., Buccella peruviana, and Elphidium spp. The calcareous nannofossil assemblage recovered is a typical cold-water association, dominated by Calcidiscus leptoporus, Coccolithus pelagicus, Emiliana huxleyi and Gephyrocapsa oceanica. A dendrogram classification by cluster analysis was made for each microfossil group. The results of these analyses were coincident, showing a liaison between changes in the assemblages of benthic foraminifera and calcareous nannofossils. Those results, jointly with the sedimentological information, lead to the identification of three different paleoenvironments along the Napostá N1 site. The lower part of the succession represents an estuarine environment with larger marine connection. The middle part represents a gradual passage to a more restricted estuarine environment, and the upper part represents the establishment of the modern continental fresh-water environment.  相似文献   

16.
17.
《Journal of Structural Geology》1999,21(8-9):1183-1187
Orogenic belts are geometrically complex owing to repeated deformation. Within this complexity, there is evidence that may suggest a common pattern of sequential steeply dipping and gently dipping foliations. Seven possible explanations are presented for the sequential development of these foliations, which can probably be reduced to four of general importance: (1) the passage of thrust sheets over flats and ramps; (2) switching of the maximum and minimum compressive stress orientations during orogenesis; (3) reversal of structural development owing to strong rheological anisotropy; and (4) back-rotation of crenulation hinges during crenulation cleavage development. It is suggested that all four of these reflect fundamental dynamic processes at work to build an orogen, and therefore that sequentially overprinted steeply and gently dipping foliations also reflect such fundamental processes. This illustrates that detailed geometrical analysis at the meso- and microscales can provide valuable input to dynamic models of orogenesis.  相似文献   

18.
International trade of discarded electronics (e-waste) has become a matter of concern over the last decade because of the actual and potential harms associated with their hazardous materials. An initiative under the aegis of the UN called the Best-of-Two-Worlds (Bo2W) philosophy is one solution to the e-waste problem that has gained some traction. Our dual purpose is to examine the ethical grounds of Bo2W and to propose an alternative program for action. We call this alternative ethical electronics repair, reuse, repurposing, and recycling (EER4). To explore the ethical grounds of Bo2W and to articulate EER4 as an alternative, we draw on notions of ethics, technology, and organization developed in science and technology studies (STS) and diverse economies literatures while empirically we explore a mixed methods case study of a small recycling firm in northern Mexico. Conceptually and empirically, our analysis points to a need for a richer imagination of the possibilities for economic action oriented toward managing discarded electronics. More broadly, our findings may act as a reminder that the space between use and discard proliferates the literal and figurative resources for enriching the imagination and enactment of diverse economic possibilities via the action of repair, reuse, repurposing, and recycling.  相似文献   

19.
In the present study, mass movements (landslide and mudslide) bound to a gully located at Mendong, a suburb of Yaoundé in Cameroon were examined using hydrological, geotechnical and geomorphological observations. The data indicate that water is an important causative factor of mass movements in the area studied. In fact, the water flow (waste water and runoff) provokes the saturation of materials at the slope foot. These materials lose their mechanical qualities and some deep ruptures generate landslide. During the rainy season, when the cumulative rainfall is more than 200 mm, these landslides are accompanied by mudslides that generate disturbances on the infrastructure situated around the gully and farther downstream. The economic and environmental damages resulting from the Mendong mass movements are considerable, such as degradation of the topography, losses in farm land, transportation and downstream sedimentation in a pond situated at the slope foot, loss of life and damage to the economy. All this calls for a multidisciplinary and integrated approach to hazard assessment and risk mitigation, which included data collection and interpretation, growing public and authority awareness, and preventing or reducing runoff and waste water flows by proper management and drainage.  相似文献   

20.
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