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1.
鲁西平邑归来庄金矿床成矿流体研究   总被引:6,自引:0,他引:6  
对鲁西平邑地区归来庄金矿成矿晚阶段蚀变矿物方解石的流体包裹体和稳定同位素进行了详细的研究后发现:保存于方解石脉中的包裹体均为气液两相盐水溶液,均一温度在110℃~250℃之间,冰点变化于-2.8℃~-9.3℃之间,对应的盐度在4.65%~13.18%之间。同位素研究结果显示:矿床的δ^34S值介于-0.71‰~2.990‰之间,δ^13CPDB值为-3.3‰~0.0‰,δDSMOW为-48‰~-61‰,δ^18O水值在-1.13‰~5.07‰之间。硫同位素研究表明成矿流体来源于地幔,碳、氢、氧同位素则显示有较多的大气降水混入。锆石SHRIMP测年结果暗示归来庄金矿形成于中侏罗世,其成因与角砾岩体的隐爆、流体的减压沸腾和深循环的古大气水混入有关。  相似文献   

2.
攀西大陆槽稀土矿床深源成矿流体的稳定同位素证据   总被引:3,自引:0,他引:3  
万德芳  田世洪 《地球学报》2004,25(2):161-164
通过对大陆槽矿床的成矿流体稳定同位素研究表明,矿体石英中流体包裹体的δD、δ^18O和δ^13C值分别为-87‰、 6.0‰和-8.4‰,矿石(氟碳铈矿)的δ^13C为-8.0‰,矿体萤石中流体包裹体的δD和δ^18O分别为-99‰和-11.6‰。研究表明,矿床的成矿流体应为少量大气降水混合的深源成矿流体,流体包体中和矿石中的碳则可能源自较深的壳幔混熔源区。  相似文献   

3.
陇南的阳山金矿床是中国人民武装警察黄金部队近年来在陕甘川交界地带发现的一个特大型金矿床。该矿床 3 0余件样品的流体包裹体分析结果表明 :1.镜下石英中流体包裹体类型丰富多样。据室温状态下流体包裹体的相态、加热状态下流体包裹体的性状及产出特征 ,鉴别出两种成因类型及九种物理状态类型 ;2 .流体包裹体显微测温结果显示本区的均一温度主要集中在 2 60~ 3 10℃ ,2 2 0~ 2 40℃ ,15 0~ 190℃等三个区间 ,流体组份体系接近于NaCl-H2 O -CO2 体系 ,,成矿流体密度估计在 0 .3 5~ 1.0 2 g·cm- 3之间 ,成矿压力估计小于 1Kbar ,流体包裹体盐度估计在 2 .5~ 6.5wb %NaCl之间 ;3 .从流体包裹体成分分析获得的 pH值在 6.91~ 7.1之间 ,还原参数H4 +CO +H2 /CO2 的摩尔数比值在 0 .0 0 9~ 0 .0 5之间 ,具有浅成中偏碱性和弱还原环境成矿特点 ;4.石英中流体包裹体的δD( -SMOW ) 值在 -92 .4‰~ -62 .9‰之间 ,δ1 8O石英 ( -SMOW ) 值在 -3 .0 9‰~ +0 .41‰之间 ,δ1 8OH2O( -SMOW ) 值在 -12 .13‰~ -8.48‰之间。综合分析认为成矿可能主要与低温热液作用有关。  相似文献   

4.
新疆小热泉子铜(锌)矿床同位素地球化学研究及其意义   总被引:1,自引:0,他引:1  
刘申态 《地质与勘探》2011,47(4):624-632
热泉子铜(锌)矿床位于准噶尔板块与塔里木板块对接带北侧的哈尔力克-大南湖晚古生代陆源岛弧带。通过同位素地球化学研究,石英中δ^18O在6.5‰~10‰之间,校正后石英和闪锌矿中流体的δ^18OH2o为-2.95‰~1.73‰,包裹体中δDH2o为-105‰— -66‰;结合矿区基本地质特征,成矿流体很有可能为次火山热液...  相似文献   

5.
新疆-甘肃北山金矿南带的成矿流体演化和成矿机制   总被引:1,自引:0,他引:1  
刘伟  潘小菲 《岩石学报》2006,22(1):171-188
北山金矿南带是西北5省区规模最大的金矿带。选择北山南带的新金厂、老金厂和小西弓金矿床,在矿床地质和岩相学研究的基础上,对脉石英的流体包裹体进行了显微温度计和激光拉曼探针气体成分测定;对石英和矿石黄铁矿的包裹体H2O,CO2和CH4进行了H和C同位素组成测定,对石英和黄铁矿分别做了O和S同位素组成测定。3个金矿床的脉石英含有富CO2+CH4、H2O溶液以及H2O-CO2+CH4包裹体。小西弓金矿床流体包裹体的均一化温度主要介于270℃-450℃,一部分H2O溶液包裹体圈闭了高盐度流体(16.43—18.63wt.%NaCl equiv.),大部分H2O溶液包裹体和全部富CO2+CH。包裹体代表了中-低盐度(2.8%-13.6%)流体。新金厂金矿床流体包裹体的均一化温度主要介于210℃-346℃;一部分流体包裹体圈闭了高盐度(10.98%~14%NaCl equiv.)流体,一部分H2O溶液包裹体和绝大多数富CO2+CH4包裹体圈闭了中-低盐度(2.9%-8.81%NaCl equiv.)流体。老金厂金矿床H2O溶液包裹体的均一化温度主要分布于141℃-400℃,含盐度介于1.4%-8.28%,属于中-低盐度流体。进行了大气降水-围岩^18O/^16O、D/H交换反应模拟。小西弓矿床早期硫化物-石英脉金矿成矿流体对应较高的水/岩比(=0.01—0.05),其^18O/^16O和D/H组成更受钾长花岗岩者控制,硫化物的δ^34S值也接近钾长花岗岩的黄铁矿者,指示热液流体围绕着钾长花岗岩的对流淋滤。成矿晚期,围绕着花岗岩侵入体的热液对流崩溃,矿区围岩内发育更大尺度的彼此分离的弥漫性流体渗透淋滤;相应地,小西弓矿床晚期蚀变岩金矿成矿流体的8D值对应低水/岩比(0.005-≈0.01),其δ^18O值变化范围较宽,受当地中元古界变质岩控制,蚀变岩型金矿黄铁矿的δ^34S值也接近中元古界长英质片岩的黄铁矿者。新金厂金矿和老金厂金矿成矿流体的δD值和δ^18O值对应的水/岩值分别介于0.004—0.01和0.007~0.02,与岩浆流体或者下二叠统哲斯群辉绿岩和英安岩围岩具有更密切的关系。新金厂金矿和老金厂金矿黄铁矿样品的δ^34S值介于-2.58‰和-6.32‰,指示S来源于下二叠统哲斯群辉绿岩、英安岩和碳质板岩围岩。3个金矿的石英包裹体CO2(δ^13C=-2.20‰--9.14‰),以及石英和黄铁矿包裹体CH4(δ^13C=013.10‰--27.40‰)不平衡;前者来源于幔源岩浆去气,后者来源于哲斯群碳质板岩或者中元古界长英质片岩中的还原碳。3个金矿黄铁矿包裹体的CO(δ^13C=-10.79‰--23.62‰)主要来源于哲斯群碳质板岩或中元古界长英质片岩中的还原碳,但是,也混合了较少的岩浆CO2。包裹体CO2和CH4δ^13C值的系统变化,也反映了从岩浆侵位和去气、流体对流,到围岩中流体大面积弥漫性渗透淋滤的演化过程。CH4介入成矿流体,导致流体不混溶和金的沉淀。北山金矿南带的形成既不同于典型的造山带型金矿床,也不同于与侵入岩有关的金矿床。我们提出北山金矿南带的成矿模式为:岩浆去气和流体对流、岩石挤压破碎、流体弥漫性渗透淋滤。  相似文献   

6.
东海水晶矿床位于苏鲁超高压变质带中,它的成因机制及其与超高压变质作用的关系一直是大家关注的问题。本文运用流体包裹体、硅氧同位素地球化学以及微量元素地球化学,对东海水晶矿床的成因进行了初步研究。结果显示,含晶石英脉中流体包裹体主要有单液相、气液两相以及H2O-CO2流体包裹体,其中以气液两相流体包裹体为主,大小在5~50μm,但在含金红石发晶的水晶中气液两相流体包裹体最大可达300μm。其形成温度可以分为3个区间,即100℃~120℃,160℃~220℃和240℃~260℃;而其盐度也集中于0~2wt%NaCl,4~12wt%NaCl和14~16wt%NaCl三个区间,反映了多期流体的叠加作用。激光拉曼和流体包裹体群成分分析可知,流体包裹体中除了H2O和CO2外,还有N2、CH4、H2S和C2H6等,并且在不同的爆裂温度情况下,流体包裹体所释放的成分有所差别。东海水晶矿床中不合金红石发晶的石英的δ^18O变化范围在-5.6~+4.6‰,δ^34Si变化范围在-0.2~+0.2‰之间;而含金红石发晶的石英的δ^18O变化范围在10.5~14.9‰,δ^34Si变化范围在~0.2~+0.1‰之间。相对来说,与水晶热液作用有关的鳞片状黑云母比斜绿泥石更加富集Nb、Cr、Fe、V、W、Ti和Zr等。本文认为东海水晶矿床的形成在富舍石英的榴辉岩在大陆板块俯冲折返过程中及其以后,由不同时期、不同性质、不同成分流体叠加作用下的结果,而舍金红石发晶的形成则是叠加富Nb、Fe流体的结果。  相似文献   

7.
吉尔吉斯斯坦北天山构造带的矿床学数据缺乏,制约了天山造山带境内外成矿对比。布丘克金矿床位于吉尔吉斯斯坦北天山构造带中部。金矿体为石英复脉,呈带状发育于NWW向韧性剪切带中。矿体倾向SSW,倾角60°~70°,赋矿围岩主要为侵入于早古生代变质碎屑杂岩中的正长斑岩。布丘克金矿床成矿期石英流体包裹体观察、石英H-O同位素、硫化物S同位素测试结果显示,布丘克金矿床石英脉中包裹体大小集中在2~10μm之间,类型以H2O-CO2型、富CO2型、水溶液型包裹体为主,成分以富CO2、含CH4为特征。成矿流体具有中温(200~320℃)、低盐度(3%~7%NaCleqv)特征;石英δDV-SMOW值介于-108.1‰~-90.2‰之间,δ18O流体值介于4.86‰~9.26‰之间;黄铁矿δ34S分布在0‰左右(-0.9‰~1.6‰)。综合本文数据、矿床地质特征、区域地质资料,本文认为布丘...  相似文献   

8.
新疆萨瓦亚尔顿金矿位于西南天山西端,受NNE向脆韧性剪切带控制。对绢云母化蚀变岩进行了^40Ar/^39Ar法年龄测定,表明金主成矿时代为三叠纪。根据黄铁矿流体包裹体氦、氩同位素、石英流体包裹体的碳、氧同位素组成,讨论了萨瓦亚尔顿金矿成矿流体的来源。结果表明石英流体包裹体中δ^18OSMOW变化于14.5100-24.2‰,CO2的δ^CPDB变化范围较大,为-8.69‰~+4.98‰,暗示成矿流体中的碳来源于地幔和海相碳酸盐岩。黄铁矿流体包裹体的^3He/^4He变化较大,为0.04~1.11R/Ra,^40Ar/^36Ar变化较小,介于301~348。综合分析认为萨瓦亚尔顿金矿的成矿流体为地幔流体和地壳流体混合的产物,以地壳流体为主。  相似文献   

9.
甘肃省文县阳山金矿床流体包裹体的地球化学特征   总被引:20,自引:6,他引:20  
甘肃省文县阳山金矿床是近年来在陕甘川交界地带发现的一个产于泥盆系浅变质岩系的特大型金矿床。流体包裹体的系统分析结果表明:(1)镜下石英和方解石中流体包裹体的类型丰富多样。据室温状态下流体包裹体的相态、加热状态下流体包裹体的性状及产出特征,鉴别出2种成因类型及7种物理状态类型;(2)流体包裹体显微测温结果显示本区的均一温度在105~310℃之间,主要集中在260~310℃、220~240℃、150~190℃3个区间,成矿流体组分体系接近于NaCl H2O CO2体系,成矿流体密度估计在0 35~1 02g/cm3之间,成矿压力估计在400×105~800×105Pa之间,流体包裹体盐度估计在2 5%~10 4%NaCl之间;(3)从流体包裹体成分分析获得的pH值为6 91~7 1,还原参数n(CH4+CO+H2)/n(CO2)的摩尔数比值在0 009~0 050之间,表明具有浅成中偏碱性和弱还原环境成矿的特点;(4)石英中流体包裹体的δDSMOW值为-92 4‰~-62 9‰,δ18O石英SMOW值在-3 09‰~+0 41‰之间,δ18OH2OSMOW值在-12 13‰~-8 48‰之间。综合分析认为成矿可能主要与低温热液作用有关。  相似文献   

10.
通过矿床流体包裹体岩相学、显微测温学和包裹体激光拉曼光谱分析研究成矿流体性质,探讨矿床成因类型。研究结果表明,流体包裹体有气液两相、含纯液相和纯气相包裹体3种类型。气相成分以CO2为主,其次为H2O,总体属CH4-H2O-CO2体系;结合氢氧同位素地球化学特征(δD值为-64.1‰~-124.4‰;δ18O值为1.34‰~-6.96‰),确定成矿流体是岩浆热液与大气降水的混合流体。含矿硫(δ34S)指示硫主要为深部岩浆来源,并经历了陆壳硫的混染,包裹体均一温度以240℃~270℃区间为主,属中低温热液矿床。  相似文献   

11.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

12.
本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。  相似文献   

13.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

14.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

15.
Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.  相似文献   

16.
本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。  相似文献   

17.
Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×106 1 of partially treated effluent and about 600 m3 of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.  相似文献   

18.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

19.
滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.  相似文献   

20.
岩石密度和超高压岩石折返速率   总被引:1,自引:3,他引:1  
在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。  相似文献   

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