黄河干流潼关断面非点源污染负荷估算

基于平均浓度法原理,根据黄河中游降雨径流特点,将年内过程分为汛期和非汛期两个阶段,同时将高含沙水流中的污染负荷分为水体中的溶解态污染负荷、泥沙吸附态负荷两部分,提出了多沙河流非点源污染负荷估算模型;根据黄河干流潼关断面1950-2006年实测水沙资料,结合水体、泥沙污染物浓度测定试验,分别计算了潼关断面2006年以及丰水年(P=25%)、平水年(P=50%)、枯水年(P=75%)3种不同代表年型下的非点源污染负荷.结果表明:黄河干流潼关断面年污染负荷以汛期为主,汛期污染负荷以非点源为主;非点源污染负荷中,硝酸盐氮、氨氮以溶解态为主,总磷以吸附态为主;潼关断面非点源污染负荷占全年负荷比例:丰水年时,硝酸盐氮占63.09%,氨氮占61.32%,总氮占87.17%、总磷占89.83%;枯水年时,硝酸盐氮占26.92%,氨氮占24.62%,总氮占67.60%、总磷占71.73%.2006年,硝酸盐氮、氨氮、总氮和总磷非点源污染负荷占全年比例依次为:17%、14%、15%和41%.     

颗粒态氮磷负荷模型研究

为研究妫水河流域的颗粒态氮磷非点源污染来源,以控制非点源污染,在官厅水库周围进行了野外人工降雨试验。试验数据表明,氮磷输移率与产沙率具有很好的相关性,颗粒态氮、磷的平均相关系数分别为0.9594和0.9772。建立了新的颗粒态氮磷负荷模型,其中富集系数等于泥沙中总氮总磷百分含量与土壤中百分含量之比。根据妫水河流域的土壤图、土地利用图及数字高程模型,应用新的模型研究了妫水河流域颗粒态氮磷污染负荷的空间分布。结果表明,颗粒态氮磷主要来自地表植被覆盖差的丘陵和山地。     

基于污染负荷核算的岷江流域总磷污染成因分析及对策

总磷是长江流域水环境污染的首要超标因子,岷江作为长江上游流量最大的支流,总磷污染严重,对长江总磷污染贡献较大。为了解岷江流域总磷污染,采用排污系数法,计算得到2016年岷江流域污染源总磷入河量为1 154 t,以农村生活污染负荷占比最高(51.3%),其次为城镇生活源(28.7%)、农业非点源(8.24%)、工业源(9.57%)、畜禽养殖源(1.21%),城市径流源(0.99%)最低;在空间上岷江流域总磷污染负荷呈中游(64.2%)>下游(32.6%)>上游(3.1%)的特点,与岷江干流总磷浓度变化趋势相符,其中成都市总磷污染负荷最高(51.2%),与区域人口密度高、生产和生活活动密集有关。结合资料收集和现场调查,岷江流域总磷污染成因主要包括农村生活污染治理缺口较大、城镇生活污染处理基础设施建设不足、工业企业密布、部分支流总磷污染严重、水污染治理导向不全面。针对岷江总磷污染负荷分布特征及成因,提出“上游保护优质水体、中游治理重污染水体、下游恢复不达标水体”的分区污染防治对策,统筹流域监管体制机制,强化岷江流域水环境保护和治理。     

太湖水体氮、磷赋存量的逐月变化规律研究

基于中国科学院太湖湖泊生态系统研究站2005~2009年对太湖逐月叶绿素a、氮、磷各形态因子及水深的监测,结合太湖大浦水文站的逐日水位数据,估算出2005~2009年太湖的逐日水量,并运用泰森多边形法,估算出太湖水体总氮（TN）、总磷（TP）、溶解性总氮（TDN）、溶解性总磷（TDP）、硝态氮（NO3）、铵态氮（NH4）、亚硝态氮（NO2）、反应性活性磷（PO₄）、颗粒态总氮（TPN）、颗粒态总磷（TPP）、浮游藻类叶绿素a（Chla）的逐月动态变化过程。结果表明:（1）太湖2005~2009年TN、TDN、NO₂、NO₃、NH₄、TP、TDP、PO₄、TPN、TPP、Chla的平均赋存量分别为1.36×104t、1.02×104t、0.02×104t、0.37×104t、0.25×104t、514.34 t、147.30 t、51.44 t、0.34×104t、367.04 t、7.92 t,不同月份、年际之间变化剧烈,变幅分别为106%、142%、657%、252%、233%、95%、196%、276%、236%、131%、276%;（2）2007年6月无锡贡湖水厂"饮用水危机"事件之后,截止到2009年12月,太湖水体各形态氮及总磷赋存量的下降趋势不明显,溶解性总磷、反应性活性磷的赋存量反而增高,反映出营养盐控制任务的艰巨性。本研究表明,对于年水量变幅巨大的大型湖泊,全湖水体营养盐赋存量在评估水体营养盐污染状况中是一个有价值的指标;对于太湖流域的污染控制效果,仅从浓度角度评价具有一定的缺陷,有必要从水体营养盐赋存量的变化规律上探讨其治理效果。     

千岛湖流域不同土地利用方式对氮和磷流失的影响

从流域尺度研究氮、磷随地表径流的流失是国内外研究的热点.通过研究千岛湖流域降雨径流中总氮(TN)、总磷(TP)、可溶氮(DN)和可溶磷(DP)浓度变化,探讨不同土地利用方式对氮素、磷素流失的影响,结果表明不同土地利用方式下日降雨量与径流水中的总氮、可溶氮、总磷和可溶磷浓度均呈显著正相关;不同土地利用方式下土壤中降雨径流中总氮和总磷浓度变异较大.红薯地和园地等有人工耕种的坡地氮磷流失浓度最大,草地和林地等受人工影响干扰少的土地利用方式氮磷流失浓度相对较少.高坡林地降雨径流中氮磷流失浓度大于缓坡林地,平均DN/TN值和DP/TP值变化较小,分别为0.45和0.22左右.     

江苏固城湖流域1951-2000年农业非点源氮、磷输移的数值模拟研究

选择位于长江下游的固城湖流域作为研究区域,基于分布式流域水文模型SWAT,采用数值模拟的手段,反演了1951～2000年流域农业非点源氮、磷的输移规律。模拟结果与实测值的一致性反映了模型的良好模拟能力。比较两个时段的模拟结果发现,1981～2000年,流域农业非点源氮、磷年平均浓度和输移量分别为:总氮0.82mg/L和411.88×10³kg/a,总磷0.084mg/L和43.04×10³kg/a;远高于1951～1960年的氮、磷年平均浓度和输移量分别为:总氮0.22mg/L和49.55×10³kg/a,总磷0.036mg/L和7.67×10³kg/a。模拟主要反映了流域下垫面条件和农作物耕作模式对农业非点源氮、磷浓度及输移量的影响。     

丹江鹦鹉沟小流域氮素随径流的迁移及对水质的影响

计算小流域非点源氮素流失负荷,并以此开展丹江水源区水体污染源解析和控制研究。基于流域断面及小区监测试验,利用平均浓度法对鹦鹉沟流域氮素年均流失模数和不同土地利用类型的非点源污染负荷进行计算分析。结果表明:径流水质中主要是总氮质量浓度超标,且硝氮质量浓度均大于氨氮质量浓度;当坡耕地坡度大于25°时,氮素流失严重,水质极差;农村生产生活污染物排放对水质有很大影响,从断面1到把口站,硝氮质量浓度和总氮质量浓度增加较大;农地、草地和林地的总氮年均径流流失模数分别为0.36、0.22和0.09t/(a·km2);流域出口非点源污染物氨氮、硝氮和总氮的平均质量浓度分别为0.17,4.71和7.55mg/L,点源污染物氨氮、硝氮和总氮的平均质量浓度分别为0.20、2.12和4.08mg/L。总体来说,鹦鹉沟流域径流中总氮的流失模数为0.89t/(a·km2),总氮是影响水质的主要污染物,需加强对坡耕地氮素流失和农村生活垃圾的治理。     

SWAT模型在大洋河流域非点源污染模拟中的运用研究

基于SWAT模型,以大洋河流域为研究流域,定量模拟了大洋河流域2000-2010年非点源污染,研究结果表明:SWAT模型适合于大洋河流域的非点源污染模拟,模型在参数率定期和验证模拟总氮和总磷相对误差均小于30%,模拟确定性系数达到0.5以上,满足流域非点源污染模拟精度要求;大洋河流域总氮和总磷峰值主要集中在7-9月份。研究成果对于大洋河流域水环境保护和治理提供参考价值。     

天津围海造陆区吹填土氮磷的分布特征

天津临港经济区地处滨海, 完全是由填海造陆形成的人工陆地。土壤是港口航道清淤淤泥、近海海沙吹填围海造陆后形成的吹填土, 其性质特殊, 研究吹填土壤中氮磷空间分布对了解该区域环境状况有重要意义。研究发现:天津临港吹填土整体含氮量较低, 按土层深度分布, 平均质量分数为161.73~240.09 mg/kg;含磷量相对丰富, 平均质量分数为355.54~443.27 mg/kg;总氮变异系数较大, 总磷变异系数较小, 氮、磷质量分数主要受不同区域吹填土性质影响。吹填土中有机磷质量分数较少, 平均仅占总磷的3.83%, 吹填土中磷大多以无机磷形式存在, 其相对质量分数从大到小为:钙结合磷(Ca-P) >铁结合磷(Fe-P) >铝结合磷(Al-P) >闭蓄态磷(Oc-P) >碎屑磷(De-P) >交换态磷(Ex-P)。研究表明, 临港吹填土氮、磷质量分数水平对近海环境有潜在富营养污染威胁。     

海河流域大型水库饮用水水源地水环境安全评价及应用

对水库型水源地水环境安全评价的理论和方法进行研究,构建了基于驱动力-压力-状态-影响-风险模型(DPSIR)的水库型水源地水环境安全评价指标体系,综合评价指标体系包括了降水、污染物入库量、水质状态指标、水质达标率以及水华爆发影响因子5个方案,11项指标。将该指标体系应用于岳城水库水环境安全评价,其结论主要有:(1)该模型的驱动力是降水带入面源污染,压力是流域输入水库的污染负荷,状态指标是TN、TP以及COD_Mn等水质参数,影响指标是水库水质达标率,风险指标则是氮磷比、水温等;(2)岳城水库4、5、6和9月处于较安全状态,但由于受地表径流污染负荷影响,在7、8月处于预警状态。将评价结果与实际水环境安全状况进行比较,吻合程度好,因此该模型可应用于海河流域大型水库饮用水水源地水环境安全评价。     

Modeling impacts of sediment delivery ratio and land management on adsorbed non-point source nitrogen and phosphorus load in a mountainous basin of the Three Gorges reservoir area, China

Agricultural nonpoint source (NPS) pollution at the Three Gorges reservoir area in China has been increasingly recognized as a threat to aquatic environment in recent years due to the serious eutrophication problem. Adsorbed NPS pollution is one of the major forms of NPS pollution in mountainous regions, the essential of the adsorbed NPS pollution is soil loss. Thus, simple, highly sensitive and continuous methods are required to simulate and quantify sediments yield at watershed scales. It is imperative to construct an integrated model to estimate the sediment yield and adsorbed NPS pollution load. According to the characteristics of climate, hydrology, topography, geology, geomorphology and land use types in Three Gorges reservoir area, a GIS-based dynamic-integrated-distributed model of annual adsorbed NPS load was presented in view of impacts of the rainfall intensity, sediment delivery ratio (SDR) and land management, where the temporally dynamic-continuous model of annual sediment yield was established by modifying the revised Universal Soil Loss Equation (RUSLE), and the spatially integrated-distributed model of annual adsorbed NPS load was then developed via the correlation between sediment yield and adsorbed NPS load. Furthermore, a case study of the Jialing River basin in China was applied to validate the integrated model, the dynamic-distributed coupling among GIS technology, sediment yield model, and adsorbed NPS load model was achieved successfully. The simulation results demonstrate the following: (1) runoff and sediment are influenced greatly by rainfall intensity, SDR and vegetation cover; rainfall and land management show high sensitivities to the integrated model; the average annual adsorbed TN and TP pollution loads from 2006 to 2010 decreased by 76 and 74 % compared with the previous treatment (1990), respectively. (2) Spatio-temporal variations of adsorbed NPS nitrogen and phosphorus load are mainly related to different land use types and the background level of nutriments in topsoil; different land use types have different contribution rates; the largest contribution rates of adsorbed total nitrogen (TN, 58.9 %) and total phosphorus (TP, 53 %) loads are both from the dryland cropland. (3) The identification of critical source areas can help to implement the prevention and control measures aiming at the reduction of water environmental pollution. These results will provide useful and valuable information for decision makers and planners to take sustainable land use management and soil conservation measures for the control of sediment pollution in the Three Gorges reservoir area. The application of this model in the catchment shows that the integrated model may be used as a major tool to assess sediment yield risks and adsorbed NPS pollution load at mountainous watersheds.     

Simulation of spatial and temporal distribution on dissolved non-point source nitrogen and phosphorus load in Jialing River Watershed,China

Jialing River, which covers a basin area of 160,000 km² and a length of 1,280 km, is the largest tributary of the catchment area in Three Gorges Reservoir Area, China. In recent years, water quality in the reservoir area section of Jialing River has been degraded due to land use and the rural residential area induced by non-point source pollution. Therefore, the semi-distributed land-use runoff process (SLURP) hydrological model has been introduced and used to simulate the integrated hydrological cycle of the Jialing River Watershed (JRW). A coupling watershed model between the SLURP hydrological model and dissolved non-point source pollution model has been proposed in an attempt to evaluate the potential dissolved non-point source pollution load; it enhances the simulation precision of runoff and pollution load which are both based on the same division of land use types in the watershed. The proposed model has been applied in JRW to simulate the temporal and spatial distribution of the dissolved total nitrogen (DTN) and dissolved total phosphorus (DTP) pollution load for the period 1990–2007. It is shown that both the temporal and spatial distribution of DTN and DTP load are positively correlated to annual rainfall height. Land use is the key factor controlling the distribution of DTN and DTP load. The source compositions of DTN and DTP are different, where average DTN pollution load in descending order is land use 67.2%, livestock and poultry breeding 30.5%, and rural settlements 2.2%; and for DTP, livestock and poultry breeding is 50%, land use 48.8%, and rural settlements 1.2%. The contribution rates of DTN and DTP load in each sub-basin indicate the sensitivity of the results to the temporal and spatial distribution of different pollution sources. These data were of great significance for the prediction and estimation of the future changing trends of dissolved non-point source pollution load carried by rainfall runoff in the JRW and for studies of their transport and influence in the Three Gorges Reservoir.     

Geospatial modeling for assessing the nutrient load of a Himalayan lake

This research makes use of the remote sensing, simulation modeling and field observations to assess the non-point source pollution load of a Himalayan lake from its catchment. The lake catchment, spread over an area of about 11 km², is covered by different land cover types including wasteland (36%), rocky outcrops (30%), agriculture (12%), plantation (12.2%), horticulture (6.2%) and built-up (3.1%) The GIS-based distributed modeling approach employed relied on the use of geospatial data sets for simulating runoff, sediment, and nutrient (N and P) loadings from a watershed, given variable-size source areas, on a continuous basis using daily time steps for weather data and water balance calculations. The model simulations showed that the highest amount of nutrient loadings are observed during wet season in the month of March (905.65 kg of dissolved N, 10 kg of dissolved P, 10,386.81 kg of total N and 2,381.89 kg of total P). During the wet season, the runoff being the highest, almost all the excess soil nutrients that are trapped in the soil are easily flushed out and thus contribute to higher nutrient loading into the lake during this time period. The 11-year simulations (1994–2004) showed that the main source areas of nutrient pollution are agriculture lands and wastelands. On an average basis, the source areas generated about 3,969.66 kg/year of total nitrogen and 817.25 kg/year of total phosphorous. Nash–Sutcliffe coefficients of correlation between the daily observed and predicted nutrient load ranged in value from 0.80 to 0.91 for both nitrogen and phosphorus.     

塔里木河干流上游中、下段河床淤积和耗水对生态环境的影响

塔里木河干流上游中、下段河床一直呈淤积状态, 新渠满站1965-2007年总淤积厚度达120 cm, 平均年淤积3.0 cm. 其中: 1965-1990年25 a淤积50 cm, 年均淤积2.0 cm, 1991-2007年17 a中河床淤积加快, 总淤积70 cm, 年均淤积4.7 cm. 由于河床淤积, 河道行洪断面缩水, 洪水漫溢不断增大, 导致上游段耗水量呈不断增加趋势, 2001年起上游段己成为干流最大的耗水区. 阿克苏河、和田河和叶尔羌河3条源流出山口多年平均年输沙量为6310×10~4t, 进入塔里木河干流龙头站--阿拉尔站多年平均年输沙量为2050×10~4t, 干流上游段多年平均年泥沙淤积量为1462×10~4t, 占塔里木河阿拉尔站多年平均年输沙量的71.3%, 是干流最大的泥沙淤积区, 也是现今最大的洪水漫溢区和耗水区. 塔里木河干流上、中、 下游各水文点年输沙量呈急剧減少趋势, 泥沙淤积河道主要是上游段的沙雅二牧场至英巴扎318 km河段. 塔里木河上游段河长495 km, 多年平均区间耗水量14.48×10~8m~3, 占阿拉尔站多年径流量的31.5%;中游河长398 km, 多年平均区间耗水量24.84×10~8m~3, 占阿拉尔站年径流量的54.0%;下游河长428 km, 多年平均区耗水量6.68×10~8m~3, 占阿拉尔站年径流量的 14.5%. 上、 中游段多年平均区间耗水量39.32×10~8m~3, 占阿拉尔站年径流量的85.5%. 上游耗水量从2001年起成为塔里木河干流最大的耗水区, 导致2002、 2005和2006年上、中游耗水量达到50.0×10~8m~3, 占阿拉尔站年径流量的88%, 成为历史最大值.     

Integration of monthly water balance modeling and nutrient load estimation in an agricultural catchment

Non-point sources pollution has become a serious environmental problem in the aquatic systems throughout the world. The Xitiaoxi catchment is located in the southwest of Taihu Basin, contributing large amounts of runoff and associated nutrients to Taihu Lake. Thus, identifying critical non-point sources pollution in this catchment is urgent and essential to control water pollution, improve the water quality, and reduce the pollutants drained into water bodies. The present study integrated a monthly water balance model with the export coefficient model for total nitrogen and total phosphorus loads estimation in the Xitiaoxi catchment in southeastern China. The simulated monthly runoff are in good agreement with the observed streamflow at both Hengtangcun and Fanjiancun stations with Nash?CSutcliffe coefficients higher than 0.80. The predictions showed reasonable ranges from 1687 to 2046?t/y (2002?C2005) for total nitrogen loads, and from 106 to 157?t/y for total phosphorus loads (1999?C2007), respectively, which are consistent with the observed values at Hengtangcun. Overall, the monthly export coefficient model coupling monthly water balance simulation to export coefficient model presented both the seasonal dynamics and magnitude for streamflow and nutrients loads, which generally match well with the observations. These findings demonstrate that the proposed model can provide encouraging results and can be used as an efficient tool to identify the pollution sources for planning and management of large-scale agricultural catchment.     

黄河流域近期水沙变化及其趋势预测

针对黄河水沙近期发生显著变化的现象,利用黄河上中游干支流水文泥沙定位观测资料,综合"水文法"、"水保法"和数学模拟等多种方法,对黄河流域1997-2006年水沙变化情势进行了评估,分析了水沙变化机制,并预测了未来的变化趋势。分析表明,与多年平均相比,黄河河源区径流量年均减少43.90亿m3,其中降雨等自然因素的影响量占92.26%,人类活动影响量占7.74%;与1970年前相比,黄河实测径流量年均减少112.1亿m3,其中水利水土保持综合治理等人类活动作用占76.50%,因降雨影响占23.50%;实测输沙量较1970年以前年均减少11.80亿t,其中水利水土保持综合治理等人类活动的作用为49.75%,降雨的影响为50.25%;人类活动与降雨变化对水沙变化的影响差异较大,就黄河中游地区总体而言,人类活动的减水作用远大于降雨的影响,人类活动的减沙作用与降雨影响基本相当,不宜笼统说黄河中游水沙变化主要是人类活动所致或主要是降雨变化所致; 2050年以前黄河来水来沙量总体呈平偏枯趋势,但不排除个别年份或短时段仍会发生丰水丰沙的可能性。     

土壤与养分流失综合监测方法在密云水库流域的应用

土壤与养分流失综合监测方法是根据通用流失方程的基本原理,在对我国中东部南北不同环境条件下大量周年实测数据的统计、分析基础上建立的适合我国南北地区的水土流失与面源污染一体化定量监测方法。本研究采用该方法对密云水库流域2001年度的土壤和氮素养分流失的空间分布,不同土地利用方式对土壤和氮素养分流失的影响,以及泥沙、养分的入库量进行了系统的监测,且利用水文站的实测数据对监测结果进行检验。结果显示,该监测方法对土壤和氮素流失监测的相对误差分别为2.75%~19.63%和-18.78%,监测效果较好。该监测方法具有技术先进、方便、实用、可更新性强和效果好的诸多特点,在我国现有相关资料积累条件下,适用范围较广。随着相关研究的进一步深入,该监测方法可通过改进满足更高时空监测需求,具有较好的应用前景。     

1956—2008年鄱阳湖流域水沙输移趋势及成因分析

利用鄱阳湖流域代表性水文站1956—2008年实测年径流量及年输沙量资料序列,采用Mann-Kendall秩相关检验法,研究鄱阳湖流域水沙量年际变化趋势和可能发生突变的时间,并从流域降雨、用水、水库拦沙、水土流失及其治理等方面分析了鄱阳湖流域水沙变化的主要影响因素。研究结果表明:鄱阳湖地区来水量和出湖水量有小幅增大趋势;鄱阳湖流域来沙量呈异常显著减小趋势,发生突变的年份为1998—1999年;实测出湖沙量从2002年开始呈明显的减少趋势。通过对有关影响因素的研究,发现鄱阳湖流域气候变化降雨量减少对近10年鄱阳湖出入湖径流量的减少影响显著;水库滞沙是鄱阳湖入湖沙量减少的主要原因;出湖沙量变化主要受上游水库群的影响,还有近年湖区采砂的影响。     

三峡库区低等级土质道路侵蚀研究

以三峡库区界垭小流域内不同交通荷载土质道路为研究对象,通过自然降雨观测研究其侵蚀规律和污染物流失特征。研究结果表明,交通荷载大的干道产流率和侵蚀率均高于交通荷载低的支道,对产流率影响显著的因子主要为降雨量,对产沙率影响显著的因子为降雨量、雨强。雨型对污染物的流失特征影响显著,前期集中型降雨下,污染物流失过程线与降雨过程线同步性较好,泥沙、总氮、铵态氮、泥沙结合态磷和溶解态磷均发生了较强的初始冲刷效应;中期集中型降雨下,污染物流失浓度峰值优先于雨强峰值,且氮和磷等初始冲刷强度低于前期集中型降雨,泥沙无初始冲刷效应。