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1.
ABSTRACT
The mineralogy and isotope geochemistry of carbonate minerals in the Coorong area are determined by the water chemistry of different depositional environments ranging from seawater to evaporitically modified continental water. The different isotopic compositions of coexisting calcite and dolomite suggest that each of the above two minerals was formed from water of composition and origin unique to that specific mineral. In addition, the dolomite was not formed by simple solid state cation exchange.
The occurrence of two types of dolomite was shown by isotope analysis and SEM observations. The dolomite, which is isotopically light (δ13 C = -1 to -2% 0 ; δ18 O=+3 to +5%0 ) and of fine grain size (˜ 0·5 μm) probably precipitated under the influence of evaporitically modified continental water. Coarser grained dolomite (up to 4 μm) is isotopically heavier (δ13 C=+3 to +4%0 ; δ18 O=+5 to + 6%0 ) contains Mg in excess of Ca and was formed in or close to equilibrium with atmospheric CO2 probably by the dolomitization of aragonite. 相似文献
The mineralogy and isotope geochemistry of carbonate minerals in the Coorong area are determined by the water chemistry of different depositional environments ranging from seawater to evaporitically modified continental water. The different isotopic compositions of coexisting calcite and dolomite suggest that each of the above two minerals was formed from water of composition and origin unique to that specific mineral. In addition, the dolomite was not formed by simple solid state cation exchange.
The occurrence of two types of dolomite was shown by isotope analysis and SEM observations. The dolomite, which is isotopically light (δ
2.
Danuta Peryt Krystyna Wyrwicka Charles Orth Moses Attrep Jr Leonard R. Quintana 《地学学报》1994,6(2):158-165
Two sections of the Upper Cenomanian and Lower Turonian in central and south-east Poland were investigated for foraminifers, CaCO3 content, carbon content insoluble in HCl (Corg ) and in the carbonates (Ccarb ), carbon and oxygen isotopic composition of bulk-rock carbonates and elemental abundances. The Cenomanian/Turonian boundary interval is characterized by the appearance of more marly facies, a δ13 C and δ18 O stable isotope anomaly, a considerable increase in Corg content and decrease in Ccarb content and substantial changes in the foraminiferal assemblages. A major carbon stable isotope excursion with a shift of +2 (PDB) occurs in the lowermost Whiteinella archaeocretacea Zone. The late Cenomanian δ13 C anomaly is associated with heavy δ18 O values. The peak value of δ13 C corresponds to the minima in P/B ratio and in diversity of foraminiferal assemblages. A late Cenomanian anoxic event is thought to be responsible for changes in foraminiferal assemblages. However, elemental abundance analyses do not show changes in the concentrations of trace elements. This may be explained by the long distance between studied area and a source of enrichment which was probably located in the western hemisphere. 相似文献
3.
Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints 总被引:3,自引:0,他引:3
Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO2 -H2 O inclusions that have a constant range in CO2 content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO2 -H2 O inclusions (140 to 340C). Estimates of fluid salinity for CO2 -H2 O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ18 O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ18 O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water. 相似文献
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ
4.
JAAN-MATI PUNNING TÖNU MARTMA HELGI KESSEL REIN VAIKMÄE 《Boreas: An International Journal of Quaternary Research》1988,17(1):27-31
The carbon (δ13 C) and oxygen (δ18 O) isotopic composistion in mollusc shells in mainly determined by the isotopic composition of water and dissolved bicarbonate. The δ18 O values of water show a good correlation with the salinity of the Baltic. This correlation served as a basis for reconstructing palaeosalinity and for stratifying the marine sediments according to the δ18 O values of the carbonate skeletons of subfossil shells. The δ13 C values in shells are mainly determined by the isotopic composition of land-originating bicarbonate, especially in the carbonate skeleton of Lymnaea balthica , which inhabits the immediate coastal zone. According to the δ18 O data, salinity in the investigated area (the coastal area of W and NW Estonia) was highest (about 9–11%) during the Littorina stage. The Limnae a stage had, in general, a salinity similar to the contemporary one, but during some phases possibly exceeding it by 2–3%. 相似文献
5.
Geochemical Process of Gas Hydrate Formation in the Nankai Trough Based on Chloride and Isotopic Anomalies in Interstitial Water 总被引:2,自引:0,他引:2
Abstract: Interstitial water expelled from gas hydrate-bearing and -free sediments in the Nankai Trough are analyzed in terms of Cl-, SO4 2 -, δ18 O and δD. The baselines for the Cl- concentration and δ18 O value are close to seawater values (530 mM and 0%), indicating that the interstitial water is of seawater origin. The δD values decrease with depth, implying isotopic exchange of hydrogen between upwelling biogenic methane depleted in D and interstitial water. The Cl- concentrations in gas hydrate-bearing sediments are anomalously low, while the δ18 O and δD values are both high, suggesting that the water forming these gas hydrates was poor in Cl- and enriched in 18 O and D during gas hydrate formation. Calculation of the gas hydrate saturations using Cl "and δ18 O anomalies gives results of up to 80 % in sand, and shows that the δ18 O baseline is not consistent with the Cl" baseline. The δ18 O baseline increases by +1% in gas hydrate-free clay and silt. This is considered to be caused by clustering of water molecules after gas hydrate dissociation in response to the upward migration of the base of gas hydrate stability, as indicated by the presence of a double bottom-simulating reflector at this site. The water clusters enriched in 18 O are responsible for the increase in the δ18 O baseline with normal Cl". The abrupt shallowing of the base of gas hydrate stability may induce the dissociation of gas hydrates and the accumulation of gases in the new stability zone, representing a geological process that increases gas hydrate saturation. 相似文献
6.
Abstract: The Kanamaru pegmatite is one of the two largest pegmatite deposits in Japan and is rich in K–feldspar, which is maximum microcline. The mica minerals and microcline from this ore deposit were studied for K-Ar ages and δ18 O ratios. Biotite gives K-Ar age of 78. 5 Ma, but microcline is much younger in age of 66. 0 and 58. 3 Ma. Oxygen isotopic equilibrium temperature of the biotite-quartz pair is 625°C. Using closure temperature of the K-Ar system for biotite and microcline, cooling rate of the pegmatite is calculated to be 88°C/m. y. at the beginning but 12°C/m. y. in the later period of the cooling history. The microcline is slightly depleted in 18 O, yielding apparent equilibrium temperatures of 230°C and 155°C on quartz-microcline pairs. It is suggested that the fluid phase, magmatic and partly meteoric in origin, contained in the solidifying pegmatite, was interacted with the original orthoclase and converted it to microcline during the subsolidus stage. 相似文献
7.
Stable isotopic signature of a palaeoaquifer, Mississippian Alamogordo Member limestones, Sacramento Mountains, New Mexico, USA 总被引:1,自引:0,他引:1
Nine stratigraphic sections, each ≈5 m thick, were sampled from the Alamogordo Member limestones of the Lake Valley Formation, Sacramento Mountains, New Mexico, USA. Four stratigraphic sections consist entirely of lime mudstone and wackestone, whereas the other five sections have a prominent layer of crinoidal packstone about 1 m thick at their base. Stable isotopic analyses reveal that the lime muds in the sections with basal packstone layers show a downward decrease in δ18 O and constant δ13 C values, whereas those in the sections solely composed of lime mudstone and wackestone have, in general, relatively uniform δ18 O and δ13 C values. The diagenesis of the Alamogordo Member limestones was previously believed to have been governed by the downward percolation of meteoric water from a regional pre-Pennsylvanian exposure surface ≈100 m above this unit. However, the uniform δ13 C and downward decrease in δ18 O values in the lime muds in the sections with basal packstones indicate that the meteoric water ascended within the Alamogordo Member, rather than descended from the overlying exposure surface. This indicates that the basal packstones were probably a conduit for meteoric water. This is further supported indirectly by the relatively uniform δ18 O and δ13 C values of the lime mud in the sections without basal packstones. The implications are that the oxygen isotopic gradients may be used to identify palaeoaquifers, flow directions within these aquifers and that meteoric diagenesis below an exposure surface could be governed by flow through a palaeoaquifer. 相似文献
8.
Oxygen Isotopic Characteristics of Granitic Intrusions Related to Haobugao Zn-Pb-Cu-Sn Skarn Deposit, East Inner Mongolia, China 总被引:2,自引:0,他引:2
Jingbin Wang Lijuan Wang Yuwang Wang Tiejun Li Hidehiko Shimazaki 《Resource Geology》2004,54(2):205-208
Abstract. Granitic rocks related to the formation of Haobugao Zn-Pb-Cu-Sn skarn deposit, Inner Mongolia, China, show unusual low whole-rock δ18 O values down to -8.8 % (V-SMOW), whereas separated quartz crystals from those rocks give positive δ18 O values of+4.1 to +9.9 %. Chemical analyses and microscopic observation of those granitic rocks confirm that they suffered hydrothermal alteration. Some skarn specimens and quartz from the Haobugao deposit also show negative δ18 O values. The isotopic evidence indicates that intensive meteoric water circulation occurred at the time of granitic intrusion, and caused the pervasive hydrothermal alteration of granitic rocks and the precipitation of skarn deposit in this area. 相似文献
9.
A breccia vein sampled from a shear zone in greenschist facies metapelites at Mount Isa, Queensland, Australia, shows a systematic variation in vein geometry that is related to the geometry of folding and faulting within the sample. Calcite vein-fill is coarse grained and equigranular, suggesting precipitation in a fluid-filled space. Partially folded veins suggest that veining occurred during folding and faulting. The breccia vein contains a central zone in which dilation has occurred simultaneously in all directions in the plane of section, implying that this was a zone of high fluid pressure and nearly isostatic differential stress during folding and faulting. From these observations, it can be inferred that the breccia vein was a zone of high permeability and a likely fluid channel during deformation. This hypothesis was tested by stable isotope analysis of veins and host rocks. The calcite veins have δ13 C values of -11.1 ± 0.1% and δ18 O values of 6-10%o , whereas the host metapelite has δ13 C values of -10.62 and -10.11% and δ18 O values of 14-15%o . These values are consistent with an igneous-derived, H2 O-dominated fluid that exchanged little oxygen with the host rocks, but derived much of its carbon from the wall rock. The isotopic disequilibrium between the veins and the wall rock confirms that the fluid was externally derived, and that the breccia vein acted as a channel for large-volume fluid flow within the shear zone. 相似文献
10.
Stanislaw Halas Janina Szaran Maciej Czarnacki Ahmad Tanweer 《Geostandards and Geoanalytical Research》2007,31(1):61-68
Refinements have been made to achieve over 99% yield in the conversion of CO to CO2 in order to improve the reproducibility and accuracy of δ18 O measurements in sulfates. BaSO4 (10-15 mg) was mixed with an identical amount of spectrographic-grade graphite and loaded into a Pt boat. The mixture was gradually heated to 1100 °C to reduce sulfate to CO and CO2 ; the former gas was simultaneously converted to CO2 by a glow discharge between Pt electrodes immersed in a magnetic field (produced by a pair of external neodymium magnets). A small memory effect was noticed during the analysis (less than 0.3‰ per 10‰ difference in δ18 O between two subsequently analysed samples). The memory effect, however, was suppressed by repetitive preparation of the same specimen. CO2 produced in this way from sulfate reference samples was analysed on a dual inlet and triple collector mass spectrometer along with CO2 equilibrated with VSMOW, GISP and SLAP water reference samples. To avoid large departures of measured isotope ratios from 18 O/16 O of the working calibrator we used CO2 gas prepared from ocean water sulfate for this purpose. The calibrated δ18 O values (in ‰) obtained in this way for NBS-127, IAEA SO-5 and IAEA SO-6 reference materials were 8.73 ± 0.05, 12.20 ± 0.07 and -10.43 ± 0.12, respectively. 相似文献
11.
Kathrin Abraham Sophie Opfergelt François Fripiat Anne-Julie Cavagna Jeroen T.M. de Jong Stephen F. Foley Luc André Damien Cardinal 《Geostandards and Geoanalytical Research》2008,32(2):193-202
We report silicon isotopic determinations for USGS rock reference materials BHVO-1 and BHVO-2 using a Nu Plasma multi-collector (MC)-ICP-MS, upgraded with a new adjustable entrance slit, to obtain medium resolution, as well as a stronger primary pump and newly designed sampler and skimmer cones ("B" cones). These settings, combined with the use of collector slits, allowed a resolution to be reached that was sufficient to overcome the 14 N16 O and 14 N2 interferences overlying the 30 Si and the 28 Si peaks, respectively, in an earlier set-up. This enabled accurate measurement of both δ30 Si and δ29 Si. The δ value is expressed in per mil variation relative to the NBS 28 quartz reference material. Based on data acquired from numerous sessions spread over a period of six months, we propose a recommended average δ30 Si of −0.33 ± 0.05‰ and −0.29 ± 0.11‰ (2se) for BHVO-1 and BHVO-2, respectively. Our BHVO grand mean silicon isotope composition (δ30 Si =−0.31 ± 0.06‰) is significantly more negative than the only published value for BHVO-2, but is in very good agreement with the recently established average value of ocean island basalts (OIB), confirming the conclusion that the OIB reservoir has a distinct isotopic composition from the solar reservoir as sampled by chondrites. 相似文献
12.
Alireza Karimzadeh Somarin Stephen A. Kissin Donald D. Heerema Daniel J. Bihari 《Resource Geology》2009,59(2):107-120
The Archean mafic–ultramafic complex of Lac des Iles, Ontario, Canada, hosts economic platinum group elements (PGE)-Au-Cu-Ni mineralization in the Roby Zone. All lithologies in the North Roby Zone have been affected by hydrothermal alteration. The alteration products include talc (the most dominant mineral), anthophyllite, serpentine, actinolite, tremolite, chlorite, hornblende, zoisite, clinozoisite, epidote and sericite. In the altered rocks, light rare earth elements (La, Ce, Nd, Sm), Pb, Rb, Ba, Cs, S and possibly Y have been added by hydrothermal solution whereas Eu and heavy rare earth elements (Yb, Gd, Dy, Er) remained immobile. There are five types of fluid inclusions in the pegmatitic plagioclase with homogenization temperature and salinity ranging from 240°C to 445°C and 15.37 to 48.52 wt% equivalent NaCl, respectively. The δ18 O and δD of talc range form 6.2‰ to 6.9‰ and −28‰ to −48‰, respectively. δ18 O and δD water in equilibrium with talc during the hydrothermal alteration suggest a modified source for the hydrothermal solution. Microthermometry and stable isotope studies suggest that high temperature–high salinity fluid was diluted by, and mixed with, low temperature–low salinity meteoric solution. This mechanism precipitated the hydrothermal assemblage and redistributed trace elements during and after pegmatite formation in the North Ruby Zone. 相似文献
13.
Abstract. Carboniferous-Permian limestones of the Akiyoshi Plateau, in the Inner Zone of southwestern Japan, are composed of essentially pure calcium carbonate containing only small amounts of other elements, and they are accompanied by marble and copper skarn deposits near the contact with late Cretaceous granitoids. The δ18 O values of the Akiyoshi limestones range widely from 7.6 to 28.3% and are mostly lower than those of other areas of the same age (23–29%), whereas the differences among the δ13 C values are small. The δ18 O values are negatively correlated with Mn and Fe contents. Samples with high δ18 O (>25%) and δ13 C (>2%) values do not contain Fe, Zn, or Pb, but those with low δ18 O values tend to be rich in these elements, indicating that these elements were introduced by interaction with H2 O dominant fluids, possibly of magmatic origin. Potential scores for evaluating the degree of interaction with hydro thermal fluids were calculated for δ18 O, δ13 C, Fe, Mn, Zn, Pb, and Sr. Higher scores implying much hydrothermal interaction were evident in the Mt. Hananoyama area, where there are many skarn deposits, and along faults oriented mainly NNW-SSE. Therefore, these are promising areas for exploring for blind deposits. It is likely that the hydrothermal fluid traveled through the limestones along fractures at the time of the granitic intrusions. However, the potential scores here are much smaller than those in the Pb-Zn mineralized area of the Kamioka mine, so more detailed petrological and mineralogical investigations are necessary. 相似文献
14.
The evolution of fluorine-rich felsic magmas: source dichotomy, magmatic convergence and the origins of topaz granite 总被引:3,自引:0,他引:3
Topaz granite is alkali-feldspar granite that contains essential albite, quartz, K-feldspar, lithium-mica, and topaz. As a group topaz granites are characterized by their extreme enrichment in F (up to 3 wt%) and a wide variety of lithophile elements. They can be subdivided into a 'low-P2 O5 subtype' (P2 O5 < 0.1 wt%, Al2 O3 < 14.5 wt%, SiO2 > 73 wt%) and a 'high-P2 O5 subtype' (P2 O5 > 0.4 wt%, Al2 O3 > 14.5 wt%, SiO2 < 73 wt%), the δ18 O values of which indicate a dichotomy of source rock: the low-P2 O5 subtype (δ18 O < 10‰) having a meta-igneous protolith and the high-P2 O5 subtype (δ18 O > 10 ‰) a source with a significant component of pelitic material. The unusually high F contents enhance the efficacy of melt segregation and crystal-melt fractionation and so facilitate extreme differentiation in topaz granite magmas. Very low melt volumes restrict the bulk composition of the partial melts regardless of the nature of the source; and extreme fractionation forces them along a path of magmatic convergence, to produce a group of granitic rocks with near-minimum compositions so enriched in a variety of lithophile elements (Li, Nb, Ta, Sn) that economic mineralization often results. 相似文献
15.
The flow of surface-derived fluids through Alice Springs age middle-crustal ductile shear zones, Reynolds Range, central Australia 总被引:4,自引:0,他引:4
The south-east Reynolds Range, central Australia, is cut by steep north-west-trending Alice Springs age ( c. 334 Ma) shear zones that are up to hundreds of metres wide and several kilometres long with reverse senses of movement. Amphibolite facies (550–600 °C, 500–600 MPa) shear zones cut metapelites, while greenschist facies shear zones (420–535 °C, 400–650 MPa) cut metagranites. The sheared rocks commonly underwent metasomatism implying that the shear zones were the pathways of significant fluid flow. Altered granites within greenschist facies shear zones have gained Si and K but lost Ca and Na relative to their unsheared counterparts, suggesting that the fluid flowed down-temperature (and hence probably upward) through the shear zones. Time-integrated fluid fluxes calculated from silica addition are up to 2.1×1010 mol m−2 ( c. 4.2×105 m3 m−2 ). Similar time-integrated fluid fluxes are also estimated from changes in K and Na. The sheared granitic rocks locally have δ18 O values as low as 0 which is much lower than the δ18 O values of the adjacent unsheared granites (7 to 9), implying that the fluid which flowed through these shear zones was derived from the surface. For the estimated time-integrated fluid fluxes, the fluids would be able to retain their isotopic signature for many tens to hundreds of kilometres. The flow of surface-derived fluids into the ductile middle crust, with subsequent expulsion upwards through the shear zones, may have been driven by seismic activity accompanying the Alice Springs deformation. 相似文献
16.
Abstract. The Onsen site is an active submarine hydrothermal system hosted by the Desmos caldera in the Eastern Manus Basin, Papua New Guinea. The hydrothermal fluid is very acidic (pH=1.5) and abundant native sulfur is deposited around the vent. The δ34 S values of native sulfur range from -6.5 to -9.3 %o. δ34 S values of H2 S and SO4 in the hydrothermal fluid are -4.3 to -9.9 %o and +18.6 to +20.0 %o, respectively. These δ34 S values are significantly lower than those of the other hydrothermal systems so far reported. These low δ34 S values and the acidic nature of the vent fluids suggest that volcanic SO2 gas plays an important role on the sulfur isotope systematic of the Onsen hydrothermal system. Relationship among the δ34 S values of S-bearing species can be successively explained by the model based on the disproportionation reaction starting from the volcanic SO2 gas. The predicted δ34 S values of SO2 agree with the measured whole rock δ34 S values. δD and δ18 O values of clay minerals separated from the altered rock samples also suggest the contribution of the magmatic fluid to the hydrothermal system. Present stable isotopic study strongly suggests that the Onsen hydrothermal site in the Desmos caldera is a magmatic submarine hydrothermal system. 相似文献
17.
Large amounts of fluid, bound up in the hydrated upper layers of the ocean crust, are consumed at convergent margins and released in subduction zones through devolatilization. The liberated fluids may play an integral role in subduction zone processes, including the generation of arc-magmas. However, exhumed subduction zone rocks often record little evidence of large-scale fluid flow, especially at deeper levels within the subduction zone. Basaltic pillows from the high-pressure Corsican and Zermatt-Saas ophiolites show a range of δ18 O values that overall reflect seafloor alteration prior to subduction. However, comparison between the δ18 O values of the cores and rims of the pillows suggests that the δ18 O values of the pillow rims at least have been modified during subduction and high-pressure metamorphism. Pillows that have not undergone high-pressure metamorphism generally have rims with higher δ18 O values than their cores, whereas the converse is the case in pillows that have undergone high-pressure metamorphism. This reversal in the core to rim oxygen isotope relationship between unmetamorphosed and metamorphosed pillows is strong evidence for fluid–rock interaction occurring during subduction and high-pressure metamorphism. However, the preservation of different δ18 O values in the cores and rims of individual pillows and within and between different pillows suggests that fluid flow within the subduction zone was strongly channelled. Resetting of the δ18 O values in the pillow rims was probably due to fluid-hosted diffusion that occurred over relatively short time-scales (<1 Myr). 相似文献
18.
Seasonal and interannual variability of Siberian river discharge in the Laptev Sea inferred from stable isotopes in modern bivalves 总被引:2,自引:0,他引:2
THOMAS MUELLER-LUPP HELMUT ERLENKEUSER HENNING A. BAUCH 《Boreas: An International Journal of Quaternary Research》2003,32(2):292-303
Stable oxygen and carbon isotope profiles from modern bivalve shells were investigated in order to reconstruct short-term hydrographical changes in the river-shelf system of the Laptev Sea. Oxygen isotopic profiles obtained from the aragonitic species Astarte borealis exhibit amplitude cycles interpreted as annual hydrographical cycles. These records reflect the strong contrast between summer and winter bottom water conditions in the Laptev Sea. The seasonal variations in δ18 O are mainly controlled by the riverine freshwater discharge during summer with 0.5‰ per salinity unit. Corrected for a defined species-dependent fractionation offset of -0.37‰, time-dependent salinity records were reconstructed from these δ18 O profiles. They indicate a good correspondence to seasonal hydrographic changes and synoptical data. Persistent trends with shell growth towards more negative δ13 C values are observed in all specimens and appear to be related to metabolic changes of the bivalves during ontogeny. In contrast, short-term fluctuations are likely linked to seasonal variabilities of the river water outflow patterns and enhanced phytoplankton productivity during summer. This is corroborated by a clear watermass-related distinction of the various δ13 C records made on the basis of water depth and distance from the riverine source. 相似文献
19.
Many different types of water and processes have been proposed for the formation of dolomites. The three phases of hydrothermal dolomites in the Middle Atlas Causse were investigated to elucidate their formation processes. The first two of these are associated with sphalerite and galena in stratiform and open space-filling deposits. These formed early in the history of the deposition of the Pb–Zn mineralization and commonly reveal a paragenetic overlap. A later phase, post-dating Pb–Zn mineralization, is reflected in saddle dolomite.
All three phases show a decrease in δ18 O and δ13 C values passing from sterile (unmineralized) to mineralized rocks, and isotopic signatures are independent of the carrier facies. However, early-formed dolomites can be separated into two distinct groups on the basis of δ18 O values. Type 1 dolomites host stratiform ore deposits, whereas type 2 dolomites host an open space-filling ore-body. Later saddle dolomites are more depleted in 18 O than either of these.
The early hydrothermal and saddle dolomites precipitated from similar fluids during three distinct events, but formed by two mechanisms: replacement (hydrothermal dolomite) and cement precipitation (saddle dolomite). They show different isotopic signatures and apparently formed at different temperatures. Field data, petrographic and stable isotope results suggest a continuum of replacement, during the Carixian for the early hydrothermal dolomite 1, and during the Toarcian for early hydrothermal dolomite 2, followed by a cement precipitation phase for saddle dolomite. 相似文献
All three phases show a decrease in δ
The early hydrothermal and saddle dolomites precipitated from similar fluids during three distinct events, but formed by two mechanisms: replacement (hydrothermal dolomite) and cement precipitation (saddle dolomite). They show different isotopic signatures and apparently formed at different temperatures. Field data, petrographic and stable isotope results suggest a continuum of replacement, during the Carixian for the early hydrothermal dolomite 1, and during the Toarcian for early hydrothermal dolomite 2, followed by a cement precipitation phase for saddle dolomite. 相似文献
20.
Stable Isotope Study of the Langshan Polymetallic Mineral District, Inner Mongolia, China 总被引:3,自引:0,他引:3
Abstract: A comprehensive stable isotope investigation was carried out to clarify the geneses of the ore deposits in the Langshan Pb-Zn mineral district. The lead isotope study shows that these deposits were probably formed from 2. 0 to 1. 5 Ga, and were deformed and metamorphosed 1. 45 Ga. Ore lead could be a mixture of mantle lead and crustal lead. The C and S isotope results indicate that these deposits were precipitated in closed or semi-closed rift basins, and the source of sulfur might be Proterozoic ocean sulfate. The H and O isotope results indicate that the δD and δ18 O values of rocks were changed by water-rock interaction during metamorphism and hydrothermal alteration. The scale of δD and δ18 O shift of rocks reflects the grade of metamorphism and alteration as well as the water-rock ratios. However, the water-rock ratios in the metamorphic processes of Langshan mineral district were relatively low, and the source of water during metamorphism is suggested to be ancient meteoric water. Based on isotopic results and the geological background, it is concluded that these deposits may belong to Proterozoic sedimentary exhalative (SEDEX) type. 相似文献