蔡家营铅—锌—银矿床的稳定同位素地球化学研究

河北蔡家营矿床是大型中温热液充填－交代脉型铅－锌－银矿床。其硫化物的δ＾３４Ｓ值为２．２‰－７．８‰，同世代共存的１０个硫化物对的Δ＾３４Ｓ值表明，Ｆｅ－（Ｚｎ、Ｐｂ）－Ｓ系统的硫同位素非平衡分馏占主导，硫是岩浆（为主）与老变质岩层硫的混合来源。石英及其流体包裹体的δ＾１８ＯＳＭＯＷ和δＤＳＭＯＷ值（‰）按混合模式计算表明，成矿流体为混合的岩浆和大气降水，早期成矿流体以岩浆为主，尔后则变为以大气降     

康滇地轴东缘铅锌矿床铅硫同位素地球化学研究

康滇地轴东缘不同时代碳酸盐地层中铅锌矿床的铅同位素研究表明,其＾２０７Ｐｂ／＾２０４Ｐｂ与＾２０８Ｐｂ／＾２０４Ｐｂ呈良好线性关系,＾２０７Ｐｂ／＾２０６Ｐｂ和＾２０８Ｐｂ／＾２０６Ｐｂ为一常数。结合对本区床的稀土元素及成矿流体地球化学的研究,判定不同层位铅锌矿床是在同一个成矿体系同时形成的,一次成矿,其成矿年龄为２４５Ｍａ;同时说明不同矿床成矿金属有相同的来源,主要来自上地幔。成矿硫以来自地层中     

河南围山城金银成矿带铅同位素地球化学及矿床成因

桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,所有矿床赋存于上元古界歪头山组地层,并具有层控特征。矿石矿物的铅同位素组成为²⁰⁶Pb/²⁰⁴Pb=16.753~17.216,²⁰⁷Pb/²⁰⁴Pb=15.417~15.638,²⁰⁸Pb/²⁰⁴Pb=38.251~39.050;与歪头山组地层的铅同位素组成一致,而与桐柏地区的其他地层、岩体差别较大,表明成矿物质来自赋矿地层歪头山组。围山城成矿带应属于典型的层控造山型金银成矿系统,它形成于中生代扬子与华北板块的陆陆碰撞造山过程,碰撞造山期间的下插板片变质脱水诱发了矿带内流体成矿系统的发育,强烈的流体-岩石相互作用使歪头山组内的成矿物质被萃取、迁移、聚集到碳质绢云片岩层。     

晋北火山岩型金银矿床同位素地球化学特征

晋北地区是浅成低温热液金银矿床重要分布区。金银矿床与火山岩岩体密切相关。与成矿有关的石英斑岩、石岗斑岩基 Rb-Sr等时线年龄为136-167Ma，为燕山早中期产物，（87Sr/86Sr）。为0.7058-0.7065，属幔壳混源型。铅同位素资料表明，支家地银矿和刁泉银、金、铜矿铅同位素组成与高于庄组白云岩及有关次山岩岩石铅组成相似，可能均属壳幔混合源。耿庄金矿铅同位素属异常铅。金银矿床的δ34S值分布范围为-0.8‰-+9.6‰,算术平均值为3.8‰，为岩浆热液型特征。成矿流体氢氧同位素及碳酸盐的碳氧同     

浙东新昌—永嘉银（铅—锌）矿带同位素地球化学研究

浙东新昌－永嘉银（铅－锌）矿带中，主要有嵊县毫石、新昌拔茅、天台大岭口及黄岩五部等大－中型银矿床或含银铅－锌矿床。在这些典型矿床的专题研究基础上，本文根据它们的成岩成矿年龄时差及氢、氧、硫和铅同位素地球化学特征，提出了“中生代地热水淋滤汲取成矿”的成因机制和成矿模式。地热水环流－汲取成矿活动的主体部分发生在火山岩层内。成矿体是大气降水来源的浅循环地热水，在其环流过程中淋滤汲取周围岩石中的成矿物质（     

云南澜沧铅锌银铜矿床稳定同位素地球化学研究

澜沧铅锌银铜多金属硫化物矿床产于石炭系火山岩和碳酸盐岩中。矿床硫同位素研究表明硫具胡来自下地壳或上地幔的特征。据铅构造模式认为矿石铅为上地壳铅和地幔铅的混合物，具有多来源的特点。矿物及其包裹体的氢、氧同位素组成反映出成矿溶液早期以岩浆水为主，稍晚有大气降水混入。脉石矿物主方解石的碳同位素组成表明成矿过程中热液同围岩进行了广泛的物质成份交换。为与燕山期次火山活动有关的热液矿床。     

康滇地轴东侧的铅锌矿床与铅同位素地球化学

康滇池轴东侧的铅锌矿带是我国的主要铅锌矿带之一。铅同位素地球化学研究是铅锌矿床研究的重要内容之一。本文探讨了康滇地轴铅锌矿床研究中的铅同位素地球化学应用问题,指出铅同位素模式年龄不能用作矿化年龄,应当用铅同位素示踪来追踪成矿物质来源。     

新疆可可塔勒铅锌矿床同位素地球化学研究

同位素资料表明,可可塔勒铅锌矿床成矿时代为早泥盆世,与下泥盆统海相火山岩系年代一致;矿石铅主要来自于活动造山带,与弧盆系火山岩有关,属幔壳混合铅;矿石的硫源与赋矿围岩或后期脉状矿石的硫源存在明显的差异,前者属细菌成因硫和海水硫酸盐还原硫的混合,后者属深部火山硫或岩浆硫;主成矿期的成矿介质水主要是海水,可能有少量大气降水加入,后期矿化则以混合岩浆水为主。矿床形成属海底火山喷气－沉积迭加改造型矿床。     

Isotope Tracing and Prospecting Assessment of Gold-Silver Deposits in Zhejiang Province

Three different types of gold and silver deposits in Zhejiang Province(Huangshan gold deposit, Zhilingtou gold-silver deposit and Haoshi silver deposit) showmarked differences in lead and strontium isotopic composition, suggesting three differentsources and geneses of these deposits. The Huangshan gold deposit features low initial Srisotope ratios and low μ values or low content of radiogenic Pb and its ore-forming materialscame primarily from the upper mantle; the Zhilingtou gold-silver deposit shows high initial Srisotope ratios and high μ values or high content of radiogenic Pb and the ore-forming materialswere derived mainly from the upper crust; and the Haoshi silver deposit has its Pb and Srisotope ratios between the above two cases with the ore-forming materials stemming from boththe mantle and the crust. The characteristic Pb isotopic composition may serve as an indicatorfor prospecting for different types of ore deposits.     

Isotope Geochemistry of the Xinchang -Yongjia Silver (Lead-Zinc)Ore Belt in Eastern Zhejiang Province

In the Xinchang-Yongjia silver (lead-zinc) ore belt, there mainly occur the large to medium-sized Haoshi, Bamao, Dalingkou and Wubu silver deposits or silver-bearing lead-zinc deposits. On the basis of researches on these typical deposits, the mechanism of leaching-drawing mineralization of Mesozoic geothermal water and the related model are put forward in this paper in the light of the time interval between rock and formation ages as well as hydrogen, oxygen, sulphur and lead isotope geochemical characteristics. The major metallogenic process occurred in volcanic rock layers. The ore-forming fluids are geothermal water coming from meteoric water and circulating at shallow layers. This geothermal water leached and absorbed ore-forming materials from its country rocks during its flowing (such metallogenic elements as silver, lead-zinc and sulphur mainly came from consolidated volcanic rocks), leading to the formation of meso - epithermal silver deposits.     

Lead Isotopic Composition and Lead Source in the Bainiuchang Ag-polymetailic Deposit,Yunnan Province,China

The Bainiuchang deposit in Yunnan Province,China,is located geographically between the Gejiu ore field and the Dulong ore field.In addition to the>7000 t Ag reserves,the deposit also boasts of large-scale Pb,Zn and Sn reserves with a lot of dispersed elements(In,Cd,Ge,Ga,etc.).We have determined systematically the Pb isotope composition of the deposit.The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district,are ~(206)Pb/~(204)Pb=17.758-18.537,~(207)pb/~(204)pb=15.175-15.862 and ~(208)pb/~(204)pb=37.289-39.424,while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are ~(206)Pb/~(204)Pb=17.264-18.359,~(207)Pb/~(204)Pb=14.843-15.683 and ~(208)Pb/~(204)Pb=36.481-38.838, respectively.In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole- rock samples from the mining district,we have determined the Pb isotope composition and acquired the Pb isotope ratios as:~(206)Pb/~(204)Pb=18.224-18.700,~(207)Tpb/~(204)Pb=15.595-15.797 and ~(208)Pb/~(204)Pb= 38.193-39.608.Then,in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field,we have determined the Pb isotope composition and obtained the isotope ratios as:~(206)Pb/~(204)Pb=18.434-19.119,~(207)Pb/~(204)Pb=15.644-15.693,and ~(208)Pb/~(204)Pb=38.514-38.832.And the Pb isotope ratios of Cambrian sedimentary rocks,which are exposed in the Bainiuchang mining district,are ~(206)Pb/~(204)Pb=18.307-19.206,~(207)Pb/~(204)Pb= 15.622-15.809,and ~(206)Pb/~(204)Pb=38.436-39.932.By comparing the two types of ores with respect to their Pb isotope compositions,it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age,but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district.     

Lead Isotopic Composition and Lead Source in the Bainiuchang Ag-polymetallic Deposit, Yunnan Province, China

The Bainiuchang deposit in Yunnan Province, China, is located geographically between the Gejiu ore field and the Dulong ore field. In addition to the 〉7000 t Ag reserves, the deposit also boasts of large-scale Pb, Zn and Sn reserves with a lot of dispersed elements （In, Cd, Ge, Ga, etc.）. We have determined systematically the Pb isotope composition of the deposit. The Pb isotope ratios of the ores that are of sea-floor exhalative sedimentary origin in the northwest of the mining district, are 206pb/204pb = 17.758-18.537, 207pb/204pb = 15.175-15.862 and 206pb/204pb = 37.289-39.424, while those of ores that are of magmatic hydrothermal superimposition origin in the southeast of the mining district, are 206pb/204pb = 17.264-18.359, 207pb/204pb = 14.843-15.683 and 208pb/204pb = 36.481-38.838, respectively. In terms of the Pb isotope composition of feldspar in magmatic rocks or magmatic whole- rock samples from the mining district, we have determined the Pb isotope composition and acquired the Pb isotope ratios as： 206pb/204pb -- 18.224-18.700, 207pb/204pb -- 15.595-15.797 and 208pb/204pb -- 38.193-39.608. Then, in the light of the Pb isotope composition of metamorphic rock samples from the Proterozoic basement exposed in the Dulong ore field, we have determined the Pb isotope composition and obtained the isotope ratios as： 206pb/204pb -- 18.434-19.119, 207pb/204pb -- 15.644-15.693, and 208pb/204pb = 38.514-38.832. And the Pb isotope ratios of Cambrian sedimentary rocks, which are exposed in the Bainiuchang mining district, are 206pb/204pb = 18.307-19.206, 207pb/204pb = 15.622-15.809, and 208pb/204pb = 38.436-39.932. By comparing the two types of ores with respect to their Pb isotope compositions, it is indicated that lead in the Bainiuchang deposit was derived largely from the lower-crust granulite which is earlier than Neoproterozoic in age, but the Yanshanian magmatic hydrothermal fluids probably provided a part of ore-forming elements such as Sn for the ore blocks in the south of the mining district.     

浙江弄坑金银矿区黄铁矿成分标型研究

为确定弄坑矿区金银矿化成因类型及对该矿区深部矿化远景进行预测,应用找矿矿物学方法研究了浙江武义弄坑金银矿区黄铁矿成分及其特征比值（如S/Fe、Fe/（S＋As）、Co/Ni、S/Se、Se/Te、Au/Ag）、S、Pb同位素特征,分析了黄铁矿成分的成因标型及找矿标型,为该矿化区矿化成因类型的确定提供可靠性的矿物学依据.同时,利用黄铁矿微量元素的三角形图解对本矿区深部矿化远景进行了预测.结论显示,该区金银矿化属浅成低温火山热液成因类型,在矿化区的深部地段可望找到富的金银矿化体.     

浙江安吉港口多金属矿床铅物质来源初探——铅同位素证据

位于浙西北安吉港口的铅锌银(钼)多金属矿床,是新近在钦杭成矿带东北缘发现的一个产于大陆环境且具较好前景的矿床.文章通过对矿区坞山关杂岩体三套岩性单元、细粒花岗岩和方铅矿铅同位素的全面对比研究,探讨了矿床的铅物源岩浆岩.矿区中的方铅矿为含较高放射性成因铅的J-型铅,在铅同位素的V1-V2和△γ-Δβ图解中,本次研究的样品分别落入华南和岩浆作用上地壳混合地幔铅范围,显示出方铅矿与华南地球化学省壳幔混合岩浆作用的密切关系.矿区铅锌矿体的方铅矿铅同位素比值显示其具有共同的物质来源,并基本保持了细粒花岗岩206Pb/204Pb值的特征,而207Pb/204Pb值具有坞山关杂岩体和细粒花岗岩混合的特征,208Pb/204Pb和208Pb/206Pb值则仅显示出与细粒花岗岩最相近.方铅矿铅同位素比值特征和比值等值线分布形式显示,铅主要来源于细粒花岗岩,杂岩体对铅成矿贡献了少量的206Pb和207Pb,矿区地层对铅成矿贡献了一定的208Pb.安吉矿区进一步针对铅的找矿工作围绕细粒花岗岩展开,取得成果的可能性更大.     

小秦岭地区文峪和东闯石英脉型金矿床铅及硫同位素研究

小秦岭地区文峪和东闯金矿床均是华北地台南缘的大型金矿床，金和金(铅）矿化主要在太古宙太华群变质岩层内呈脉状产出，并且同中生代燕山期花岗岩类具密切的时空分布关系。文章对文峪金矿床、东闯金（铅）矿床、花岗岩类侵入岩和变质岩地层的硫和铅同位素组成进行了系统研究，对不同地质体的硫和铅同位素变化特征进行了详细讨论。研究结果表明：中生代花岗岩体起源于太古言变质岩的重熔和岩浆结晶分异作用。金的成矿作用发生在中生代燕山期，成矿物质主要来自花岗岩类侵入岩，岩浆热流体对太古富变质岩地层的淋滤作用亦为金矿床的形成提供了部分物质来源。     

湘中锑(金)矿床成矿物质来源——Ⅱ.同位素地球化学证据

文章从碳、氢、氧、硫、铅、锶等同位素地球化学方面探讨了湘中锑金矿床的成矿物质与成矿流体来源。研究表明：湘中盆地中锑矿床的碳、硫等矿化剂主要来源于基底地层，而盆地边缘锑（金）矿床的碳、硫等矿化剂来源于深部岩浆作用；Au,Sb等成矿物质都来源于基底碎屑岩；成矿流体主要为大气降水。     

西藏努日、程巴铜-钼-钨矿床硫铅同位素地球化学

努日、程巴矿床是冈底斯成矿带东段南缘紧邻雅鲁藏布江缝合带产出的两个斑岩-矽卡岩矿床,两矿床矿化元素组合分别为Cu-Mo-W和Mo-Cu。文章以努日和程巴矿床中主要金属硫化物为研究对象,采用S、Pb同位素研究方法对矿床成矿物质来源进行探讨。硫同位素研究结果表明,两矿床硫同位素组成δ34S值范围均较窄,具明显塔式分布特征,矿床硫主要来自于深源岩浆;努日矿床硫同位素组成在空间上具有一定的变化规律,指示矿区41线附近存在隐伏岩体。矿石铅同位素组成表明,两矿床成矿物质中均有幔源和壳源物质的参与,不同的是壳源物质源区存在差异,努日矿床壳源物质源区为拉萨地块结晶基底,而程巴矿床壳源物质则可能来源于印度—亚洲大陆碰撞过程中的印度大陆岩石圈物质。努日和程巴矿床的矿化元素组合与其成矿物质源区特征是相对应的,冈底斯成矿带矿化元素组合由南向北的分带性系不同的壳源物质基础加之不同程度的幔源物质混染造成的。