黄铁矿成因形态学

在1981—1986年野外工作的基础上,作者对胶东三县四个金矿床黄铁矿晶体形态进行了系统研究,对其中2495粒晶体进行了统计,对300粒晶体进行了测角,对60粒晶体进行了微形貌观察。根据以上实际工作及国内外有关资料提出了黄铁矿晶休常见单形出现频率的定量资料与晶体微形貌的特点,特别是{210}面上负条纹的特征与成因探讨。并讨论了黄铁矿晶体形态与分带性,与形成温度,与主、微量成分,与共生组合及与矿化等的关系。查明黄铁矿形态及其晶面微形貌的发育与硫逸度、温度、冷却速度等密切相关。在以上基础上提出了胶东四个金矿床中蚀变岩型金矿及石英脉型金矿两种成因类型黄铁矿形态特征上的五点差异。最后对黄铁矿研究方法要点进行了总结。     

韧性剪切带中的香炉碗子金矿床成因和黄铁矿找矿矿物学研究

香炉碗子金矿床产于韧性剪切带内,具有多期成矿的特点。矿床成因属浅成低温热液—蚀变岩型金矿床。黄铁矿形成于两个成矿阶段。早期黄铁矿含金量较少,其晶体形态主要为{hko}、{hko}+{100}。晚期黄铁矿以富含金为特征,主要为它形晶,呈细脉浸染状产出。黄铁矿的热电性特征可作为金矿的找矿标志。利用成矿阶段形成的黄铁矿所求出的产矿系数可以圈定矿体。其产矿系数<4010×10~(-2)者为工业矿体。     

Chromatographic study of formation conditions of rhombododecahedral diamond crystals

The results of chromatographic study of the formation of rhombododecahedral diamonds synthesized in the Fe-Ni-(Ti)-C system at 5.5–6.0 GPa and 1350–1450°C are presented, including crystals with rounded surfaces of the rhombododecahedron with parallel striation, which are morphological analogues of natural diamonds abundant at various kimberlite, lamproite, and placer deposits. Chromatography was performed at 150°C with mechanical breakup of diamonds. The stable release of methane when diamonds of habit {110} are crushed is established. It is concluded that the appearance of the habit rhombododecahedron may be related not only to the effect of temperature and pressure on crystal growth but also to reductive conditions of crystallization. At the same time, the appearance of significant amounts of hydrocarbons in the system probably results in stopping of the growth of faces {110} and {100} and, instead, formation of specific surfaces that are composed of microscopic accessories faced by planes {111}.     

陕川丁家林-太阳坪金矿床黄铁矿标型特征

金矿床中黄铁矿的化学元素、晶体形态、粒度等标型特征与其形成的物理化学环境及介质条件密切相关.通过对陕川丁家林-太阳坪金矿区主要载金矿物黄铁矿在韧性剪切变形-构造分异热液期与脆性剪切变形-构造分异热液期化学元素含量对比,以及黄铁矿形态、粒度分析,研究黄铁矿与金矿物关系.丁家林-太阳坪金矿黄铁矿形态以{100}、{210}单晶及{100} {210}聚晶为其标型.黄铁矿在空间分布特征来看,深部成矿的可能性不大.应沿丁家林-太阳坪脆-韧性剪切带寻找金矿.     

Geochemical characteristics of pyrite in Duolanasayi gold deposit, Xinjiang

The Duolanasayi gold deposit, 60 km NW of Habahe County, Xinjiang Uygur Autonomous Region, is a mid-large-scale gold deposit controlled by brittle-ductile shearing, and superimposed by albitite veins and late-stage magma hydrothermal solutions. There are four types of pyrite, which are contained in the light metamorphosed rocks (limestone, siltstone), altered-mineralized rocks (chlorite-schist, altered albite-granite, mineralized phyllite), quartz veins and carbonatite veinlets. The pyrite is the most common ore mineral. The Au-barren pyrite is present mainly in a simple form and gold-bearing pyrite is present mainly in a composite form. From the top downwards, the pyrite varies in crystal form from {100} and {210} {100} to {210} {100} {111} to {100} {111}. Geochemical studies indicate that the molecular contents of pyrite range from Fe1.057S2 to Fe0.941S2. Gold positively correlates with Mn, Sr, Zn, Te, Pb, Ba and Ag. There are four groups of trace elements: Fe-Cu-Sr-Ag, Au-Te-Co, As-Pb-Zn and Mn-V-Ti-Ba-Ni-Cr in pyrite. The REE characteristics show that the total amount of REE (ΣREE) ranges from 32.35×10 -6 to 132.18×10 -6; LREE/HREE, 4.466-9.142; (La/Yb)N, 3.719-11.133; (Eu/Sm)N, 0.553-1.656; (Sm/Nd)N, 0.602-0.717; La/Yb, 6.26-18.75; δEu, 0.628-2.309; δCe, 0.308-0.816. Sulfur isotopic compositions (δ 34S=-2.46‰--7.02‰) suggest that the sulfur associated with gold mineralization was derived from the upper mantle or lower crust.     

东伙房金矿中黄铁矿和石英的某些标型特征及其找矿意义

主要对黄铁矿及石英的某些标型特征进行研究，并推测成矿的有利部位，研究发现，本区成矿阶段的黄铁矿为ｎ＋ｐ混合型，ｐ型含量愈高，矿化愈好，金品位高值区与热电系数标志值５００～７００部位吻合，主成矿阶段出现（１００）＋（３２１）＋（２１０）＋（３２１）及（１００）＋（２１０）＋（１１１）黄铁矿聚形，石英热发光强度大（大于０．５Ｒ）发光曲线峰多（双峰），总积分强度大于４．３Ｒ是本区主成矿阶段的一个标志。     

A study of the internal structure of variety III diamonds by X-ray section topography

The internal structure of variety III diamonds (Orlov 1977) was examined by X-ray section topography. The crystal space was found to be divided into six cubic sectors of a face-form of rhombododecahedroid variety III (Shafranovsky 1961). The defect lines on the topographs are the traces of {110} defect planes. It is concluded that separate 〈111〉 fibres are grouped into {110} layers (lamellae). The internal structure of the crystals is characterized by continuous warping of crystal planes and is directly connected with {110} defect planes which are tilt boundaries. Examples of variants of filling cubic sectors are given and their connection with misorientation shown on topographs demonstrated. The characteristic internal structure of variety III diamonds can account for their morphological features and structure-dependent properties; for examples, the cleavage on {110} and {100}.     

Zur Morphologie des Taramellits

Zusammenfassung Taramellit kommt im westlichen Nordamerika an mindestens acht Fundstellen vor, wo er bis jetzt wenig beachtet wurde. Die Taramellite dieser Fundstellen sind alle sehr Ti-reich. Bisher wurde Taramellit nach dem ersten Vorkommen, Candoglia in Italien, meist als faserig beschrieben. Die Ti-reichen Taramellite in Nordamerika, besonders die in California, welche mit Sanbornit und Gillespit vorkommen, erscheinen aber als gut ausgebildete Einkristalle. Es wurden viele solche Kristalle goniometrisch gemessen. Obgleich etwa dreißig Formen verzeichnet wurden, ist der Habitus der orthorhombischen Kristalle meist durch das Vorherrschen der Pinakoide und einiger {hk0} und {0kl} Prismen bedingt. Am häufigsten ist der tafelige habitus nach {100}.

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On the morphology of taramellite

Summary Taramellite is known from at least eight localities in western North America but has received little notice. The taramellite at all of these localities is especially Ti-rich. Hitherto taramellite has mostly been described as fibrous after its habit at the type locality, Candoglia, Italy. The Ti-rich taramellites of North America, especially those found with sanbornite and gillespite in California, occur as well-developed single crystals. Many such crystals were measured goniometrically. Though about thirty forms were recorded, the habit of the orthorhombic crystals is mostly determined by the pinacoids and a few {hk0} and {0kl} prisms. A tabular habit with {100} dominant is most common.

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herrn Prof. Dr.H. Meizner zum 70. Geburtstag gewidmet.     

广西龙头山金矿床黄铁矿标型特征及其地质意义

广西龙头山金矿床是大瑶山成矿带内重要的金矿床,矿区发育大量不同类型的黄铁矿。根据黄铁矿的产出特征,将黄铁矿划分为5个世代,对应着5个成矿阶段:电气石-石英-硫化物阶段(Ⅰ)、石英-黄铁矿-黄铜矿阶段(Ⅱ)、石英-多金属硫化物阶段(Ⅲ)、石英-黄铁矿-闪锌矿阶段(Ⅳ)、石英-黄铁矿阶段(Ⅴ)。不同阶段黄铁矿晶形均以{100}为主,少见{210};金含量与{210}含量呈正相关。黄铁矿晶胞参数为5.411 86~5.415 52,变化幅度不大,与钴含量呈正相关,主成矿阶段受金含量影响而变大。形貌及砷含量变化特征表明,{210}和金含量随砷含量降低而升高,说明砷含量降低利于{210}的出现,且金与砷不存在正相关关系。形貌特征及微量元素特征均反映主成矿阶段温度应220℃,且多集中于300℃的范围;δFe—δS图解及矿床地质特征表明,成矿热液主要为岩浆热液。综合分析认为,龙头山金矿床为中-高温岩浆期后热液矿床。