PAA冲洗液在三山岛蚀变岩型金矿中的应用

三山岛蚀变岩型金矿地层复杂，钻孔施工难度大，试验采用PAA冲洗液，取得较好效果。介绍了冲洗液的配方、配制方法及应用效果。     

胶东三山岛金矿蚀变岩地球化学研究

胶东是我国最主要的原生金矿矿集区,金总储量占全国现有储量的1/4强。该地区金矿成矿时间集中在120±10Ma,空间上可分为3个成矿带:招远-莱州成矿带、蓬莱-栖霞成矿带和牟平-乳山成矿带。金矿类型主要为石英脉型和蚀变岩型。     

胶东三山岛北海域金矿床热液蚀变作用研究

三山岛北海域金矿床位于胶东金矿省的西北缘,是2015年新发现的超大型金矿床（储量470 t、Au品位4.30 g/t）,金矿体赋存于中生代玲珑式花岗岩中,主矿体受三山岛-仓上断裂带控制。中生代含矿的玲珑式花岗岩显示了复杂的蚀变、矿化共生组合关系。三山岛-仓上断裂的活动使热液流体发生渗透,导致断裂带两侧发生广泛的钾化蚀变。随后,大规模的绢云母化沿主断裂两侧形成。随着断层泥的形成,其作为"阻挡层"使含矿流体不能运移到断裂带上盘,成矿流体在下盘发生强烈的绢云母-石英-黄铁矿蚀变并伴有金的析出。最后石英-碳酸盐脉的形成标志着与金成矿相关热液活动减弱。钾化和绢英岩化岩石的平衡计算揭示了SiO2、MgO和CaO带入,TiO2、K2O基本不变,而Na2O表现为带出;大多数主量元素受强烈的矿物反应影响。Au、Ag、Bi、As、Pb、Zn等相关成矿元素呈带入特征,它们之间多呈正相关关系且与黄铁绢英岩化有密切关系,显示出在水岩反应过程中不同类型的元素具有复杂的地球化学行为。蚀变组合和流体包裹体研究表明,成矿流体以中低温（126~351℃）、中低盐度（1.02%~10.48% NaCleqv）为特征,属于CO2-H2O-NaCl±CH4体系。在热液流体中,金可能主要以Au（HS）2-络合物的形式运移;黄铁绢英岩化过程中,硫化作用使Au（HS）2-络合物失稳分解导致Au沉淀富集成矿。华北克拉通的重新活化导致软流圈上涌和大量火成岩的形成,也为胶东发生大规模金成矿作用提供了充足的的热能和流体输入。     

蚀变岩型金矿床地球化学新模型

以山东招远河东金矿为例,系统采集地表＋５４ｍ至－８０ｍ七个不同标高中段的地球化学样品,详细研究了包括碱性元素在内的２０余种常、微量元素在蚀变岩中的分布特征,重新建立了典型蚀变岩型金矿床找矿评价的元素组合模式、物化探异常模式和地球化学分带模型,指出了深部找矿方向和探采工作应注意的问题。     

新疆康古尔糜棱岩岩带蚀变岩型金矿床地质特征及成因

康古尔金矿床赋存于晚古生代中－中酸性火山岩系中，受韧性剪切带控制，不同于国内外典型火山岩型金矿床，是一个矿床成因比较独特的金矿床。     

三山岛金矿床载金硫化物特征及其地质意义

三山岛金矿床和焦家金矿床虽然均为“焦家式金矿”的典型代表,但两者的矿物共生组合、载金硫化物矿物成分特点、金矿物的成色,以及围岩蚀变类型、强度,矿化阶段的发育情况等都有明显的差异。三山岛金矿床的毒砂、砷黝铜矿含量较高,黄铜矿的Cu／Fe、方铅矿的Pb／S也较高。这些特征与三山岛金矿的多金属硫化物阶段更发育的事实一致,反映了该矿床可能在矿床(或矿体)分带方面表现了比焦家金矿较浅部较外围的特征,这对深部远景具有指示意义。     

小秦岭金矿含金石英脉中石英晶体微形貌研究

利用微分干涉显微镜等手段对小秦岭金矿含金石英脉中不同成矿阶段的石英晶体微形貌进行了研究。石英晶体{101^-1}、{011^-1}、{101^-0}单形晶面上不同特征的微形貌对了解石英晶体的生长机理、生长速率、生长环境的变化及成矿溶液的过饱和度具有重要意义，同时也可提供成矿阶段划分及晶体生长时热力学条件的信息。     

甘肃安家岔金矿床铅同位素地球化学研究

通过对安家岔金矿床铅同位素地球化学特征研究及其与邻区地层、岩浆岩和有关矿床铅同位素的对比结果表明：（１）本矿床石铅是一种以高放射成因为主的混合型铅，且明显表现出有大气降水参与热液成矿的铅同位素地球化学特征，反映本矿床属于沉积－强烈改造型金矿床；（２）本矿床成矿物质的直接来源主要为志留系；（３）本区的金矿成矿作用和主要与志留系重熔有关的岩浆岩的关系最为密切，因此，在志留系展布区内，Ｉ类岩浆岩密集出现     

Auriferous Quartz Veins from the Dongping Gold Deposit,NW Hebei Province and Metallogenesis—Fluid Inclusion Rb—Sr Isochron Evidence

The Dongping gold deposit, situated on the northern margin of the North China Platform, is a composite deposit composed of auriferous quartz vein-type and altered rock-type ore bodies. It is hosted in the inner contact zone of an alkaline intrusion which was intruded into Archean metamorphic rocks and was formed not later than the Hercynian period. Auriferous quartz veins of the deposit are dated with the fluid inclusion Rb-Sr isochron method at 103 ± 4 Ma, indicating that the gold deposit was formed in the Yenshanian period.⁸⁷Sr/⁸⁶Sr sourcetracing shows the ore forming materials came dominantly from alkaline intrusions. These results, combined with other isotope and REE data, suggest that the Dongping gold deposit is not a traditional magmatic hydrothermal deposit, but a reworked hydrothermal deposit related to heated and evolved meteoric water. This project (49372105) is financially supported by the National Natural Science Foundation of China.     

山东省胶东地区焦家式金矿床中含金石英大脉流体包裹体的特征

著名的焦家式金矿以破碎蚀变岩型矿化为特征,但近年来也发现有含金石英大脉。含金石英大脉的流体包裹体以气液两相为主,含液相CO2包裹体次之;均一温度主峰在290℃附近,次峰在200℃附近;盐度主要为(2～10)%NaCl;估算压力为20～38MPa;包裹体气相成分以H2O为主,其次为CO2;黄铁矿包裹体离子组成一般Na+>K+>Ca2+,SO42->Cl->F-,石英包裹体离子组成一般K+>Na+>Ca2+(变形石英Na+>K+>Ca2+),SO42->Cl->F-。焦家式金矿含金石英大脉的上述特征与玲珑式金矿含金石英脉类似,但与处于同一矿床的破碎蚀变岩型矿化有一定差异。含金石英大脉以充填为特征,而破碎蚀变岩型矿化以交代为特征。     

河北中山沟金矿含金石英脉中锆石U-Pb年代学及Hf同位素研究

热液石英脉型金矿石中锆石可以来自围岩,也可以由热液活动形成.因此,对其研究有助于揭示成岩成矿信息.中山沟金矿位于河北省张家口—宣化(张宣)地区,主要呈石英脉型产于水泉沟岩体西段,是张宣幔枝构造核部的典型金矿床之一.本文在矿区地质特征基础上,主要开展含金石英脉内锆石形态学特征、LA-ICP-MS U-Pb同位素测年以及H...     

胶东三山岛北部海域金矿床石英热释光和晶胞参数特征及其找矿意义

胶东是中国最重要的黄金资源基地之一,近年来深部找矿取得重大突破,特别是在三山岛北部海域发现超大型金矿床.深入研究其成矿规律,对于指导今后的找矿勘探意义重大.笔者应用成因矿物学和找矿矿物学理论,选取该矿床的贯通性矿物石英,对其热释光和晶胞参数特征的时空分布规律及与金矿化的关系进行了系统研究.结果 表明:(1)石英热释光曲...     

夏杖子金矿载金矿物石英的标型特征及成因探讨

石英是夏杖子金矿床主要脉石矿物及载金矿物之一,通过对石英的化学成分、流体包裹体、稀土元素特征、红外吸收光谱和同位素组成等的分析研究,结果表明,夏杖子金矿床的石英流体包裹体主要为单相液体H2O包裹体为主,气液包裹体较少,占5%～10%,另还有一种更少见的富HO4包裹体。液相成分和氢氧同位素揭示成矿流体为岩浆热液和大气降水的混合流体。包裹体的均一温度90℃～210℃,盐度7.0%～11%,为中—低温、低盐度成矿流体。石英稀土元素组成与岩浆岩一致,说明石英与岩浆岩有着渊源关系。夏杖子金矿为燕山晚期浅成中低温岩浆热液金矿床。     

Ore-forming fluids associated with granite-hosted gold mineralization at the Sanshandao deposit, Jiaodong gold province, China

The Sanshandao gold deposit, with total resources of more than 60 t of gold, is located in the Jiaodong gold province, the most important gold province of China. The deposit is a typical highly fractured and altered, disseminated gold system, with high-grade, quartz-sulphide vein/veinlet stockworks that cut Mesozoic granodiorite. There are four stages of veins that developed in the following sequence: (1) quartz-K-feldspar-sericite; (2) quartz-pyrite±arsenopyrite; (3) quartz-base metal sulfide; and (4) quartz-carbonate. Fluid inclusions in quartz and calcite in vein/veinlet stockworks contain C-O-H fluids of three main types. The first type consists of dilute CO₂–H₂O fluids coeval with the early vein stage. Molar volumes of these CO₂–H₂O fluid inclusions, ranging from 50–60 cm³/mol, yield estimated minimum trapping pressures of 3 kbar. Homogenization temperatures, obtained mainly from CO₂–H₂O inclusions with lower CO₂ concentration, range from 267–375 °C. The second inclusion type, with a CO₂–H₂O±CH₄ composition, was trapped during the main mineralizing stages. These fluids may reflect the CO₂–H₂O fluids that were modified by fluid/rock reactions with altered wallrocks. Isochores for CO₂-H₂O±CH₄ inclusions, with homogenization temperatures ranging from 204–325 °C and molar volumes from 55 to 70 cm³/mol, provide an estimated minimum trapping pressure of 1.2 kbar. The third inclusion type, aqueous inclusions, trapped in cross-cutting microfractures in quartz and randomly in calcite, are post-mineralization, and have homogenization temperatures between 143–228 °C and salinities from 0.71–7.86 wt% NaCl equiv. Stable isotope data show that the metamorphic fluid contribution is minimal and that ore fluids are of magmatic origin, most likely sourced from 120–126 Ma mafic to intermediate dikes. This is consistent with the carbonic nature of the fluid, and the cross-cutting nature of those deposits relative to the host Mesozoic granitoid.Editorial handling: R.J. Goldfarb     

二道岔金矿332隐伏金矿床地质特征

二道岔金矿332隐伏金矿赋存于太古宙夹皮沟岩群三道沟岩组和腰抢子片麻岩中,属于石英脉型金矿床,矿石易选,易加工,开发经济效益好。因此,总结该矿床地质特征,对该区普查找矿具有指导意义。