The generation of ductile and brittle shear bands in a low-angle mylonite zone

In the Saint-Barthélemy Massif, French Pyrenees, a ductile thrust zone developed in gneisses during retrogression from lower amphibolite facies conditions to the upper greenschist facies. The last major structures formed in the zone are isolated shear bands, divided into three types.Anastomosing, inhomogenous ultramylonitic shear bands (Type I) are subparallel to the mylonitic foliation in the gneiss (S_g). Most of these bands developed by ductile deformation processes only.Planar, homogeneous ultramylonite bands (Type II) are usually oblique to S_g. They generated as pseudotachylyte bands by brittle fracturing and underwent strong subsequent ductile deformation.Type III shear bands are planar and oblique to S_g. They consist of pseudotachylyte, weakly affected by ductile deformation.Type I, II and III bands seem to represent progressively younger structures on a local scale, linked to falling P-T conditions. The systematic variation in orientation of the different shear bands with respect to S_g is interpreted as being due to a different response of brittle and ductile structures to the orientation of the kinematic frame and the rock anisotropy.     

Repeated parallel deformation in part of the eastern Sierra Nevada,California and its implications for dating structural events

Study of a thick section of late Paleozoic to mid-Cretaceous sedimentary and volcanogenic rocks in eastcentral Sierra Nevada has revealed an involved structural succession not readily apparent when analysed under the traditional assumptions of structural analysis (e.g. parallel structures are of the same age).Earliest structures in the area occur as sparse folds in late Paleozoic rocks, whereas in Triassic to mid-Cretaceous rocks earliest structures occur as penecontemporaneous slumps. Upon these earliest structures are superimposed slaty cleavage with associated lineations and subsequent crenulations. The slaty cleavage across the area is statistically parallel, as are the axial planes of crenulations which fold the slaty cleavage. Such a succession would traditionally be interpreted as representing two periods of deformation, the first forming the slaty cleavage and the second the crenulation of the slaty cleavage. There is evidence, however, to indicate that the slaty cleavage itself was formed during more than one period of deformation and the same may be true for the crenulations. Dykes emplaced in Jurassic rocks have been dated (U/Pb) as mid-Cretaceous and lie parallel to what is probably an early slaty cleavage direction. The dykes, however, also bear a slaty cleavage, albeit weaker than in the host rock. In addition, quantitative strain determinations of rocks in the area show that the older units are more strongly deformed than the younger units. These and other data suggest that the statistically parallel slaty cleavage and related structures (folds, lineations, etc.) found in the Jurassic and older rocks have formed during at least two, and possibly three, increments of strain, each increment separated by a lengthy period of geologic time, possibly as much as 45 Ma or more. Crenulations of the slaty cleavage at any point (subsequently formed after each period of slaty cleavage formation) may even predate slaty cleavage formed later at another nearby point.While it is possible to set up a chronology between earlier (tectonic and/or penecontemporaneous slumps) and later structures (slaty cleavage, folds, lineations, etc.), it is not valid to designate for the entire area a relative time sequence of formation of slaty cleavage and crenulations in the Jurassic or older rocks by the usual methods (e.g. S₂, S₃, F₂, F₃, etc.). These later structures can only be designated as Only in the youngest stratigraphic unit in the area, which has been subjected to one deformation (mid-Cretaceous), can a valid structural succession be applied areally.We suggest that multiphase, parallel structures, comparable to those we have described, may be a relatively common phenomenon in orogenic belts. Until one arrives at a thorough understanding of the detailed stratigraphy and the absolute ages of units in key relationships to the structures, it may only be possible to delineate the broadest of time sequences for the structures concerned.     

鞍山附近“樱桃园组”的构造样式及其时代讨论

本文区分了“樱桃园组”岩石在元古主构造旋回的三幕变形,详细描述了各幕SFL组合和按区段进行了投影。主变形幕D₁的构造最发育,F₁控制着本区的岩性分布。构造序列及样式变化显示由高塑性向脆性的变形格式。本组与下伏的太古鞍山群变粒岩在构造序列、样式和变质相上都有显著差异,过去许多地质学家把二者混划为一个单位,统名“鞍山群”,属太古宙。但本组与上覆的辽河群(上元古)的构造样式和变质相却相似,故其时代相当于早元古Ferrian期。     

Tectonic analysis of progressive secondary deformation in the hinge of a major Caledonian fold nappe,north-western Ireland

Polyphase deformation chronologies established within the mid-crustal portions of orogenic belts have classically been attributed to regional-scale ‘events’ which generate distinct structural sequences that can be directly correlated across large tracts of the orogenic belt. However, concepts of progressive deformation in which minor structures may be continually generated, amplified and redeformed within a unifying kinematic framework suggest that regional correlation of minor structures is both misguided and misleading. Detailed structural analysis of lower amphibolite facies Dalradian metasediments in north-west Ireland does, however, demonstrate that a coherent and meaningful deformation chronology can be established within the framework of individual fold nappes. Protracted deformation has resulted in the generation of a series of overprinting, secondary structures (D₄–D₉), which are kinematically linked to the continued structural evolution and south-east directed translation of the crustal-scale (D₃) Ballybofey (fold) Nappe. Secondary (D₄) crenulation axes initiated at an oblique angle to the direction of nappe transport both rotate and amplify into larger scale folds, which are subparallel to transport and demonstrate successive stages of diachronous folding. Continued nappe-related deformation induces southwards verging contractional (D₅) folds, which are particularly well developed and focused into reactivated ductile (D₃) thrust zones generated during the initial stages of nappe translation. Subsequent to thickening-induced ductile extension and collapse of the nappe, a return to contractional tectonics is marked by major episodes of broad, open buckle folding developed orthogonal to both the overturned limb (D₇) and upper limb (D₈) of the nappe. Detailed structural analysis and investigation of secondary folds and overprinting fabrics provides a valuable insight into the protracted kinematic evolution of major fold nappes.     

Structural and kinematic analysis of the Early Paleozoic Ondor Sum-Hongqi mélange belt,eastern part of the Altaids (CAOB) in Inner Mongolia,China

We present a structural and kinematic study of an Early Paleozoic subduction mélange and a magmatic arc that form the main elements of the Southern Orogen Belt of Inner Mongolia, which lies in the eastearn part of the Altaids or Central Asia Orogenic Belt. The structural analysis of the mélange conducted in the Hongqi and Ondor Sum areas (western Inner Mongolia) shows two phrases of ductile deformation. The D₁ event is responsible for the pervasive S₁ foliation, NW–SE striking L₁ stretching lineation and F₁ intrafolial folds. These microstructures are coeval with a greenschist facies metamorphism. During D₂, NW-verging F₂ folds associated with a S₂ axial planar cleavage deformed S₁ and L₁. The D₁ kinematic criteria indicate a top-to-the-NW sense of shear. D₁ and D₂ developed before the unconformable deposition of the Early Devonian shallow water sandstone. A lithosphere scale geodynamic model involving an Early Paleozoic southeast-directed subduction beneath the North China Craton and late Silurian collision of the North China Craton with an hypothetical microcontinent is proposed to account for the microstructural evolution.     

Correlation of in situ modulus of deformation with degree of weathering, RMR and Q-system

Geotechnical investigation projects in Korea produced data on the in situ modulus of deformation of rock masses (E _M) measured with the borehole test, rock mass rating (RMR), and Q-system. The modulus of deformation of rock masses was correlated with the degree of weathering, RMR, and Q values. Determination of E _M for each degree of weathering allows for the results to be used to classify the degree of weathering or to predict E _M. The relation between E _M and RMR is represented by $ E_{\text{M}} = 10^{{\frac{{{\text{RMR}} - 16}}{50}}} $ , which returns values 2–3 times lower than those reported in previous studies. Despite scatter in the values, due to larger dataset used in this study, the proposed equation may be used to predict the in situ modulus of deformation from RMR values. In addition, the relation between modulus of deformation and Q values is $ E_{\text{M}} = 10^{{0.32{ \log }Q + 0.585}} $ .     

Transpressional deformation,strain partitioning and fold superimposition in the southern Chinese Altai,Central Asian Orogenic Belt

Transpressional deformation has played an important role in the late Paleozoic evolution of the western Central Asian Orogenic Belt (CAOB), and understanding the structural evolution of such transpressional zones is crucial for tectonic reconstructions. Here we focus on the transpressional Irtysh Shear Zone with an aim at understanding amalgamation processes between the Chinese Altai and the West/East Junggar. We mapped macroscopic fold structures in the southern Chinese Altai and analyzed their relationships with the development of the adjacent Irtysh Shear Zone. Structural observations from these macroscopic folds show evidence for four generations of folding and associated fabrics. The earlier fabric (S₁), is locally recognized in low strain areas, and is commonly isoclinally folded by F₂ folds that have an axial plane orientation parallel to the dominant fabric (S₂). S₂ is associated with a shallowly plunging stretching lineation (L₂), and defines ∼NW-SE tight-close upright macroscopic folds (F₃) with the doubly plunging geometry. F₃ folds are superimposed by ∼NNW-SSE gentle F₄ folds. The F₃ and F₄ folds are kinematically compatible with sinistral transpressional deformation along the Irtysh Shear Zone and may represent strain partitioning during deformation. The sub-parallelism of F₃ fold axis with the Irtysh Shear Zone may have resulted from strain partitioning associated with simple shear deformation along narrow mylonite zones and pure shear-dominant deformation (F₃) in fold zones. The strain partitioning may have become less efficient in the later stage of transpressional deformation, so that a fraction of transcurrent components was partitioned into F₄ folds.     

Rock Mass Stability Investigation Around Tunnels in an Underground Mine in USA

Stability and deformation of rock masses around tunnels in underground mines play significant roles on the safety and efficient exploitation of the ore body. Therefore, understanding of geomechanical behavior around underground excavations is important and necessary. In this study, a three-dimensional numerical model was built and stress analyses were performed by using 3DEC software for an underground mine in USA using the available information on stratigraphy, geological structures and mechanical properties of rock masses and discontinuities. Investigations were conducted to study the effect of the lateral stress ratio (K₀), material constitutive models, boundary conditions and rock support system on the stability of rock masses around the tunnels. Results of the stress, displacement, failure zone, accumulated plastic shear strain and post-failure cohesion distributions were obtained for these cases. Finally, comparisons of the deformation were made between the field deformation measurements and numerical simulations.     

On the survival of intergranular coesite in UHP eclogite

Coesite is typically found as inclusions in rock‐forming or accessory minerals in ultrahigh‐pressure (UHP) metamorphic rocks. Thus, the survival of intergranular coesite in UHP eclogite at Yangkou Bay (Sulu belt, eastern China) is surprising and implies locally “dry” conditions throughout exhumation. The dominant structures in the eclogites at Yangkou are a strong D₂ foliation associated with tight‐to‐isoclinal F₂ folds that are overprinted by close‐to‐tight F₃ folds. The coesite‐bearing eclogites occur as rootless intrafolial isoclinal F₁ fold noses wrapped by a composite S₁–S₂ foliation in interlayered phengite‐bearing quartz‐rich schists. To evaluate controls on the survival of intergranular coesite, we determined the number density of intergranular coesite grains per cm² in thin section in two samples of coesite eclogite (phengite absent) and three samples of phengite‐bearing coesite eclogite (2–3 vol.% phengite), and measured the amount of water in garnet and omphacite in these samples, and also in two samples of phengite‐bearing quartz eclogite (6–7 vol.% phengite, coesite absent). As coesite decreases in the mode, the amount of primary structural water stored in the whole rock, based on the nominally anhydrous minerals (NAMs), increases from 107/197 ppm H₂O in the coesite eclogite to 157–253 ppm H₂O in the phengite‐bearing coesite eclogite to 391/444 ppm H₂O in the quartz eclogite. In addition, there is molecular water in the NAMs and modal water in phengite. If the primary concentrations reflect differences in water sequestered during the late prograde evolution, the amount of fluid stored in the NAMs at the metamorphic peak was higher outside of the F₁ fold noses. During exhumation from UHP conditions, where NAMs became H₂O saturated, dehydroxylation would have generated a free fluid phase. Interstitial fluid in a garnet–clinopyroxene matrix at UHP conditions has dihedral angles >60°, so at equilibrium fluid will be trapped in isolated pores. However, outside the F₁ fold noses strong D₂ deformation likely promoted interconnection of fluid and migration along the developing S₂ foliation, enabling conversion of some or all of the intergranular coesite into quartz. By contrast, the eclogite forming the F₁ fold noses behaved as independent rigid bodies within the composite S₁–S₂ foliation of the surrounding phengite‐bearing quartz‐rich schists. Primary structural water concentrations in the coesite eclogite are so low that H₂O saturation of the NAMs is unlikely to have occurred. This inherited drier environment in the F₁ fold noses was maintained during exhumation by deformation partitioning and strain localization in the schists, and the fold noses remained immune to grain‐scale fluid infiltration from outside allowing coesite to survive. The amount of inherited primary structural water and the effects of strain partitioning are important variables in the survival of coesite during exhumation of deeply subducted continental crust. Evidence of UHP metamorphism may be preserved in similar isolated structural settings in other collisional orogens.     

Progressive development of structures in a ductile shear zone

In the Singhbhum Shear Zone of eastern India successive generations of folds grew in response to a progressive ductile shearing. During this deformation a mylonitic foliation was initiated and was repeatedly transposed. The majority of fold hinges were formed in an arcuate manner at low angles to the Y-axis in an E-W trending subhorizontal position and major segments of the fold hinges were then rotated towards the down-dip northerly plunging X-axis. The striping and intersection lineations were rotated in the same manner. The down-dip mylonitic lineation is a composite structure represented by rotated early lineations and newly superimposed stretching lineations. The consistent asymmetry of the folds, the angular relations between C and S surfaces and the evidence of two-dimensional boudinage indicate that the deformation was non-coaxial, but with a flattening type of strain with λ₁ ⪢ λ₂. The degree of non-coaxiality varied both in space and time. From the progressive development of mesoscopic structures it is concluded that the 2–3 km wide belt of ductile shear gave rise to successive anastomosing shear zones of mesoscopic scale. When a new set of shear lenses was superimposed on already sheared rocks, the preexisting foliation generally lay at a low angle to the lenses. No new folds developed where the acute angle was sympathetic to the sense of shear displacements. Where the acute angle was counter to the sense of shear, the pre-existing foliation, lying in the instantaneous shortening field, was deformed into a set of asymmetric folds.     

Geology and Active Tectonics of the Lalmai Hills,Bangladesh–An Overview from Chittagong Tripura Fold Belt Perspective

The Lalmai Hills is a low amplitude anticline with significant variations in landforms, situated along the western fringe of the Chittagong-Tripura Fold Belt (CTFB) and immediate east of the Indo-Burmese deformation front. This fold belt of the Bengal Basin along with more easterly Indo-Burman Range (IBR) developed as a consequence of the oblique collision between Indian and Burmese plates. This neotectonic activity is still continuing and shaping the geomorphology of the area. This study is conducted based on the geomorphological observation of the topo maps and satellite images, and through reconnaissance field work. Stream length gradient index (SL Index) and Mountain front sinuosity (S_mf) reveals the relative status of tectonic activity. Anomalous SL index values confirm the position of the sympathetic minor faults and also relate to the local stratigraphy. A 2D structural model based on the seismic section reveals thrusts controlled wedge-shape upliftment of the central part as pop-up anticlinal structure. The western thrust is the direct result of the collision of the Indian and Burmese plates, and the eastern one is the back thrust of the western fault. Low S_mf value found in the western flank signifies recent tectonics and relatively high S_mf value in the eastern flank indicates that weathering intensity is relatively greater compared to western flank. Finally, the findings not only enhanced the understanding of geomorphic evolution and active tectonics of the Lalmai Hills area but also the overall tectonic and geomorphic evolution of the western most folded part of the CTFB.     

Lateral protrusions in the structure of the Earth’s lithosphere

The factual material and modeling results concerning the geology of specific structural elements defined as lateral protrusions, or flowing layers, are considered. The formation of such structural elements is a fundamental phenomenon that controls many features of the structural evolution and geodynamics of platform basement and foldbelts. A lateral protrusion, or flowing layer, is a spatially constrained, nearly horizontal geological body with attributes of 3D tectonic flow (rheid deformation) and lateral transport of rock masses. Flowing layers are large lateral protrusions that play important role in the structure of the continental and oceanic lithosphere. They embody the internal mobility of huge rock bodies and confirm the possibility of their lateral redistribution at different depths of the continental lithosphere. The lateral displacement of rocks within such assemblies may occur in the regime of cold deformation, heating, metamorphism, and ductile flow of rocks under subsolidus conditions or in the process of their partial melting.     

Shear criteria in granite and migmatite deformed in the magmatic and solid states

Microstructural criteria for the determination of the sense of shear in rocks homogeneously deformed in the partially melted state are similar to those which apply to solid-state deformation. Sense of shear determination is either direct, deduced from the sense of rotation of markers, or indirect, involving the obliquity between the shear and foliation planes, or between the successive foliations imprinted at different stages of progressive deformation.This study is a by-product of the detailed structural and microstructural investigation of a high-grade metamorphic rock pile (Variscan Vosges Massif, France) which underwent subhorizontal shearing during partial melting and further solidification. Depending on the rock chemistry, on the position in the pile and the relative timing of progressive deformation, layered migmatites and homogeneous granites were variously deformed in the partially melted and solid states. The sense of shear obtained from these rock types, using the criteria presented here, consistently gives a top to SW direction.     

Confined pyrolysis of Tertiary lacustrine source rocks in the Western Qaidam Basin,Northwest China: Implications for generative potential and oil maturity evaluation

The parameter S₁ + S₂ (genetic potential) of Rock-Eval analysis is widely used as an evaluation of the genetic potential for the source rocks. Oligocene–Miocene saline lacustrine source rocks in the western Qaidam basin have low total organic C contents (TOC), most around 0.5% with a few exceptions >1.0%. Mineral matrix effects are substantial for source rocks with low TOC, resulting in relatively low S₁ and S₂ peaks. Based on the results of confined pyrolyses (sealed Au capsules) on 6 Oligocene–Miocene source rocks from the western Qaidam basin, with TOC ranging between 0.48% and 2.22%, the relationship between the S₁ + S₂ parameter and the maximum amount of extracted bitumen or saturated and aromatic hydrocarbons (SA) after the confined pyrolysis has been established as follows: bitumen (mg/g rock) = 1.4924 × (S₁ + S₂) + 0.3201 (r = 0.987), or SA (saturates + aromatics) (mg/g rock) = 0.7083 × (S₁ + S₂) + 0.4045 (r = 0.992). Based on these formulas, the amounts of hydrocarbons generated from source rocks can be reasonably estimated. The typical crude oils with low biomarker maturities in this region appear substantially different to the pyrolysates of these six rocks at 180–300 °C but comparable to the pyrolysates at 320 °C and higher temperatures based on molecular parameters. This result, in combination with the physical and gross compositions of the crude oils, suggests that the majority of these crude oils were generated from the source rocks during the main oil-generative stage, possibly at a maturity higher than R_o 0.74%.     

康定大渡河矿田北缘孔玉金矿区控矿构造特征与成矿动力学环境

孔玉金矿区地处川滇构造带北缘,是大渡河金矿田的组成部分之一;矿体主要赋存于盖层泥盆系黑色岩系中,已有的年龄数据分别有13.2 Ma、9.55 Ma,代表喜马拉雅期成矿。川滇构造带历经中、新元古代和显生宙2个巨型构造旋回,矿床的形成叠加了被动大陆边缘、活动大陆边缘交替历史条件下岩石圈的伸展、裂陷和收缩、碰撞造山作用,发育大量韧性-脆韧性剪切带构造,成矿地球动力学环境极其复杂。矿床的动力变形样式与构造活动阶段并非同步发育,矿化就位时代滞后于赋矿围岩的剪切变形时代;构造运动控制了元素在地壳中的分布和分配,在含矿岩系中氧化物含量除SiO_2、Fe_2O_3显著偏高外,其他氧化物含量如K_2O、CaO、Al_2O_3、MgO、FeO等均明显偏低,构造地球化学特征表现为富Si、Fe,贫Na、K;依据元素在不同构造类型和单元中分配的规律性,区内成矿有用组分的分散和富集过程可分为矿源层、变质热液初步富集和成矿作用3个阶段。     

Mineralogical and geochemical characteristics of the hydrothermal illite from Hoam granite,South Korea: Implications for episodic fluid injections in the hydrothermal alteration system

Two stages of illite mineralization are recognized in the hydrothermal alteration zone of the Hoam granite. These illites are formed as a result of pervasive alteration by re-equilibration with high water/rock in a brittle environment below <2 km; the mineralization timing is middle Oligocene (26–27 Ma), coinciding with the timing of crustal deformation related to the opening of the East Sea (Sea of Japan). The mineralogical and geochemical characteristics of the clearly distinguished illites at each site indicate that they were mineralized from different fluid injections in distinct geological environments. Illites at the site-1 alteration zone are characterized by high-K content [K_0.84 per O₁₀(OH)₂], 2M₁ polytype of 99 %, hexagonal plate shape, and coexistence with pyrite. These observations indicate that the illites were formed in a slow cooling system (>250 °C), high fS₂, and a relatively acidic environment. The pseudomorphic replacement combined with matrix-filling texture indicates that the illites at the site-1 alteration zone recorded the changes in fluid conditions from low to high water-rock ratio. In contrast, the illites at the site-2 alteration zone show the coexistence of polytypes (2M₁, 1M, and 1M_d), high-K illites [(K_0.83 per O₁₀(OH)₂]/low-K illites [K_0.63 per O₁₀(OH)₂], platy/hairy shapes, and presence of magnetite. Furthermore, this alteration zone no longer exhibits primary textures because of pervasive alteration induced by the dissolution-precipitation process. These results indicate that they were formed in a rapid cooling system and were continuously under conditions of high water-rock ratio, as well as in a less acidic and fS₂ environment than that observed at the site-1 alteration zone. The behavior of trace elements for each illite primarily depends on the constituents of the hydrothermal fluid, which reflect different degrees of fluid evolution. The enrichment of high field strength elements (Nb and Ta), large ion lithophile elements (B, Be, and Cs), rare earth elements, and actinide elements (U and Th) in illite at the site-2 alteration zone shows that these elements formed by a more evolved fluid than that of the illite at the site-1 alteration zone. In addition, negative Ce anomalies at the site-2 alteration zone indicate that these crystallized in a reducing environment. Considering the mineralogical and geochemical properties of illites at the site-1 and site-2 alteration zones, the illite mineralization in the Hoam granite was likely generated by at least two episodes of hydrothermal illite mineralization, which originated from episodic injections of fluids, rather than continuously evolved fluids.     

Theoretical growth morphology of whewellite CaC2O4·H2O

The morphological theory of Hartman and Perdok (1955, 1956) allows to deduce the character of a growth form {hkl} on the basis of structural data alone. Its application to the structure of whewellite leads to the identification of forms {100}, {010}, {021}, {011}, {12 \(\bar 1\) } and {121} which show during the growth a flat surface profile (flat forms F). These forms occur very frequently in the crystals we grew from pure aqueous solutions at supersaturation β≦1,90. Other forms, {001} and {10 \(\bar 1\) }, possibly show a double character (F or S, where S stays for related faces showing a stepped profile during the growth) according to the bonds assumed within some periodic bond chains (PBCs). Alternative ways of bonding water molecules lead to different structures of the same PBC. The different energy corresponding to these structures may explain the complex morphology of both natural and synthetic crystals grown at high β values.     

Evolution of the first supernovae in protogalaxies: Dynamics of mixing of heavy elements

The paper considers the evolution of the supernova envelopes produced by Population III stars with masses ofM _* ?? 25?C200M _?? located in non-rotating protogalaxies with masses of M ?? 10⁷ M _?? at redshifts z = 12, with dark-matter density profiles in the form of modified isothermal spheres. The supernova explosion occurs in the ionization zone formed by a single parent star. The properties of the distribution of heavy elements (metals) produced by the parent star are investigated, as well as the efficiency with which they are mixed with the primordial gas in the supernova envelope. In supernovae with high energies (E ? 5 × 10⁵² erg), an appreciable fraction of the gas can be ejected from the protogalaxy, but nearly all the heavy elements remain in the protogalaxy. In explosions with lower energies (E ? 3 × 10⁵² erg), essentially no gas and heavy elements are lost from the protogalaxy: during the first one to threemillion years, the gas and heavy elements are actively carried from the central region of the protogalaxy (r ?? 0.1r _v , where r _v is the virial radius of the protogalaxy), but an appreciable fraction of the mass of metals subsequently returns when the hot cavity cools and the envelope collapses. Supernovae with high energies (E ? 5 × 10⁵² erg) are characterized by a very low efficiency of mixing of metals; their heavy elements are located in the small volume occupied by the disrupted envelope (in a volume comparable with that of the entire envelope), with most of the metals remaining inside the hot, rarified cavity of the envelope. At the same time, the efficiency of mixing of heavy elements in less energetic supernovae (E ? 3 × 10⁵² erg) is appreciably higher. This comes about due to the disruption of the hot cavity during the collapse of the supernova envelope. However, even in this case, a clear spatial separation of regions enriched and not enriched in metals is visible. During the collapse of the supernova envelope, the metallicity of the gas is appreciably higher in the central region ([Z] ?? ?1 to 0) than at the periphery ([Z] ?? ?2 to ?4) of the protogalaxy; most of the enriched gas has metallicities [Z] ?? ?3.5 to ?2.5. The masses of enriched fragments of the supernova envelope remain appreciably lower than the Jeans mass, except in regions at the center of the protogalaxy upon which the surrounding enriched gas is efficiently accreted. Consequently, the birth of stars with metallicities close to those characteristic of present-day Galactic stars is very probable in the central region of the protogalaxy.     

Fluid control of localized mineral domains in limestone pressure solution structures

Grain-to-grain and stylolitic solution structures in two central Appalachian Siluro–Devonian limestone macroscale folds contain one of four distinct mineral assemblages that are characterized by the dominant iron-phase mineral present: (1) chlorite±illite±pyrite±calcite±quartz±TiO₂±goethite, (2) chlorite±illite±pyrite altered to iron oxide/hydroxide±calcite ±quartz±TiO₂, (3) chlorite±illite±magnetite±calcite±quartz, and (4) chlorite±illite±goethite±calcite±quartz±TiO₂. Optical reflectance microscopy and SEM–EDS was used to characterize the mineralogy and mineral morphology of these structures. Geochemical modeling was used to constrain the conditions of formation and preservation.The primary control on solution structure mineral assemblage was the redox conditions present in the solution structures during burial and deformation. The redox conditions on the microscale may have been controlled by the local fluid chemistry and the presence–absence of hydrocarbons and organic acids within the formation fluids, and the influx of externally derived fluids by fracture formation during the folding process. The wide variation in mineralogy of the solution structures shows that they were ‘chemical factories’ where a variety of chemical reactions took place during rock dissolution. In particular, the formation of authigenic magnetite in solution structures has significant implications for paleomagnetic applications, and use of anisotropy of anhysteretic remanent magnetization and anisotropy of magnetic susceptibility fabrics.     

胶东海阳所超镁铁岩中强亲铁元素的地球化学特征及其构造环境探讨

强亲铁元素与亲石元素具有不同的地球化学行为，因此能够从不同的角度为造山带中超镁铁岩的成因及演化提供重要信息。位于苏鲁造山带东北端的胶东海阳所超镁铁岩主要由橄榄岩和辉石岩组成，它们常以团块状赋存于花岗质片麻岩中。虽然前人对这些超镁铁岩已经开展大量岩石学研究，但关于其成因及构造属性仍存在较大争议。本文开展了海阳所超镁铁岩的全岩主微量元素、强亲铁元素及Re-Os同位素的分析工作，结果显示蛇纹石化橄榄岩具有较高的MgO和Fe₂O₃^T含量，较低的Al₂O₃、TiO₂和CaO含量，明显富集流体迁移元素（U、Pb），亏损高场强元素（Zr、Hf），强亲铁元素没有发生明显分异，但Ru显示正异常，表明海阳所蛇纹石化橄榄岩是经历了低-中等程度部分熔融及熔/流体交代作用影响的残余地幔橄榄岩。海阳所辉石岩的主量元素表现出明显的结晶分异特征，稀土元素较原始地幔富集，铂族元素（PGEs）含量较低且发生了明显的分异，表明辉石岩的地幔源区经历过高程度的部分熔融和硫化物的分离。海阳所蛇纹石化橄榄岩的Os同位素地球化学特征表现出大洋亲和性，与辉石岩不具有熔体-残留体的关系。由于该地区发育较深层次的韧性剪切带，蛇纹石化橄榄岩中的橄榄石与辉石表现出韧性变形的特征，同时有辉石岩侵入到橄榄岩的现象，表明该地区的蛇纹石化地幔橄榄岩与辉石岩既不同时，也不同源，因此，暗示了该套岩石组合可能形成于大洋核杂岩（OCC）与洋脊型蛇绿岩（MOR）堆晶岩交互发育环境。