Influence of runout‐path material on emplacement of the Round Top rock avalanche,New Zealand

Factors influencing the distance a disintegrating rock mass travels as it spreads across the landscape after detaching from a slope include the volume and mechanical properties of the material, local topography and the materials encountered in the runout path. Here we investigate the influence of runout‐path material on the mobility and final morphology of the Round Top rock avalanche deposit, New Zealand. This rock avalanche of mylonitic schist ran out over a planar surface of saturated fluvial gravel. Longitudinal ridges aligned radial to source grade into smaller aligned hummocks and digitate lobes in the distal reach. Soils and river gravels in the runout path are found bulldozed at elongate ridge termini where they formed local obstacles halting avalanche motion at these locations, thus aiding development of prominent elongate ridges on the deposit. Further travel over the disrupted substrate led to avalanche–substrate mixing at the base of the debris mass. Field observations combined with subsurface geophysical investigations and laboratory analogue models illustrate the processes of substrate deformation features at the Round Top rock avalanche. Copyright © 2009 John Wiley & Sons, Ltd.     

Multi‐method (14C, 36Cl, 234U/230Th) age bracketing of the Tschirgant rock avalanche (Eastern Alps): implications for absolute dating of catastrophic mass‐wasting

Correct and precise age determination of prehistorical catastrophic rock‐slope failures prerequisites any hypotheses relating this type of mass wasting to past climatic regimes or palaeo‐seismic records. Despite good exposure, easy accessibility and a long tradition of absolute dating, the age of the 230 million m³ carbonate‐lithic Tschirgant rock avalanche event of the Eastern Alps (Austria) still is relatively poorly constrained. We herein review the age of mass‐wasting based on a total of 17 absolute ages produced with three different methods (¹⁴C, ³⁶Cl, ²³⁴U/²³⁰Th). Chlorine‐36 (³⁶Cl) cosmogenic surface exposure dating of five boulders of the rock avalanche deposit indicates a mean event age of 3.06 ± 0.62 ka. Uranium‐234/thorium‐230 (²³⁴U/²³⁰Th) dating of soda‐straw stalactites formed in microcaves beneath boulders indicate mean precipitation ages of three individual soda straws at 3.20 ± 0.26 ka, 3.04 ± 0.10 ka and 2.81 ± 0.15 ka; notwithstanding potential internal errors, these ages provide an ‘older‐than’ (ante quam) proxy for mass‐wasting. Based on radiocarbon ages (nine sites) only, it was previously suggested that the present rock avalanche deposit represents two successive failures (3.75 ± 0.19 ka bp , 3.15 ± 0.19 ka bp ). There is, however, no evidence for two events neither in surface outcrops nor in LiDAR derived imagery and drill logs. The temporal distribution of all absolute ages (¹⁴C, ³⁶Cl, ²³⁴U/²³⁰Th) also does not necessarily indicate two successive events but suggest that a single catastrophic mass‐wasting took place between 3.4 and 2.4 ka bp . Taking into account the maximum age boundary given by reinterpreted radiocarbon datings and the minimum U/Th‐ages of calcite precipitations within the rock avalanche deposits, a most probable event age of 3.01 ± 0.10 ka bp can be proposed. Our results underscore the difficulty to accurately date catastrophic rock slope failures, but also the potential to increase the accuracy of age determination by combining methods. Copyright © 2016 John Wiley & Sons, Ltd.     

Continental hydrothermal sedimentary siliceous rock and genesis of superlarge germanium (Ge) deposit hosted in coal: A study from the Lincang Ge deposit,Yunnan, China

The study on marine hydrothermal sedimentationtends to be perfect at present, and a suit of hydrother-mal sedimentary distinguishing criterions (includingstructure, conformation, geochemistry, etc.) has beenfound[1—12]. While it is unsubstantial on the study ofhydrothermal sedimentation in continental deposi-tional environment, and little was known about therelation between continental hydrothermal sedimenta-tion and metal mineralization. The Lincang Ge deposit,hosted in coal with independent…     

Insights into river bank erosion processes derived from analysis of negative erosion‐pin recordings: observations from three recent UK studies

Recent studies of river bank erosion in three catchments in the UK have been characterized by the persistent occurrence of negative erosion‐pin results. The cause of these negative recordings is considered with reference to field data from the Afon Trannon, Nant Tanllwyth and River Arrow, and to a laboratory study of freeze–thaw and desiccation processes. It seems that there is potential for, and in some cases evidence of, a number of different circumstances that generate negative results, but none of these alone is sufficient to explain all incidents. Factors considered include: deposition of sediment during high flows; soil fall from the upper parts of the bank on to lower erosion pins; loosening of the soil surface and expansion/contraction of the soil mass with fluctuations in temperature and moisture content; movement of the erosion‐pin within the bank and human interference. Each has its own implications for the use of erosion pins. Further issues arise when including negative data in subsequent data analysis, and it is demonstrated that attempts to correlate erosion rates with hydro‐meteorological data in order to ascertain causes of erosion will be influenced by the way in which negative data are handled. It is thus suggested that any study of river bank erosion using erosion pins should state whether or not negative data were obtained, and if so, how they were included in data analysis. Failure to include this information could lead to comparison of mean erosion rates that reflect bank processes very differently. The studies presented here offer a clear example of the value of ‘anomalous’ field data: results which do not appear to fit expected patterns can reveal as much about the processes in operation as those that do. Copyright © 2002 John Wiley & Sons, Ltd.     

Schmidt‐hammer exposure‐age dating (SHD) of snow‐avalanche impact ramparts in southern Norway: approaches,results and implications for landform age,dynamics and development

Schmidt‐hammer exposure‐age dating (SHD) was applied to the problem of dating the diachronous surfaces of five distal river‐bank boulder ramparts deposited by snow avalanches plunging into the Jostedøla and Sprongdøla rivers in the Jostedalsbreen region of southern Norway. Approaches to local high‐precision linear age calibration, which controlled in different ways for boulder roundness, were developed. The mean age (SHD_mean) and the maximum age (SHD_max) of surface boulders were estimated for whole ramparts, crests and distal fringes. Interpretation was further assisted by reference to R‐value distributions. SHD_mean ages (with 95% confidence intervals) ranged from 520 ± 270 years to 5375 ± 965 years, whereas SHD_max ages (expected to be exceeded by <5% of surface boulders) ranged from 675 to 9065 years. SHD ages from the Jostedøla ramparts tended to be older than those associated with the Sprongdøla, rampart crests were younger than the respective distal fringes, and use of relatively rounded boulders yielded more consistent SHD ages than angular boulders. The SHD_mean ages indicate differences in recent levels of snow‐avalanche activity between ramparts and provide insights into rampart dynamics as boulders are deposited on rampart crests and, in smaller numbers, on the distal fringes. SHD_max ages provide minimum age estimates of rampart age (i.e. the time elapsed since the ramparts began to form) and suggest that at least some of the ramparts have been developing since the early Holocene. Copyright © 2015 John Wiley & Sons, Ltd.     

Occurrence, thermal evolution and primary migration processes derived from studies of organic matter in the Lucaogou source rock at the southern margin of the Junggar Basin, NW China

The Lucaogou Formation carbonate-rich oil shale source rock is exposed at the southern margin of the Junggar Basin, Xinjiang, NW China. We have sampled it in detail and conducted microstructural, mineralogical and geochemical studies, including thin section petrography, UV fluorescence petrography, X-ray diffraction, vitrinite reflectance, bitumen reflectance, fluid inclusion analysis and Raman spectroscopy. Organic matter is disseminated through the carbonate-bearing siltstone source rocks and concentrated in numerous bedding parallel stylolites and in two sets of carbonate veins, one along bedding parallel fractures and the other cross-cutting stylolites and bedding. The research about maturity of organic matter finds vitrinite reflectance values increase from the dispersed kerogen (0.64%) to the stylolites (the one of oriented vitrinite is 0.72% and the one of migrated bitumen is 2.38%); Homogenization temperatures of fluid inclusions in veins containing hydrocarbon fluid inclusions show an increase from 178.5℃ in the bedding parallel veins to 222℃ in the cross-cutting veins, confirmed by Raman spectroscopy. These results support a model of progressive heating accompanied by fluid loss during later stages of thermal maturation of source rock and the onset of primary migration. Obviously, the occurrence of organic matter is the trace of hydrocarbon primary migration, and the bedding lamination surfaces and cross-cutting fissures are the principal pathways of hydrocarbon-bearing fluids migration. Bedding lamination surfaces evolved into stylolites along the earliest primary migration pathways, followed by bedding parallel and cross-cutting fissures.     

Rainfall/runoff processes in a small peri‐urban catchment in the Andes mountains. The Rumihurcu Quebrada,Quito (Ecuador)

Situated at the foot of the Pichincha volcano, the city of Quito is frequently subjected to hydroclimatic hazards. In 1995 an 11·2 km² watershed, located in the vicinity of the city, was equipped with eight rain gauges and two flow gauges to better understand the local rainfall/runoff transformation processes. Rainfall simulation experiments were carried out on more than 40 one‐square‐metre plots to measure infiltration point‐processes. The high density of measurement devices allowed us to identify the origin and nature of the various contributions to runoff for the different physiographic units of the watershed: urban area from an altitude of 2800 to 3200 m; farmland, pasture and forested land, and finally páramo above 3900 m. Runoff occurs mainly in the lower part of the basin and is caused by urbanization; however, the natural soils of this area can also produce Hortonian runoff, which is predominant in a few events. This contribution can be studied through rainfall simulation experiments. In the upper natural zone, the younger and more permeable soils generate less runoff on the slopes. However, almost permanently saturated contributing areas, which are located in the bottom of the quebradas, may generate flood events, the size of which depends on the extent of the area concerned. Variations in the runoff coefficients are related first to the baseflow and second to the amount of rainfall in the previous 24 h. This analysis, which underlines the complexity of a small, peri‐urban, volcanic catchment, is a necessary preliminary to runoff modelling in an area where very few experiments have been carried out on small catchments. Copyright © 2001 John Wiley & Sons, Ltd.     

Distribution,age, and origin of a submarine landslide deposit in the Pleistocene Kiwada Formation,forearc basin fill on the Boso Peninsula,east‐central Japan: Constraints from tephro‐ and biostratigraphy

A mass‐transport deposit named MTD1 (up to 100 m in thickness) is intercalated in the upper Kiwada Formation, a Pleistocene forearc basin fill on the Boso Peninsula, east‐central Japan. The present study aims to examine the origin, age, and distribution of MTD1. MTD1 consists mainly of mudstone blocks containing thin very fine‐ to medium‐grained sandstones, and ranges from tens of centimeters to more than tens of meters in length and thickness. Correlation of marker tuff beds and application of the biostratigraphy of calcareous nannofossils suggest that the blocks in MTD1 were derived from the underlying strata. The total thickness of the stratified blocks from the different stratigraphic horizons exceeds 60 m, implying that MTD1 originated from deeply‐excavated slope failure. The slope failure occurred in a short time interval at ca 1.3 Ma. MTD1 provides an estimate of the height of the escarpment on the basis of the stratigraphic origin of the blocks.     

Hydrological effects of water reservoirs on hydrological processes in the East River (China) basin: complexity evaluations based on the multi‐scale entropy analysis

Using the multi‐scale entropy analysis (MSE), we study the effects of water reservoirs on the river flow records based on long streamflow series covering January 1, 1954 and December 31, 2009 at four representative hydrological stations, i.e. the Longchuan, the Heyuan, the Lingxia and the Boluo stations. Hydrological effects of two major water reservoirs, the Xinfengjiang and the Fengshuba water reservoirs, are evaluated. The results indicate that: (1) before the construction of the water reservoirs, the complexity of the streamflow series comes to be decreasing from the upper to the lower East River and which should be attributed to the topographical properties and buffering effects of the river channel; (2) construction of water reservoirs greatly increases the complexity degree of the hydrological processes, and this influence is subjected to a damping process with the increase of distance between the water reservoirs and the hydrological stations; (3) power generation is the major function of the water reservoirs in the East River basin. The results of this study should be of theoretical and scientific merits in terms of conservation of the ecological environment and also water resources management under the influences of climate changes and intensifying human activities. Copyright © 2011 John Wiley & Sons, Ltd.     

Identifying slope processes over time and their imprint in soils of medium‐high mountains of Central Europe (the Karkonosze Mountains,Poland)

Soils in mountainous areas are often polygenetic, developed in slope covers that relate to glacial and periglacial activities of the Pleistocene and Holocene and reflect climatic variations. Landscape development during the Holocene may have been influenced by erosion/solifluction that often started after the Holocene climatic optimum. To trace back soil evolution and its timing, we applied a multi‐methodological approach. This approach helped us to outline scenario of soil transformation. According to our results, some aeolian input must have occurred in the late Pleistocene. During that time and the early Holocene, the soils most likely had features of Cryosols or Leptosols. Physico‐chemical and mineralogical analyses have indicated that the material was denudated (between late Boreal to the Atlantic) from the ridge and upper‐slope positions forming a colluvium at mid‐slope positions. Later, during the Sub‐Boreal, mass wasting of the remains of silt material deposited at the end of the Pleistocene age on the ridge top seems to have occurred. In addition, the cool and moist conditions caused the deposition of a colluvium at the lower‐slope positions. The next phase was characterized by the transformation of Leptosols/Cambisols into Podzols at upper‐slope or shoulder positions and to Albic Cambisols at mid‐slope positions. During the Sub‐Boreal period, Stagnosols started to form at the lower part of the slope catena. Overall, the highest erosion rates were calculated at the upper‐slope position and the lowest rates at mid‐slope sites. Berylium‐10 (¹⁰Be) data showed that the Bs, BC/C were covered during the Holocene by a colluvium with a different geological composition which complicated the calculation of erosion or accumulation rates. The interpretation of erosion and accumulation rates in such multi‐layered materials may, therefore, be hampered. However, the multi‐methodological reconstruction we applied shed light on the soil and landscape evolution of the eastern Karkonosze Mountains. Copyright © 2017 John Wiley & Sons, Ltd.     

Effect of human‐controlled hydrological regime on the source,transport, and flux of particulate organic carbon from the lower Huanghe (Yellow River)

Evaluating the role of fluvial transfer of terrestrial organic carbon (OC) and subsequent burial in the global carbon cycle requires the sources and fluxes of fluvial OC to be assessed, which remains poorly constrained in the Huanghe (Yellow River). Here, we report the elemental, stable isotopic, and radiocarbon activity of particulate organic carbon (POC) sampled at the outlet of Huanghe in 2012–2013. We show that the Huanghe riverine POC can be explained by binary mixing of fossil (POC_fossil) and non‐fossil (POC_non‐fossil) components, the former may reach ~40% of the total POC. The Huanghe POC_non‐fossil is mostly sourced from C3 plants, with a mean residence time of c. 2200 years. The current human‐controlled hydrological regime strongly influenced the POC sources, transport modes, and fluxes. In 2012–2013, the Huanghe delivered 0.73 Tg (1 Tg = 10¹² g) of POC to the sea, and about 28% of the annual POC flux occurred within a short human induced flood event. Globally, the Huanghe should be one of the largest rivers in the transfer and re‐burial of fossil OC. However, the fate of Huanghe fossil OC is still unconstrained and needs to be further investigated. Copyright © 2015 John Wiley & Sons, Ltd.     

Evaluation of seismic displacement demands from the September 19, 2017 Puebla‐Morelos (Mw = 7.1) earthquake in Mexico City

This short communication presents the assessment of seismic inelastic and elastic displacement demands computed from earthquake ground motions (EQGMs) recorded in Mexico City during the intermediate‐depth intraslab Puebla‐Morelos earthquake on 19 September 2017 (Mw = 7.1). Evaluation is conducted by means of peak elastic and inelastic displacement demand spectra, inelastic displacement ratio, C_R, spectra, and generalized interstory drift spectra computed for selected recording stations located in different soil sites of Mexico City, including those located in areas of reported collapsed buildings. Results of this study confirm previous observations made from interplate (subduction) EQGMs that peak inelastic displacement demands are greater than corresponding elastic counterparts for short‐to‐medium period structures, while the opposite is true for medium‐to‐long period structures. Possible basin site effects were identified from generalized interstory drift spectra. It is also shown that an equation introduced in the literature to obtain estimates of C_R developed from interplate EQGMs provides also a good estimate for mean C_R computed from the intermediate‐depth intraslab EQGMs.     

New insights on the origin of troctolites from the breakaway area of the Godzilla Megamullion (Parece Vela back‐arc basin): The role of melt‐mantle interaction on the composition of the lower crust

The troctolites and olivine‐gabbros from the Dive 6 K‐1147 represent the most primitive gabbroic rocks collected at the Godzilla Megamullion, a giant oceanic core complex formed at an extinct spreading segment of the Parece Vela back‐arc basin (Philippine Sea). Previous investigations have shown that these rocks have textural and major elements mineral compositions consistent with a formation through multistage interaction between mantle‐derived melts and a pre‐existing ultramafic matrix. New investigations on trace element mineral compositions basically agree with this hypothesis. Clinopyroxenes and plagioclase have incompatible element signatures similar to that of typical‐MORB. However, the clinopyroxenes show very high Cr contents (similar to those of mantle clinopyroxene) and rim having sharply higher Zr/REE ratios with respect to the core. These features are in contrast with an evolution constrained by fractional crystallization processes, and suggest that the clinopyroxene compositions are controlled by melt‐rock interaction processes. The plagioclase anorthite versus clinopyroxene Mg#[Mg/(Mg + Fe^Tot)] correlation of the Dive 6 K‐1147 rocks shows a trend much steeper than those depicted by other oceanic gabbroic sections. Using a thermodynamic model, we show that this trend is reproducible by fractionation of melts assimilating 1 g of mantle peridotite per 1 °C of cooling. This model predicts the early crystallization of high Mg# clinopyroxene, consistent with our petrological observation. The melt‐peridotite interaction process produces Na‐rich melts causing the crystallization of plagioclase with low anorthite component, typically characterizing the evolved gabbros from Godzilla Megamullion.     

Carbamazepine Removal from Groundwater: Effectiveness of the TiO2/UV,Nanoparticulate Zero‐Valent Iron,and Fenton (NZVI/H2O2) Processes

Pharmaceutical compounds, widely produced and used all around the world, are partly responsible for the widespread water pollution in the environment. Carbamazepine (CBZ) is an antiepileptic drug that persists in the environment for many years. In the present study, we used the TiO₂/UV, nanoparticulate zero‐valent iron (NZVI), and NZVI/H₂O₂ treatment processes to compare efficiency of CBZ removal from water. Influence of NZVI loading, H₂O₂ concentration, TiO₂ loading, UV lamp power, and the matrix (distilled water and groundwater) on CBZ removal efficiency was evaluated using full factorial design. Results indicated that the NZVI/H₂O₂ process oxidized CBZ within 5 min. On the other hand, the NZVI process alone did not reduce CBZ concentration after 120 min of process time. The NZVI/H₂O₂ process was equally effective in CBZ removal from both distilled water and groundwater whereas the TiO₂/UV process was less effective due to the presence of ions in groundwater. CBZ removal efficiency of the TiO₂/UV process declined 30% when the matrix was changed from distilled water to groundwater. Negative divalent ions, i.e., and , were the main cause of reduction of CBZ removal efficiency from groundwater. It is likely that these two ions adsorb onto, and consequently prevent the superoxide anion and hydroxyl radical OH^? from being generated on, the surface of the TiO₂.