安徽淮北平原钙质结核土分布及成因年代研究

提出了钙质结核土的概念,并详细研究了安徽淮北平原钙质结核土的分布规律、成因年代以及钙质结核的类型。通过地质调查、试验和勘探,并参阅工程勘察报告和文献资料,分析了安徽淮北平原钙质结核土的埋藏和分布规律,绘制了淮北平原钙质结核土平面分布图及典型地层剖面图。钙质结核土分布在淮北平原河间地块、洼地及黄泛平地上,结核层的埋藏标高与地面标高变化基本一致。在剖面上,从上到下,钙质结核一般为雏形钙质结核、完形钙质结核和钙质硬磐层,其粒径和含量随深度增大而增大,在常年地下水位附近常形成钙质硬磐层;根据14C测定的年龄分析,在剖面上,雏形钙质结核、完形钙质结核和钙质硬磐层三种形态的钙质结核年龄逐渐增大     

黄河中游黄土钙质结核及地层学意义

<正> 黄土钙质结核(Concretion)又称石灰质结核、砂薑、砂薑石、姜结人。中药用名姜石、异名(石羌)砺石及裂姜石,地质界通称为黄土钙质结核或黄土小僧。广泛赋存于黄河中游地区丰厚黄土地层中的各类钙质结核是一种土壤新生体。它是更新世以来,温湿与冷干气     

四川盆地中侏罗统沙溪庙组钙质结核的碳、氧同位素特征

四川盆地中侏罗世是恐龙最为繁盛的时期,该时期的沙溪庙组中广泛分布有成土作用形成的钙质结核,对此钙质结核的碳、氧同位素组成进行分析,结果表明,钙质结核的δ18O值在-10.50‰～-7.783‰(PDB)之间,平均值为-9.34‰,δ13C值在-9.30‰～-5.07‰(PDB)之间,平均值为-7.06‰。钙质结核的δ13C值表明这一时期四川盆地的植被以C3植物类型为主;利用Cerling的模型,推测大气CO2的浓度(分压)在1 400 ppmV～2 800 ppmV之间。中侏罗世沙溪庙组钙质结核的碳同位素组成为重建恐龙生活时代的古生态环境提供了地球化学方面的资料。     

冀西北黄土钙质结核形态及其成因动力学特征与地层环境意义

论述了冀西北山间盆地区黄土钙质结核的个体特征及群体分布特点，结合地层的时代划分，总结了钙质结核的地层学意义：中更新统结核个体大，外形多呈块状，内部以均质结构为主，在剖面中常密集成层分布；上更新统结核个体较小，多呈姜状或球状，同心结构居多，分布较稀疏。根据钙质结核在盆地内的空间分布，提出形成钙核的ＣａＣＯ３成分部分可能来自于盆地边缘基岩区，按照结晶动力学原理对钙核的形成过程进行了分析，并在此基础上，对不同特征钙质结核的形成环境进行了讨论。     

阿拉善沙漠植物钙质根管:形态特征、分类及其环境指示意义

在系统总结前人对植物钙质根管定义及形成机制的基础上,采用形态学方法对阿拉善沙漠26组不同形态的植物钙质根管进行了分类,初步统一了我国植物钙质根管的定义及其分类;通过统计阿拉善沙漠不同类型植物钙质根管在全新世的数量分布,探讨了其分布特征可能蕴含的古环境意义。结果表明,植物钙质根管是陆生植物形成的次生碳酸盐结壳,包括钙质根套、绕根结核、根模具、根导管和根状结核五种类型。其中钙质根套和绕根结核的形成受到植物生长及其根围微生物活动的影响,而根模具、根导管和根状结核的形成则不受上述作用的影响。据此将阿拉善沙漠植物钙质根管分为钙质根套和绕根结核两种类型。这两类植物钙质根管在不同时期的相对数量百分比能够指示植物钙质根管形成时期有效湿度的高低,绕根结核数量百分比较高能够指示较高的有效湿度,而钙质根套数量百分比较高则指示了较低的有效湿度。因此,从植物钙质根管中能够提取丰富的古环境信号,并将其运用于沙漠地区的古环境研究中。     

南黄海海州湾外侧钙质结核特征及其成因的研究

南黄海海州湾外侧海底残留砂中分布着大量的钙质结核,我们通过对钙质结核多方面的研究,基本查清其分布规律、形态特征、物质组成、结构构造。并证明钙质结核为晚更新世晚玉木冰期海退时,海底逐渐成陆后,在较寒冷干燥的气候条件下,由地表淡水渗透淋溶及毛细管作用而形成。冰后期海进过程中,再由海水不断侵蚀作用而裸露海底,并逐渐被海水所淹没。因此钙质结核应属陆相蒸发岩类,其形成时间大约距今25000～15000年之间。     

斯里兰卡普塔勒姆地区钙质结核的特征及成因

斯里兰卡国普塔勒姆地区滨海沉积物中发育钙质结核,其与我国黄海和东海钙质结核在成分、结构、构造和古生物化石等方面均存在差异。该地区钙质结核含有大量的海相生物化石及其碎屑,CaO的含量＞44.14％, SiO₂的含量＜12.75％,与同地区的碳酸盐软泥相比,结核相对富铁贫硅和富锶贫钡,说明生物对结核的影响大于对碳酸盐软泥的影响。结核的碳、氧同位素值负偏明显,δ¹³C＜-4.54‰,,δ¹⁸O＜-6.37‰,具有轻碳轻氧的特征。结核的矿物成分、古生物化石、主微量元素和碳、氧同位素资料说明其形成于海相环境,后期因海平面下降,受到大气淡水和地下水的影响,元素含量发生变化,形成颇具特色的钙质结核。     

川北地区下寒武统筇竹寺组钙质结核特征及成因机制

不同成因的钙质结核在研究沉积水体、早期成岩环境及泥页岩的压实程度方面具有重要意义。通过对川北地区旺苍县下寒武统筇竹寺组钙质结核抛光,发现结核内部具有层理、暗色圈层和张裂缝构造。结核和围岩的层理关系和具有漂浮状的微观结构特征表明,该地区结核是形成于压实作用之前的成岩早期结核。对结核中Al、Ti、Ca、K、Na元素分析表明,结核的元素分布受到结核内部裂缝的影响。结核内部富含生物碎屑和其形成深度为数十米的特征,推测结核主要是在硫酸盐还原带生长。结核具有暗色圈层之间层理不弯曲和元素移动的特征,揭示了结核为透入性生长,在整个结核生长阶段就开始大量同时结晶。Mg/Ca和Sr/Ca的比值说明,结核内部钙质成分为富镁方解石-生物成因方解石。结核中富含钙质成分的原因可能是围岩中的生物成因方解石大量向结核运移所致。裂缝的形态特征表明,裂缝为张裂缝。对结核上部地层的沉积特征研究表明,张裂缝的成因很可能与筇竹寺顶部的浊积岩和沧浪铺组底部的似瘤状灰岩快速搬运沉积有关。     

云南元谋盆地干润变性土中次生方解石特征及形成

土壤新生体对于研究区域环境变化、营养元素释放以及次生成矿作用具有重要意义。利用化学分析、X射线衍射、偏光显微镜和扫描电子显微镜等探讨云南省元谋盆地干润变性土钙质结核中的次生方解石的特征和形成过程。结果表明，钙质结核中次生方解石含量高，晶形完整；钙质结核以及次生方解石形成既取决于气候，也与微地形有关。次生方解石的形成过程及特征反映了自全新世以来元谋盆地主要处于干热气候环境中。     

鄂尔多斯盆地南缘铜川地区三叠系延长组油页岩中“钙质结核”的成因初探

在鄂尔多斯盆地南缘铜川地区野外露头三叠系延长组长7段油页岩中发现了一些“钙质结核”,野外露头中呈层状发育于长7段油页岩中,形态为“透镜状”、“椭球状”、“飞碟状”,直径大小约为10～70 cm。为探明其岩石类型和主要岩石组分,运用显微镜薄片鉴定、电子探针实验、能谱分析等方法,对结核体进行岩石学特征分析。在此基础上,对其成因进行初步探讨。岩石学特征显示,霸王庄和宜君套滩剖面的“钙质结核”主要成分为重结晶方解石和晶粒方解石,具“球粒状”结构,岩石类型为灰岩;瑶曲聂家河剖面结核体主要岩石类型为泥-粉晶白云岩。分析认为这些“钙质结核”其野外产状和岩石成分,符合热水沉积碳酸盐岩和受热液活动影响的特征,并且铜川地区在长7期具备热液活动的条件。初步认为这些“钙质结核”为湖底热液活动成因的湖相碳酸盐岩。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

湖北宜昌王家湾五峰组顶部Chondrites的发现及其环境意义

本文报道了湖北宜昌王家湾剖面五峰组笔石页岩段观音桥层发现的遗迹化石Chondrites的分布及其生态特点。结合生物相和同期上扬子海盆相对海平面的变化,分析了盆地水体底域在缺氧一富氧转折时期的古氧相变化特征：指出五峰组笔石页岩段上部地层沉积底域为典型的缺氧环境,在其与上覆观音桥段之间的沉积转换面附近发生了从无氧到有氧的转变,观音桥段中Hirnantia动物群繁盛于富氧的海底环境。     

Alteration of Chalcocite in Tamoshan,Siujen,Kuangsi

It is the purpose of this paper to state briefly the alteration of chalcociteand its products.The specimens were collected by W.Y.Chang' fromTamoshan~2,about 675 m above sea-level.The exact locality of occurrence ison the west slope of the Yao Mountain~(?),12 km SE of Chichenchieh~4,15 kmNE of Tungmu~(?),and 48 km SW of the Siujen~(?) City.     

Analysis of F, Al, Mn, Zn, Fe, Cu, Ca and Mg concentrations in brick teas from main producing areas in China

Brick-tea-type fluorosis is a peculiar endemic disease in China, which had been discovered in minority areas of western China since 1980, and distributed mainly in Tibet, Inner Mongolia, Gansu, Xinjiang, Qinghai and parts of Sichuan Province. The prevalence rate of fluorosis in Tibetan and Mongolian nationality people was higher. Epidemiological investigation showed that fluorosis morbidity and degrees were different in different brick-tea drinking areas, and it was probably caused by drinking various kinds of brick tea from different regions. Therefore, we collected 33 samples of brick tea from six provinces where minority nationalities were accustomed to drinking a large quantity of brick tea. F concentrations were determined by the combustion hydrolysis-ion selective electrode method. The results showed that among the brick teas, the F concentrations ranged from the minimum 74.1 mg/kg in Yunnan Province to the maximum 991.2 mg/kg in Sichuan Province. Besides, there was a great difference among the various kinds of brick tea, and F concentrations decreased in the order of Kang brick tea, Green brick tea, Black brick tea, Mi brick tea, Fu brick tea, Chitsu ping tea, Puerh tea, and Tuo tea. The average F concentration in brick teas was 431.92 mg/kg.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

等离子体质谱法测定岩石中的锆、铪、铌、钽

本文建立了用HF、HNO3 在高压釜内溶解样品 ,准确测定花岗岩样品中Nb、Ta、Zr、Hf的ICP MS分析方法。分析结果与推荐值的偏差在 5 %以内。该方法具有简单、准确、测定元素多的特点。本文还对高压釜酸溶和碱熔方法进行了对比实验。     

贵州安顺地区岩腊片区水淹坝岩溶内涝成因分析

水淹坝岩溶内涝是安顺市西秀区发育最大范围的岩溶内涝,严重制约了当地经济发展。本文以岩溶地下水系统为单元,通过开展1:10000水文地质调查、地球物理勘探、水文地质钻探等手段,查明内涝所在区的岩溶发育特征、水文地质条件。在此基础上分析得出,水力坡度小、岩层倾角缓造成地下河管道淤塞;人类工程活动使有水落水洞口堵塞,加之广阔的集雨面积和连续的强降雨是造成水淹坝岩溶内涝的主要原因。通过对水淹坝内涝成因分析,为岩溶内涝灾害综合整治提供参考依据。     

Partitioning of manganese,iron, copper,zinc, lead,cobalt, and nickel in black coatings on stream boulders in the vicinity of the Magruder mine,Lincoln Co., Georgia

Sequential digestions of Fe-Mn oxide coated boulders collected upstream and downstream from the Magruder mine, Lincoln Co., Georgia, indicate probable partitioning relationships for Zn, Cu, Pb, Co, and Ni with respect to Mn and Fe. Initial digestion with 0.1M hydroxylamine hydrochloride (Hxl) in 0.01M HNO₃ selectively dissolyes Mn oxides, whereas subsequent digestion with 1:4 HCl dissolves remaining Fe oxides.The results indicate that partitioning is not constant, but varies systematically with respect to the location of metal-rich waters derived from sulfide mineralization. Upstream from the mineralized zone Zn and Ni are distinctly partitioned to the Fe oxide component and Co and Cu are partitioned to the Mn oxide component. Immediately downstream from the mineralized zone, Mn oxides become relatively more enriched in Zn, whereas Fe oxides are relatively more enriched in Cu, Co, and Ni. Analytical precision for Pb is poor, but available data suggests it is more closely associated with Fe oxides.For routine geochemical surveys utilizing coated surfaces, a one-step digestion method is probably adequate. Parameters useful for detecting sulfide mineralization are metal concentrations normalized to surface area or various ratios (e.g. Zn/(Mn + Fe), Cu/Mn, Pb/Fe). Ratios can be obtained much faster, and at lower analytical costs than conventional analysis of stream sediment.