40Ar/39Ar Ages and stratigraphy of the Latera caldera,Italy

The Latera caldera is a well-exposed volcano where more than 8 km³ of mafic silica-undersaturated potassic lavas, scoria and felsic ignimbrites were emplaced between 380 and 150 ka. Isotopic ages obtained by ⁴⁰Ar/³⁹Ar analysis of single sanidine crystals indicate at least four periods of explosive eruptions from the caldera. The initial period of caldera eruptions began at 232 ka with emplacement of trachytic pumice fallout and ignimbrite. They were closely followed by eruption of evolved phonolitic magma. After roughly 25 ky, several phonolitic ignimbrites were deposited, and they were followed by phreatomagmatic eruptions that produced trachytic ignimbrites and several smaller ash-flow units at 191 ka. Compositionally zoned magma then erupted from the northern caldera rim to produce widespread phonolitic tuffs, tephriphonolitic spatter, and scoria-bearing ignimbrites. After 40 ky of mafic surge deposit and scoria cone development around the caldera rim, a compositionally zoned pumice sequence was emplaced around a vent immediately northwest of the Latera caldera. This activity marks the end of large-scale explosive eruptions from the Latera volcano at 156 ka.     

A volcanological and geochemical investigation of Boa Vista,Cape Verde Islands; 40Ar/39Ar geochronology and field constraints

Boa Vista, the easternmost island in the Cape Verde archipelago, consists of volcanic products, minor intrusions and a thin partial sedimentary cover. The first 15 age results from ⁴⁰Ar/³⁹Ar incremental heating analysis of groundmass separates from volcanic and plutonic rocks from Boa Vista are presented. The combination of age results and field observations demonstrates that the volcanic activity that formed the island occurred in three main stages: (1) > 16 Ma, (2) 15–12.5 Ma and (3) 9.5–4.5 Ma. The first stage, restricted to the north eastern part of the island, is dominated by ankaramitic lavas. The second stage, consisting of evolved lavas of phonolitic–trachytic compositions and nepheline syenites, makes up large central parts of the island. The large volume of evolved rocks and the extended eruption period of several Ma make stage 2 in Boa Vista unique to Cape Verde. Mainly basanites and nephelinites were erupted during the third stage, initially dominated by eruption of subaerial mafic lavas around 9 Ma. Pillow lavas are erupted around 7 Ma whereupon dominantly subaerial mafic lavas were erupted. Stage 3 saw volcanism in many centres distributed mainly along the present coastline and with activity partly overlapping in time. The volcanic evolution of Boa Vista constrains the initiation of volcanic activity in the Cape Verde archipelago to the eastern islands. Major and trace element geochemistry of 160 volcanic and plutonic rocks representing the entire exposed chronological sequence on Boa Vista is presented, revealing an extremely well developed Daly Gap. Only a little was modified from the mafic magmas that rose in small batches from the mantle. Compositional variation distinguishes each volcanic complex and was to a large extent present in the mantle melts. The highly evolved stage 2 phonolites and trachytes are related through the fractional crystallization of three compositionally distinct magmas. Two of these may have been derived by crystal fractionation of primitive Boa Vista melts, whereas the third was not.     

The eruptive history of the Tequila volcanic field, western Mexico: ages, volumes, and relative proportions of lava types

The eruptive history of the Tequila volcanic field (1600 km²) in the western Trans-Mexican Volcanic Belt is based on ⁴⁰Ar/³⁹Ar chronology and volume estimates for eruptive units younger than 1 Ma. Ages are reported for 49 volcanic units, including Volcán Tequila (an andesitic stratovolcano) and peripheral domes, flows, and scoria cones. Volumes of volcanic units 1 Ma were obtained with the aid of field mapping, ortho aerial photographs, digital elevation models (DEMs), and ArcGIS software. Between 1120 and 200 kyrs ago, a bimodal distribution of rhyolite (~35 km³) and high-Ti basalt (~39 km³) dominated the volcanic field. Between 685 and 225 kyrs ago, less than 3 km³ of andesite and dacite erupted from more than 15 isolated vents; these lavas are crystal-poor and show little evidence of storage in an upper crustal chamber. Approximately 200 kyr ago, ~31 km³ of andesite erupted to form the stratocone of Volcán Tequila. The phenocryst assemblage of these lavas suggests storage within a chamber at ~2–3 km depth. After a hiatus of ~110 kyrs, ~15 km³ of andesite erupted along the W and SE flanks of Volcán Tequila at ~90 ka, most likely from a second, discrete magma chamber located at ~5–6 km depth. The youngest volcanic feature (~60 ka) is the small andesitic volcano Cerro Tomasillo (~2 km³). Over the last 1 Myr, a total of 128±22 km³ of lava erupted in the Tequila volcanic field, leading to an average eruption rate of ~0.13 km³/kyr. This volume erupted over ~1600 km², leading to an average lava accumulation rate of ~8 cm/kyr. The relative proportions of lava types are ~22–43% basalt, ~0.4–1% basaltic andesite, ~29–54% andesite, ~2–3% dacite, and ~18–40% rhyolite. On the basis of eruptive sequence, proportions of lava types, phenocryst assemblages, textures, and chemical composition, the lavas do not reflect the differentiation of a single (or only a few) parental liquids in a long-lived magma chamber. The rhyolites are geochemically diverse and were likely formed by episodic partial melting of upper crustal rocks in response to emplacement of basalts. There are no examples of mingled rhyolitic and basaltic magmas. Whatever mechanism is invoked to explain the generation of andesite at the Tequila volcanic field, it must be consistent with a dominantly bimodal distribution of high-Ti basalt and rhyolite for an 800 kyr interval beginning ~1 Ma, which abruptly switched to punctuated bursts of predominantly andesitic volcanism over the last 200 kyrs.Electronic Supplementary Material Supplementary material is available in the online version of this article at Editorial responsility: J. Donnelly-NolanThis revised version was published online in January 2005 with corrections to Tables 1 and 3.An erratum to this article can be found at     

Ar/Ar geochronology of Neogene phreatomagmatic volcanism in the western Pannonian Basin,Hungary

Neogene alkaline basaltic volcanic fields in the western Pannonian Basin, Hungary, including the Bakony–Balaton Highland and the Little Hungarian Plain volcanic fields are the erosional remnants of clusters of small-volume, possibly monogenetic volcanoes. Moderately to strongly eroded maars, tuff rings, scoria cones, and associated lava flows span an age range of ca. 6 Myr as previously determined by the K/Ar method. High resolution ⁴⁰Ar/³⁹Ar plateau ages on 18 samples have been obtained to determine the age range for the western Pannonian Basin Neogene intracontinental volcanic province. The new ⁴⁰Ar/³⁹Ar age determinations confirm the previously obtained K/Ar ages in the sense that no systematic biases were found between the two data sets. However, our study also serves to illustrate the inherent advantages of the ⁴⁰Ar/³⁹Ar technique: greater analytical precision, and internal tests for reliability of the obtained results provide more stringent constraints on reconstructions of the magmatic evolution of the volcanic field. Periods of increased activity with multiple eruptions occurred at ca. 7.95 Ma, 4.10 Ma, 3.80 Ma and 3.00 Ma.     

Eruptive history and petrology of Mount Drum volcano,Wrangell Mountains,Alaska

Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80×200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occurred in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km³ of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO₂, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in ⁸⁷Sr/⁸⁶Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and disequilibrium mineral assemblages. In addition, some dacites and andesites contain Mg and Ni-rich olivines and/or have high MgO, Cr, Ni, Co, and Sc contents that are not in equilibrium with the host rock and indicate mixing between basalt or cumulate material and more evolved magmas. Incompatible element variations suggest that fractionation is responsible for some of the compositional range between basaltic andesite and dacite, but the rhyolites have K, Ba, Th, and Rb contents that are too low for the magmas to be generated by fractionation of the intermediate rocks. Limited Sr-isotope data support the possibility that the rhyolites may be partial melts of underlying volcanic rocks. Received March 13, 1993/Accepted September 10, 1993     

The occurrence of Mt Barca flank eruption in the evolution of the NW periphery of Etna volcano (Italy)

Geological surveys, tephrostratigraphic study, and ⁴⁰Ar/³⁹Ar age determinations have allowed us to chronologically constrain the geological evolution of the lower NW flank of Etna volcano and to reconstruct the eruptive style of the Mt Barca flank eruption. This peripheral sector of the Mt Etna edifice, corresponding to the upper Simeto valley, was invaded by the Ellittico volcano lava flows between 41 and 29 ka ago when the Mt Barca eruption occurred. The vent of this flank eruption is located at about 15 km away from the summit craters, close to the town of Bronte. The Mt Barca eruption was characterized by a vigorous explosive activity that produced pyroclastic deposits dispersed eastward and minor effusive activity with the emission of a 1.1-km-long lava flow. Explosive activity was characterized by a phreatomagmatic phase followed by a magmatic one. The geological setting of this peripheral sector of the volcano favors the interaction between the rising magma and the shallow groundwater hosted in the volcanic pile resting on the impermeable sedimentary basement. This process produced phreatomagmatic activity in the first phase of the eruption, forming a pyroclastic fall deposit made of high-density, poorly vesicular scoria lapilli and lithic clasts. Conversely, during the second phase, a typical strombolian fall deposit formed. In terms of hazard assessment, the possible occurrence of this type of highly explosive flank eruption, at lower elevation in the densely inhabited areas, increases the volcanic risk in the Etnean region and widens the already known hazard scenario.     

The geology of Mount Hasan stratovolcano, central Anatolia, Turkey

Mount Hasan is a double-peaked stratovolcano, located in Central Anatolia, Turkey. The magmas erupted from this multi-caldera complex range from basalt to rhyolite, but are dominated by andesite and dacite. Two terminal cones (Big Mt. Hasan and Small Mt. Hasan) culminate at 3253 m and 3069 m respectively. There are four evolutionary stages in the history of the volcanic complex (stage 1: Kecikalesi volcano, 13 Ma, stage 2: Palaeovolcano, 7 Ma, stage 3: Mesovolcano and stage 4: Neovolcano). The eruptive products consist of lava flows, lava domes, and pyroclastic rocks. The later include ignimbrites, phreatomagmatic intrusive breccias and nuées ardentes, sometimes reworked as lahars. The total volume is estimated to be 354 km³, the area extent 760 km². Textural and mineralogical data suggest that both magma mixing and fractional crystallization were involved in the generation of the andesites and dacites. The magmas erupted from the central volcanoes show a transition with time from tholeite to calc-alkaline. Three generations of basaltic strombolian cones and lava flows were emplaced contemporaneously with the central volcanoes. The corresponding lavas are alkaline with a sodic tendency.     

Degassing and differentiation in subglacial volcanoes, Iceland

Within the neovolcanic zones of Iceland many volcanoes grew upward through icecaps that have subsequently melted. These steep-walled and flat-topped basaltic subglacial volcanoes, called tuyas, are composed of a lower sequence of subaqueously erupted, pillowed lavas overlain by breccias and hyaloclastites produced by phreatomagmatic explosions in shallow water, capped by a subaerially erupted lava plateau. Glass and whole-rock analyses of samples collected from six tuyas indicate systematic variations in major elements showing that the individual volcanoes are monogenetic, and that commonly the tholeiitic magmas differentiated and became more evolved through the course of the eruption that built the tuya. At Herdubreid, the most extensively studies tuya, the upward change in composition indicates that more than 50 wt.% of the first erupted lavas need crystallize over a range of 60°C to produce the last erupted lavas. The S content of glass commonly decreases upward in the tuyas from an average of about 0.08 wt.% at the base to < 0.02 wt.% in the subaerially erupted lava at the top, and is a measure of the depth of water (or ice) above the eruptive vent. The extensive subsurface crystallization that generates the more evolved, lower-temperature melts during the growth of the tuyas, apparently results from cooling and degassing of magma contained in shallow magma chambers and feeders beneath the volcanoes. Cooling may result from percolation of meltwater down cracks, vaporization, and cycling in a hydrothermal circulation. Degassing occurs when progressively lower pressure eruption (as the volcanic vent grows above the ice/water surface) lowers the volatile vapour pressure of subsurface melt, thus elevating the temperature of the liquidus and hastening liquid-crystal differentiation.     

The Negra Muerta Volcanic Complex, southern Central Andes: geochemical characteristics and magmatic evolution of an episodically active volcanic centre

This petrologic analysis of the Negra Muerta Volcanic Complex (NMVC) contributes to understanding the magmatic evolution of eruptive centres associated with prominent NW-striking fault zones in the southern Central Andes. Specifically, the geochemical characteristics and magmatic evolution of the two eruptive episodes of this Complex are analysed. The first one occurred as an explosive eruption at 9 Ma and is represented by a strongly welded, fiamme-rich, andesitic to dacitic ignimbrite deposit. The second commenced with an eruption of a rhyolitic ignimbrite at 7.6 Ma followed by effusive discharge of hybrid lavas at 7.3 Ma and by emplacement of andesitic to rhyodacitic dykes and domes. Both explosive and effusive eruptions of the second episode occurred within a short time span, but geochemical interpretations permit consideration of the existence of different magmas interacting in the same magma chamber. Our model involves an andesitic recharge into a partially cooled rhyolitic magma chamber, pressurising the magmatic system and triggering explosive eruption of rhyolitic magma. Chemical or mechanical evidence for interaction between the rhyolitic and andesitic magma in the initial stages are not obvious because of their difference in composition, which could have been strong enough to inhibit the interaction between the two magmas. After the initial explosive stages of the eruption at 7.6 Ma, the magma chamber become more depressurised and the most mafic magma settled in compositional layers by fractional crystallisation. Restricted hybridisation occurred and was effective between adjacent and thermally equivalent layers close to the top of the magma chamber. At 7.3 Ma, increments of caldera formation were accompanied by effusive discharge of hybrid lavas through radially disposed dykes whereby andesitic magma gained in importance toward the end of this effusive episode in the central portion of the caldera. Assimilation during turbulent ascent (ATA) is invoked to explain a conspicuous reversed isotopic signature (⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd) in the entire volcanic series. Therefore, the 7.6 to 7.3 Ma volcanic rocks of the NMVC resulted from synchronous and mutually interacting petrological processes such as recharge, fractional crystallization, hybridisation, and Assimilation during Turbulent Ascent (ATA).Geochemical characteristics of both volcanic episodes show diverse type and/or depth in the sources and variable influence of upper crustal processes, and indicate a recurrence in the magma-forming conditions. Similarly, other minor volcanic centres in the transversal volcanic belts of the Central Andes repeated their geochemical signatures throughout the Miocene.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of the eruptive history of Mount Erebus,Antarctica: volcano evolution

Mt. Erebus, a 3,794-meter-high active polygenetic stratovolcano, is composed of voluminous anorthoclase-phyric tephriphonolite and phonolite lavas overlying unknown volumes of poorly exposed, less differentiated lavas. The older basanite to phonotephrite lavas crop out on Fang Ridge, an eroded remnant of a proto-Erebus volcano and at other isolated locations on the flanks of the Mt. Erebus edifice. Anorthoclase feldspars in the phonolitic lavas are large (~10 cm), abundant (~30–40%) and contain numerous melt inclusions. Although excess argon is known to exist within the melt inclusions, rigorous sample preparation was used to remove the majority of the contaminant. Twenty-five sample sites were dated by the ⁴⁰Ar/³⁹Ar method (using 20 anorthoclase, 5 plagioclase and 9 groundmass concentrates) to examine the eruptive history of the volcano. Cape Barne, the oldest site, is 1,311±16 ka and represents the first of three stages of eruptive activity on the Mt. Erebus edifice. It shows a transition from sub-aqueous to sub-aerial volcanism that may mark the initiation of proto-Erebus eruptive activity. It is inferred that a further ~300 ky of basanitic/phonotephritic volcanism built a low, broad platform shield volcano. Cessation of the shield-building phase is marked by eruptions at Fang Ridge at ~1,000 ka. The termination of proto-Erebus eruptive activity is marked by the stratigraphically highest flow at Fang Ridge (758±20 ka). Younger lavas (~550–250 ka) on a modern-Erebus edifice are characterized by phonotephrites, tephriphonolites and trachytes. Plagioclase-phyric phonotephrite from coastal and flank flows yield ages between 531±38 and 368±18 ka. The initiation of anorthoclase tephriphonolite occurred in the southwest sector of the volcano at and around Turks Head (243±10 ka). A short pulse of effusive activity marked by crustal contamination occurred ~160 ka as indicated by at least two trachytic flows (157±6 and 166±10 ka). Most anorthoclase-phyric lavas, characteristic of Mt. Erebus, are less than 250 ka. All Mt. Erebus flows between about 250 and 90 ka are anorthoclase tephriphonolite in composition.Editorial responsibility: J. Donelly-Nolan     

Miocene silicic volcanism in southwestern Idaho: geochronology,geochemistry, and evolution of the central Snake River Plain

New ⁴⁰Ar-³⁹Ar geochronology, bulk rock geochemical data, and physical characteristics for representative stratigraphic sections of rhyolite ignimbrites and lavas from the west-central Snake River Plain (SRP) are combined to develop a coherent stratigraphic framework for Miocene silicic magmatism in this part of the Yellowstone ‘hotspot track’. The magmatic record differs from that in areas to the west and east with regard to its unusually large extrusive volume, broad lateral scale, and extended duration. We infer that the magmatic systems developed in response to large-scale and repeated injections of basaltic magma into the crust, resulting in significant reconstitution of large volumes of the crust, wide distribution of crustal melt zones, and complex feeder systems for individual eruptive events. Some eruptive episodes or ‘events’ appear to be contemporaneous with major normal faulting, and perhaps catastrophic crustal foundering, that may have triggered concurrent evacuations of separate silicic magma reservoirs. This behavior and cumulative time-composition relations are difficult to relate to simple caldera-style single-source feeder systems and imply complex temporal-spatial development of the silicic magma systems. Inferred volumes and timing of mafic magma inputs, as the driving energy source, require a significant component of lithospheric extension on NNW-trending Basin and Range style faults (i.e., roughly parallel to the SW–NE orientation of the eastern SRP). This is needed to accommodate basaltic inputs at crustal levels, and is likely to play a role in generation of those magmas. Anomalously high magma production in the SRP compared to that in adjacent areas (e.g., northern Basin and Range Province) may require additional sub-lithospheric processes. Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users. This paper constitutes part of a special issue dedicated to Bill Bonnichsen on the petrogenesis and volcanology of anorogenic rhyolites.     

Eruption of kimberlite magmas: physical volcanology, geomorphology and age of the youngest kimberlitic volcanoes known on earth (the Upper Pleistocene/Holocene Igwisi Hills volcanoes, Tanzania)

The Igwisi Hills volcanoes (IHV), Tanzania, are unique and important in preserving extra-crater lavas and pyroclastic edifices. They provide critical insights into the eruptive behaviour of kimberlite magmas that are not available at other known kimberlite volcanoes. Cosmogenic ³He dating of olivine crystals from IHV lavas and palaeomagnetic analyses indicates that they are Upper Pleistocene to Holocene in age. This makes them the youngest known kimberlite bodies on Earth by >30?Ma and may indicate a new phase of kimberlite volcanism on the Tanzania craton. Geological mapping, Global Positioning System surveying and field investigations reveal that each volcano comprises partially eroded pyroclastic edifices, craters and lavas. The volcanoes stand <40?m above the surrounding ground and are comparable in size to small monogenetic basaltic volcanoes. Pyroclastic cones consist of diffusely layered pyroclastic fall deposits comprising scoriaceous, pelletal and dense juvenile pyroclasts. Pyroclasts are similar to those documented in many ancient kimberlite pipes, indicating overlap in magma fragmentation dynamics between the Igwisi eruptions and other kimberlite eruptions. Characteristics of the pyroclastic cone deposits, including an absence of ballistic clasts and dominantly poorly vesicular scoria lapillistones and lapilli tuffs, indicate relatively weak explosive activity. Lava flow features indicate unexpectedly high viscosities (estimated at >10² to 10⁶?Pa?s) for kimberlite, attributed to degassing and in-vent cooling. Each volcano is inferred to be the result of a small-volume, short-lived (days to weeks) monogenetic eruption. The eruptive processes of each Igwisi volcano were broadly similar and developed through three phases: (1) fallout of lithic-bearing pyroclastic rocks during explosive excavation of craters and conduits; (2) fallout of juvenile lapilli from unsteady eruption columns and the construction of pyroclastic edifices around the vent; and (3) effusion of degassed viscous magma as lava flows. These processes are similar to those observed for other small-volume monogenetic eruptions (e.g. of basaltic magma).     

Ar–Ar geochronology of Santo Antão, Cape Verde Islands

Santo Antão, the northernmost island of the Cape Verde Archipelago, consists entirely of silica-undersaturated volcanic products and minor intrusions. ⁴⁰Ar–³⁹Ar incremental heating experiments have been carried out on 24 samples that cover the entire exposed chronological sequence. The oldest lavas (7.57±0.56 Ma), representing an older volcanic basement, are exposed about 620 m above mean sea level. After an interval of quiescence of up to 4.3 Ma the volcanic activity resumed and continued at low eruption rates. The older basement is unconformably overlain by a ca. 810-m-thick lava sequence that spans an age range from 2.93±0.03 to 1.18±0.01 Ma. This sequence is cut by many dykes and sills. Simultaneous volcanic activity occurred in the northeastern, central and eastern part of the island. A phonolitic pumice deposit that forms a noteworthy feature over most of the island has an estimated age of 0.20 Ma. This predates volcanic activity that formed the highest point of the island (Tope de Coroa) which has an age of 0.17±0.02 Ma. The most recent eruption on the island formed nephelinitic lavas in the Porto Novo region at 0.09±0.03 Ma. The oldest volcanism exposed on Santo Antão, which took place about 7.6 Ma ago, was simultaneous with waning activity on Maio at the eastern end of the Cape Verde Archipelago.     

Postshield volcanism and catastrophic mass wasting of the Waianae Volcano, Oahu, Hawaii

 The 3.9- to 2.9-Ma Waianae Volcano is the older of two volcanoes making up the island of Oahu, Hawaii. Exposed on the volcanic edifice are tholeiitic shield lavas overlain by transitional and alkalic postshield lavas. The postshield "alkalic cap" consists of aphyric hawaiite of the Palehua Member of the Waianae Volcanics, overlain unconformably by a small volume of alkalic basalt of the Kolekole Volcanics. Kolekole Volcanics mantle erosional topography, including the uppermost slopes of the great Lualualei Valley on the lee side of the Waianae Range. Twenty new K–Ar dates, combined with magnetic polarity data and geologic relationships, constrain the ages of lavas of the Palehua member to 3.06–2.98 Ma and lavas of the Kolekole Volcanics to 2.97–2.90 Ma. The geochemical data and the nearly contemporaneous ages suggest that the Kolekole Volcanics do not represent a completely independent or separate volcanic event from earlier postshield activity; thus, the Kolekole Volcanics are reduced in rank, becoming the Kolekole Member of the Waianae Volcanics. Magmas of the Palehua and Kolekole Members have similar incompatible element ratios, and both suites show evidence for early crystallization of clinopyroxene consistent with evolution at high pressures below the edifice. However, lavas of the Kolekole Member are less fractionated and appear to have evolved at greater depths than the earlier Palehua hawaiites. Postshield primary magma compositions of the Palehua and Kolekole Members are consistent with formation by partial melting of mantle material of less than 5–10% relative to Waianae shield lavas. Within the section of Palehua Member lavas, an increase with respect to time of highly incompatible to moderately incompatible element ratios is consistent with a further decrease in partial melting by approximately 1–2%. This trend is reversed with the onset of eruption of Kolekole Member lavas, where an increase in extent of partial melting is indicated. The relatively short time interval between the eruption of Palehua and Kolekole Member lavas appears to date the initial formation of Lualualei Valley, which was accompanied by a marked change in magmatic conditions. We speculate that the mass-wasting event separating lavas of the Palehua and Kolekole Members may be related to the formation of a large submarine landslide west and southwest of Waianae Volcano. Enhanced decompression melting associated with removal of the equivalent volume of this landslide deposit from the edifice is more than sufficient to produce the modeled increase of 1–2% in extent of melting between the youngest Palehua magmas and the posterosional magmas of the Kolekole Member. The association between magmatic change and a giant landsliding event suggests that there may be a general relationship between large mass-wasting events and subsequent magmatism in Hawaiian volcano evolution. Received: 1 September 1996 / Accepted: 26 November 1996     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar dating of the eruptive history of Mount Erebus,Antarctica: summit flows,tephra, and caldera collapse

Eruptive activity has occurred in the summit region of Mount Erebus over the last 95 ky, and has included numerous lava flows and small explosive eruptions, at least one plinian eruption, and at least one and probably two caldera-forming events. Furnace and laser step-heating ⁴⁰Ar/³⁹Ar ages have been determined for 16 summit lava flows and three englacial tephra layers erupted from Mount Erebus. The summit region is composed of at least one or possibly two superimposed calderas that have been filled by post-caldera lava flows ranging in age from 17 ± 8 to 1 ± 5 ka. Dated pre-caldera summit flows display two age populations at 95 ± 9 to 76 ± 4 ka and 27 ± 3 to 21 ± 4 ka of samples with tephriphonolite and phonolite compositions, respectively. A caldera-collapse event occurred between 25 and 11 ka. An older caldera-collapse event is likely to have occurred between 80 and 24 ka. Two englacial tephra layers from the flanks of Mount Erebus have been dated at 71 ± 5 and 15 ± 4 ka. These layers stratigraphically bracket 14 undated tephra layers, and predate 19 undated tephra layers, indicating that small-scale explosive activity has occurred throughout the late Pleistocene and Holocene eruptive history of Mount Erebus. A distal, englacial plinian-fall tephra sample has an age of 39 ± 6 ka and may have been associated with the older of the two caldera-collapse events. A shift in magma composition from tephriphonolite to phonolite occurred at around 36 ka.Editorial responsibility: Julie Donnelly-Nolan     

腾冲火山活动的时代和岩浆来源问题

47个腾冲火山岩样品的K-Ar年龄值域在0.09和17.84Ma之间。4条火山岩的⁴⁰Ar/³⁶Ar-⁴⁰K/³⁶Ar等时线年龄分别为2.93、0.81、0.31和0.13Ma。火山喷发的时代从中新世到更新世,喷发的高潮在晚更新世。腾冲火山目前还不是死火山,而腾冲及其邻区的热事件（侵入-热变质-喷发）又是连续发生的。20个样品的Rb和Sr含量、稳定Sr同位素初始比（0.70578-0.71437）以及其它地球化学资料还表明,这些火山岩是属于板块碰撞带生成的高钾钙碱性岩浆系列。火山岩的母岩浆来源于地幔的玄武岩浆,但在上升过程中受到过富含放射性成因Sr的地壳物质的强烈渐进混染。     

The Pleistocene cinder cones surrounding Volcán Colima, Mexico re-visited: eruption ages and volumes, oxidation states, and sulfur content

Located at the volcanic front in the western Mexican arc, in the Colima Rift, is the active Volcán Colima, which lies on the southern end of the massive (∼450 km³) Colima-Nevado volcanic complex. Along the margins of this andesitic volcanic complex, is a group of 11 scoria cones and associated lavas, which have been dated by the ⁴⁰Ar/³⁹Ar method. Nine scoria cones erupted ∼1.3 km³ of alkaline magma (basanite, leucite-basanite, minette) between 450 and 60 ka, with >99% between 240 and 60 ka. Two additional cones (both the oldest and calc-alkaline) erupted <0.003 km³ of basalt (0.5 Ma) and <0.003 km³ of basaltic andesite (1.2 Ma), respectively. Cone and lava volumes were estimated with the aid of digital elevation models (DEMs). The eruption rate for these scoria cones and their associated lavas over the last 1.2 Myr is ∼1.2 km³/Myr, which is more than 400 times smaller than that from the andesitic Colima-Nevado edifice. In addition to these alkaline Colima cones, two other potassic basalts erupted at the volcanic front, but ∼200 km to the ESE (near the historically active Volcán Jorullo), and were dated at 1.06 and 0.10 Ma. These potassic suites reflect the tendency in the west-central Mexican arc for magmas close to the volcanic front to be enriched in K₂O relative to those farther from the trench.Ferric-ferrous analyses on pristine samples from the alkaline cones adjacent to V. Colima and V. Jorullo indicate that their oxygen fugacities relative to the nickel-nickel oxide buffer are significantly higher (ΔNN0=2–4) than those for the calc-alkaline magma types (0–1.5). These ΔNNO values correlate positively with Ba concentrations and likely reflect the influence of a slab-derived fluid. As a result of the high oxidation states, the solubility of sulfur in these potassic magmas is enhanced. Indeed the sulfur content of both the whole rock and the apatite phenocrysts (and in olivine melt inclusions reported in the literature) suggest that part of their pre-eruptive sulfur gas (SO₂) concentrations could have been discharged to the atmosphere in amounts comparable to the 1982 eruption of El Chichón, although over a prolonged period spanning thousands of years (not per eruption).Electronic Supplementary Material Supplementary material is available for this article at Editorial responsibility: J. Donnelly-Nolan     

Apoyo caldera, Nicaragua: A major quaternary silicic eruptive center

Apoyo caldera, near Granada, Nicaragua, was formed by two phases of collapse following explosive eruptions of dacite pumice about 23,000 yr B.P. The caldera sits atop an older volcanic center consisting of lava flows, domes, and ignimbrite (ash-flow tuff). The earliest lavas erupted were compositionally homogeneous basalt flows, which were later intruded by small andesite and dacite flows along a well defined set of N—S-trending regional faults. Collapse of the roof of the magma chamber occurred along near-vertical ring faults during two widely separated eruptions. Field evidence suggests that the climactic eruption sequence opened with a powerful plinian blast, followed by eruption column collapse, which generated a complex sequence of pyroclastic surge and ignimbrite deposits and initiated caldera collapse. A period of quiescence was marked by the eruption of scoria-bearing tuff from the nearby Masaya caldera and the development of a soil horizon. Violent plinian eruptions then resumed from a vent located within the caldera. A second phase of caldera collapse followed, accompanied by the effusion of late-stage andesitic lavas, indicating the presence of an underlying zoned magma chamber. Detailed isopach and isopleth maps of the plinian deposits indicate moderate to great column heights and muzzle velocities compared to other eruptions of similar volume. Mapping of the Apoyo airfall and ignimbrite deposits gives a volume of 17.2 km³ within the 1-mm isopach. Crystal concentration studies show that the true erupted volume was 30.5 km³ (10.7 km³ Dense Rock Equivalent), approximately the volume necessary to fill the caldera. A vent area located in the northeast quadrant of the present caldera lake is deduced for all the silicic pyroclastic eruptions. This vent area is controlled by N—S-trending precaldera faults related to left-lateral motion along the adjacent volcanic segment break. Fractional crystallization of calc-alkaline basaltic magma was the primary differentiation process which led to the intermediate to silicic products erupted at Apoyo. Prior to caldera collapse, highly atypical tholeiitic magmas resembling low-K, high-Ca oceanic ridge basalts were erupted along tension faults peripheral to the magma chamber. The injection of tholeiitic magmas may have contributed to the paroxysmal caldera-forming eruptions.     

Refinement of the late Quaternary geologic history of Erebus volcano,Antarctica using Ar/Ar and Cl age determinations

Six new ⁴⁰Ar/³⁹Ar and three cosmogenic ³⁶Cl age determinations provide new insight into the late Quaternary eruptive history of Erebus volcano. Anorthoclase from 3 lava flows on the caldera rim have ⁴⁰Ar/³⁹Ar ages of 23 ± 12, 81 ± 3 and 172 ± 10 ka (all uncertainties 2σ). The ages confirm the presence of a second, younger, superimposed caldera near the southwestern margin of the summit plateau and show that eruptive activity has occurred in the summit region for 77 ± 13 ka longer than previously thought. Trachyte from “Ice Station” on the eastern flank is 159 ± 2 ka, similar in age to those at Bomb Peak and Aurora Cliffs. The widespread occurrences of trachyte on the eastern flank of Erebus suggest a major previously unrecognized episode of trachytic volcanism. The trachyte lavas are chemically and isotopically distinct from alkaline lavas erupted contemporaneously in the summit region < 5 km away.     

Volatile-rich magma injection into the feeding system during the 2001 eruption of Mt. Etna (Italy): its role on explosive activity and change in rheology of lavas

The explosive behavior and the rheology of lavas in basaltic volcanoes, usually driven by differentiation, can also be significantly affected by the kinetics of magma degassing in the upper portion of the feeding system. The complex eruption of 2001 at Mt. Etna, Italy, was marked by two crucial phenomena that occurred at the Laghetto vent on the southern flank of the volcano: 1) intense explosive activity and 2) at the end of the eruption, emission of a lava flow with higher viscosity than flows previously emitted from the same vent. Here, we investigate the hypothesis that these events were driven by the injection of volatile-rich magma into the feeding system. The input and mixing of this magma into a reservoir containing more evolved magma had the twofold effect of increasing 1) the overall concentration of volatiles and 2) their exsolution with consequent efficient vesiculation and degassing. This led to an explosive stage of the eruption, which produced a ~75-m-high cinder cone. Efficient volatile loss and the consequent increase of the liquidus temperature brought about the nucleation of Fe-oxides and other anhydrous crystalline phases, which significantly increased the magma viscosity in the upper part of the conduit, leading to the emission of a high viscosity lava flow that ended the eruption. The 2001 eruption has offered the opportunity to investigate the important role that input of volatile-rich magma may exert in controlling not only the geochemical features of erupted lavas but also the eruption dynamics. These results present a new idea for interpreting similar eruptions in other basaltic volcanoes and explaining eruptions with uncommonly high explosivity when only basic magmas are involved.