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1.
Petrological indices and major element chemistry may be used to select individual plutons within a batholith which are most likely to be tin bearing. The origin and evolution of only the selected individual plutons may be assessed using trace elemental contents and dispersions, (Rb, Ba, Pb, Zn, Mo, Li, Be, F, and W) and selected elemental ratios, K/Na, Ba/Rb, (Li × 1000)/K, Li/Zn, and F/Li. This information may also be used to assess the ore bearing potential of the plutons. The method has been applied to three plutons within the South Mountain Batholith of Nova Scotia, using 75 whole rock major and trace element analyses. The results suggest that only the New Ross Pluton, in which several tin prospects are known, might be ore bearing. All the plutons are considered to be deeply eroded and any economic cassiterite deposits have probably been removed by erosion.  相似文献   

2.
Three southern Nova Scotia plutons crystallized rapidly at 375 Ma from magma containing both mantle and crustal components. Isotopic and chemical data suggest that the crustal contribution included both lower crustal material and Cambro-Ordovician turbidites of the host Meguma Group. Despite local evidence of mixing and mingling of magmas, the bulk of the plutons evolved by assimilation and fractional crystallisation. Evolved portions of the plutons have compositions appropriate for development of rare-metal pegmatite fields, but pegmatites are relatively rare and little differentiated. Like parental plutons, pegmatites fall into biotite+plagioclase and muscovite+potassium feldspar assemblages. The latter locally contain Mn-rich garnet+biotite, giving calculated PT conditions of pegmatite crystallisation of 620°C, 0.44 GPa under water-saturated conditions. Host rocks at the time of emplacement experienced PT conditions varying from <500° to 620°C at 0.44 GPa. Beryl-bearing pegmatites occur only where host rocks were below sillimanite-grade, and pegmatites of any kind are scarce in sillimanite-grade host rocks. Rarity of pegmatites can be ascribed to a combination of insufficient amounts of F, Li, and B in the magma with rapid cooling which prevented extensive fractionation and undercooling. Our data suggest rather that peraluminous suites, produced by rapid heating due to incursions of lithospheric mantle into supracrustal rocks, and typified by biotite-rich, cordierite-bearing plutons, are not favorable locales for major rare-metal-enriched pegmatite fields. Such fields appear to require relatively prolonged anatexis resulting from crustal thickening, or an areally extensive mafic underplate,  相似文献   

3.
Chemical analyses are given for actinolitic hornblendes of tonalitic rocks from the Hercynian belt of Northern Portugal. The distribution of elements between amphibole and co-existing biotite is studied. The composition of the amphiboles is analysed in the light of experimental data on amphiboles and the physical conditions of crystallization inferred from the study of the biotite and rock series. The data on the biotites lead to the definition of a temperature of 800°C for the crystallization of actinolitic hornblendes with Mg/(Mg + Fe) ratios of 0·72-0·61 at pressures of about 3 Kb and fO2 defined by FMQ.  相似文献   

4.
Tin-bearing granitic rocks of northeast Queensland range in age from Precambrian to Permian. They are high-level granites or adamellites enriched in volatile elements, such as Li, Be, B, and F. Tin contents are significantly higher than those of non-stanniferous granites, but lower than values reported for many tin granites elsewhere. A distribution of tin in which a high proportion of samples have tin contents significantly higher than background values, appears to be a useful criterion of potential tin mineralization. An uneven distribution of tin in the crust (or possibly the upper mantle) would explain the difference in tin contents of granites associated with tin mineralization, compared with granites from areas which do not contain tin deposits.No correlation of granite geochemistry with lead/zinc or copper mineralization was found. In particular, granites associated with such mineralization do not show anomalous abundances of Pb, Zn, or Cu. If mineralization is regarded as an independent by-product of magma generation rather than the result of differentiation processes, then this lack of correlation is explicable.  相似文献   

5.
天山石炭-二叠纪后碰撞花岗质岩石地球化学研究   总被引:16,自引:1,他引:16  
在对前人研究资料综合的基础上,重点对天山造山带不同构造单元中石炭—二叠纪后碰撞花岗岩地球化学特征进行了对比研究,认为天山石炭—二叠纪后碰撞花岗质岩石属高钾钙碱—钾玄岩系列,以钙碱系花岗质岩石类型为主。其中,发育在裂谷带中的石炭—二叠纪花岗质岩石较发育在古微地块中或其边缘的花岗质岩石富MgO、TiO2、Na2O,贫K2O、Nb、Th,两者具有不同的源区。裂谷带中的花岗质岩石多与火山岩同源,由含不同程度壳源组分的壳幔混合源岩浆形成,而古微地块花岗质岩石主要来自壳源。处于同一类构造位置但不同地区的花岗质岩石化学成分也不相同,如天山西端伊犁地块南缘的托木尔峰花岗质岩石较天山中东段南部的库鲁克塔格花岗质岩石富Fe、Mg、K、Nb、Sr,而贫Zr、Ba,它们均是壳源成因,反映了天山东、西地壳基底组分的不同。石炭—二叠纪裂谷带中的花岗质岩石在天山东、西段也有差别,东段的觉罗塔格和博格达花岗质岩石较天山西段伊犁裂谷中的花岗质岩石明显地富Nb、Th而贫Sr、Ba,反映出东、西天山石炭—二叠世花岗岩源区不同。花岗质岩石的正εNd值并不是来源于与基性、超基性岩浆活动有关的幔源组分,而是来自于幔源火山岩浆活动。  相似文献   

6.
7.
Geochemistry of biotites from granitic rocks,Northern Portugal   总被引:2,自引:0,他引:2  
The biotites from a series of rocks ranging in composition from tonalite to granite have been analysed for both major and trace elements.The relations between chemical composition and paragenesis of the biotites are studied. Most biotites co-exist with potassium feldspar and ilmenite. Variations in composition can be correlated with the occurrence of amphibole, primary muscovite and aluminosilicates in the rocks.Variation diagrams of the trace element contents and element ratios of biotite are compared to those of the host rocks. Fractionation of elements can be defined more accurately as the influence of other mineral phases is eliminated.Variations in the proportions of the octahedrally co-ordinated Al, Ti and Fe3+ are correlated with the conditions of crystallization and comparisons made with biotites from other suites of calc-alkali rocks.In the light of the experimental data available, the petrographic observations and the chemical data it is apparent that biotites crystallized from systems in which fO2 was buffered, its values remaining close to that of the buffer FMQ. From the same data, a temperature of 800°C for fO2 = 10?14to 10?15 bars is deduced as prevalent during the crystallization of the tonalites while for the granites, at a temperature of crystallization of 680°C, fO2 = 10?16to 10?18 bars.A calc-alkali trend of fractionation is therefore apparent with decreasing fO2 while fH2O2 remains relatively high.  相似文献   

8.
The granitic and charnockitic intrusions in the Precambrian migmatites around Farsund in southern Norway have previously been shown to be successively intruded as well as being geochemically different. Rb- and Sr-isotope data support the conclusion that they are intruded with a separate time interval and that the Farsund charnockite is younger (852±41 m.y.) than the Lyngdal hornblende granite (932±38 m.y.). Furthermore, the different initial ratios (0.7128 and 0.7054, respectively) disprove a comagmatic origin unless large-scale contamination has occurred.  相似文献   

9.
Concordant granite sheets from the granulite facies Scourian Complex, N.W. Scotland exhibit the following features:
  1. a common planar fabric with their host pyroxene granulites;
  2. the presence of an exsolved ternary feldspar phase;
  3. a low-pressure, water-saturated minimum composition;
  4. K/Rb ratios (450–1,350) distinctly higher than most upper crustal granites but similar to the surrounding granulites;
  5. low absolute concentrations of the rare earth elements (REEs), light REE enrichment, and large positive Eu anomalies.
It is proposed that the granite sheets have originated by anatexis of gneisses undergoing granulite facies metamorphism — gneisses that were already essentially dry and depleted in incompatible elements. Their unusual trace element chemistry may be explained by either disequilibrium melting and/or sub-solidus reequilibration of the granite sheets with the surrounding gneisses. Isotopic and trace element data suggest that cross-cutting, potash-rich pegmatites represent reworking of the granite sheets during a later amphibolitization.  相似文献   

10.
句高  梁一鸿  孙晓  周静 《世界地质》2018,37(2):374-384
通过LA-ICP-MS锆石U-Pb定年和岩石化学分析,研究了张广才岭南段上营北岩体和帽儿山岩体的形成年代,地球化学特征和形成环境。上营北岩体为中粗粒钾长花岗岩,帽儿山岩体为中细粒黑云母钾长花岗岩。上营北岩体的加权平均年龄为178.9±2.7 Ma,帽儿山岩体为183.7±2.4 Ma,均为早侏罗世侵入岩。上营北岩体和帽儿山岩体主量元素都具有Si O_2和K_2O含量较高,Ti O_2、Mg O、Ca O含量较低,TFe O/Mg O值较高的特点;上营北岩体A/CNK=0.98~1.08,里特曼指数σ=1.51~2.66;帽儿山岩体含铝指数A/CNK=1.00~1.01,里特曼指数σ=2.12~2.36。上营北岩体稀土元素配分模式为海鸥型,轻重稀土分馏不明显;帽儿山岩体稀土元素配分模式为右倾型,轻稀土较重稀土富集;两个岩体均富集Rb、K,Ba、Nb、Ta、Sr、Ti、P、Ho、Er、U、Eu等元素出现不同程度的亏损。地球化学特征分析显示上营北岩体和帽儿山岩体均为A_2型花岗岩,为后造山型花岗岩,形成于兴蒙造山带后造山的伸展环境。  相似文献   

11.
The parameters used for the acquisition of the IBERSEIS deep seismic reflection profile in the SW Iberian Peninsula provide seismic images of the deep crust as well as a high resolution section of the shallow subsurface. A very dense array of sources and receivers allowed high resolution tomographic studies in zones of special interest (granitic plutons). The three dimensional tomographic inversion produced velocity models along a 500 m wide and 1000 m deep strip along the IBERSEIS transect in the areas of La Bazana, La Dehesilla, Feria and Villafranca. In these high resolution velocity models (sampled by 50 × 50 × 50 m cells), high velocity anomalies indicate the geology and extension of the granitic plutons at depth. This directly correlates with the surface outcrops. Moreover, tomographic models provided valuable information for the geometry and characterization of fractured and fresh domains in a rock volume. Furthermore, a piggy back seismic acquisition experiment using additional seismic instrumentation from the University of Paris Sud (40-channel DMT) provided perpendicular, offline recordings of the Vibroseis sources. This additional recording system was deployed perpendicularly to the main IBERSEIS seismic reflection line and provided additional 3D control.  相似文献   

12.
南秦岭勉略带北光头山花岗岩体群的成因及其构造意义   总被引:31,自引:15,他引:31  
南秦岭勉略带北部花岗岩体从闪长岩到花岗闪长岩和花岗岩变化,反映了钙碱性岩岩石组合特征,矿物组成以长石、石英、黑云母和少量角闪石为主,副矿物有锆石、磷灰石、磁铁矿和榍石,岩石化学上它们相对高K、Sr,Zr/Y比值较高,富集LEE和LILE,贫化HFSE,与后碰撞富钾钙碱性I型花岗岩特征一致。此外,它们明显亏损Nb、Ta,低Y、Yb和有较高的 LaN/YbN和Sr/Y比值,多数岩体发育淬冷岩浆结构的暗色闪长质微粒包体,包体与寄主花岗岩的稀土及微量元素存在明显差异,证明它们是地壳增厚背景下,可能由下部地壳拆沉作用导致的分别来自幔源和下部地壳熔融的二元岩浆混合演化的产物。个别高分异岩体的Fetot/Mg比值高、明显亏损Sr、Ba、Ti、P,呈现了向强分异A型花岗岩过渡的后碰撞富钾过铝偏碱性花岗岩特征。因此,结合西部岩体形成年代早于东部岩体分析,西部形成时代较早偏中基性的含有大量闪长质微粒包体的岩体代表了早期下部地壳拆沉作用的发生,东部形成较晚分异程度高的高钾钙碱性Ⅰ型花岗岩体的出现指示了南、北两大陆块碰撞汇聚后向伸展的转折,而更晚期高度分异的姜家坪富钾花岗岩体的出现则表明秦岭造山带已进入主碰撞结束期的伸展拉张演化阶段,并预示了新的板内演化期的到来。  相似文献   

13.
The anorogenic igneous rocks of Mull consist essentially of a lava pile of predominantly basaltic composition, cut by an intrusive complex. The basement consists of Precambrian metamorphic rocks of the Moine Series underlain by Lewisian gneiss. The intrusive complex contains a significant proportion of granitic intrusions which can be ascribed to three successive centres of activity, Centres 1–3. We report new major and trace element, including rare earth element analyses, 87Sr/86Sr ratios and 18O values for a comprehensive collection of granitic rocks from the 3 centres. The 18O values range from +4 to –6 indicating variable extent of interaction between the rocks and heated meteoric groundwater. However, correlations of 18O with other major and trace element data and 87Sr/86Sr ratios are uniformly low, apart from Fe2O3. It is thus unlikely that the interaction of the rocks with meteoric water has systematically altered the chemical (including Sr isotope) characteristics. The chemical and Sr isotope data reflect magmatic values and can therefore be used to comment on the petrogenesis of the granitic rocks.These data indicate that there are important differences between granitic rocks of the centres with Centre 1 forming one distinct group and Centres 2 and 3 a different group. For a given SiO2 value, the Centre 1 granites have higher Na2O, MgO, P2O5, TiO2, Sr, and V and lower Al2O3, MnO, Zn, Zr, and Y than those of Centres 2 and 3. In addition, the Centre 1 granites have lower REE contents and higher CeN/YbN ratios than those of Centres 2 and 3. Granites from all three centres have Eu anomalies, those of Centre 3 being generally greater (Eu/Eu* = 0.66–0.10). Finally, there are important Sr isotope distinctions between the three Centres; calculated initial 87Sr/86Sr ratios for the Centre 1 granites (using 58.2Ma) range between 0.71366–0.71646 (average 0.71530) and have a general correlation of 87Sr/86Sr with 87Rb/86Sr. The initial 87Sr/86Sr ratios of the Centre 2 granites range from 0.70663 to 0.70868, but the 87Sr/86Sr data do not define an isochron. Finally, data for the Centre 3 granites define a Rb-Sr wholerock isochron with an age of 58.2±2.5 Ma and an initial 87Sr/86Sr ratio of 0.71003 ±36.Both the chemical trends and isotopic data for the Mull granites can be interpreted in terms of contrasted origins for the granitic rocks of the two groups. The relatively primitive chemical composition and high initial 87Sr/86Sr ratios of the Centre 1 granites indicate a substantial crustal contribution and we consider that these granites formed by a combination of partial melting of Lewisian basement together with some magma derived by fractional crystallization of basaltic magma. In contrast, the chemical and isotope data for the Centre 2 and 3 granites are consistent with formation dominantly by fractional crystallization of basaltic magma, together with a relatively small proportion of crustal contamination. A model is proposed which emphasises that acid magmatism in Mull is a consequence of the rise and crystallization of basic magma into continental crust. Granite magma has formed both by partial melting and by fractional crystallization and both of these events probably occurred under open system conditions.With oxygen isotope analyses by J.J. Durham, Geochemical Division, Institute of Geological Sciences, 64–78 Grays Inn Road, London, WC1X 8NG, England  相似文献   

14.
The Sardinia-Corsica batholith was structured in the late stage of the Hercynian orogenesis. The granitoids intrude mainly metamorphic complexes grading from zeolite up to amphibolite facies. The batholith is heterogeneous consisting of complexes with different affinity, chemical composition, age and degree of deformation. The present paper reports major-and trace-element data for selected samples coming only from Sardinian outcrops.

The rocks range from gabbro-diorite to tonalite, monzogranite and leucogranite. The two latter lithologies are the most abundant, gabbrodiorites and tonalites occurring in minor amounts and mainly in northern-central Sardinia. Over 75% of the granitoids contain microgranular enclaves of magmatic origin. The age of the rocks falls in the interval between 307 and 281 Ma. Sr isotope initial ratios are high, ranging between 0.7083 and 0.7107.

REE, Rb, Sr, Ba, Zr, Th, Ta, Hf, Co and Sc abundances were determined on selected samples. All elements follow three types of trends vs. CaO, which is used as differentiation index. Two trends show positive and negative correlations while the third one shows a bell-shaped pattern. LREE have different degrees of enrichment (La = 20−120× ch) and HREE show variable fractionation with prevailing (Tb/Yb)n<1. The two peraluminous samples have very different geochemical characteristics.

From the geochemical point of view all the rocks coming from the Sardinian segment of the batholith display a typical calc-alkaline chemical character showing the imprint of both “normal and mature” continental arc geodynamic environments.

Geochemical trends suggest some petrogenetic constraints. The complete sequence of differentiation can be neither the product of crystal/liquid fractionation processes starting from a single basic parent magma nor the product of an AFC process. On the contrary, a two-stage model can be proposed. In the first stage a mafic melt of subcrustal origin interacted with monzogranitic magmas derived from 25–35% degree of melting of a crustal biotite amphibolitic source. Such a mixing process acted together with a crystal/liquid fractionation process to give tonalites and granodiorites. In the second stage lesser degrees of melting of the same crustal source could give the late-stage leucogranitic masses.

A possible scenario, able to take into account field and geochemical data, can be suggested for the genesis of this suite and we propose it as a working model for future investigations.  相似文献   


15.
16.
17.
There are two main granitic rocks cropping out in the study area:1) the syn-orogenic granites are moderately weathered,jointed,exfoliated and characterized by low relief.These rocks are subdivided into tonalite and granodiorite.They are essentially composed of plagioclase,quartz,biotite,hornblende and potash feldspar;and 2) the post-orogenic granites,characterized by high relief terrain and represented by monzogranite,syenogranite and alkali granite.The monzogranites suffered hydrothermal alteration in particular along joints,faults,shear zones and fractures,which recorded the highest values of radioactivity,reflecting the role of post-magmatic alteration processes in the enhancement of radioactivity.The hydrothermal alteration(desilicification and hematitization) resulted in the formation of mineralized(altered) granites.The altered granites are enriched in TiO 2,Al 2 O 3,FeO T,MnO,MgO,Na 2 O,Rb,Sr,Y,Zr,Zn,Ga and Co and depleted in SiO 2,CaO,P 2 O 5,Nb,Pb,Cu,Ni and Cr relative to the fresh monzogranite.The investigated granites contain basic xenoliths as well as pockets of pegmatites.Perthites,quartz,plagioclase and sometimes biotite,represent the essential constituents.Some accessory minerals like zircon are metamicted reflecting their radiogenic nature.The alkali granites are characterized by the presence of aegirine,rebeckite and arfvedsonite.Both syn-and post-orogenic granites show some variations in their bulk chemical compositions.The older granitoids are metaluminous and exhibit characteristics of I-type granites and possess an arc tectonic environment.On the other hand,the younger granites are peraluminous and exhibit the characteristics of post-collisional granites.It is interpreted that radioactivity of the studied rocks is mainly controlled by both magmatic and post-magmatic activities.Frequently,the post-orogenic granites host zoned and unzoned pegmatite pockets.Some of these pockets anomalously attain high radioactivity.The syenogranites and the pegmatites are characterized by high contents of SiO 2 and K 2 O and low CaO and MgO.They have transitional characters from highly fractionated calc-alkaline to alkaline.The alkali granites related to A2-subtype of A-type granites.The post-orogenic granites were originated from magma of dominant crustal source materials and related to post-collisional setting under extensional environment.  相似文献   

18.
Mineralization with exchangeable rare earth element (REE) and yttrium (MEX-REY) has been recognized in the weathering profiles in South China since the early 1970's. This type of REY mineralization occurs in weathering profiles of parent rocks ranging in composition from granite to acidic volcanic rocks and lamprophyre. The majority of the known resources occurring in the weathering profiles of granitic rocks. Total resources of this type of REY amount to millions tons of rare earth oxides, and therefore represent one of the most important types of rare earth resources in China, particularly for heavy rare earth elements (HREE) and yttrium.Accumulation of REY in the weathering profiles of granitic rocks is strongly controlled by the resistance to weathering of the principal REY-bearing accessory minerals in the parent rocks; only a limited proportion of total REY (< 30%) is incorporated in the rock-forming minerals. MEX-REY more commonly occur in weathering profiles developed on granitic rocks within which most of the REY are incorporated in accessory minerals weakly resistant to weathering (doverite, parisite, etc.). For the well-developed weathering profiles, three horizons can be distinguished from surface downwards: the lateritic horizon (A), the weathered horizon (B), and the weathering front (C). Continuous leaching, coupled with low rate of denudation, results in the accumulation of REY in the subsurface horizons (the B and C horizons), and thus results in REE differentiation within the well-developed, layered, and mature weathering profiles. Exchangeable REY, which can be replaced by cations like NH4+ and Na+ etc. in electrolyte solutions and can be removed by complexing agents such as EDTA, are commonly the major form of REE occurrence in the B horizon. Cerium is enriched in the top layer (A horizon) and depleted in the subsurface horizons of the weathering profiles, most likely due to the oxidation of Ce(III) to Ce(IV) followed by cerianite formation or absorption onto clays and/or Fe and Al oxyhydroxides.  相似文献   

19.
Early Proterozoic supracrustal and plutonic rocks from the Gold Hill-Wheeler Peak area in northern New Mexico define three populations: amphibolite—diorite—tonalite, hornblendite—cumulus amphibolite and felsic volcanics and porphyries. Also present are mid-Proterozoic granites. Amphibolites are similar in Ti, Zr, Cr, Ni and REE contents to young calc-alkaline and arc basalts and diorites and tonalites are similar in composition to young andesites and to high-Al2O3 tonalites, respectively. Felsic volcanics resemble young felsic volcanics from mature arc systems in their immobile-element contents. Geochemical model studies suggest that the amphibolites, hornblendites, diorites and tonalites are related by progressive fractional crystallization of a hydrous parent tholeiite magma produced from partial melting of undepleted lherzolite. Amphibolites represent parent tholeiites modified by olivine removal. Hornblendite is an early solid residue comprised chiefly of hornblende, clinopyroxene, and olivine; diorite and cumulus amphibolite represent respectively residual solid (clinopyroxene, plagioclase, hornblende) and liquid, after 50% crystallization. Tonalite represents a residual liquid after 80% crystallization. Felsic volcanic rocks are produced by partial melting of a tonalite or diorite source with granulite-facies mineralogy in the lower crust. Granites have a similar origin to felsic volcanics although requiring an inhomogeneous source with the presence of residual hornblende or garnet.The calc-alkaline igneous rocks in the Gold Hill-Wheeler Peak area suggest the presence of an arc system in northern New Mexico during the Early Proterozoic. The fact that these rocks interfinger with and are overlain by mature clastic sediments favors a model in which a continental arc system is uplited, eroded and buried by cratonic sediments from the north.  相似文献   

20.
The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in 87Sr/86Sr310 Ma between 0.708 and 0.712, Nd310 Ma values between − 1 and − 4 and δ18O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ18O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.  相似文献   

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