Microwave remote sensing of Jupiter's atmosphere from an orbiting spacecraft

Microwave remote sounding from a spacecraft flying by or in orbit around Jupiter offers new possibilities for retrieving important and presently poorly understood properties of its atmosphere. In particular, we show that precise measurements of relative brightness temperature as a function of off-nadir emission angles, combined with absolute brightness temperature measurements, can allow us to determine the global abundances of water and ammonia and study the dynamics and deep circulations of the atmosphere in the altitude range from the ammonia cloud region to depths greater than 30 bars in a manner which would not be achievable with ground-based telescopes.     

Jupiter's zone-belt structure at radio wavelengths: II. Comparison of observations with model atmosphere calculations

Model atmosphere calculations are presented which simulate high-resolution maps of Jupiter's radio emission. They are compared with observations recently obtained at the Very Large Array at 1.3, 2.0, 6.1, and 20.5 cm with resolutions ranging from 0.075 to 0.218 Jovian radii (I. de Pater and J. R. Dickel (1986). Jupiter's zone-belt structure at radio wavelengths. I. Observations. Astrophys. J., in press). The models indicate that ammonia gas is strongly depleted in the upper atmosphere with respect to the solar value both in zones and belts. At very high levels in the atmosphere (P < 0.3−0.5 bar) the gas is undersaturated and distributed uniformly over the planet. In the cloud formation region (0.5 < P < 2 bar), the ammonia depletion is largest in the belts, where it extends down to depths corresponding to 1.8–2 bar. In the zones, the lower ammonia abundances are found down to pressures of 1 bar. Deeper into the Jovian atmosphere, at pressures ≥2.2 bar, the gas is overabundant relative to the solar value by nearly a factor of 2 in both zones and belts. The altitude distribution of the ammonia gas is explained in terms of chemistry, cloud physics, and atmospheric dynamics. The undersaturation at high levels in the atmosphere is attributed to photodissociation of ammonia gas under influence of solar UV photons, coupled with Jupiter's meteorology (up- and downward drafts in the atmosphere). The general depletion of this gas throughout Jupiter's upper atmosphere may be caused by trapping of the gas in a layer of NH₄SH particles, and/or in an aqueous ammonia cloud. The cloud deck responsible for trapping ammonia gas is thicker above zones than belts. If the observed depletion of ammonia gas is entirely due to trapping in an NH₄SH cloud, the difference in thickness of this cloud between zones and belts gives rise to a temperature difference of 3–4°K between the two regions. This temperature difference may trigger the zonal wind motions in Jupiter's atmosphere near the cloud tops.     

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.     

The abundance of ammonia in the atmosphere of Jupiter

A laboratory curve of growth analysis was made on the lines in two ammonia bands located at 6450 Å and 10800 Å and the abundance of ammonia in the atmosphere of Jupiter was determined. Lines in the 6450 Å band appear to fall on the weak line section of the curve of growth, while those in the 10800 Å band fall in the transition region. The abundance values obtained from these bands are 13.0±3 m atm and 15±8 m atm, respectively.Measurements of the intensity distribution in the 6450 Å band in the laboratory and in the Jovian spectra show that the intensity of several lines in this band is highly dependent on the temperature. Strengths for some of the lines in the 6450 Å band were determined and half-widths of some strong lines were also measured. The effective pressure found from these half-width values is 2.5 atmospheres.Contributions from the University of Illinois, Chicago Circle Physics Department, No. 12.     

Greenhouse models of the atmosphere of titan

The greenhouse effect is calculated for a series of model atmospheres of Titan containing varying proportions of methane, hydrogen, helium, and ammonia. The pressure induced transitions of hydrogen and methane are the major sources of infrared opacity. For each model atmosphere we first computed its temperature structure with a radiative-convective equilibrium computer program and then generated its brightness temperature spectrum to compare with observed values. This comparison indicates that the methane-to-hydrogen ratio is 1_?.67⁺², the surface pressure is at least 0.4atm, and the surface temperature at least 150°K. In addition, except possibly close to the surface, the amount of ammonia is far less than the saturation vapor value. Large amounts of helium may also be present. Many of the successful model atmospheres have methane condensation clouds in the upper troposphere, which help reconcile spectroscopic gas abundances and the observed ultraviolet albedo of Titan with the gas amounts required for the greenhouse effect. The occurrence of large amounts of hydrogen may be a prerequisite for the occurrence of large amounts of methane in the atmosphere and vice versa. This hypothesis may help explain why Titan is the only satellite in our solar system known to have an atmosphere.     

MGS TES observations of the water vapor above the seasonal and perennial ice caps during northern spring and summer

We report on new retrievals of water vapor column abundances from the Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) data. The new retrievals are from the TES nadir data taken above the ‘cold’ surface areas in the North polar region (T_surf < 220 K, including seasonal frost and permanent ice cap) during spring and summer seasons, where retrievals were not performed initially. Retrievals are possible (with some modifications to the original algorithm) over cold surfaces overlaid by sufficiently warm atmosphere. The retrieved water vapor column abundances are compared to the column abundances observed by other spacecrafts in the Northern polar region during spring and summer and good agreement is found. We detect an annulus of water vapor growing above the edge of the retreating seasonal cap during spring. The formation of the vapor annulus is consistent with the previously proposed mechanism for water cycling in the polar region, according to which vapor released by frost sublimation during spring re-condenses on the retreating seasonal CO₂ cap. The source of the vapor in the vapor annulus, according to this model, is the water frost on the surface of the CO₂ at the retreating edge of the cap and the frost on the ground that is exposed by the retreating cap. Small contribution from regolith sources is possible too, but cannot be quantified based on the TES vapor data alone. Water vapor annulus exhibits interannual variability, which we attribute to variations in the atmospheric temperature. We propose that during spring and summer the water ice sublimation is retarded by high relative humidity of the local atmosphere, and that higher atmospheric temperatures lead to higher vapor column abundances by increasing the water holding capacity of the atmosphere. Since the atmospheric temperatures are strongly influenced by the atmospheric dust content, local dust storms may be controlling the release of vapor into the polar atmosphere. Water vapor abundances above the residual polar cap also exhibit noticeable interannual variability. In some years abundances above the cap are lower than the abundances outside of the cap, consistent with previous observations, while in the other years the abundances above the cap are higher or similar to abundances outside of the cap. We speculate that the differences may be due to weaker off-cap transport in the latter case, keeping more vapor closer to the source at the surface of the residual cap. Despite the large observed variability in water vapor column abundances in the Northern polar region during spring and summer, the latitudinal distribution of the vapor mass in the atmosphere is very similar during the summer season. If the variability in vapor abundances is caused by the variability of vapor sources across the residual cap then this would mean that they annually contribute relatively little vapor mass to significantly affect the vapor mass budget. Alternatively this may suggest that the vapor variability is caused by the variability of the polar atmospheric circulation. The new water vapor retrievals should be useful in tuning the Global Circulation Models of the martian water cycle.     

Interrelationships among meteoric metals,meteors, interplanetary dust,micrometeorites, and meteorites

Abstract— Meteor science, aeronomy, and meteoritics are different disciplines with natural interfaces. This paper is an effort to integrate the chemistry and mineralogy of collected interplanetary dust particles (IDPs), micrometeorites, and meteorites with meteoric data and with atmospheric metal abundances. Evaporation, ablation, and melting of decelerating materials in the Earth's atmosphere are the sources of the observed metal abundances in the upper atmosphere. Many variables ultimately produce the materials and phenomena we can analyze, such as different accretion and parent‐body histories of incoming extraterrestrial materials, different interactions of meteors with the Earth's middle atmosphere, meteor data reduction, and complex chemical interactions of the metals and ions with the ambient atmosphere. The IDP‐like and unequilibrated ordinary chondrite matrix materials are reasonable sources for observed meteoric and atmospheric metals. The hypothesis of hierarchical dust accretion predicts that low, correlated refractory element abundances in cometary meteors may be real. It implies that the CI or cosmic standard is not useful to appreciate the chemistry of incoming petrologically heterogeneous cometary matter. The quasi steady‐state metal abundances in the lower thermosphere and upper mesosphere are derived predominantly from materials with cometary orbital characteristics and velocities such as comets proper and near‐Earth asteroids. The exact influence of atmospheric chemistry on these abundances still needs further evaluation. Metal abundances in the lower mesosphere and upper stratosphere region are mostly from materials from the asteroidal belt and the Kuiper belt.     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.     

Optical spectrum of the bipolar nebula AFGL 2688

Based on echelle spectra obtained at the prime focus of the 6-m telescope, we have determined for the first time the detailed chemical composition of one of the components of the bipolar nebula identified with the intense infrared source AFGL 2688 by the model-atmosphere method. The iron abundance [Fe/H]=?0.59 dex derived for AFGL 2688 suggests that the object probably belongs to an intermediate population of the Galaxy. The stellar atmosphere exhibits high carbon and nitrogen abundances, [C/Fe]=+0.73 and [N/Fe]=+2.00, and C/O>1, confirming that the object is at the post-AGB stage. However, the detected overabundance of s-process elements (yttrium and barium) relative to iron is modest: [X/Fe]=+0.55. The lanthanides are even less enhanced: for La, Ce, Pr, and Nd, the mean abundance relative to iron is [la/Fe]=+0.26. This behavior of the heavy metals is consistent with the low intensity of the 21-μm band in the infrared spectrum of AFGL 2688; the intensity of this emission band is great in the spectra of all the studied PPN with large overabundances of s-process elements. An analysis of the radial velocities measured from spectral features originating in the atmosphere and in the circumstellar shell has revealed a high-velocity (～60 km s^?1) component of the stellar wind from AFGL 2688.     

CELIAS - Charge, Element and Isotope Analysis System for SOHO

The CELIAS experiment on SOHO is designed to measure the mass, ionic charge and energy of the low and high speed solar wind, of suprathermal ions, and of low energy flare particles. Through analysis of the elemental and isotopic abundances, the ionic charge state, and the velocity distributions of ions originating in the solar atmosphere, the investigation focuses on the plasma processes on various temporal and spatial scales in the solar chromosphere, transition zone, and corona. CELIAS includes 3 mass- and charge-discriminating sensors based on the time-of-flight technique: CTOF for the elemental, charge and velocity distribution of the solar wind, MTOF for the elemental and isotopic composition of the solar wind, and STOF for the mass, charge and energy distribution of suprathermal ions. The instrument will provide detailed in situ diagnostics of the solar wind and of accelerated particles, which will complement the optical and spectroscopic investigations of the solar atmosphere on SOHO. CELIAS also contains a Solar Extreme Ultraviolet Monitor, SEM, which continously measures the EUV flux in a wide band of 17 – 70 nm, and a narrow band around the 30.4 nm He II line.Principal-InvestigatorPrincipal-Investigator for data phase     

On the abundances of carbon dioxide isotopologues in the atmospheres of mars and earth

The isotopic composition of carbon dioxide in the Martian atmosphere from the measurements of Mars Science Laboratory have been used to estimate the relative abundances of CO₂ isotopologues in the Martian atmosphere. Concurrently, this study has revealed long-standing errors in the amounts of some of low-abundance CO₂ isotopologues in the Earth’s atmosphere in the databases of spectroscopic parameters of gases (HITRAN, etc.).     

Mafic silicate mapping on Mars: effects of palagonitic material, multiple mafic silicates, and spectral resolution

The visible to near-infrared spectral reflectance properties of intimate and areal pyroxene?+?palagonitic material mixtures as well as pure mafic silicates (low-calcium pyroxene, high-calcium pyroxene, pigeonite, olivine) and mixtures of these minerals were analyzed at high spectral resolution (5 nm) as well as with non-contiguous band passes equivalent to recent HST observations and the Pathfinder IMP in order to determine the quality and quantity of mineralogical information (end member compositions, abundances, and grain sizes) derivable in the presence of palagonitic material. In the case of pyroxene?+?palagonitic material mixtures, pyroxene is detectable at abundances as low as 10 wt%, and its composition can be constrained because (a) its diagnostic absorption feature (located near 1000 nm) persists even for high palagonitic material abundances, and (b) palagonitic material does not appreciably alter the wavelength position of this band (<4 nm variation). For broad band data (such as Pathfinder IMP band passes), different mafic silicates can be discriminated and palagonitic material abundances constrained using a variety of reflectance ratios and three-point “absorption band depths.” However, other properties of mafic silicate?±?palagonitic material assemblages, such as mafic silicate major element compositions, grain sizes, and end member abundances, generally cannot be rigorously quantified. The use of multiple reflectance ratios can, however, be used to identify relative changes in these properties, as most changes in mafic silicate?±?palagonitic material assemblage properties are characterized by a unique corresponding set of reflectance ratio variations. The observed spectral-assemblage property trends are consistent with those expected from the known spectral properties of the end members.     

Epistemic bimodality and kinetic hypersensitivity in photochemical models of Titan's atmosphere

We show that photochemical models of Titan's atmosphere can give rise to bimodal distributions in the abundances of some major compounds, like C₂H₂ and C₂H₄. Sensitivity analysis enabled us to identify the causes and conditions of this bimodality. We propose several methods to control this behavior in photochemical models. In particular, we point out the importance of two key reactions and the needs for a critical evaluation of the kinetic data. We also show that the abundances of some compounds are hypersensitive to the ratio [CH₄]/[H], suggesting that a time-dependent variation of this ratio might lead to a real bistability in the high atmosphere of Titan.     

A new model of the hydrogen and helium-broadened microwave opacity of ammonia based on extensive laboratory measurements

Close to 2000 laboratory measurements of the microwave opacity and refractivity of gaseous NH₃ in an H₂/He atmosphere have been conducted in the 1.1-20 cm wavelength range (1.5-27 GHz) at pressures from 30 mbar to 12 bar and at temperatures from 184 to 450 K. The mole fraction of NH₃ ranged from 0.06 to 6% with some additional measurements of pure NH₃. The high accuracy of these results have enabled development of a new model for the opacity of NH₃ in a H₂/He atmosphere under jovian conditions. The model employs the Ben-Reuven lineshape applied to the published inversion line center frequencies and intensities of NH₃ (JPL Catalog—[Pickett, H.M., Poynter, R.L., Cohen, E.A., Delitsky, M.L., Pearson, J.C., Müller, H.S.P., 1998. J. Quant. Spectrosc. Radiat. Trans. 60, 883-890]) with empirically-fitted line parameters for H₂ and He broadening, and for the self-broadening of some previously unmeasured ammonia inversion lines. The new model for ammonia opacity will provide reliable results for temperatures from 150 to 500 K, at pressures up to 50 bar and at frequencies up to 40 GHz. These results directly impact the retrieval of jovian atmospheric constituent abundances from the Galileo Probe radio signal absorption measurements, from microwave emission measurements conducted with Earth-based radio telescopes and with the future NASA Juno mission, and studies of Saturn's atmosphere conducted with the Cassini Radio Science Experiment and the Cassini RADAR 2.1 cm passive radiometer.     

Spectral properties of hydrogen,helium, methane,and ammonia at thermal infrared wavelengths

We present some results of a theoretical and laboratory program to determine the thermal infrared spectral properties of the principal gaseous constituents of the atmosphere of Jupiter. G. Birnbaum has measured laboratory spectra in the 16 to 1000 um wavelength range for hydrogen and hydrogen-helium mixtures at Jovian temperatures. These are compared to theoretically computed spectra in order to determine the temperature dependence of the line strengths in the pressure-induced rotational band and the overlap parameters from the translational band. Existing spectral data for methane do not agree well with measurements of the ν₄ band at room temperature. A revised allocation of line intensities is proposed. Existing data for the ν₂ (10 um) band of ammonia do agree reasonably well with measurements at room temperature and at ?77δC, but there are some important discrepancies which remain to be explained.     

An analysis of the spectrum of Alpha Ursae Minoris

Three spectrograms of the cepheid Alpha Ursae Minoris (Polaris) taken at a dispersion of 17.8 Å mm^–1 on 18, 19, and 20 January, 1971 have been analysed for the determination of the abundances of some elements. The analysis shows that the abundances of metals in the atmosphere of Polaris is similar to the Sun.     

A determination of Jovian ammonia abundance based on a 2 μm spectrum

A spectrum of Jupiter in the two micron region has been analyzed to determine the Jovian ammonia abundance. The result is a ?4 cm - amagat, assuming an airmass factor η = 2.5 and a single effective reflecting layer for this wavelength. This is compared with the abundances observed at other wavelengths.     

The photochemical model of Titan’s atmosphere and ionosphere: A version without hydrodynamic escape

There are observational and theoretical evidences both in favor of and against hydrodynamic escape (HDE) on Titan, and the problem remains unsolved. A test presented here for a static thermosphere does not support HDE on Titan and Triton but favors HDE on Pluto. Cooling of the atmosphere by the HCN rotational lines is limited by rotational relaxation above 1100 km and self-absorption below 900 km on Titan. HDE can affect the structure and composition of the atmosphere and its evolution. Hydrocarbon, nitrile, and ion chemistries are strongly coupled on Titan, and attempts to calculate them separately may result in significant errors. Here we apply our photochemical model of Titan’s atmosphere and ionosphere to the case of no hydrodynamic escape. Our model is still the only after-Cassini self-consistent model of coupled neutral and ion chemistry. The lack of HDE is a distinct possibility, and comparing models with and without HDE is of practical interest. The mean difference between the models and the neutral and ion compositions observed by INMS are somewhat better for the model with HDE. A reaction of NH₂ with H₂CN suggested by Yelle et al. (2009) reduces but does not remove a significant difference between the ammonia abundances in the models and INMS observations. Losses of methane and nitrogen and production and deposition to the surface of hydrocarbons and nitriles are evaluated in the model, along with lifetimes and evolutionary aspects.     

Water vapor abundance in Venus' middle atmosphere from Pioneer Venus OIR and Venera 15 FTS measurements

The Pioneer Venus Orbiter Infrared Radiometer and Venera 15 Fourier Transform Spectrometer observations of thermal emission from Venus' middle atmosphere between 10° S and 50° N have been independently re-analyzed using a common method to determine global maps of temperature, cloud optical depth, and water vapor abundance. The spectral regions observed include the strong 15 μm carbon dioxide band and the 45 μm fundamental rotational water band. The different spatial and spectral resolutions of the two instruments have necessitated the development of flexible analysis tools. New radiative transfer and retrieval models have been developed for this purpose based on correlated-k absorption tables calculated with up-to-date spectral line data. The common analysis of these two sets of observations has hence been possible for the first time. From the PV OIR observations, the cloud-top unit optical depth pressure showed a minimum of ∼110±10 mbars in the evening equatorial region and a maximum of ∼160±12 mbars in the morning mid-latitude regions. From the Venera 15 FTS spectra, the cloud-top pressure was found to increase from morning values of ∼120±10 to 200±30 mbars in the late afternoon/early evening region. The cloud-top water vapor abundances observed by the PV OIR instrument were found to fluctuate from 10±5 ppm at night up to 90±15 ppm in the equatorial cloud-top region shortly after the sub-solar point. The mean Venera 15 FTS water vapor abundances were found to be 12±5 ppm with only a slight enhancement over the equatorial latitude bands and no clear day-night distinction. The common analysis of these two sets of observations broadly validates previously published individual findings. The differences in the retrieved atmospheric state can no longer be attributed to radiative transfer modeling bias and suggest significant temporal variability in the middle atmosphere of Venus.     

The coating hypothesis for ammonia ice particles in Jupiter: Laboratory experiments and optical modeling

We report laboratory experiments and modeling calculations investigating the effect of a hydrocarbon coating on ammonia ice spectral signatures. Observational evidence and thermochemical models indicate an abundance of ammonia ice clouds in Jupiter's atmosphere. However, spectrally identifiable ammonia ice clouds are found covering less than 1% of Jupiter's atmosphere, notably in areas of strong vertical transport, indicating a short lifetime for the signature of ammonia absorption on condensed ammonia particles [Baines, K.H., Carlson, R.W., Kamp, L.W., 2002. Icarus 159, 74-94]. Current literature has suggested coating of ammonia ice particles by a hydrocarbon haze as a possible explanation for this paradox. The work presented here supports the inference of a coating effect that can alter or suppress ammonia absorption features. In the experiments, thin films of ammonia ices are deposited in a cryogenic apparatus, coated with hydrocarbons, and characterized by reflection-absorption infrared spectroscopy. We have observed the effects on the ammonia ice absorption features near 3 and 9 μm with coverage by thin layers of hydrocarbons. Modeling calculations of these multilayer thin films assist in the interpretation of the experimental results and reveal the important role of optical interference in altering the aforementioned ammonia spectral features. Mie and T-matrix scattering calculations demonstrate analogous effects for ammonia ice particles and investigate the relative effects of ammonia ice particle size, shape, and coating layer thickness on the ice particle spectral signatures.