Long-chain alkenones and U37′ variability along a south–north transect in the Western Pacific Ocean

In this paper, we present 50 surface water samples collected during the IMAGES III cruise (June–July 1997) along a transect from New Zealand to the China Sea (42°S–178°E, 21°N–120°E) covering a temperature range from 13.3 to 30.4 °C. A very worthwhile aspect of this study is a coupling of both biomarker (alkenone) and coccolithophorid counting. We show that the U₃₇^k′–temperature relationship is very similar to the Prahl et al. [Geochim. Cosmochim. Acta 52 (1988) 2203] culture calibration and to the global core top calibration of Müller et al. [Geochim. Cosmochim. Acta 62 (1998) 1757]. However, in the warmest surface waters of the Western Pacific ocean (>26.4 °C) where Gephyrocapsa oceanica is likely the most widespread species, the associated U₃₇^k′ has a constant value of 1.0. The consequence is that above this temperature threshold, U₃₇^k′ cannot be used as an accurate paleothermometer.     

The effect of upwelling on the distribution and stable isotope composition of Globigerina bulloides and Globigerinoides ruber (planktic foraminifera) in modern surface waters of the NW Arabian Sea

Hydrographic changes in the NW Arabian Sea are mainly controlled by the monsoon system. This results in a strong seasonal and vertical gradient in surface water properties, such as temperature, nutrients, carbonate chemistry and the isotopic composition of dissolved inorganic carbon (δ¹³C_DIC). Living specimens of the planktic foraminifer species Globigerina bulloides and Globigerinoides ruber, were collected using depth stratified plankton tows during the SW monsoon upwelling period in August 1992 and the NE monsoon non-upwelling period in March 1993. We compare their distribution and the stable isotope composition to the seawater properties of the two contrasting monsoon seasons. The oxygen isotope composition of the shells (δ¹⁸O_shell) and vertical shell concentration profiles indicate that the depth habitat for both species is shallower during upwelling (SW monsoon period) than during non-upwelling (NE monsoon period). The calcification temperatures suggest that most of the calcite is precipitated at a depth level just below the deep chlorophyll maximum (DCM), however above the main thermocline. Consequently, the average calcification temperature of G. ruber and G. bulloides is lower than the sea surface temperature by 1.7±0.8 and 1.3±0.9 °C, respectively. The carbon isotope composition of the shells (δ¹³C_shell) of both species differs from the in situ δ¹³C_DIC found at the calcification depths of the specimens. The observed offset between the δ¹³C_shell and the ambient δ¹³C_DIC results from (1) metabolic/ontogenetic effects, (2) the carbonate chemistry of the seawater and, for symbiotic G. ruber, (3) the possible effect of symbionts or symbiont activity. Ontogenetic effects produce size trends in Δδ¹³C_shell–DIC and Δδ¹⁸O_shell–w: large shells of G. bulloides (250–355μm) are 0.33‰ (δ¹³C) and 0.23‰ (δ¹⁸O) higher compared to smaller ones (150–250 μm). For G. ruber, this is 0.39‰ (δ¹³C) and 0.17‰ (δ¹⁸O). Our field study shows that the δ¹³C_shell decreases as a result of lower δ¹³C_DIC values in upwelled waters, while the effects of the carbonate system and/or temperature act in an opposite direction and increase the δ¹³C_shell as a result lower [CO₃²⁻] (or pH) values and/or lower temperature. The Δδ¹³C_shell–DIC [CO₃²⁻] slopes from our field data are close to those reported literature from laboratory culture experiments. Since seawater carbonate chemistry affects the δ¹³C_shell in an opposite sense, and often with a larger magnitude, than the change related to productivity (i.e. δ¹³C_DIC), higher δ¹³C_shell values may be expected during periods of upwelling.     

Mid–late Holocene monsoon climate retrieved from seasonal Sr/Ca and δO records of Porites lutea corals at Leizhou Peninsula, northern coast of South China Sea

South China Sea (SCS) is a major moisture source region, providing summer monsoon rainfall throughout Mainland China, which accounts for more than 80% total precipitation in the region. We report seasonal to monthly resolution Sr/Ca and δ¹⁸O data for five Holocene and one modern Porites corals, each covering a growth history of 9–13 years. The results reveal a general decreasing trend in sea surface temperature (SST) in the SCS from 6800 to 1500 years ago, despite shorter climatic cycles. Compared with the mean Sr/Ca–SST in the 1990s (24.8 °C), 10-year mean Sr/Ca–SSTs were 0.9–0.5 °C higher between 6.8 and 5.0 thousand years before present (ky BP), dropped to the present level by 2.5 ky BP, and reached a low of 22.6 °C (2.2 °C lower) by 1.5 ky BP. The summer Sr/Ca–SST maxima, which are more reliable due to faster summer-time growth rates and higher sampling resolution, follow the same trend, i.e. being 1–2 °C higher between 6.8 and 5.0 ky BP, dropping to the present level by 2.5 ky BP, and reaching a low of 28.7 °C (0.7 °C lower) by 1.5 ky BP. Such a decline in SST is accompanied by a similar decrease in the amount of monsoon moisture transported out of South China Sea, resulting in a general decrease in the seawater δ¹⁸O values, reflected by offsets of mean δ¹⁸O relative to that in the 1990s. This observation is consistent with general weakening of the East Asian summer monsoon since early Holocene, in response to a continuous decline in solar radiation, which was also found in pollen, lake-level and loess/paleosol records throughout Mainland China. The climatic conditions 2.5 and 1.5 ky ago were also recorded in Chinese history. In contrast with the general cooling trend of the monsoon climate in East Asia, SST increased dramatically in recent time, with that in the 1990s being 2.2 °C warmer than that 1.5 ky ago. This clearly indicates that the increase in the concentration of anthropogenic greenhouse gases played a dominant role in recent global warming, which reversed the natural climatic trend in East Asian monsoon regime.     

Stable carbon isotope ratios in tree rings of co-occurring species from semi-arid tropics in Africa: Patterns and climatic signals

Although several proxies have been proposed to trace the course of environmental and climatological fluctuations, precise paleoclimate records from the tropics, notably from Africa are still sorely lacking today. Stable carbon isotopes (δ¹³C) in tree rings are an attractive record of climate. In this study, the patterns and climatic signals of δ¹³C ratios were determined on tree rings of deciduous (Acacia senegal, Acacia tortilis, Acacia seyal) and an evergreen (Balanites aegyptiaca) species, from a semi-arid Acacia Woodland in Ethiopia. δ¹³C inter-annual patterns are synchronous among the co-occurring species. A declining trend with time was observed in δ¹³C, notably for B. aegyptiaca, which could be due to anthropogenic increases in atmospheric CO₂ concentration and decrease in atmospheric δ¹³C. Tree ring δ¹³C values of all the species revealed significant negative correlation with precipitation amount but not with temperature and relative humidity. The δ¹³C series of the deciduous species shows a higher correlation (r = − 0.70 to − 0.78) with precipitation than the evergreen species (r = − 0.55). A master δ¹³C series, composed of the average of the three Acacia species, displayed stronger significant correlation (r = − 0.82) than any of the individual species δ¹³C series. The weak relationship between temperature and δ¹³C in this study indicates that photosynthetic rate is not a significant factor. Moisture stress, however, may have a direct impact on the stomatal conductance and explain the strong negative relationship between δ¹³C and precipitation. The results demonstrate the potential of δ¹³C in tree rings to reflect physiological responses to environmental changes as a vehicle for paleoclimatic reconstruction, which is important to understand tree response to past and future climate change.     

Coral Sr/Ca and Mg/Ca records in Con Dao Island off the Mekong Delta: Assessment of their potential for monitoring ENSO and East Asian monsoon

The climate of the South China Sea (SCS) is dominated by the East Asian monsoon (EAM) and can be related to the El Niño-Southern Oscillation (ENSO) owing to the interaction between ENSO and the EAM. An annually-banded coral (Porites sp.) collected from Con Dao Island in the southern SCS was measured for Sr/Ca and Mg/Ca ratios at near-monthly resolution through the annual bands of AD 1948–1999. This island is only ~ 90 km from the Mekong Delta coast and thus significantly influenced by riverine discharge, suggesting relatively severe environmental stress on corals. The Sr/Ca time series shows a clear annual cyclicity chiefly modulated by sea-surface temperature (SST), whereas the Mg/Ca time series exhibits an indistinct annual cyclicity, indicating that the previously-proposed coral Mg/Ca thermometry is greatly disturbed. An instrumental SST record in Con Dao Island (since 1980) has been compared with the Sr/Ca time series to calibrate a Sr/Ca thermometer. The Sr/Ca vs. SST comparison shows that the Sr/Ca thermometer is sometimes disturbed by some factor and that almost all of the disturbances occur around the annual-maximum SST in the warm/wet season. The Sr/Ca data around the annual-minimum SST in the cool/dry season is almost free from the disturbance and thus useful as a SST proxy. The disturbances of the Sr/Ca and Mg/Ca thermometers may be ascribed to the Mekong River discharge and its accompanying phenomena (i.e., large freshwater input, suspended-sediment loads, intense phytoplankton blooms, etc.), which are likely to disturb coral physiological processes. Applying the Sr/Ca thermometer to the whole Sr/Ca time series provides a SST reconstruction from 1948 through 1999. Reconstructed annual-minimum SSTs show a clear quasi-biennial oscillation significantly correlated with ENSO, indicating that the annual-minimum SST in the southern SCS tends to be higher (lower) in El Niño (La Niña) phases. This is compatible with previous observations that the East Asian winter monsoon is weakened (strengthened) in El Niño (La Niña) phases. The reconstructed SST record suggests a warming of 1.0 °C for the latter half of the 20th century. The Sr/Ca and Mg/Ca time series exhibit similar decadal-to-bidecadal variations, which do not seem to be primarily due to SST variability but rather due to some other factor possibly related to disturbance or fluctuation of coral physiological processes. Although both of our Sr/Ca and Mg/Ca data are affected, to a greater or lesser extent, by some non-temperature factor, a part of the Sr/Ca data provides a useful SST proxy and suggests that coral-based SST reconstruction in the southern SCS may be an effective means for monitoring the EAM and ENSO.     

The soft X-ray polychromator for the Solar Maximum Mission

The 1.4–22.4 Å range of the soft X-ray spectrum includes a multitude of emission lines which are important for the diagnosis of plasmas in the 1.5–50 million degree temperature range. In particular, the hydrogen and helium-like ions of all abundant solar elements with Z > 7 have their primary transitions in this region and these are especially useful for solar flare and active region studies. The soft X-ray polychromator (XRP) is a high resolution experiment working in this spectral region. The XRP consists of two instruments with a common control, data handling and power system. The bent crystal spectrometer is designed for high time resolution studies in lines of Fe i-Fe xxvi and Ca xix. The flat crystal scanning spectrometer provides for 7 channel polychromatic mapping of flares and active regions in the resonance lines of O viii, Ne ix, Mg xi, Si xiii, S xv, Ca xix, and Fe xxv with 14 spatial resolution. In its spectral scanning mode it covers essentially the entire 1.4–22.5 Å region.This paper summarizes the scientific objectives of the XRP experiment and describes the characteristics and capabilities of the two instruments. Sufficient technical information for experiment feasibility studies is included and the resources and procedures planned for the use of the XRP within the context of the Solar Maximum Mission is briefly discussed.     

The reaction of carbonates in contact with laser-generated,superheated silicate melts: Constraining impact metamorphism of carbonate-bearing target rocks

We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO₂ at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO₂ and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO₂ produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.     

An attempt to interpret the temperature profile of the KTB pilot drillhole (Germany) by paleoclimatic considerations

The temperature profile of the KTB pilot drillhole, T(z)_KTB-PH,is distinctly nonlinear: a temperature deficit ΔT (relative to a linear temperature-depth profile) is especially pronounced in the depth range 500–3500 m. The depth dependence of the deficit, Δ(z) is compared to be anticipated effect of surface paleoclimatic variations, ΔT_pc(z), at the drillsite on the temperature profile. The latter can be calculated from available paleo-climatic models. If ΔT_pc(z) is added to T(z)_KTB-PH, a nearly linear temperature-depth curve results with an average geothermal gradient of 27.9°C/km. This, together with an average vertical thermal conductivity of 3.0 W/mK, estimated from KTB drillcore data, implies a heat flow density at the KTB site of 84 mW/m². This modelled value is in good agreement with heat flow determinations in the adjacent Eger graben structure (Western Bohemian massif).     

Phytochemical changes in leaves of subtropical grasses and fynbos shrubs at elevated atmospheric CO2 concentrations

The effects of elevated atmospheric CO₂ concentrations on plant polyphenolic, tannin, nitrogen, phosphorus and total nonstructural carbohydrate concentrations were investigated in leaves of subtropical grass and fynbos shrub species. The hypothesis tested was that carbon-based secondary compounds would increase when carbon gain is in excess of growth requirements. This premise was tested in two ecosystems involving plants with different photosynthetic mechanisms and growth strategies. The first ecosystem comprised grasses from a C₄-dominated, subtropical grassland, where three plots were subjected to three different free air CO₂ enrichment treatments, i.e., elevated (600 to 800 μmol mol⁻¹), intermediate (400 μmol mol⁻¹) and ambient atmospheric CO₂. One of the seven grass species, Alloteropsis semialata, had a C₃ photosynthetic pathway while the other grasses were all C₄. The second ecosystem was simulated in a microcosm experiment where three fynbos species were grown in open-top chambers at ambient and 700 μmol mol⁻¹ atmospheric CO₂ in low nutrient acid sands typical of south western coastal and mountain fynbos ecosystems. Results showed that polyphenolics and tannins did not increase in the grass species under elevated CO₂ and only in Leucadendron laureolum among the fynbos species. Similarly, foliar nitrogen content of grasses was largely unaffected by elevated CO₂, and among the fynbos species, only L. laureolum and Leucadendron xanthoconus showed changes in foliar nitrogen content under elevated CO₂, but these were of different magnitude. The overall decrease in nitrogen and phosphorus and consequent increase in C:N and C:P ratio in both ecosystems, along with the increase in polyphenolics and tannins in L. laureolum in the fynbos ecosystem, may negatively affect forage quality and decomposition rates. It is concluded that fast growing grasses do not experience sink limitation and invest extra carbon into growth rather than polyphenolics and tannins and show small species-specific chemical changes at elevated atmospheric CO₂ concentrations. Responses of fynbos species are varied and were species-specific.     

The significance of coral reefs as global carbon sinks— response to Greenhouse

Coral reefs are net sinks for C, principally as CaCO₃ accretion. It is possible to predict quite accurately the rate of production, given adequate information about any particular reef environment. The best data set for an extensive region is that for the Great Barrier Reef (GBR). Careful analysis of this region and the incorporation of previously documented present day system calcification rates suggest net production (G) from G = 1 (kg CaCO₃ m⁻² yr⁻¹) for fringing reefs, to G = 1.9 for planar (infiled platform) reefs, G = 3 for ribbon reefs and lagoonal reefs. The 20,055 km² of reefs in the GBR are thus estimated to average G = 2.4, resulting in a total production of 50 million tonnes yr⁻¹. In a 50–100 year Greenhouse scenario of rising sealevel, we predict that recolonisation of present day reef flats will be extensive and prolific. Production will increase substantially, and this could be by as much as 40% (ranging from 0% for deep shoals to 180% for fringing reefs) to give 70 million tonnes yr⁻¹ if the rate of sealevel rise reaches or exceeds 6–8 mm yr⁻¹We estimate 115,000 km² of oceanic atolls worldwide. Drawing on points equivalence from the detailed analysis of the GBR, we estimate the atolls presently produce 160 million tonnes yr⁻¹. We predict that a similar 40% increase could be possible in the next 100 years or so resulting in a production of 220 million tonnes.Accepting an existing estimate of 617,000 km² for reefs worldwide, drawing from our projections from the GBR and the atolls, and making some assumptions about the remaining reef types (we suggest fringing reefs to dominate) we estimate global reef production at the present time to be 900 million tonnes yr⁻¹. Within the next 100 years or so, we suggest this rate could almost double to 1800 million tonnes. In the long term (several centuries) we predict that the continuing trend of recolonisation, particularly of fringing and planar reefs could result in the production of > 3000 million tonnes yr⁻¹ if rates of sealevel rise approaching or exceeding 6–8 mm yr⁻¹ are achieved. Eventually (> 500 yr), reefs could actually “drown” due to inability to match the rate of sealevel increase if that rate significantly exceeds 6–8 mm yr⁻¹.Thus, coral reefs at present act as a sink for 111 million tonnes C yr⁻¹, the equivalent of 2% of present output of anthropogenic CO₂. In the short term Greenhouse scenario (100 yr) we predict this could increase to the equivalent of 4% of the present CO₂ output. In the much longer term (several centuries), if all trends continue, this could increase to the equivalent of as much as 9% of the present CO₂ output.Unfortunately, we also predict that this considerable sink for C will be most likely of negative value in alleviating Greenhouse because of the immediate effect of CaCO₃ precipitation is to raise the P_CO2 of the surface oceans — ie, ot encourage CO₂ efflux to the atmosphere. We do not attempt to quantify this effect.Other Greenhouse changes such as seawater temperature increase, changes in cloud cover, increased rainfall and runoff, increased storm activity, and changes in dissolved CO₂ concentration and surface ocean circulation may complicate the reef response. However, we suggest that sealevel rise will be the dominant influence, at least during the next 100 years or so.     

The masers of E-type methanol in orion KL and SGR B2

Using a simplified model the statistical equilibrium and radiative transfer equations of E-type-CH₃OH are solved for Orion KL and SgrB2. According to our calculation results and the observation data taken by Matsakiset al. (1980) and Morimotoet al. (1985a, b), the physical conditions of both sources are estimated. In theJ ₂-J ₁ E methanol maser region of Orion KL, the density, kinetic temperature, dust temperature, and the fractional abundance are 0.8–2×10⁶ cm^–3, 150, 30–90 K, 0.8–8×10^–6. In the 4_–1-3₀ E and 5_–1-4₀ E methanol maser region of Sgr B2 the correspondance physical conditions above are 10⁴ cm³, 45, 23 K, and 7×10^–7, respectively.     

The chemical evolution in a model of contracting cloud

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.     

Twinned calcite as an indicator of high differential stresses and low shock pressure conditions during impact cratering

Shock-related calcite twins are characterized in calcite-bearing metagranite cataclasites within crystalline megablocks of the Ries impact structure, Germany, as well as in cores from the FBN1973 research drilling. The calcite likely originates from pre-impact veins within the Variscan metagranites and gneisses, while the cataclasis is due to the Miocene impact. Quartz in the metagranite components does not contain planar deformation features, indicating low shock pressures (<7 GPa). Calcite, however, shows a high density (>1/μm) of twins with widths <100 nm. Different types of twins (e-, f-, and r-twins) crosscutting each other can occur in one grain. Interaction of r- and f-twins results in a-type domains characterized by a misorientation relative to the host with a misorientation angle of 35°–40° and a misorientation axis parallel to an a-axis. Such a-type domains have not been recorded from deformed rocks in nature before. The high twin density and activation of different twin systems in one grain require high differential stresses (on the order of 1 GPa). Twinning of calcite at high differential stresses is consistent with deformation during impact cratering at relatively low shock pressure conditions. The twinned calcite microstructure can serve as a valuable low shock barometer.     

Incremental melting in the ureilite parent body: Initial composition,melting temperatures,and melt compositions

Ureilites are carbon‐rich ultramafic achondrites that have been heated above the silicate solidus, do not contain plagioclase, and represent the melting residues of an unknown planetesimal (i.e., the ureilite parent body, UPB). Melting residues identical to pigeonite‐olivine ureilites (representing 80% of ureilites) have been produced in batch melting experiments of chondritic materials not depleted in alkali elements relative to the Sun’s photosphere (e.g., CI, H, LL chondrites), but only in a relatively narrow range of temperature (1120 ºC–1180 ºC). However, many ureilites are thought to have formed at higher temperature (1200 ºC–1280 ºC). New experiments, described in this study, show that pigeonite can persist at higher temperature (up to 1280 ºC) when CI and LL chondrites are melted incrementally and while partial melts are progressively extracted. The melt productivity decreases dramatically after the exhaustion of plagioclase with only 5–9 wt% melt being generated between 1120 ºC and 1280 ºC. The relative proportion of pyroxene and olivine in experiments is compared to 12 ureilites, analyzed for this study, together with ureilites described in the literature to constrain the initial Mg/Si ratio of the UPB (0.98–1.05). Experiments are also used to develop a new thermometer based on the partitioning of Cr between olivine and low‐Ca pyroxene that is applicable to all ureilites. The equilibration temperature of ureilites increases with decreasing Al₂O₃ and Wo contents of pyroxene and decreasing bulk REE concentrations. The UPB melted incrementally, at different fO₂, and did not cool significantly (0 ºC–30 ºC) prior to its disruption. It remained isotopically heterogenous, but the initial concentration of major elements (SiO₂, MgO, CaO, Al₂O₃, alkali elements) was similar in the different mantle reservoirs.     

Spectral analysis and the two-dimensional distribution of physical parameters in a quiescent prominence

The profiles of H and Ca ii K lines of a arch quiescent prominence on April 1, 1971 have been analyzed and the two-dimensional distributions of electron temperature T _e , micro-turbulence velocity v _t and the column number density of hydrogen along the line-of-sight N _H have been obtained. T _e , _t , and N _H are found to be 7500 K, 6 km s^–1 and 2.2 ^× 10¹⁸ cm^–2 on an average, respectively. The electron temperature at the central part of the prominence and along the two arcades are greater than that at the edges, while the distribution of the micro-turbulence velocity in these regions is opposite. There is no systematic variation in T _e and v _t , from the center to the periphery as described by Hirayama (1971). The column number density in the central region is lower than that at the two edges.The contour lines of T _e , _t , and N _H are predominantly vertical rather than horizontal. This implies that the height-variation of physical parameters in filamentary structure is small. The arrangement of this structure in the prominence is likely to be arched and is probably in the direction of magnetic field lines.Operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

Non-adiabatic interactions in excitedC 2 H molecules and their relationship toC 2 formation in comets

A unified picture of the photodissociation of theC ₂ H radical has been developed using the results from the latest experimental and theoretical work. This picture shows that a variety of electronic states ofC ₂ are formed during the photodissociation of theC ₂ H radical even if photoexcitation accesses only one excited state. This is because the excited states have many avoided corssings and near intersections where two electronic states come very close to one another. At these avoided crossings and near intersections, the excited radical can hop from one electronic state to another and access new final electronic states of theC ₂ radical. The complexity of the excited state surfaces also explains the bimodal rotational distributions that are observed in all of the electronic states studied. The excited states that dissociate through a direct path are limited by dynamics to produceC ₂ fragments with a modest amount of rotational energy, whereas those that dissociate by a more complex path have a greater chance to access all of phase space and produce fragments with higher rotational excitation. Finally, the theoretical transition moments and potential energy curves have been used to provide a better estimate of the photochemical lifetimes in comets of the different excited states of theC ₂ H radical. The photochemically active states are the 2²₊, 2²II, 3²II, and 3²₊, with photodissociation rate constants of 1.0×10^–6, 4.0×10^–6, 0.7×10^–6, and 1.3×10^–6s^–1, respectively. These rate constants lead to a total photochemical lifetime of 1.4×10⁵ s.     

The 2003 November 14 occultation by Titan of TYC 1343-1865-1: II. Analysis of light curves

We observed a stellar occultation by Titan on 2003 November 14 from La Palma Observatory using ULTRACAM with three Sloan filters: u^′, g^′, and i^′ (358, 487, and 758 nm, respectively). The occultation probed latitudes 2° S and 1° N during immersion and emersion, respectively. A prominent central flash was present in only the i^′ filter, indicating wavelength-dependent atmospheric extinction. We inverted the light curves to obtain six lower-limit temperature profiles between 335 and 485 km (0.04 and 0.003 mb) altitude. The i^′ profiles agreed with the temperature measured by the Huygens Atmospheric Structure Instrument [Fulchignoni, M., and 43 colleagues, 2005. Nature 438, 785–791] above 415 km (0.01 mb). The profiles obtained from different wavelength filters systematically diverge as altitude decreases, which implies significant extinction in the light curves. Applying an extinction model [Elliot, J.L., Young, L.A., 1992. Astron. J. 103, 991–1015] gave the altitudes of line of sight optical depth equal to unity: 396±7 and 401±20 km (u^′ immersion and emersion); 354±7 and 387±7 km (g^′ immersion and emersion); and 336±5 and 318±4 km (i^′ immersion and emersion). Further analysis showed that the optical depth follows a power law in wavelength with index 1.3±0.2. We present a new method for determining temperature from scintillation spikes in the occulting body's atmosphere. Temperatures derived with this method are equal to or warmer than those measured by the Huygens Atmospheric Structure Instrument. Using the highly structured, three-peaked central flash, we confirmed the shape of Titan's middle atmosphere using a model originally derived for a previous Titan occultation [Hubbard, W.B., and 45 colleagues, 1993. Astron. Astrophys. 269, 541–563].     

Primary production and microbial activity in the euphotic zone of Lake Baikal (Southern Basin) during late winter

Three years of regular weekly/biweekly monitoring of seasonal changes in temperature, transparency, chlorophyll a (CHL) and bacteria [erythrosine-stained microscopic counts and cultivable colony forming units (CFUs)] at the vertical profile in the South basin of Lake Baikal (51°54′195″N, 105°04′235″E, depth 800 m) were evaluated. In more detail, the structure and function of phytoplankton and the microbial loop in the euphotic layer at the same site were investigated during the late-winter–early-spring period under the ice. The depth of euphotic zone (up to 1% of surface irradiation) was 35 to 40 m. Primary production was measured three times a week with the ¹⁴C method in 2, 10, 20, 30 and 40 m. Maximum production was found in 10 m, with lower values towards the surface (light inhibition) and towards the lower layers. The total production in cells larger than 1 μm in the column (0–40 m) was 204–240 mg C d⁻¹ m⁻², 30–40% of it being in cells 1–3 μm (mostly picocyanobacteria), which represented roughly 9% of the total chlorophyll a (estimated from pigment analyses). A major part of phytoplankton biomass was formed by diatoms (Synedra acus Hust., Asterionella formosa Hass. and Stephanodiscus meyerii Genkal & Popovskaya). Total production (including extracellular, dissolved organic matter) was 235–387 mg C day⁻¹ m⁻², and the exudates were readily used by bacteria (particles 0.2–1 μm). This part amounted to 1–5% of cellular production in 2 to 20 m and 11–77% of cellular production in 20–40 m, i.e., in light-limited layers. From 0 to 30 m, chlorophyll a concentration was 0.8 to 1.3 μg l⁻¹, wherefrom it decreased rapidly to 0.1 μg l⁻¹ towards the depth of 40 m. Bacteria (DAPI-stained microscopic counts) reached 0.5–1.4×10⁶ ml⁻¹; their cell volumes measured via image analysis were small (average 0.05 μm⁻³), often not well countable when erythrosine stain was used. Bacterial biomasses were in the range of 6–21 μg C l⁻¹. Numbers of colony forming units (CFUs) on nutrient fish-agar were c. 3–4 orders lower than DAPI counts. The amounts of heterotrophic protists were low, whereby flagellates reached 6 to 87 ml⁻¹ and ciliates, 0.2–1.2 ml⁻¹ (mostly Oligotrichida). Bacterial production was measured in the same depths as primary production using ³H-thymidine (Thy) and ¹⁴C-leucine (Leu) uptake. Consistently, bacterial abundances, biomasses, thymidine and leucine production were higher by 30–50% in layers 2, 10 and 20 m compared with that in the deeper 30 and 40 m, where cellular primary production was negligible. Leucine uptake in the deeper layers was even three times lower than in the upper ones. From the comparison of primary and bacterial production, bacteria roughly use 20–40% of primary production during 24 h in the layers 2 to 20 m.     

O VI (λ = 1032 Å) profiles in and above an active region prominence,compared to quiet Sun center and limb profiles

O vi ( = 1032 Å) profiles have been measured in and above a filament at the limb, previously analyzed in H i, Mg ii, Ca ii resonance lines (Vial et al., 1979). They are compared to profiles measured at the quiet Sun center and at the quiet Sun limb.Absolute intensities are found to be about 1.55 times larger than above the quiet limb at the same height (3); at the top of the prominence (15 above the limb) one finds a maximum blue shift and a minimum line width. The inferred non-thermal velocity (29 km s^–1) is about the same as in cooler lines while the approaching line-of-sight velocity (8 km s^–1) is lower than in Ca ii lines.The O vi profile recorded 30 above the limb outside the filament is wider (FWHM = 0.33 Å). It can be interpreted as a coronal emission of O vi ions with a temperature of about 10⁶ K, and a non-thermal velocity (NTV) of 49 km s^–1. This NTV is twice the NTV of quiet Sun center O vi profiles. Lower NTV require higher temperatures and densities (as suggested by K-coronameter measurements). Computed emission measures for this high temperature regime agree with determinations from disk intensities of euv lines.     

Interstellar catalysis

Since gas-phase reactions alone cannot account for the observed abundances of H₂ in the typical interstellar cloud, one or more surface reactions are probably involved. Of the three possible candidates, only the catalytic production of H₂ on transition metal grains is supported by laboratory evidence. Using the rate equations developed in a previous paper for this process, the steady-state equilibrium abundances of H, H₂,e ^–, H⁺, H^–, H₂ ⁺, and H₃ ⁺ are calculated for large (r>10 pcs;M10² M ), tenuous (n=10²–10⁴ cm^–3) hydrogen dust clouds under a wide variety of conditions. In addition to the four rate equations involved in the catalytic reactions, 18 gas-phase and one additional surface reaction—the physical adsorption of H-atoms on cold, dielectric surfaces and their subsequent recombination and desorption as H₂ molecules—are included in the calculations. It is found that metal grains can produce as much interstellar H₂ as the best physical adsorption mechanism under optimum conditions if the extinction in the visible is less than 5^m.0. The three critical parameters for efficient catalysis (activation energy of desorption, grain temperature, and the number density of available sites) are examined, and it is shown that catalytic reactions are efficient producers of H₂ under all but the most unfavorable conditions.